Vous êtes sur la page 1sur 10

Asset Integrity Management Programs

for Ammonia Plant Facilities


Effectively managing the integrity of key assets in ammonia plant facilities is essential to maintaining
high levels of both personnel and process safety as well as ensuring that economic benefits are
obtained from the investment in those facilities. This paper reviews the essential elements of an asset
integrity management program that were addressed in a recent audit of several world-class ammonia
plants that typically produce more than 500,000 metric tons of ammonia per year. Methods for
judging the effectiveness of an asset integrity management program are reviewed.

Carl E. Jaske
HSI GROUP, INC.

Steven J. Weichel
DNV GL USA, INC.

Michiel P. H. Brongers
DNV GL USA, INC.

Introduction The processes described above require critical

M
equipment, including piping, pressure vessels,
ost ammonia plants use a hydrocarbon boilers, tanks, compressors, turbines, valves, in-
feedstock, typically natural gas, to pro- strumentation, structures, and electrical cabling.
duce hydrogen by means of steam me- This includes equipment that operates at low
thane reforming. Hydrogen is then combined temperatures and other equipment that operates
with nitrogen to produce ammonia by means of at very high temperatures. Some of the equip-
the Haber-Bosch process. After sulfur is removed ment also is exposed to corrosive operating con-
from the feed gas, the gas is preheated before be- ditions. To maintain and assure reliable operation
ing mixed with steam and fed to the primary re- of such equipment, world-class ammonia plants
former. The gas from the primary reformer is typically employ asset integrity management
mixed with air in the secondary reformer to pro- (AIM) programs.
duce the synthesis gas. This gas then flows
through shift reactors to produce carbon dioxide, In a previous paper [1], the authors presented an
which is removed from the mixture before the overview of important features of an AIM pro-
methanation process followed by ammonia syn- gram for ammonia and methanol plants. The pre-
thesis. sent paper focusses on the essential elements of

2018 115 AMMONIA TECHNICAL MANUAL


AIM programs that were included in a recent na- RBI Risk Based Inspection.
tional facilities audit/benchmarking study of 30
companies in Trinidad & Tobago’s energy sector
[2]. This audit covered rating both the organiza- High Consequence Intolerable
tion’s AIM systems and the application of those Low Frequency Risk
systems to equipment in the facility. Process
Safety
What is asset integrity management? Asset integ-
rity has two components: (1) technical integrity
is the management of barriers, which are typi-
cally non-physical such as operating limits, and
(2) process safety is the management of hazards Lower Consequence
to prevent major incidents. Performing these two Higher Frequency
activities together is then referred to as asset in- Personal
tegrity management. When properly imple- Tolerable Safety
mented, AIM enables a company to use an asset Risk
efficiently while safeguarding life and environ-
ment.
Likelihood of Occurrence
In the framework of AIM, it is important to con-
Figure 1. Comparison of Risk for Process Safety
sider the difference between process safety and
with Risk for Personal Safety.
personal safety. Figure 1 compares these two as-
pects of safety in terms of risk. Process safety in-
cidents usually have a lower frequency and Topics Covered in Audit
higher consequences than personal safety. Pro-
cess safety is not as intuitive as personal safety The following twelve topics were reviewed and
because people often lack personal experience rated in the audit of AIM systems in ammonia
with it. Since high consequences and potentially plants. The highlighted ones are discussed in this
massive and lasting impacts are considered unac- paper.
ceptable, process safety necessitates highly relia- • Leadership
ble controls. Thus, managing process hazards is
• Planning and administration
not directly linked to managing personal health
• Risk management
and safety.
• Training & competence
• Contractor management
Nomenclature • Communication & promotion
• Project management
AIM Asset Integrity Management • Asset management
E&I Electrical & Instrumentation
• Change management
FFS Fitness for Service
• Learning from events
HSEQ Health, Safety, Environment, and Quality
KPIs Key Performance Indicators • Emergency response
LOC Loss of Containment • Results & review
MOC Management of Change
PHA Process Hazard Analysis Application of AIM to the following eight cate-
PSM Process Safety Management gories of equipment was rated in the audit of am-
PSV Pressure Safety Valve monia plants:
QA Quality Assurance • Electrical & instrumentation

