Project 01-3137 - EHC - Well #4u#5 - 2015-04-27 - Normal Case

Process Design 01
Raw Water Flocopac - RO1-2-3 - MB

Raw Water Flow 70 m³/h IN OUT

86 m³/h 87 m³/h

Calculation: = 5a - 4 = 1a+6+15+24 = 2a - 3 = 5b 6+7 7/Rec7*(100-Rec7)

Line Number: 1a 1b 2 3 4 5a 5b 6
Parameter Raw Water 1a Raw Water 1b Raw Water Treatm. Raw Water Treatm. Raw Water Treatm. Raw Water Treatm. Raw Water Treatm. Raw Water Treatm.
Feed Flow Clear Water Clear Water Clear Water GF
Well #5 Well #4 Flocculator Sludge Settler Overflow Total pH adjusted Back Wash
40 m³/h 30 m³/h 54 m³/h 0,74 t/h 53 m³/h 97 m³/h 97 m³/h 2,9 m³/h
8
Avarage Flow
1
TSS 7,20 ppm 1,00 ppm < 38,2 ppm ~ 300 kg DM/t < 5,0 ppm < 3,0 ppm < 3,0 ppm 98,0 ppm
0
TOC 0,00 ppm 0,00 ppm 0,0 ppm 0,0 ppm 0,0 ppm 0,0 ppm 0,0 ppm
5
TDS 10166 ppm 16515 ppm 8212 ppm 8505 ppm 9779 ppm 9801 ppm 9801 ppm
5
Conductivity ~ 15885 µS/cm ~ 25805 µS/cm ~ 12831 µS/cm ~ 13289 µS/cm ~ 15280 µS/cm ~ 15314 µS/cm ~ 15314 µS/cm
1
Silica SiO2 21,60 ppm 26,00 ppm 17,3 ppm 17,3 ppm 17,6 ppm 17,6 ppm 17,6 ppm
4
Temperature 28,0 °C 28,0 °C 29 °C 29 °C 29 °C 29 °C 29 °C
9
pH - Value 6,85 7,20 ~ 6,3 ~ 11,5 ~ 9,3 ~ 6,3 ~ 6,3
2
Hardness as CaCO3 3415 ppm 4960 ppm 2941 ppm 76 ppm 1571 ppm 1571 ppm 1571 ppm

Sodium Na +
1
2270 ppm 4433 ppm 1894 ppm 3256 ppm 3155 ppm 3155 ppm 3155 ppm
Potassium K +
10/1
49,0 ppm 107 ppm 42,3 ppm 42,3 ppm 57,6 ppm 57,6 ppm 57,6 ppm
Magnesium Mg ++ 1
562 ppm 650 ppm 431 ppm 10 ppm 206 ppm 206 ppm 206 ppm
Calcium Ca ++
1
594 ppm 915 ppm 468 ppm 14 ppm 290 ppm 290 ppm 290 ppm
Strontium Sr++
10
22,00 ppm 22,00 ppm 17,30 ppm 17,30 ppm 16,23 ppm 16,23 ppm 16,23 ppm
Barium Ba ++
10
0,03 ppm 0,03 ppm 0,02 ppm 0,02 ppm 0,02 ppm 0,02 ppm 0,02 ppm
Boron B +++
10
1,20 ppm 1,20 ppm 1,26 ppm 1,26 ppm 1,19 ppm 1,19 ppm 1,19 ppm
Manganese Mn ++ 0
0,00 ppm 0,00 ppm 0,000 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,000 ppm
Aluminium Al+++
7
0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm
Ammonium NH4+ 7
0,10 ppm 0,10 ppm 2,65 ppm 2,65 ppm 1,50 ppm 1,50 ppm 1,50 ppm
Chloride Cl-
1
4536 ppm 8330 ppm 3678 ppm 3734 ppm 4623 ppm 4623 ppm 4623 ppm
Fluoride F-
6
1,00 ppm 1,00 ppm 0,80 ppm 0,80 ppm 0,76 ppm 0,76 ppm 0,76 ppm
Sulfate SO4-- 1
1758 ppm 1620 ppm 1382 ppm 1382 ppm 1254 ppm 1289 ppm 1289 ppm
Bicarbonate HCO3-
9
327 ppm 188 ppm 248 ppm 0,00 ppm 58,32 ppm 58 ppm 58 ppm
Carbonate CO3--
8
0,27 ppm 0,37 ppm 0,07 ppm 0,00 ppm 13,80 ppm 0,02 ppm 0,02 ppm
- 1
Nitrate NO3 18,6 ppm 221,0 ppm 24 ppm 24,4 ppm 84,6 ppm 84,6 ppm 85 ppm
Phosphate PO43- 7
0,02 ppm 0,02 ppm 0,59 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm
1
Iron Total 5,50 ppm 0,16 ppm 4,11 ppm 0,01 ppm 0,05 ppm 0,05 ppm 0,05 ppm
1
Iron Dissolved 5,50 ppm 0,16 ppm 4,11 ppm 0,01 ppm 0,05 ppm 0,05 ppm 0,05 ppm
Alkalinity (as CaCO3; < 500 ppm) 407 ppm 161 ppm
Ca (as CaCO3; < 1000 ppm)
m-Value (> 3 mmol/l for CT-BD)
Holding Time Index (< 150 h)

