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PART : CHEMISTRY
2. An organic compound is estimated through Dumus method and was found to evolve 6 moles of CO 2, 4
moles of H2O and 1 mole of nitrogen gas. The formula of the compound is:
,d dkcZfud ;kSfxd dk M;wek fof/k ls vkdyu djus ij ik;k x;k fd 6 eksy CO2, 4 eksy H2O rFkk 1 eksy
ukbVªkstu mRlftZr gksrs gSaA bl ;kSfxd dk lw=k gS %
(1) C6H8N (2) C6H8N2 (3) C12H8N2 (4) C12H8N
Ans. (2)
6CO2
Combustion
Sol. CxHyNz 1N2
by Dumas method
1 mole
4H2O
on applying POAC
we get the formula C6H8N2
6CO2
4H2O
POAC ykxw djus ij
izkIRk lw=k C6H8N2
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| JEE MAIN-2019 | DATE : 11-01-2019 (SHIFT-1) | CHEMISTRY
3. Two blocks of the same metal having same mass and at temperature T 1 and T2, respectively, are
brought in contact with each other and allowed to attain thermal equilibrium at constant pressure. The
change in entropy, S, for this process is:
,d gh /kkrq ds leku lagfr okys nks Cykdksa dks Øe'k% rki T1 rFkk T2 ij ijLij ,d nwljs ds lEidZ esa yk;k x;k
fu;r nkc ij Å"eh; lkE; izkIr djus fn;k x;kA bl izØe esa ,UVªkih ifjorZu S gS %
1
T T2 (T1 T2 ) 2
(1) 2CP In 1 (2) 2CP In
4T1T2 T1T2
(T T2 )2 T T2
(3) CP In 1 (4) 2CP In 1
4T1T2 2T1T2
Ans. (3)
T1 T2
Sol. TFinal =
2
T
SI CP n f
T1
T
SII CP n f
T2
S SI SII
T T 2
1 2
T2 2
= CP n f CP n
T1T2 T1T2
4. For the cell Zn(s) |Zn2+ (aq)||Mx+ (aq) |M(s), different half cells and their standard electrode potentials
are given below :
Mx+(aq)/M(s) Au3+(aq)/ Au(s) Ag+(aq)/Ag(s) Fe3+(aq)/Fe2+(aq) Fe2+(aq)/Fe(s)
EMx / M/( V ) 1.40 0.80 0.77 –0.44
If EZn2 / Zn = –0.76 V, which cathode will give a maximum value of Ecell per electron transferred ?
(1) Au3+ / Au (2) Fe3+ / Fe2+ (3) Fe2+ / Fe (4) Ag+ / Ag
lsy Zn(s) |Zn2+ (aq)||Mx+ (aq) |M(s) ds fy, fofHkUu v)Z&lsy rFkk ekud bysDVªksM foHko uhps fn;s x;s gSa
Mx+(aq)/M(s) Au3+(aq)/ Au(s) Ag+(aq)/Ag(s) Fe3+(aq)/Fe2+(aq) Fe2+(aq)/Fe(s)
EMx / M/( V ) 1.40 0.80 0.77 –0.44
;fn EZn2 / Zn = –0.76 V, rks izfr bysDVªkWu LFkkukarj.k ds fy, dkSu ls dSFkksM dk Ecell lokZf/kd gksxk %
(1) Au3+ / Au (2) Fe3+ / Fe2+ (3) Fe2+ / Fe (4) Ag+ / Ag
Ans. (1)
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5. The correct match between item (I) and item (ii) is:
Item - I Item – II
(A) Norethindrone (P) Anti-biotic
(B) Ofloxacin (Q) Anti-Fertility
(C) Equanil (R) Hypertension
(S) Analgesics
enksa (I) rFkk (ii) ds chp lgh lqesy gS %
en - I en – II
(A) ukWj,fFkuMªku (P) izfrtSfod
(B) vk¶yksDlkflu (Q) izfrtuu {kerk
(C) ,DoSfuy (R) vfrruko
(S) ihM+kgkjh
(1) (A) (Q); (B) (R); (C) (S) (2) (A) (R); (B) (P); (C) (S)
(3) (A) (Q); (B) (P); (C) (R) (4) (A) (R); (B) (P); (C) (R)
Ans. (3)
Sol. Fact and information based.