AMMONIA TECHNICAL MANUAL 116 2018


• Facility piping programs. Some plants held quarterly “town
• Fired heaters & boilers hall” style meetings to keep workers up to date.
• Pressure vessels Additionally, most plants used newsletters, elec-
• Pressure safety valves tronic communication, bulletin boards, and em-
• Rotating equipment ployee recognition to keep personnel informed.
• Tanks Some companies encouraged staff to attend in-
dustry meetings and conferences that address
• Structures
safety and integrity management.
For the most part, the ammonia plants that were
audited were rated above the average of the 30 Risk Management
energy companies that were included in the over-
all audit. These plants and others that were above The companies included in the audit employed a
average were typically part of large multi-na- systematic approach to managing their exposure
tional organizations with well developed process to intrinsic risk by control of major accident haz-
and personnel safety cultures. ards. An example of a risk management approach
is provided in ISO 31000 and 31010 [4, 5]. In-
The twelve audit topics do not stand alone, but tie trinsic risk scores remain fairly static and change
together to form an AIM plan. As will be dis- only with significant changes at the site, such as
cussed later, ISO 55000 – Asset Integrity Man- inventories and processes, local population, or
agement [3] defines 24 different topics that surrounding environment. Intrinsic risk can be
should be contained in a complete AIM plan. Im- assessed using safety hazard grouping and envi-
portant aspects are discussed in the remaining ronment hazard grouping in accordance with the
sections of this paper, organized under the head- SEVESO III Directive on the Control of Major
ings Leadership, Risk Management, Manage- Accident Hazards (COMAH) approach [6], as il-
ment of Change, and Emergency Response. lustrated in Figure 2.

Leadership
Commitment and buy-in from upper manage-
ment all the way down to the personnel working
daily in the plant are needed for a truly effective
and successful AIM program. The audit showed Figure 2. Rating the Intrinsic Risk of Major Ac-
that the ammonia plants have leadership that de- cident Hazards.
fines their organizations’ vision, purpose, goals,
policies, and values. These were typically Company leadership teams were committed to a
aligned with those of other internal and external defined risk management policy that engaged
stakeholders. The leaders of these organizations stakeholders and aligned with the culture of the
also identified the major risks of the ammonia organization. The organizations provided the re-
production business and each of the audited sources needed to carry out the risk management
plants had established a formal program for pro- program, measure its effectiveness, and make
cess safety management (PSM). improvements.

In our audit of the ammonia plants’ management Both internal and external factors were used to
systems, we found that various levels of manage- define the types of risks that the organization
ment from team foremen to the plant manager to considered, the processes that they used to man-
corporate management typically supported AIM age risk, and the types of risk criteria that they
considered. These criteria included the types of

2018 117 AMMONIA TECHNICAL MANUAL


consequences that can occur and what events can 1. Terminating is the elimination or avoid-
cause them, measures of likelihood of events, ance of risk by deciding not to undertake
how risk levels are determined, and levels of risk a particular activity or course of action.
acceptability. 2. Treating the risk can include taking ac-
tions to modify its likelihood and/or alter-
Typical risk management activities include the ing its consequences.
following steps: 3. Transferring risk is sharing the risk with
other parties. Examples include using a
• Identification
joint venture and using insurance.
• Analysis
4. Tolerating a risk is accepting both its like-
• Evaluation lihood and potential consequences.
Risk identification consists of determining the The selection and implementation of control
risk sources, their causes, and their potential im- strategies are reviewed and modified if needed
pacts, including if knock-on effects are possible. periodically as part of the AIM program.
A knock-on effect is a secondary or incidental ef-
fect that is indirectly caused by an event. The The ammonia plants employ a hierarchy of con-
main tasks of risk analysis are determining the trols to manage the risks.
magnitude of potential consequences and the
likelihood of those consequences. The risks are 1. Engineering or design controls are the
evaluated by comparing them with the estab- first choice to eliminate risks where pos-
lished criteria, so controls can be selected to re- sible.
sult in risks that are in accordance with the risk 2. Administrative controls including proce-
management policy. dures, rules, work permits and warning
signs are the next choice to mitigate risk.
The ammonia plants used process hazard analy- 3. Personal and environmental protective
sis (PHA) techniques to identify and evaluate the equipment are the last line of defense.
various process safety risks in their facilities.
Most of them used a formal risk-based inspection Materials and products are identified, labeled,
(RBI) approach for their pressure vessels and stored, and inspected to ensure that their quality
piping systems. Some of the plants also applied is properly controlled. Process controls are main-
RBI to their ammonia storage tanks. RBI was tained within critical parameters as part of pro-
typically not applied to the plant structures or cess safety management.
electrical and instrumentation systems because
formal RBI procedures have not been developed The benchmarking study revealed that several
for these applications. However, the plants did ammonia plants replaced their converter vessel
have inspection programs for electrical and in- because a potential problem had been identified
strumentation, with emphasis on equipment re- with a major weld seam. The plant management
lated to safety. Inspection of structures was often and owners decided that they could not accept the
a lower priority and identified as an area of im- risk of this large, high pressure vessel failing
provement. even though the cost of replacement was quite
high.
Risk control strategies typically included the fol-
lowing four options: (1) terminate, (2) treat,
(3) transfer, or (4) tolerate.