8
CO2 ~ 62 ppm ~ 16 ppm ~ 133 ppm ~ 0 ppm ~ 0 ppm ~ 29 ppm ~ 29 ppm

1
Max. Wert Betrachtung Brunnen
2
Berechnet aus dem Mittelwert für Ca u. Mg
3
Entspricht m-Value
4
Annahme
5
Berechnet
6
Normalwert für Meerwasser
7
Normalwert für Brunnenwasser
8
Berechnet aus pH u. HCO3
9
Mittelwert Brunnen
10
Nalco Analyse
0
Not detected

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Project 01-3137 - EHC - Well #4u#5 - 2015-04-27 - Normal Case

CT Zirkulation 4700 m³/h Cl 197 ppm

Process Design 01
Raw Water Flocopac - RO1-2-3 - MB 1,50% Evaporation 70,5 m³/h Capacity
0,01% Drifft Loss (D) 0,24 m³/h 700 m³
Raw Water Flow 0,21% Blow Down (B) 9,84 m³/h
Summe (A) 80,6 m³/h

Calculation: 8+9 9/Rec9*(100-Rec9) 9a + 10 + 13 20 + 21 11+12 9-9a-12-13 A - 12 - 19 - 22b A B 8 - 17 8 / 100% * Rec.17 = 16

Line Number: 7 8 9 9a 10 11 12 13 14 15 16 17 16a
Parameter Raw Water Treatm. Desalination Desalination Desalination Potab. Water Potab. Water Potab. Water Raw Water Treatm. CT CT Desalination Desalination Brine Treatment
GF RO1 RO1 RO 1 Perm. Potab. Wat. RO1 Perm. Blow RO2 RO2 Crystallizer
Treated Water Concentrate Permeate Demin. Potab. Wat. 1 Potab. Wat. 2 CT MakeUp 1 CT MakeUp 2 Make Up Down Concentrate Permeate First Fill
94 m³/h 24 m³/h 71 m³/h 12 m³/h 11 m³/h 1 m³/h 10 m³/h 47 m³/h 81 m³/h 10 m³/h 12 m³/h 12 m³/h 12 m³/h
97 % Rec. 75 % Rec. Factor 8 50 % Rec.

TSS < 0,1 ppm 0,0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm < 150 ppm 0,0 ppm ~ 0 ppm 0,39%
TOC 0,0 ppm 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm 0 ppm ~ 0 ppm 0 ppm
TDS 9801 ppm 39022 ppm 60 ppm 60 ppm 110 ppm 110 ppm 110 ppm 60 ppm 57 ppm 457 ppm 77783 ppm 257 ppm 78319 ppm
Conductivity ~ 15314 µS/cm ~ 60972 µS/cm ~ 94,0 µS/cm ~ 94,0 µS/cm ~ 172 µS/cm ~ 172 µS/cm ~ 172 µS/cm ~ 94,0 µS/cm ~ 89,3 µS/cm ~ 714 µS/cm ~ 121535 µS/cm ~ 402,2 µS/cm ~ 122373 µS/cm
Silica SiO2 17,6 ppm 70 ppm 0,18 ppm 0,18 ppm 0,18 ppm 0,18 ppm 0,18 ppm 0,18 ppm 0,15 ppm 1,16 ppm 139 ppm 0,80 ppm 139 ppm
Temperature 29 °C 29 °C 29 °C 29 °C 29 °C 29 °C 29 °C 29 °C 38 °C 38 °C 29 °C 29 °C 80 °C
pH - Value ~ 6,3 ~ 6,7 ~ 4,9 ~ 4,9 ~ 7,0 ~ 7,0 ~ 7,0 ~ 4,9 ~ 4,7 ~ 4,7 ~ 7,1 ~ 5,1 ~ 8,9

