‫ا ارا ‪:‬‬ ‫ض‪/1‬اورة‪1‬‬ ‫

ا
او‬
‫‪2009/2008‬‬
‫ا‪-‬ة ‪.2 :‬س‪.‬‬ ‫‪.'(.2 www.9alami.com‬ع‪.‬ح‪.‬أ‪3.‬‬ ‫ا‪$%‬ه"‬
‫ا‪/-‬ع‬ ‫ا‪01%‬‬
‫‪:12-3‬‬
‫‪5‬ث ‪3‬ه (‪8‬ف <; ‪ 7"83 ،3:‬ا‪  6-‬ا"‪ 2: t = 0 45‬ا‪ C-‬ذي ا@ر‪3‬ب ‪. x = 0‬‬
‫‪ ;E-‬ا‪-‬ن )ا‪H3 (1;F‬ات ا@ر‪3‬ب ) ‪ M 81 y M (t‬أ‪ L( x M = 16 cm IJ‬ا‪.2:K‬‬
‫‪  .1‬أي ‪ ;J3 45‬ا‪ 6-‬ا‪. M 81‬‬
‫‪ .2‬أ<‪   O‬ا‪%‬ر ا‪N 6-‬ل ا‪.;5‬‬
‫‪ .3‬أ‪ : -‬ا‪-‬ة ا‪ ∆t :K‬ا‪5%3 %‬ك ‪ I‬ا‪. M 81‬‬
‫ب‪ -‬ا‪N S%%‬ل ا‪.R%‬‬
‫‪ ;FU ;E: .4‬ا‪  ;5‬ا"‪% ( t = 4 ms 45‬ر ا"‪ X" 1 cm V‬ارق ‪  4 cm ;E-‬اا‪.CY‬‬

‫‪:22-3‬‬
‫]‪   8‬ا‪%‬ر ا‪6-‬ت ق ا‪ 3J‬دا[; ‪:‬ء ا‪. Veau = 1,50. 10 m.s 5‬‬
‫‪3‬‬ ‫‪−1‬‬

‫ار ‪I6‬ز ( ^ و ‪6-" 0YL‬ت ق ا‪  ;-]% ،3J‬اا[ ‪ 7- 5%‬ا‪.5‬‬
‫‪[( ;1%3‬ة و‪: 7‬ر ‪H3 5% ( x' x) -1%:‬ات ‪ 7-‬ا‪ A 2%81 2( 5‬أ‪ x A = 0 m IJ‬و ‪B‬‬
‫أ‪ ) . x B = 50 m IJ‬أ‪ 4‬ا‪.(2;F‬‬
‫‪ ;E-‬ا‪ ^]( ;`3 3 ;F‬و ا‪1%‬ل ا‪6-‬ت ق ا‪F3 : 3J‬ن ا[ة  ا‪. A 81‬‬
‫‪ : .1‬ه ا‪ ;[-‬ا‪a‬ي ]‪ ^]( 8‬ا‪6-‬ت و ا‪a‬ي ]‪ 8‬ا‪.I1%‬‬
‫‪ .2‬أ‪ : -‬ه ا‪-‬ة ا‪ ∆t :K‬ا‪ ^]( 2( "b‬و ا‪1%‬ل ا‪6-‬ت ق ا‪.3J‬‬
‫ب‪ -‬أ<‪ 7- O‬ا‪  p 5‬ا‪. A 81‬‬
‫]‪ 8‬ا‪ ) X5-‬ا‪H3 (4;F‬ات ‪ ;1%3 : x L( ∆t‬ا[ة ‪ 2:‬ا‪ A 81‬إ‪ X‬ا‪. B 81‬‬
‫‪ 7- 2  .3‬ا‪ ∆t L( p 5‬و ‪. Veau‬‬
‫‪H3 ;E: .4‬ات ‪). x L( p‬أ‪ ;1‬ا‪ 5 ;F‬إ‪ X‬ور‪ Y‬ا‪.(5%‬‬

‫‪:32-3‬‬
‫]‪ %‬ا‪ ; %‬ا‪--‬ج (‪]-‬د ‪(CH 3 ) 3 C − Cl + 2 H 2 O → (CH 3 ) 3 C − OH + H 3O + Cl :‬‬
‫‪+‬‬ ‫‪−‬‬