AMMONIA TECHNICAL MANUAL 118 2018


Management of Change limited lifetimes. In such cases, they were re-
quired to be replaced by a permanent change at
Effective management of change (MOC) pro- the earliest opportunity or no later than the next
cesses are essential component of AIM pro- turnaround.
grams. Two main types of change occur in oper-
ating ammonia facilities: organizational and Communication of Change
engineering.
Good communication is essential for effective
Management of Organizational Change management of change. In an ever-changing am-
monia plant workplace, effective communication
Organizational change is a constant in modern fa- is critical both to inform and motivate personnel.
cilities and should be controlled with an effective Good communication is more than telling; it
change management process. The process should should be an interactive process of giving and
include mechanisms for effectively retaining crit- getting understanding. Promotional campaigns
ical skills and capabilities and for addressing the and a variety of communication channels should
risks associated with changing the structure of be used to promote process safety as well as
the organization. health, safety, environment, and quality (HSEQ)
improvement in a fresh and interesting way. Ex-
The audit of ammonia plants revealed that most ceptional group and individual performance
of them have some type of system to make sure should be identified and widely communicated to
that staff with the proper skill levels fill the or- reinforce positive behaviors.
ganizational positions related to AIM. However,
such systems were not normally part of their for- The audited ammonia facilities required approv-
mal MOC processes. als of changes from all affected groups. Changes
affecting safety and asset integrity were reviewed
Management of Engineering Change at daily, weekly, and monthly staff meetings.
Staff were recognized for outstanding perfor-
Effective engineering change management pro- mance and for identifying problems or potential
vides a coherent, systematic, and simple mecha- safety issues that led to the need for change.
nism for identifying and controlling hazards
throughout the process of change with emphasis
on the transition phase. Well implemented, MOC Learning from Events
ensures that the health, safety, and environment
of the facility and its personnel are not compro- Learning from events is critical to continual im-
mised by inadequate evaluation of hazards, provement in safety, environmental and business
threats, and other potential undesired events re- performance. An effective system for learning
lated to change. MOC also ensures that the in- from events can transform undesired events into
tended benefits of the change are fully realized as opportunities for improvement. Managers should
planned. strive to create a no-blame culture to foster high
levels of event reporting. Personnel should be en-
The audit showed that the ammonia plants had a couraged to report near-misses because they of-
documented, formal process for managing engi- fer the greatest number of learning opportunities.
neering changes. This MOC process typically is All events should be assessed for risk, consider-
tracked and documented through a computerized ing what did happen and what could have hap-
database system to ensure tracking, signoff, and pened (actual vs. potential consequence), and in-
retention of records. Temporary changes were vestigated appropriately. This effort should
found to go through the same process and have involve all relevant personnel. Investigations
must uncover the basic (underlying) causes of