ukWjfFkUMªksu bDosfuy
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6. Match the metals (column I) with the coordination compound(s)/ emzyme (s) (column II):
(column I) (column II)
Metal Coordination compound(s)/enzyme(s)
(A) Co (i) Wilkinson catalyst
(B) Zn (ii) ChlorophyII
(C) Rh (iii) Vitamin B12
(D) Mg (iv) Carbonic anhydrase
èkkrqvksa (dkWye I) dks milgla;kstu ;kSfxdksa@,Utkbe (dkWye II) ds lkFk lqesfyr dhft,&
(dkWye I) (dkWye II)
èkkrq milgla;kstu ;kSfxd@,Utkbe
(A) Co (i) fofYdlau mRizsjd
(B) Zn (ii) DyksjksfQy
(C) Rh (iii) foVkfeu B12
(D) Mg (iv) dkcksZfud ,UgkbMªst
(1) (A)-(i);(B)-(ii);(C)-(iii);(D)-(iv) (2) (A)-(iv);(B)-(iii);(C)-(i);(D)-(ii)
(3) (A)-(iii);(B)-(iv);(C)-(i);(D)-(ii) (4) (A)-(ii);(B)-(i);(C)-(iv);(D)-(iii)
Ans. (3)
Sol. Based on Fact rF; ij vk/kkfjrA
7. The correct order of the atomic radii of C, Cs, Al, and S is:
C, Cs, Al, rFkk S ds ijek.oh; f=kT;kvksa dk lgh vuqØe gS %
(1) C < S < Al <Cs (2) S < C < Al < Cs
(3) S < C < Cs < Al (4) C < S < Cs < Al
Ans. (1)
Sol. On going down the group size increases. From left to right in a period size decreases.
oxZ es uhps tkus ij vkdkj c<+rk gS vko`rZ esa cka;s ls nka;s tkus ij vkdkj ?kVRkk gSA
O O O
H
O–(CH2)4–C HNC(CH2)4–C–N
(1) (2)
n n
O O
H
C–(CH2)4–N OC–(CH2)4O
(3) (4)
n n
Ans. (1)
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O
(1) NaNO2,H3O
Sol. H2N–(CH2)4–C–OH
O
HO–(CH2)4–C–OH
O
(O–(CH2)4–C)n Polymerisation
Polymer
O O O OH
Ans. (4)
Cl Cl
+
Sol. HBr Alco. KOH Tautomerism
HO
O O Br O
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11. If a reaction follows the Arrhenius equation the plot lnk vs 1/(RT) gives straight line with a gradient (–y)
unit . The energy required to activate the reactant is :
(1) –y unit (2) y unit (3) y/R unit (4) yR unit
;fn ,d vfHkfØ;k vkgsZfuvl lehdj.k dk vuqlj.k djrh gS] rks IykV lnk vs 1/(RT), rks izo.krk (–y) ek=kd ds
lkFk ,d lh/kh js[kk nsrk gSA vfHkdkjdksa dks lfØ; djus ds fy, vko';d ÅtkZ gS %
(1) –y ek=kd (2) y ek=kd (3) y/R ek=kd (4) yR ek=kd
Ans. (2)
1
Sol. Slope of nk v/s –y –Ea
RT
1
nk rFkk ds e/; vkjs[k dk <+ky = – Y = –Ea
RT
Ea y
H
OH O N NH
(1) (2) (3) (4)
CHO
NH2
Ans. (3)
O O
C–OC2H5 H2 + Ni C–OC2H5
Sol.
CN NH2
DIBAL-H
N CH=O
NH2
13 Consider the reaction, N2(g) + 3H2(g) 2NH3(g). The equilibrium constant of the above reaction is
KP. If pure ammonia is left to dissociate, the partial pressure of ammonia at equilibrium is given by
(Assume that pNH3 ptotal at equilibrium)
33 / 2 K1/
p P
2 2
33 / 2 K1/
p P
2 2
K1/
p P
2 2
K1/
p P
2 2
(1) (2) (3) (4)
16 4 4 16
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Ans. (1)
1
Sol. 2NH3 N2 + 3H2 K'P =
kP
PTotal = P = PN2 PH2 PNH3 PN2 PH2
P
PN2
4
3P
PH2
4
3
P 3P
1 4
4
kP 2
PNH3
3
3 2 P2
PNH3 kP 1/ 2
16
14. The element that usually does NOT show variable oxidation states is :
lkekU; :i ls ifjorZuh; vkDlhdj.k voLFkk ugha iznf'kZr djus okyk rRo gS %
(1) Cu (2) Ti (3) Sc (4) V
Ans. (3)
Sol. Sc shows only +3 oxidation state.
