ALOX Rust Preventives

Product Overview

© The Lubrizol Corporation 2006, all rights reserved

Selection Process

© The Lubrizol Corporation 2006, all rights reserved

 Define The Substrate: What Are We Trying To
Protect?

• Aluminum (Non-Ferrous)
• Cast Iron
• Cold Rolled Steel
• Galvanized
• Phosphated Metals

© The Lubrizol Corporation 2006, all rights reserved

 Define The Surface
• Polished
• Porous
• Pretreatment
• Sand Blasted

© The Lubrizol Corporation 2006, all rights reserved

 Define The Conditions
• Acid Atmosphere
• Indoor Storage
• Outdoor Storage
• Salt Atmosphere

© The Lubrizol Corporation 2006, all rights reserved

 Selection of Film Type
• Greasy Film
• Oily Film
• Waxy Film
• Protective Coating

© The Lubrizol Corporation 2006, all rights reserved

 Selection of Diluent

• Solvent Based
• Oil Based
• Water Based

© The Lubrizol Corporation 2006, all rights reserved

Defining Test Procedures

© The Lubrizol Corporation 2006, all rights reserved

Humidity Cabinet: Humidity Test Conditions
(ASTM D-1748)
Accelerated Testing for Indoor Storage Under
Conditions of High Humidity

• 49°C / 120°F Water Temperature

• Selected Substrate Panels & Panel Surface
• Run to Failure (Not to Exceed 60 Days)
• 60 Days Humidity Cabinet = 5 Years Protection

© The Lubrizol Corporation 2006, all rights reserved

Fluid Testing Humidity Cabinet
Humidity Test Conditions (ASTM D-1748)

5-3-00
© The Lubrizol Corporation 2006, all rights reserved MW 11 150
Fluid Testing Humidity Cabinet
Humidity Test Conditions (ASTM D-1748)

5-3-00
© The Lubrizol Corporation 2006, all rights reserved MW 11 150
 Salt Spray
Salt Spray Test (ASTM B-117)
Federal Standard 791B Method 4001.2
Accelerated Testing for Outdoor Storage In
Salt Atmosphere Conditions

• 40°C / 100°F Water Temperature

• 5.0 % Brine Solution
• Selected Substrate Panels & Panel Surface
• Run to Failure (Not to Exceed 60 Days)
• 60 Days Salt Spray = 5 Years Protection

© The Lubrizol Corporation 2006, all rights reserved

 Acid Fume
ALOX Test Method AQCT-25
Ford Test Method MC BJ 7-6 (Modified)
Accelerated Testing for Indoor Storage
Under Acid Atmosphere Conditions

• Selected Substrate Panels & Panel Surface

• Coat Panel With Inhibitor Solution
• Place in 4N Hydrochloric Acid Atmosphere
• Test Chamber @ 72°F
• Run to Failure

© The Lubrizol Corporation 2006, all rights reserved

 Stack Stain Test
MIL-C-22235A Method 4.4.3
Accelerated Testing to Determine the Effect of Water
Contamination, Heat and Metal to Metal Contact on
Coiled or Stacked Metal Surfaces

• Selected Substrate Panels & Panel Surface

• Coat Panels With Inhibitor Solution
• Stack Panels in a Sandwich Arrangement
• Place in Oven @ 82°C / 180°F for 24 Hours

© The Lubrizol Corporation 2006, all rights reserved

 Water Displacement
MIL-PRF-16173E Method 4.6.14
Test Procedure to Show the Ability of a Corrosion
Inhibitor Compound to Displace Water From A Metal
Surface
• Selected Substrate Panels & Panel Surface
• Submerse Panel in Distilled Water for 5 Seconds
• Submerse Panel in Inhibitor Solution for 15 Seconds
• Static Humidity Chamber @ ~ 77oF for 1 Hour

© The Lubrizol Corporation 2006, all rights reserved

 Water Separation
ALOX Test Method AQCT-19
Test to Measure the Ability of a Corrosion
Inhibitor Compound to Separate Water Carryover
From Rinse Operations