2018 119 AMMONIA TECHNICAL MANUAL


events before determining the necessary correc- The high and medium high levels of safety risk
tive and preventive actions. These actions should made up 154 or 39.5% of the incidents. Plant
be tracked to completion and the results should management and engineering staff should review
be communicated to all necessary stakeholders. the reports of such incidents and make sure that
the issues that caused them have been properly
Besides learning from events within their own fa- addressed in their AIM program. They also
cilities, personnel can learn from events that oc- should consider sharing incidents from their
cur elsewhere in the ammonia industry. This in- plant by participating in safety-oriented confer-
cludes neighboring plants in an industrial estate, ences and symposia. In fact, many of the organi-
other plants within the organization, and similar zations included in the AIM audit participate in
plants within the global ammonia industry. An the AIChE symposia.
especially important source of relevant industry
information are the publications from this annual The results of our audit showed that the ammonia
symposium on safety in ammonia plants [7]. In plants were open to employee feedback. There
2005, Pattabathula et al. [8] reviewed 290 inci- typically was a blame-free culture in the organi-
dents that had been reported in the first 49 sym- zations. Reporting of safety related events, in-
posia. In 2015, Pattabathula and Richardson [9] cluding near-misses, was encouraged. Most of
updated this review to summarize the 86 inci- the plants applied root-cause analysis in their in-
dents that had been reported in the next 10 sym- vestigation of incidents. Some plants sent staff to
posia. In the current study, we identified 14 more corporate meetings to share learnings with other
relevant incidents from papers published in the plants in their global organization. In a few cases,
2015, 2016, and 2017 symposia [10-21]. the plant personnel participated in local or inter-
national conferences where events related to
Based on the descriptions of the 390 incidents in AIM were discussed.
the referenced papers, we used our judgment to
estimate a level of safety risk for each one based
on the following four categories: Emergency Response
• Low: likely to result in no or slight injury Effective emergency preparedness requires plan-
• Medium Low: likely to result in minor in- ning and practicing in advance so that, in the
jury and affect work performance event of an emergency, the harm to people, to the
• Medium High: likely to result in severe environment, and to the business is minimized.
injury or disability Potential emergencies need to be identified and
• High: likely to result in loss of life categorized across the spectrum of risk including
the extreme cases, such as low-likelihood, high-
Our results are summarized in Table 1. consequence events. The level of consequence
impact should be determined for each scenario
Risk Category Total Percentage
that is considered. Plans should then be devel-
Low 14 3.6% oped to respond to each of these emergencies.
Systems for emergency communication should
Medium Low 222 56.9%
be established and technical systems, for exam-
Medium High 140 35.9% ple, fire protection and emergency power. Teams
High 14 3.6% of experienced personnel should be established
to execute the emergency plans; their compe-
Total 390 100% tence should be ensured through regular training,
Table 1. Summary of estimated safety risk for in- drills, and exercises. Finally, adequate first aid
cidents reported in previous ammonia safety and medical support should be available if re-
symposia. quired.

AMMONIA TECHNICAL MANUAL 120 2018


The plants in the AIM audit had developed emer- IMPLEMENTATION OF PROGRAM
gency response plans that included training on-
site personnel to respond to emergencies, work- Principles, requirements, and guidelines for im-
ing with neighboring plants, and coordinating plementation of an AIM program are provided in
with local emergency units. Various scenarios for ISO standards [3, 22, 23]. Figure 3 shows the re-
incidents were postulated and drills were held on lationship among the key terms used in asset
a rotating basis to practice addressing them. management while Figure 4 illustrates the key el-
ements of an assessment management system as
presented in ISO 55000 [3].

Figure 3. Relationship Among Key Terms Used in Asset Management [3]

Figure 4. Relationship Among the Key Elements of an Asset Management System [3].

