APÉNDICE E

Datos termodinámicos para

diferentes sustancias,
unicfacks en el sistema
inglés (USCS)
TABLA E-1 Depcndencla de la temperatwa en 1a.s capacidades caloríficas molares de Rases a presión cero. (Unidades en USCS)

cp=a+bT+CT*+dT3
[Th “R, ¿$ in Btu/(lbmol - “R)]

Temperatura Error, %
sustancía fórmula u d Max. Avg.
b C Rango, “R
Nitrógeno N2 6.903 -0.02085 X 1O-2 0.05957 x 10-S -0.1176 X lo-‘> 491-3240 0.59 0.34
oxígeno 02 6.085 0.2017 X 1O-2 -0.05275 X 1OF 0.05372 X 1O-9 491-3240 1.19 0.28
Aire 6.713 0.02609 X 1O-z 0.03540 x 10-S -0.08052 X lo--’ 491-3240 0.72 0.33
Hidrógeno HZ 6.952 -0.02542 X 1O-2 0.02952 X 1OF -0.03565 X 1O-9 491-3240 1.01 0.26
Monóxido de Carbono c o 6.726 0.02222 x 10-Z 0.03960 X 1OF -0.09100 x 10-g 49 1 -- 3240 0.89 0.37
Dióxido de Carbono
vapor de Agua
Oxido
, Nítrico
Oxido Nitroso
Dióxido de Nitrógeno
Amoniaco
Azufre s2 ’ 6.499 0.2943 X lo-* -0.1200 x 10-5 0.1632 X 1OV 491-3240 0.99 0.38
Dióxldo de azufre 50, so2 6.157 0.7689 X 1O-2 -0.2810 X 1O-5 0.3527 X IOV 491-3240 0.45 0.24
Trióxido de azufre 50, so, 3.918 1.935 x 10-Z -0.8256 X 1O-5 1.328 X 1OW 491-2340 0.29 0.13
Acetileno
Benzen
Metano1
Etanol
Ácido clorhídrico
Metano
Etano -1--o
Propano C& -0.966 4.044 x 10-Z -1.159 x 10-5 1.300 x 10-g 491-2740 0.40 0.12
n-Butano GH,o 0.945 4.929 X 1O-2 - 1.352 x 10-S 1.433 x 10-g 491-2740 0.54 0.24
i-Butano GH,o - 1.890 5.520 X 1O-2 - 1.696 x 10-S 2.044 X 1OW 49 l-2740 0.25 0.13
n-Pentano GH,, 1.618 6.028 X 1O-2 - 1.656 x 10-j 1.732 X IOW 491-2740 0.56 0.21
n-Hexano
Etileno
Propileno
Datos tomados de B.G. Kyle, Chemical and Proce.s 77wmodynamics, Prentice Hall, Englewood, Cliffs, N.J., 1984 (impreso con autorización).

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 TABLA E.2 Propiedades del alre a baja presión considerado SJIS Ideal. unl+des en USCS

u. h. SO, CP. C”.

T, ‘F Btu/lbm Btujlbm Btu/(lbm . ‘R) PO uo Btu/(lbm * ‘RJ Btu/(lbm - OR) k
- 300 27.28 38.231 1.3098 0.1958 17,248. 0.2394 0.1708 1.402
- 200 44.36 62.176 1.4262 1.0692 5,137.2 0.2394 0.1708 1.402
- 100 61.46 86.130 1.5043 3.3357 2,280.8 0.2395 0.1709 1.401
0 78.56 110.09 1.5631 7.8574 1,237.5 0.2397 0.1711 1.401
17 91.12 128.56 1.6002 13.504 840.65 0.2401 0.1715 1.400