• 75 ml’s of Inhibitor Solvent/Oil Solution @ ~ 77oF

• 25 ml’s of 1.0 % Solution NaOH in Tap Water
• Invert Six inversions in a 100 ml Cylinder
• Record Separation Time

© The Lubrizol Corporation 2006, all rights reserved

 Nail Climb Test
ALOX Test Method AQCT-21
Test to Measure the Penetrating Ability of
Corrosion Inhibitor Compounds
• 60 ml’s of Test Solution in 600 ml
Beaker
• Place Sandblasted Nail With 19 mm
Head 10 mm Diameter 178 mm Long
Head Down in The Center of The Test
Solution @ Ambient Temperature
• Record Distance of Climb Versus Time

© The Lubrizol Corporation 2006, all rights reserved

 PRODUCT AREAS
• Solvent Based
• Oil Based
• Water Emulsifiable
• Water Soluble
• Sulfonates

© The Lubrizol Corporation 2006, all rights reserved

 SOLVENT BASED
• Indoor Storage
• Limited Salt Spray
• Outdoor Storage
• Acid Fume
• Specialty

© The Lubrizol Corporation 2006, all rights reserved

 INDOOR STORAGE
• Water Displacing
• Water Separating
• Non-Staining
• Resistant to High Humidity
• Applied by dipping or spraying

© The Lubrizol Corporation 2006, all rights reserved

 INDOOR STORAGE
• ALOX® 2028S
• ADDCO® CP-OB-1
• ALOX® 165
• ADDCO® CP-OB-2
• ALOX® 165L

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2028S
• Barium based
• Brown waxy solid
• Suggested treat rate 4 -10%
• Ultra thin waxy film
• Applicable Mil Specs
– Mil-PRF-16173E Grades III & IV
– Mil-C-81309E

© The Lubrizol Corporation 2006, all rights reserved

 ADDCO® CP-OB-1
• Barium based
• Brown waxy solid
• Suggested treat rate 4 -10%
• Ultra thin waxy film
• Low Odor
• Light Color

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 165
• Calcium based
• Brown waxy solid
• Suggested treat rate 4 -10%
• Ultra thin waxy film
• Applicable Mil Specs
– Mil-PRF-16173E Grades III & IV

© The Lubrizol Corporation 2006, all rights reserved

 ADDCO® CP-OB-2
• Calcium based
• Brown waxy solid
• Suggested treat rate 4 -10%
• Ultra thin waxy film
• Low Odor
• Light Color

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 165L
• Calcium based
• Brown liquid
• Suggested treat rate 5 -12%
• Ultra thin oily film
• Applicable Mil Specs
– Mil-PRF-16173E Grades III & IV

© The Lubrizol Corporation 2006, all rights reserved

 LIMITED SALT SPRAY
• Resistant to salt atmospheres
• Resistant to high humidity
• Water displacing
• Suggested treat rate 12/12/76
• Applied by spraying

© The Lubrizol Corporation 2006, all rights reserved

 LIMITED SALT SPRAY
• ALOX® 2213AS
• ALOX® 2213CS
• ALOX® 2213D
• ALOX® 2214

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2213AS
• Barium based
• Brown waxy solid
• Thin greasy film
• >24<40 hrs. salt spray protection

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2213CS
• Calcium based
• Brown waxy solid
• Thin greasy film
• >64<72 hrs. salt spray protection
• Emulsifiable (28.5/5.0/66.5)
– >64<72 hrs. 5% salt spray protection

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2213D
• Calcium based
• Brown waxy solid
• Thin greasy film
• Water separating
• Non-staining
• >48<64 hrs. salt spray protection
• Can be applied by dipping or spraying

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2214
• Calcium based
• Brown waxy solid
• Thin greasy film
• Non-staining
• Water separating
• Protects against HCl fumes
• >40<48 hrs. salt spray protection
• Can be applied by dipping or spraying

© The Lubrizol Corporation 2006, all rights reserved

 OUTDOOR STORAGE
• Extended salt spray protection
• Hard waxy film
• Applied by spraying or brushing

© The Lubrizol Corporation 2006, all rights reserved

 OUTDOOR STORAGE
• ALOX® 606-55 & 55HF
• ALOX® 606-70 & 70HF
• ALOX® 2211Y

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 606-55 & 55HF
• Calcium based
• Brown viscous liquid
– Contains 45% 105oF mineral spirits
– HF – Contains 45% 142oF mineral spirits
• Recommended solids 45 - 55%
• 1500+ hrs salt spray @ 3 – 4 mils FT
• Resistant to high humidity
• Resistant to HCl fumes.