Hardness as CaCO3 1571 ppm 6279 ppm 1,30 ppm 1,30 ppm 126 ppm 126 ppm 126 ppm 1,30 ppm 16,36 ppm 131 ppm 12553 ppm 5,65 ppm 12553 ppm

Sodium Na + 3155 ppm 12557 ppm 20,63 ppm 20,63 ppm 20,63 ppm 20,63 ppm 20,63 ppm 20,63 ppm 17,39 ppm 139,1 ppm 25.024 ppm 90 ppm 25.221 ppm
Potassium K + 57,6 ppm 223 ppm 2,48 ppm 2,48 ppm 2,48 ppm 2,48 ppm 2,48 ppm 2,48 ppm 1,77 ppm 14,15 ppm 435 ppm 10,39 ppm 435 ppm
Magnesium Mg ++ 206 ppm 823 ppm 0,17 ppm 0,17 ppm 0,17 ppm 0,17 ppm 0,17 ppm 0,17 ppm 0,12 ppm 0,98 ppm 1645 ppm 0,74 ppm 1645 ppm
Calcium Ca ++ 290 ppm 1158 ppm 0,24 ppm 0,24 ppm 50,0 ppm 50,0 ppm 50,0 ppm 0,24 ppm 6,35 ppm 50,8 ppm 2316 ppm 1,04 ppm 2316 ppm
Strontium Sr++ 16,23 ppm 64,9 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,06 ppm 129,7 ppm 0,06 ppm 130 ppm
Barium Ba ++ 0,02 ppm 0,09 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,18 ppm 0,00 ppm 0,18 ppm
Boron B +++ 1,19 ppm 3,90 ppm 0,29 ppm 0,29 ppm 0,29 ppm 0,29 ppm 0,29 ppm 0,29 ppm 0,20 ppm 1,63 ppm 6,81 ppm 0,98 ppm 6,81 ppm
Manganese Mn ++ 0,000 ppm 0,000 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,000 ppm 0,00 ppm 0,000 ppm
Aluminium Al+++ 0,01 ppm 0,03 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,07 ppm 0,00 ppm 0,07 ppm
Ammonium NH4+ 1,50 ppm 5,86 ppm 0,05 ppm 0,05 ppm 0,05 ppm 0,05 ppm 0,05 ppm 0,05 ppm 0,88 ppm 7,06 ppm 11,56 ppm 0,15 ppm 0,00 ppm
Chloride Cl- 4623 ppm 18.407 ppm 28,74 ppm 28,74 ppm 28,74 ppm 28,74 ppm 28,74 ppm 28,74 ppm 24,63 ppm 197 ppm 36.687 ppm 126 ppm 36687 ppm
Fluoride F- 0,76 ppm 3,0 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,01 ppm 0,06 ppm 5,9 ppm 0,14 ppm 5,89 ppm
Sulfate SO4-- 1289 ppm 5.156 ppm 0,75 ppm 0,75 ppm 0,75 ppm 0,75 ppm 0,75 ppm 0,75 ppm 0,53 ppm 4,25 ppm 10.308 ppm 3,21 ppm 10649 ppm
Bicarbonate HCO3- 58 ppm 227 ppm 1,14 ppm 1,14 ppm 1,14 ppm 1,14 ppm 1,14 ppm 1,14 ppm 0,81 ppm 6,50 ppm 443 ppm 2,09 ppm 433 ppm
Carbonate CO3-- 0,02 ppm 1,75 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,02 ppm 8,61 ppm 0,00 ppm 27,8 ppm
-
Nitrate NO3 85 ppm 322 ppm 5,47 ppm 5,47 ppm 5,47 ppm 5,47 ppm 5,47 ppm 5,47 ppm 3,89 ppm 31,15 ppm 622 ppm 21,42 ppm 622 ppm
Phosphate PO43- 0,01 ppm 0,05 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,39 ppm 3,14 ppm 0,09 ppm 0,00 ppm 0,09 ppm
Iron Total 0,05 ppm 0,22 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,04 ppm 0,44 ppm 0,00 ppm 0,44 ppm
Iron Dissolved 0,05 ppm 0,22 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,00 ppm 0,04 ppm 0,44 ppm 0,00 ppm 0,44 ppm
Alkalinity (as CaCO3; < 500 ppm) 11 ppm
Ca (as CaCO3; < 1000 ppm) 127 ppm
m-Value (> 3 mmol/l for CT-BD) 0,1 mmol/l
Holding Time Index (< 150 h) 49 h