2018 121 AMMONIA TECHNICAL MANUAL


Asset management is part of managing the organ- Maintenance
ization and includes the management system as
well as the asset portfolio. An AIM program is an Strategic and preventative maintenance of pres-
important part of asset management. The system sure vessels, piping, tanks, rotating equipment,
includes a continuous improvement process and electrical equipment is essential for effective
where results are evaluated and fed back into var- management of asset integrity. This work in-
ious aspects of the system as required. cludes following manufacturers’ recommenda-
tions as well as accounting for local conditions
Process safety management [24] includes many within the facility. Particular attention should be
of the same items as asset integrity management given to equipment that is subject to time depend-
and is typically part of an AIM program. Im- ent degradation, such as corrosion, aging, fa-
portant items to include in AIM program are tigue, and high-temperature creep. Maintenance
quality assurance, maintenance, inspection, fit- schedules should be established, followed, and
ness-for-service assessment, and equipment re- adjusted based on experience and inspection re-
pair and replacement. The ISO standards [3, 22, sults. Maintenance of safety critical equipment,
23] were not referenced by any of the ammonia such as pressure safety valves and process con-
plants in the audit. Utilizing them is a potential trol instrumentation, is particularly important.
opportunity for improvement. PSM, quality as-
surance, maintenance, inspection, fitness-for-ser- Inspection
vice assessment, and equipment repair and re-
Inspection and monitoring of equipment and
placement were used by the plants in the audit.
structures in ammonia are essential to maintain-
ing the integrity of those assets. Risk based in-
Quality Assurance spection (RBI) following the methods of API RP
To control asset integrity, quality assurance (QA) 580 [25] or similar guidelines is used by many
is an element in all aspects of an AIM program ammonia plants to effectively plan and imple-
and should consider the equipment lifecycle. ment inspection of pressure vessels, piping, and
High quality fabrication and installation of the tanks. RBI methodology helps operators select
equipment in ammonia plants begins with robust and apply effective inspection techniques to crit-
designs based on comprehensive standards and ical equipment to manage safety risk.
specifications that carry through the procure-
ment, fabrication, transportation and delivery and Release of ammonia is a significant risk in am-
installation stages. Quality maintenance, inspec- monia operations. Facilities that apply RBI to
tion, engineering assessment, and repair and re- ammonia tanks may also further evaluate this risk
placement procedures need to be implemented to by considering the likelihood of loss of contain-
ensure that the initial condition of the equipment ment (LOC) resulting from stress-corrosion
is not significantly degraded during its operating cracking, corrosion, and structural failure and the
life. An effective AIM program requires collec- consequence of plant personnel and the local
tion, integration, and application of a large community being exposed to ammonia vapor, in-
amount of data. Continual QA reviews of these cluding accounting for containment and isolation
data are essential. systems. This additional risk assessment should
include comprehensive consequence analysis
Many of the plants in the audit had an ISO 9001 that uses a dedicated dispersion model across a
certified quality management system as part of range of release scenarios.
their asset integrity management.

AMMONIA TECHNICAL MANUAL 122 2018


Fitness for Service Assessment 5. ISO 31010, 2009, “Risk management – Risk
assessment techniques,” ISO, Geneva.
If inspection reveals defects or degradation in 6. SEVESO III Directive, 1 June 2015, Control
equipment, its fitness for service (FFS) must be of Major Accident Hazards (COMAH).
evaluated to make sure that it can safely and reli- 7. AIChE Technical Manual Collection, 1956
ably operate for a desired future period. API to 2017, Proceedings of Annual Safety in
579-1/ASME FFS-1 [26] or a similar standard is Ammonia Plants & Related Facilities Sym-
used to perform FFS assessments of possible posium, AIChE, New York.
damage identified in pressure vessels, piping, 8. Pattabathula, V., Rani, B., and Timbres, D.
and tanks in ammonia plants. The results of a FFS H., 2005, “The AIChE Ammonia Safety
assessment indicate if operation of the equipment Symposium 50 Years of Shared Experi-
as-is can continue or if a repair or replacement is ences,” Proceedings of 50th Annual Safety
required. Repairs must be made following appli- in Ammonia Plants & Related Facilities
cable standards and regulations. Replacement Symposium, AIChE, New York, pp. 12-54.
equipment should meet or exceed the require- 9. Pattabathula, V. and Richardson, J., 2015,
ments of the original equipment that is being re- “Sixty Years of History of the AIChE Am-
placed. monia Safety Symposium,” Proceedings of
60th Annual Safety in Ammonia Plants &
Summary Related Facilities Symposium, AIChE, New
York, pp. 1-26.
Asset integrity management is critical to main- 10. Orooji, A., Hosseininia, S., and Mahvelati,
taining the safe and reliable operation of ammo- E. A., 2015, “Catastrophic Explosion in the
nia plants. As reviewed in this paper, many plants CO2 Removal Unit of an Ammonia Plant,”
in the ammonia industry have established AIM Proceedings of 60th Annual Safety in Am-
programs. It also was pointed out that industry monia Plants & Related Facilities Sympo-
standards are available for effectively imple- sium, AIChE, New York, pp. 105-113.
menting asset management. 11. Aliabadi, N., John McGrath, J., Keen, D Pat-
tabathula, V., and Firth, D., 2016, “Failure
of Secondary Reformer Dome and Its Re-
References pair,” Proceedings of 61st Annual Safety in
Ammonia Plants & Related Facilities Sym-
1. Jaske, C. E., Weichel, S. J., and Brongers,
posium, AIChE, New York, pp. 41-49.
M. P. H., 2017, “Essential Elements of an
12. Stoffels, J., 2016, “Failures in Aging Am-
Asset Integrity Management Program for
monia Plants,” Proceedings of 61st Annual
Ammonia and Methanol Plants,” Paper
Safety in Ammonia Plants & Related Facili-
PVP2017-65977, Proceedings of the ASME
ties Symposium, AIChE, New York, pp. 51-
2017 Pressure Vessels and Piping Confer-
62.
ence, ASME, New York.
13. Balgobin, K. and Babwah, R., 2016, “Fail-
2. National Facilities Integrity Audit & Be-
ure of Level Bridle in Benfield Service,”
yond Workshop, 2017 Trinidad & Tobago
Proceedings of 61st Annual Safety in Am-
Energy Conference, Hyatt Regency Port of
monia Plants & Related Facilities Sympo-
Spain, January 25, 2017.
sium, AIChE, New York, pp. 71-79.
3. ISO 55000, 2014, “Asset management –
Overview, principles and terminology,”
ISO, Geneva.
4. ISO 31000, 2009, “Risk management – Prin-
ciples and guidelines,” ISO, Geneva.