Sc dsoy +3 vkDlhdj.k voLFkk n'kkZrk gSA
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17. Heat treatment of muscular pain involves radiation of wavelength of about 900 nm. Which spectral line
of H-atom is suitable for this purpose ?
[RH = 1 × 105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1 ]
(1) Paschen, 3 (2) Paschen, 5 3 (3) Balmer, 2 (4) Lyman, 1
ekalis'kh; nnZ ds Å"ek mipkj ds fy, yxHkx 900 nm ds rjaxnS/;Z ds fofdj.k dk mi;ksx gksrk gSA blds fy,
H-ijek.kq dh dkSulh LisDVªy ykbu mi;qDr gS \
[RH = 1 × 105 cm–1, h = 6.6 × 10–34 Js, c = 3 × 108 ms–1 ]
(1) ik'u, 3 (2) ik'ku, 5 3 (3) ckej, 2 (4) ykbZeSu, 1
Ans. (1)
1 1 1
Sol. R 2 2
n
1 n2
1 1 1
107 2
(3)
= 9 × 10–7 m
= 900 nm
19. The correct statement among (a) to (d) regarding H2 as a fuel are :
(a) It produces less pollutants that petrol.
(b) A cylinder of compressed dihydrogen weighs ~30 times more than a petrol tank producing the same
amount of energy.
(c) Dihydrogen is stored in tanks of metal alloys like NaNi5 .
(d) On combustion, values of energy released per gram of liquid dihydrogen and LPG are 50 and 142
kJ, respectively.
(1) (a) and (c) only (2) (b) and (d) only
(3) (a), (b) and (c) only (4) (b), (c) and (d) only
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bZa/ku ds :i esa H2 ds ckjs esa] (a) ls (d) esa ls lgh dFku gSa %
(a) ;g isVªksy dh vis{kk de iznw"kdksa dks cukrk gS
(b) mlh ek=kk dh ÅtkZ mRiUu djus ds fy, ,d isVªksy VSad dh rqyuk esa ,d laihfMr gkbMªkstu dk flfyUMj ~30
xquk vf/kd Hkkjh gksrk gSA
(c) MkbgkbMªkstu dks NaNi5 dh rjg ds /kkrq feJ/kkrq ds VSad esa j[kk tkrk gSA
(d) ngu ds mijkar] izfr xzke nzfor MkbgkbMªkstu rFkk LPG ls mRlftZr ÅtkZ ds eku Øe'k% 50 rFkk 142 kJ gSa
(1) (a) rFkk (c) ek=k (2) (b) rFkk (d) ek=k (3) (a), (b) rFkk (c) ek=k (4) (b), (c) rFkk (d) ek=k
Ans. (3)
Sol. Factual
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O
NH
Sol. Uracil is present in RNA.
N O
H
O
NH
Sol. ;wjsfly RNA es mifLFkr gSA
N O
H
22. The amphoteric hydroxide is:
mHk;/kehZ gkbMªkDlkbM gS &
(1) Sr(OH)2 (2) Mg(OH)2 (3) Ca(OH)2 (4) Be(OH)2
Ans. (4)
Sol. Be forms amphoteric hydroxide.
Be mHk;/kehZ gkbMksDlkbM cukrk gSA
23. The freezing point of a diluted milk sample is found to be –0.2°C, while it should have been –0.5°C for
pure milk. How much water has been added to pure milk to make the diluted sample ?
(1) 1 cup of water to 3 cups of pure milk
(2) 1 cup of water of 2 cups of pure milk
(3) 2 cups of water to 3 cups of pure milk
(4) 3 cups of water to 2 cups of pure milk
,d ruqd`r nqXèk izfrn'kZ dk fgekad –0.2°C ik;k x;k] tcfd fo'kq+) nqXèk dk fgekad –0.5°C gksuk pkfg,A ruqd`r
nqXèk izfrn'kZ dks cukus ds fy, fo’'kq) nqXèk esa fdruk ty feyk;k x;k gS\
(1) 3 di fo’”'kq) nqXèk esa 1 di ty
(2) 2 di fo’”'kq) nqXèk esa 1 di ty
(3) 3 di fo’”'kq) nqXèk esa 2 di ty
(4) 2 di fo’”'kq) nqXèk esa 3 di ty
Ans. (4)
Sol. Freezing point of milk = –0.5ºC Tf = 0.5ºC
Freezing point of diluted milk = –0.2ºC Tf = 0.2ºC
Tf i 0.5 K f m
Tf ii 0.2 k f m
Both has same amount of solute. Let that is x mole.