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 606-70 & 70HF
• Calcium based
• Solvent dilutable
• Soft brown solid
– Contains 30% 105oF mineral spirits
– HF – Contains 30% 142oF mineral spirits
• Recommended solids % 45 - 55
• 1500+ hrs. salt spray @ 3 – 4 mils
• Resistant to high humidity
• Resistant to HCl fumes

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2211Y
• Calcium based
• Brown hard waxy solid
• Drop melt point ~200oF
• 1500+ hrs. salt spray @ 3 – 4 mils FT
• Resistant to high humidity
• Non-Newtonian cutbacks
• Film type
– Hard – 15 – 30% in 105oF mineral spirits
– Greasy – 15/15 Oil in 105oF mineral spirits

© The Lubrizol Corporation 2006, all rights reserved

 ACID FUME
• Resistant to HCl fumes
• Resistant to high humidity
• Water Displacing

© The Lubrizol Corporation 2006, all rights reserved

 ACID FUME
• ALOX® 319FS
• ALOX® 2289S
• ALOX® 2214

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 319FS
• Oil and solvent soluble
• Brown waxy solid
• Thin waxy film
• Suggested treat rate 5 -15%

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2289S
• Oil and solvent soluble
• Brown waxy solid
• Recommended use rate 10 -15%
• Thin waxy film
• 136+ hrs. acid fume protection @ 15%

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2214
• Calcium based
• Brown waxy solid
• Thin greasy film
• Non-staining
• Water separating
• 72 hrs. acid fume protection @ 12/12/76
• Can be applied by dipping or spraying

© The Lubrizol Corporation 2006, all rights reserved

 SPECIALTY
• ALOX® 1680
– Penetrant/Lubricant
• Recommended treat 10% in kerosene
• ALOX® 111
– Concrete mold release
– Concrete forms protector
• Recommended treat 12.5% in mineral spirits
• ALOX® 436A
- Concrete mold release
Recommended treat 5% in mineral spirits

© The Lubrizol Corporation 2006, all rights reserved

 SPECIALTY
• ALOX® 904S
– Weapons cleaner, lubricant & RP
– Applicable to Mil-PRF-372D
– Suggested treat level 2 – 9% in Kerosene
• ALOX® 940AS
– Fingerprint remover
– Suggested treat rate 5 – 20% in mineral spirits

© The Lubrizol Corporation 2006, all rights reserved

 OIL BASED
• Indoor Storage
• Limited Salt Spray
• Slushing Oil
• Stamping & Drawing
• Specialty

© The Lubrizol Corporation 2006, all rights reserved

 INDOOR STORAGE
• Soluble in naphthenic oil
• Resistant to high humidity
• Thin oily films

© The Lubrizol Corporation 2006, all rights reserved

 INDOOR STORAGE
• ALOX® 318FS
• ALOX® 319FS
• ALOX® 575S
• ALOX® 2280S
• ALOX® 2290S
• ALOX® 2290AS

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 318FS
• Brown waxy solid
• Soluble in paraffinic oil
• Recommended use rate 5 -15%
• Non-ferrous metal protection

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 319FS
• Brown waxy solid
• Suggested treat rate 5 -15%
• Limited HCl fume protection

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 575S
• Barium based
• Viscous liquid
• Suggested treat rate 5 - 20%
• Can be emulsified
• Applicable to Mil-PRF-3150

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2280S
• Calcium based
• Viscous liquid
• Suggested treat rate 5 - 20%
• Can be emulsified
• Applicable to Mil-PRF-3150

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2290S
• Viscous liquid
• Suggested treat rate 5 - 20%
• Can be emulsified
• Applicable to Mil-PRF-3150

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2290AS
• Viscous liquid
• Suggested treat rate 5 - 20%
• Can be emulsified
• Applicable to Mil-PRF-3150