1,7142
.;g@ 155.53 ~:
1 LT4?3, .
600 183.57 256.27 1.7660 151.21 148.23
700 201.92 28 1.47 1.7887 210.60 116.48 0.2536 0.1850 1.371
800 220.58 306.99 1.8098 286.47 93.013 0.2568 0.1882 1.365
900 239.56 332.83 1.8295 381.97 75.295 0.2600 0.1914 1.358
1,000 258.85 358.99 1.8481 500.64 61.673 0.2631 0.1945 1.353

1,700 401.57 549.73 1.9546 2,365.0 19.316 0.2805 0.2119 1.324

1,800 422.87 577.88 1.9673 2,847.7 16.785 0.2824 0.2 138 1.321
1,900 444.34 606.22 1.9796 3,405.3 14.657 0.2842 0.2156 1.318
2,000 465.98 634.72 1.9914 4,046.l 12.859 0.2858 0.2172 1.316

3,000 689.53 926.87 2.09 10 17,268. 4.238 1 0.2973 0.2287 1.300

3,200 735.45 986.5 1 2.1077 22,045. 3.5116 0.2989 0.2303 1.298
3.400 78 1.67 1.046.5 2.1237 27,813. 2.9354 0.3004 0.2318 1.296

5,m 1,160.l 1,534.6 2.2294 129,860. 0.8893 0.3089 0.2403 1.286

Propiedades generadas con el programa GASPROPS, Wiley Professional Software, Wiley, Nueva York, 1984.
TABLA E.3 Propiedades del ar@n a baja presk3n conslduado gas Ideal. unldade en lISC

11. h. SO. CP. C”,

T, ‘F Btu/lbm Btu/lbm Btu/(lbm * ‘R) PO VO Btu/(lbm - ‘R) Btu/(lbm * ‘R) k
-300 11.914 19.857 0.7750 0.5837 7,979.2 0.1244 0.0746 1.667
-200 19.376 32.293 0.8355 1.9689 3,847.4 0.1244 0.0746 1.667
-100 26.837 44.729 0.8760 4.4455 2,360.l 0.1244 0.0746 1.667
0 34.299 57.165 0.9065 8.2088 1,633.5 0.1244 0.0746 1.667

700 86.531 144.22 1.0216 82.985 407.66 0.1244 0.0746 1.667

800 93.992 156.65 1.0319 102.05 360.09 0.1244 0.0746 1.667
900 101.45 169.09 1.0414 123.52 321.10 0.1244 0.0746 1.667
1.000 108.92 181.53 1.0502 147.50 288.68 0.1244 0.0746 1.667

1,700 161.15 268.58 1.0989 392.76 160.40 0.1244 0.0746 1.667

1,800 168.61 281.01 1.1045 439.82 149.87 0.1244 0.0746 1.667
1.900 176.07 293.45 1.1099 490.11 140.45 0.1244 0.0746 1.667

2:800 243.23 405.38 1.1501 1,099.Z 86.504 0.1244 0.0746 1.667

3,000 258.15 430.25 1.1575 1,275.7 79.112 0.1244 0.0746 1.667
3,200 273.07 455.12 1.1645 1,468.l 72.716 0.1244 0.0746 1.667
3,400 288.00 479.99 1.1711 1,677.0 67.138 0.1244 0.0746 1.667

4.600 377.54 629.23 1.2048 3,299.6 44.73 1 0.1244 0.0746 1.667

4,800 392.46 654.10 1.2096 3,635.5 42.204 0.1244 0.0746 1.667
5.ooo 407.33 678.97 1.2143 3.991.0 39.907 0.1244 0.0746 1.667
Propiedades generadas con el programa GASPROPS, Wiley Professional Software, Wiley, Nueva York, 1984.

664
TABLA E.4 PropIedades del nitrógeno a bJa presión conslderado gas Ideal, unldades en USCS

u, h, SO. CP. C”.