CO2 ~ 29 ppm ~ 22 ppm ~ 21 ppm ~ 21 ppm ~ 21 ppm ~ 21 ppm ~ 21 ppm ~ 21 ppm ~ 15 ppm ~ 0 ppm ~ 24 ppm ~ 21 ppm ~ 1 ppm

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Project 01-3137 - EHC - Well #4u#5 - 2015-04-27 - Normal Case

Process Design 01
Raw Water Flocopac - RO1-2-3 - MB

Raw Water Flow

Hydrozyklon
Calculation: 16a + 18c + 18d 16c / fact. 18a / Fact. by TSS 18a - 18 16a - 18d -18 21/Rec.21*(100-Rec.21) 23 - 22 24 + 25
Line Number: 16c 18a 18d 18b 18 18c 19 20 21 22a 22b 22c 23
Parameter Brine Treatment Brine Treatment Brine Treatment Brine Treatment Brine Treatment Brine Treatment Brine Treatment Demineraliz. Demineraliz. Boiler Condensate System Brine Treatment Polishing
Crystallizer Crystallizer Slurry Feed Crystallizer RO3 RO3 MB
Conti. Operation Slurry Discharge Centrifuge Salt Filtrate Destillate Concentrate Permeate Blow Down Steam Condensate Steam Condensate Feed Water
13,7 m³/h 2,48 t/h 0,00 t/h 1,24 t/h 0,57 t/h 1,91 t/h 11 m³/h 2,42 m³/h 10 m³/h 4,00 m³/h 4,00 m³/h 8,00 m³/h 13,70 m³/h
Factor 5,5 Factor 2 80 % Rec.

TSS 0,34% 22,0% 43,9% 95,0% 0,0% ~ 0 ppm ~ 0 ppm ~ 0 ppm

TOC 0 ppm 0 ppm ~ 0 ppm ~ 0 ppm ~ 0 ppm
TDS 122425 ppm 393820 ppm 42 ppm 232 ppm 3 ppm 29 ppm 8 ppm 8 ppm ~ 7 ppm
Conductivity ~ 191289 µS/cm ~ 65,6 µS/cm ~ 362,7 µS/cm ~ 4,9 µS/cm ~ 45,5 µS/cm ~ 12,6 µS/cm ~ 12,6 µS/cm ~ 10,8 µS/cm
Silica SiO2 254 ppm 962 ppm 0,89 ppm 0,00 ppm 0,33 ppm 0,01 ppm 0,01 ppm 0,01 ppm
Temperature 80 °C 80 °C 80 °C 80 °C 80 °C 80 °C 80 °C 29 °C 29 °C 40 °C 40 °C 40 °C 44 °C
pH - Value ~ 8,9 ~ 8,9 ~ 8,9 ~ 8,9 ~ 8,9 ~ 7,0 ~ 8,3 ~ 6,8 ~ 7,0