© The Lubrizol Corporation 2006, all rights reserved

 LIMITED SALT SPRAY
• Soluble in Naphthenic Oil
• Resistant to high humidity
• Thin oily films
• Can be emulsified

© The Lubrizol Corporation 2006, all rights reserved

 LIMITED SALT SPRAY
• ALOX® 575S
• ALOX® 2280S
• ALOX® 2290S
• ALOX® 2290AS

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 575S
• Barium based
• Viscous liquid
• Suggested treat rate 15 - 20%
• Can be emulsified
• >64<72 hrs. salt spray @ 20% in oil

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2280S
• Calcium based
• Viscous liquid
• Suggested treat rate 15 - 20%
• Can be emulsified
• >64<72 hrs. salt spray @ 20% in oil

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2290S
• Viscous liquid
• Suggested treat rate 5 - 20%
• Can be emulsified
• 72 hrs. salt spray @ 20% in oil

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2290AS
• Viscous liquid
• Low odor
• Suggested treat rate 5 - 20%
• Can be emulsified
• 72 hrs. salt spray @ 20% in oil

© The Lubrizol Corporation 2006, all rights reserved

 SLUSHING OIL
• Water Displacing
• Non-Staining
• Resistant to high humidity
• For coiled or stacked steel

© The Lubrizol Corporation 2006, all rights reserved

 SLUSHING OIL
• ALOX® 1727DS
• ALOX® 2296

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 1727DS
• Calcium based
• Viscous liquid
• Thin oily film
• Suggested treat rate 5 – 10% in oil

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2296
• Calcium based
• Brown waxy solid
• Thin oily film
• Soluble in paraffinic oil and solvent
• Suggested treat rate 5 – 10% in oil

© The Lubrizol Corporation 2006, all rights reserved

 STAMPING & DRAWING
• Lubricating
• Resistant to high humidity
• Water displacing
• Non-staining
• Thin oily film

© The Lubrizol Corporation 2006, all rights reserved

 STAMPING & DRAWING
• ALOXDRAWTM 2400
• ALOXDRAWTM 2410

© The Lubrizol Corporation 2006, all rights reserved

 ALOXDRAWTM 2400
• Calcium based
• Brown waxy solid
• Light to medium duty
• Suggested treat rate 10 – 15% in oil
• Can be emulsified

© The Lubrizol Corporation 2006, all rights reserved

 ALOXDRAWTM 2410
• Calcium based
• Brown waxy solid
• Medium to heavy duty
• Contains sulfur
• Suggested treat rate 10 – 15% in oil
• Can be emulsified

© The Lubrizol Corporation 2006, all rights reserved

 SPECIALTY
• ALOX® 502AS
– Barium based
– Viscous liquid
– Resistant to high humidity
– Suggested treat rate 1 – 5%
– Engine break-in oil
– Applicable to Mil-PRF-21260E

© The Lubrizol Corporation 2006, all rights reserved

 SPECIALTY
• ALOX® 2201ES
– Calcium based
– Viscous liquid
– Resistant to high humidity
– Suggested treat rate 5 – 10%
– Applicable to Mil-PRF-32033

© The Lubrizol Corporation 2006, all rights reserved

 WATER EMULSIFIABLE
• From emulsion base
• Self emulsifiable

© The Lubrizol Corporation 2006, all rights reserved

 WATER EMULSIFIABLE
• From emulsion base
– ALOX® 575S
– ALOX® 2280S
– ALOX® 2290S
– ALOX® 2290AS
– ALOX® 2263S
– AQUALOXTM 2320S

© The Lubrizol Corporation 2006, all rights reserved

 WATER EMULSIFIABLE
• Self emulsifiable
– AQUALOXTM 2268S
– AQUALOXTM 2328S

© The Lubrizol Corporation 2006, all rights reserved

 EMULSIFIABLE – EMULSION BASE
• Soluble in naphthenic oil
• Resistant to high humidity
• Limited salt spray protection
• Coupling agents required for stable emulsions

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 575S
• Viscous liquid
• Barium based
• Suggested emulsion base
– 28.5/5.0/66.5
• >64<72 hrs. salt spray @ 25% EB in water
• 35+ days humidity cabinet @ 10% EB in water