T, “F Btu/lbm Etu/lbm Btu/(lbm * ‘R) PO Btu/(lbm * ‘l?) Btu/(lbm * ‘R) k
-300 28.32 39.643 1.3327 0.1443 22,629. 0.2483 0.1173 1.400
-200 46.05 64.411 1.4535 0.7917 6,709.l 0.2483 0.1773 1.400
- 100 63.80 89.309 1.5344 2.4781 2,969.0 0.2483 0.1774 1.400
0 81.54 114.15 1.5954 5.8497 1,607.5 0.2484 0.1774 1.400
77 95.20 133.27 1.6338 10.062 1,091.l 0.2485 0.1775 1.400

700 208.16 290.42 1.8277 154.68 153.36 0.2593 0.1883 1.377

800 227.14 316.50 1.8492 209.66 122.91 0.2624 0.1914 1.371
900 246.45 342.90 1.8694 278.59 99.838 0.2656 0.1947 1.364
1 .onn 2hh.08 369.62 1.8884 363.96 82.041 0.2688 0.1979 1.359

11700 411.64 564.84 1.9974 1,692.2 26.108 0.2877 0.2168 1.327

1,800 433.42 593.72 2.0104 2,034.5 22.721 0.2898 0.2188 1.324
1,900 455.40 622.79 2.0230 2,429.6 19.868 0.2917 0.2207 1.321
2000 477.57 652.05 2.0352 2,883.2 17.452 0.2935 0.2225 1.319

2,800 660.13 891.36 2.1194 9,444.5 7.0603 0.3038 0.2329 1.305

3mO 706.90 952.32 2.1375 12,198. 5.8020 0.3057 0.2347 1.302
3200 754.00 1,013.6 2.1547 15,550. 4.8144 0.3072 0.2363 1.300

4,800 1,139.3 1,512.4 2.2677 76,468. 1.4070 0.3152 0.2443 1.290

5,ooo 1,188.2 1,575.5 2.2795 90,275. 1.2372 0.3158 0.2449 1.290
Propiedades generadas con el pro~ama GASPROPS, Wiky Professional Software, Wiley, Nueva York, 1984.

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TABLA L.5 RopIedades del oxigeno l baja presión ConsIderado gas Ideal, unldades en USCS

u. h. SCl. CP. C”.

T, ‘F Btu/ibm Btu/lbm Btu/(lbm - ‘R) Po 00 Btu/(lbm * ‘R) Btu/(lbm * ‘R) k
-300 24.79 34.705 1.2672 0.7280 5,124.7 0.2174 0.1553 1.400
-200 40.32 56.449 1.3730 3.9972 1,518.0 0.2174 0.1553 1.400
-100 55.86 78.195 1.4438 12.508 671.94 0.2175 0.1554 1.400
0 71.43 99.976 1.4973 29.568 363.26 0.2182 0.1561 1.398
7” 83.49 116.82 1.5312 5 1.020 245.79 0.2194 0.1573 1.395
1OC 87.12 121.87 1.5404 59.183 220.97 0.2199 0.1578 1.394
$3
$
b’f
3
IJ
Y!’

1,700 382.73 516.85 1.8662 11,241. 4.4893 0.2664 0.2043 1.304

1,800 403.22 543.55 1.8783 13,656. 3.8664 0.2677 0.2056 1.302
1,900 423.85 570.39 1.8899 16,467. 3.3484 0.2690 0.2069 1.300
2.000 444.60 591.35 1.9011 19.718. 2.9148 0.2702 0.2081 1.298

2,800 614.47 816.90 1.9783 68,381. 1.1139 0.2784 0.2163 1.287

3,000 657.92 872.77 1.9950 89,382. 0.9044 0.2803 0.2182 1.285
3.200 701.73 929.00 2.0108 115,280. 0.7418 0.2821 0.2200 1.282
3,400 745.9 1 985.60 2.0258 146,9 10. 0.6139 0.2839 0.22 18 1.280

4,600 1,018.3 1,332.5 2.1040 517,510. 0.2285 0.2940 0.2319 1.268

4,800 1,064.8 1,391s 2.1154 622,060. 0.1976 0.2955 0.2334 1.266
5,ooo 1,111.7 1,450.7 2.1265 743,290. 0.1716 0.2970 0.2349 1.264
Propiedades generadas cm el programa GASPROPS, Wiley Professional Software, Wiley, Nueva York, 1984.