Hardness as CaCO3 10807 ppm 65 ppm 6,48 ppm 0,00 ppm 0,00 ppm

Sodium Na + 42539 ppm 149.097 ppm 16,64 ppm 45,31 ppm 0,31 ppm 7,80 ppm 0,22 ppm
Potassium K + 709 ppm 2395 ppm 11,51 ppm 0,23 ppm 0,16 ppm
Magnesium Mg ++ 1417 ppm 16 ppm 0,86 ppm 0,00 ppm 0,00 ppm
Calcium Ca ++ 1992 ppm 0 ppm 1,18 ppm 0,00 ppm 0,00 ppm
Strontium Sr++ 253 ppm 1013 ppm 0,05 ppm 0,00 ppm 0,00 ppm
Barium Ba ++ 0,40 ppm 1,76 ppm 0,00 ppm 0,00 ppm 0,00 ppm
Boron B +++ 11,10 ppm 37,47 ppm 0,53 ppm 0,16 ppm 0,11 ppm
Manganese Mn ++ 0,000 ppm 0,000 ppm 0,00 ppm 0,00 ppm 0,00 ppm
Aluminium Al+++ 0,46 ppm 2,84 ppm 0,00 ppm 0,00 ppm 0,00 ppm
Ammonium NH4+ 0,00 ppm 0,00 ppm 0,19 ppm 0,01 ppm 1,00 ppm 8,04 ppm 8,04 ppm 4,70 ppm
Chloride Cl- 63698 ppm 229903 ppm 25,66 ppm 140,49 ppm 0,80 ppm 12,0 ppm 0,57 ppm
Fluoride F- 56,55 ppm 368 ppm 0,05 ppm 0,00 ppm 0,00 ppm
Sulfate SO4-- 9908 ppm 5349 ppm 3,69 ppm 0,01 ppm 0,01 ppm
Bicarbonate HCO3- 546 ppm 1244 ppm 5,37 ppm 0,08 ppm 0,06 ppm
Carbonate CO3-- 23,91 ppm 0,00 ppm 0,67 ppm 0,00 ppm 0,00 ppm
-
Nitrate NO3 1014 ppm 3423 ppm 21,34 ppm 1,50 ppm 1,06 ppm
3-
Phosphate PO4 0,08 ppm 0,00 ppm 0,00 ppm 0,00 ppm 7,90 ppm 0,00 ppm
Iron Total 1,50 ppm 8,06 ppm 0,00 ppm 0,00 ppm
Iron Dissolved 0,00 ppm 0,00 ppm 0,08 ppm 0,01 ppm 0,01 ppm 0,01 ppm
Alkalinity (as CaCO3; < 500 ppm)
Ca (as CaCO3; < 1000 ppm)
m-Value (> 3 mmol/l for CT-BD)
Holding Time Index (< 150 h)

CO2 ~ 1 ppm ~ 1 ppm ~ 1 ppm ~ 1 ppm ~ 1 ppm ~ 0 ppm ~ 0 ppm

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Project 01-3137 - EHC - Well #4u#5 - 2015-04-27 - Normal Case

Process Design 01
Raw Water Flocopac - RO1-2-3 - MB

Raw Water Flow

Calculation: 25/Rec.25*(100-Rec.25)
Line Number: 24 25
Parameter Polishing Polishing
MB MB
Concentrate Polished Water
0,137 m³/h 13,56 m³/h
Avarage Flow 99,0 % Rec.

TSS
TOC ~ 0 ppm < 0,0 ppm
TDS ~ 4852 ppm ~ 0,13 ppm
Conductivity ~ 7.582,0 µS/cm < 0,2 µS/cm
Silica SiO2 -0,24 ppm 0,01 ppm
Temperature 44 °C 44 °C
pH - Value ~ 7,0 ~ 7,0

Hardness as CaCO3

Sodium Na + 1560,30 ppm 0,05 ppm

Potassium K +
Magnesium Mg ++
Calcium Ca ++
Strontium Sr++
Barium Ba ++
Boron B +++
Manganese Mn ++
Aluminium Al+++
Ammonium NH4+ 470,32 ppm
Chloride Cl- 2716,02 ppm 0,07 ppm
Fluoride F-
Sulfate SO4--
Bicarbonate HCO3-
Carbonate CO3--
Nitrate NO3- 106,10 ppm
Phosphate PO43-
Iron Total
Iron Dissolved 0,58 ppm
Alkalinity (as CaCO3; < 500 ppm)
Ca (as CaCO3; < 1000 ppm)
m-Value (> 3 mmol/l for CT-BD)
Holding Time Index (< 150 h)

CO2

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