2018 123 AMMONIA TECHNICAL MANUAL


14. AbdAl-Wahab, I. and Abdel-Rahman, H., 22. ISO 55001, 2014, “Asset management –
2016, “Syngas Compressor Hydrodynamic Management systems – Requirements,”
Thrust Bearing Failure,” Proceedings of 61st ISO, Geneva.
Annual Safety in Ammonia Plants & Re- 23. ISO 55002, 2014, “Asset management –
lated Facilities Symposium, AIChE, New Management systems – Guidelines for the
York, pp. 103-112. application of ISO 55001,” ISO, Geneva.
15. Majeed, R. and Ali, S. 2016, “Ammonia 24. OSHA 1910.119, 2017, “Process safety
Converter Reaction Loss Followed by Fire management of highly hazardous chemi-
Incident,” Proceedings of 61st Annual cals,” Title 29 – Labor, U.S. Code of Federal
Safety in Ammonia Plants & Related Facili- Regulations, Washington, D.C.
ties Symposium, AIChE, New York, pp. 25. API Recommended Practice 580, 2016,
113-118. “Risk-based Inspection,” Third Edition,
16. Bosselaar, R., 2016, “Severe Cracks on a American Petroleum Institute, Washington,
New Duplex Syngas Loop Cooler,” Pro- DC.
ceedings of 61st Annual Safety in Ammonia 26. API 579-1/ASME FFS-1, 2016, “Fitness-
Plants & Related Facilities Symposium, For-Service,” American Petroleum Institute,
AIChE, New York, pp. 123-132. Washington, DC.
17. Orooji, A., Hosseininia, S., and Mahvelati,
E. A., 2016, “Ammonia Plants Compressor
Room Fire; Prevention and Remedies,” Pro-
ceedings of 61st Annual Safety in Ammonia
Plants & Related Facilities Symposium,
AIChE, New York, pp. 133-140.
18. Singh, I. and Mehta, S., 2017, “BFW Pre-
heater Exchanger Leak and Smooth Recov-
ery of LTS Catalyst after Wetting,”, Pro-
ceedings of 62nd Annual Safety in
Ammonia Plants & Related Facilities Sym-
posium, AIChE, New York, 39-48.
19. Sinha, R. and Lalchan, N., 2017, “HP Syn-
gas Compressor Failure Due to Reverse Ro-
tation,” Proceedings of 62nd Annual Safety
in Ammonia Plants & Related Facilities
Symposium, AIChE, New York, 49-60.
20. Turi, I., 2017, “Process Air Compressor HP
Stage Rotor Damage Due to Reverse Rota-
tion,” Proceedings of 62nd Annual Safety in
Ammonia Plants & Related Facilities Sym-
posium, AIChE, New York, 79-84.
21. Ramjattan, G. and Widrig, J. R., 2017, “Fail-
ure of a Riser Transition Assembly on a Pri-
mary Reformer,” Proceedings of 62nd An-
nual Safety in Ammonia Plants & Related
Facilities Symposium, AIChE, New York,
199-207.

AMMONIA TECHNICAL MANUAL 124 2018

Vous aimerez peut-être aussi