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2280S
• Viscous liquid
• Calcium based
• Suggested emulsion base
– 28.5/5.0/66.5
• >64<72 hrs. salt spray @ 25% EB in water
• 35+ days humidity cabinet @ 10% EB in water

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2290S
• Viscous liquid
• Suggested emulsion base
– 28.5/5.0/66.5
• 72 hrs. salt spray @ 25% EB in water
• 60+ days humidity cabinet @ 10% EB in water

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2290AS
• Viscous liquid
• Suggested emulsion base
– 28.5/5.0/66.5
• 72 hrs. salt spray @ 25% EB in water
• 60+ days humidity cabinet @ 10% EB in water

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2263S
• Barium based
• Brown waxy solid
• Suggested emulsion base
– 35/5/60
• 100 hrs. salt spray @ 20% EB in water
• 60+ days humidity cabinet @ 20% EB in water

© The Lubrizol Corporation 2006, all rights reserved

 ALOX® 2320S
• Calcium based
• Brown waxy solid
• Suggested emulsion base
– 30/3/2/65
• >64<72 hrs. salt spray @ 25% EB in water
• 60+ days humidity cabinet @ 25% EB in water
• Lubricating
– 3500 lbs Falex @ 25% EB in water

© The Lubrizol Corporation 2006, all rights reserved

 EMULSIFIABLE – SELF EMULSIFYING
• Add directly to water
• Resistant to high humidity
• Lubricating as measured by Falex

© The Lubrizol Corporation 2006, all rights reserved

 AQUALOXTM 2268S
• Brown waxy solid
• Ultra thin waxy film
• Suggested treat rate 1 – 10% in water
• 30+ days humidity cabinet @ 5% in water
• Vapor phase inhibitor
• 4500+ lbs Falex @ 1% in water

© The Lubrizol Corporation 2006, all rights reserved

 AQUALOXTM 2328S
• Brown waxy solid
• Thin greasy film
• Suggested treat rate 5 – 8% in water
• Non-staining
• 60+ days humidity cabinet @ 5% in water
• 4500+ lbs Falex @ 5% in water
• 72 hrs salt spray @ 8% in water
• Stamping and drawing additive

© The Lubrizol Corporation 2006, all rights reserved

 WATER SOLUBLE
• Resistance to high humidity
• Cast Iron Chip test protection
• Suggested treat rate 2 – 10% in water

© The Lubrizol Corporation 2006, all rights reserved

 WATER SOLUBLE
• AQUALOXTM 240

© The Lubrizol Corporation 2006, all rights reserved

 AQUALOXTM 240
• 10 days humidity cabinet @ 10% in water
• 0% rust IP 287@ 2% in 200 ppm hard water
• Hard water stable up to 600 ppm
• Low foaming

© The Lubrizol Corporation 2006, all rights reserved

 SULFONATES
• Synthetic Calcium Sulfonates
• Natural Calcium Sulfonate
• Synthetic Barium Sulfonate
• Natural Barium Sulfonate

© The Lubrizol Corporation 2006, all rights reserved

 SYNTHETIC Ca SULFONATE
• ALOX® 2292B
– TBN <5.0
– Ca sulfonate content 42%
– Medium molecular weight (~920)
– Soluble in naphthenic and paraffinic oils

© The Lubrizol Corporation 2006, all rights reserved

 SYNTHETIC Ca SULFONATE
• ALOX® 2900
– TBN <5.0
– Ca sulfonate content 42%
– High molecular weight (~1000)
– Soluble in naphthenic and paraffinic oils

© The Lubrizol Corporation 2006, all rights reserved

 SYNTHETIC Ba SULFONATE
• ALOX® 2291B
– TBN <5.0
– Ba sulfonate content 50%
– High molecular weight (~1100)
– Soluble in naphthenic and paraffinic oils

© The Lubrizol Corporation 2006, all rights reserved

 NATURAL Ba SULFONATE
• ALOX® 2299
– TBN 50.0
– Ba sulfonate content 40%
– Soluble in naphthenic and paraffinic oils

© The Lubrizol Corporation 2006, all rights reserved