‫‪. λ ( H 3O + ) = 349,8. 10 −4 S .m 2‬‬ ‫]‪λ (Cl − ) = 76,3. 10 −4 S .m 2 : 8‬‬

‫‪- .1‬ذا ‪83 C%3 2F-‬ر ه‪a‬ا ا‪5%‬ل (ا‪Y 8‬س ا‪."b-‬‬
‫‪ .2‬ا ‪6 0‬ول ا‪1%‬م‪ .‬و ا‪ S%%‬ا]‪ [H 3O + ]t 2( Yg‬و ‪  [Cl − ]t‬آ; ‪.45‬‬
‫‪ "b: 2  .3‬ا‪"5-‬ل ) ‪13 L( σ (t‬م ا‪ x ; %‬و ‪ V`< V‬ا‪"5-‬ل و ا‪ "b-‬ا‪ -‬ا@‬
‫‪i‬ت ا‪%-‬ا‪6‬ة‪.‬‬
‫‪: ]( .4‬ة ز‪ j<g "N :‬ا‪1%‬ار ‪ "b:‬ا‪"5-‬ل  ا‪. σ f = 0,374 S .m -1‬‬
‫‪−1‬‬

‫أ<‪ V`< 8] . x max O‬ا‪"5-‬ل ه ‪. V = 205 mL = 205. 10 −6 m 3 :‬‬

‫‪ .5‬ا‪ σ f ، σ (t ) L( x ]3 S%%‬و ‪. x max‬‬
‫‪ : .6‬ه ‪ ( x -Y‬ل ‪. σ = 0,200 S .m −1‬‬
‫إذن ‪ 2F-3‬ا]‪ Yg‬ا(‪ 2: 1‬ر‪H3 X5: V‬ات ‪ L( x‬ا‪).2:K‬ا‪.(6;F‬‬
‫‪ .7‬أ‪ 2  -‬ا  ا‪. x L( ; %" -`5‬‬
‫ب‪ -‬ا‪U‬ح آ‪   53 2F- m‬ا‪. t 45  : ; %‬‬
‫ت‪ :  -‬آ‪8%3 m‬ر   ا‪ L( ; %‬ا‪.2:K‬‬
‫ث‪ : -‬ه ا]‪ ;:‬ا‪5‬آ ا‪a‬ي ]"; ه‪a‬ا ا‪8%‬ر‪.‬‬
‫‪ .8‬ف ز‪ mJ 2:‬ا‪ ; %‬و <د ‪.: R%-Y‬‬
‫‪ n K` : .9‬ا‪ (`%‬ا(‪  1‬در‪< 6‬ارة أآ‪ .‬ه; ‪ -Y‬ز‪ mJ 2:‬ا‪o13 ،%( X13 ; %‬‬
‫أم ‪K3‬داد‪.‬‬
 (6@‫ا‬
:12-3
. t = 4 ms -1
SM
v= = 40 m.s −1 -2
∆t
-3
∆t = 2ms -‫أ‬
∆l = v * ∆t = 40 * 2. 10 −3 = 8 cm -‫ب‬

-4
:22-3
.I1%‫ ا‬: 2;[-‫ا‬ ‫ت‬6-‫ (]^ ا‬: 1;[-‫ ا‬-1
-2
∆t = 27 ms -‫أ‬
d 2p v * ∆t
v= = ⇒ p= = 20,25m -‫ب‬
∆t ∆t 2
v * ∆t
p = eau -3
2
-4

:32-3
.S3‫ت و اا‬g %-" @‫ ا‬-‫" ا‬b-‫ ا‬2( ‫ @ن هك ق آ‬-1
. [H 3O + ]t = [Cl − ]t =
xt
+ ‫م‬1%‫ول ا‬6 -2
V
[ ] [ ]
σ (t ) = λ ( H 3 O + ) H 3 O + + λ (Cl − ) Cl − = {λ ( H 3O + ) + λ (Cl − )} t
x
V
-3
x max
σ f = (λ1 + λ 2 ) -4
V
σ f *V
x max = = 1,80. 10 −3 mol ‫إذن‬
λ1 + λ2
σ (t )
x(t ) = x max * -5
σf
 0,200
x = 1,8. 10 −3 * = 9,62. 10 −4 mol -6
0,374
-7
1 dx
v= -‫أ‬
V dt
. V X" R%-Y + R6-‫; ا‬:]-‫ ا‬53 + ‫س‬--‫ ا‬V -‫ب‬
.oY% ‫ت‬--" R6-‫; ا‬:]-‫ ; @ن ا‬%‫   ا‬oY%3 -‫ت‬
.‫ت‬g %-‫ ا‬K‫آ‬3 -‫ث‬
t1 / 2 = 1,3 min .qI‫ ا‬R%-Y mJ x [$ :‫ز‬g‫ ا‬:K‫ة ا‬-‫ ه ا‬-8
.oY%3 -9

2010 ‫دح‬F -<‫أ‬