0.5 x mole W2
0.2 W1 x mole
5 W2
2 W1
5
W2 = W1
2
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Br2 ( vkf/kD;)
Br (excess)
2
SO3H
OH OH OH OH
Br Br Br Br Br
(1) (2) (3) (4)
Br Br
SO3H Br Br SO3H
Ans. (2)
OH OH
Br Br
Br
Sol. 2
excess
SO3H Br
It is EAS activated ring.
;g EAS lfØ;r oy; gSA
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26. For the chemical reaction X Y, the standard reaction Gibbs energy depends on temperature T (in
3
K) as rG°(in kJ mol–1) = 120 – T . The major component of the reaction mixture at T is :
8
(1) Y is T = 280 K (2) Y is T = 300 K (3) X if T = 315 K (4) X if T = 350 K
jklk;fud vfHkfØ;k X Y ds fy,] ekud vfHkfØ;k fxCl ÅtkZ rki (K esa) ij fuEufyf[kr dh rjg vkfJr
gksrh gS%
3
rG°(kJ mol–1 esa) = 120 – T
8
vfHkfØ;k feJ.k dk eq[; la?kVd T ij gS %
(1) Y ;fn T = 280 K (2) Y ;fn T = 300 K (3) X ;fn T = 315 K (4) X ;fn T = 350 K
Ans. (3)
3
Sol. At 315 K G° = 120 – 315
8
Gº = 1.875
Amount of Y will be greater than its equilibrium amount at 315 K.
Y dh ek=kk] bldh lkE; ek=kk ls vf/kd gSA
27. A solid having density of 9 × 103 kg m–3 forms face centred cubic crystals of edge length 200 2 pm.
What is the molar mass of the solid? [Avogadro constant 6 × 1023 mol–1, 3]
,d Bksl] ftldk ?kuRo 9 × 103 kg m–3 gS] Qyd dsfUnzr ?kuh; fØLVy cukrk gS ftlds dksj dh yEckbZ
200 2 pm gSA Bksl dk eksyj nzO;eku D;k gS \ [vokxknzks fu;rkad 6 × 1023 mol–1, 3]
(1) 0.0432 kg mol–1 (2) 0.0305 kg mol–1 (3) 0.4320 kg mol–1 (4) 0.0216 kg mol–1
Ans. (2)
ZM
Sol. d=
NA a3
M0
4
9 × 103 = 6 1023
(200 2 10–12 )3
M0
4
9 × 103 = 3 6 1023
2 2 2 10 –30
9 103 6 1023 24 2 10–30
M0 =
4
= 9 × 6 × 10–4 × 4 × 2 = 0.03 kg
28. The concentration of dissolved oxygen (DO) in cold water can go upto:
BaMs ty esa ?kqfyr vkWDlhtu (DO) ds lkUnzrk dh Åijh lhek gks ldrh gS %
(1) 8 ppm (2) 16 ppm (3) 14 ppm (4) 10 ppm
Ans. (4)
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29. A 10 mg effervescent tablet containing sodium bicarbonate and oxalic acid releases 0.25 ml of CO 2 at
T = 298.15 K and p = 1 bar. If molar volume of CO 2 is 25.0 L under such condition, what is the
percentage of sodium bicarbonate in each tablet ?
[Molar mass of NaHCO3 = 84 g mol–1]
lksfM;e ckbdkcksZusV rFkk vkDlSfyd vEy ;qDr ,d 10 mg dk cqncqnkus okyk VScysV T = 298.15 K rFkk p = 1 bar
ij 0.25 ml CO2 mRlftZr djrk gSA ,slh n'kk esa] ;fn CO2 dk eksyj vk;ru 25.0 L gS] rks izR;sd VScysV esa
lksfM;e ckbdkcksZusV dk D;k izfr'kr gS \
[NaHCO3 dk eksyj nzO;eku = 84 g mol–1]
(1) 0.84 (2) 33.6 (3) 8.4 (4) 16.8
Ans. (3)
Sol. 2NaHCO3 H2C2O4 Na2C2O4 2CO2 2H2O
Let mass of NaHCO3 be x mg
ekuk dh NaHCO3 dk nzO;eku x mg gSA
0.25
n= 10–5
25000
w = 84 10–5 g
84 10 –5
% 100 = 8.4%
10 –2
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