666
TABLA E.6 PropIedades del vapor de agua II baJa pmslõn considerado gas ideal. unIdades ea UXS

u. h. SOI , ,
T, "F Btu/lbm BtU/lblIl Btu/(lbm * ‘R) Po 00 Btu,,k - ‘RJ Btu,,in * ‘R) k
50 168.12 224.34 2.4802 0.0582 115,150. 0.4445 0.3342 1.330
71 177.15 236.35 2.4895 0.0610 115,720. 0.4453 0.3350 1.329
100 184.86 246.60 2.4896 0.0634 116,210. 0.4461 0.3358 1.328
200 218.66 29 1.43 2.5595 0.1194 72,654. 0.4507 0.3404 1.324
300 253.00 336.79 2.6584 0.2929 34,120. 0.4568 0.3465 1.318

1,000 515.07 676.08 2.9729 5.068 1 31788.9 0.5152 0.4048 1.272

1,100 556.02 728.06 3.0073 6.9246 2,963.l 0.5245 0.4142 1.266
1,200 597.9 1 780.98 3.0402 9.3293 2,340.3 0.5339 0.4236 1.260

2,000 966.21 1,237.6 3.2639 70.853 456.69 0.6057 0.4954 1.223

2,100 1,016.2 1,298.6 3.2882 88.311 381.30 0.6137 0.5034 1.219
2.200 1.066.9 1.360.3 3.3118 109.45 319.69 0.6213 0.5110 1.216
2;300 1;118.4 (422.8 3.3349 134.89 269.14 0.6286 0.5183 1.213

3,000 (497.1 (878.7 3.4842 522.10 87.172 0.6716 0.5612 1.197

3,200 1,610.3 2,014.O 3.5199 722.06 66.616 0.6814 0.5711 1.193
3,400 1,725.5 2,151.2 3.5564 1,005.o 50.522 0.6904 0.5800 1.190

4,800 2,572.3 3,152.5 3.7774 7,45L¿i Y.Lõ41 lJ.7360 0.625-l 1.176

5,000 2,698.6 3,300,s 3.8049 9,559.l 7.5136 0.7409 0.6306 1.175
Propiedades generadas con el programa GASPROPS, Wiley Professional Software, Wiley, Nueva York, 1984.

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TABLA E.7 PropIedades del blõxido de carbono a bah presb consitiado sas ideal, unldada en UXS

u h so. C,.
T, ‘F- Btu/lbm Btu/lbm Btu/(lbm - ’ R) PO “0 Btu/(lbm * ‘R) Btu,(& * ‘R) k

-300 18.07 25.278 0.9525 0.0145 353,760. 0.1583 0.1131 1.399

-200 30.10 41.823 1.0303 0.08 12 102,820. 0.1632 0.1181 1.382
-100 41.87 58.109 1.0852 0.2741 42,172. 0.1757 0.1305 1.346
0 55.70 76.456 1.1301 0.7400 19.964. 0.1906 0.1454 1.310
77 67.3 I 91.543 1.1604 1.4496 11,898. 0.2017 0.1565 1.289

600 164.67 212.52 1.3157 45.174 753.87 0.2555 0.2103 1.215

700 186.07 238.43 1.3391 75.792 491.72 0.2627 0.2175 1.208
800 208.15 265.03 1.3611 123.36 328.17 0.269 1 0.2240 1.202
900 230.85 292.24 1.3819 195.47 223.55 0.2750 0.2299 1.196
1,000 254.10 320.0 1 1.4016 302.42 155.12 0.2803 0.2352 1.192
;”
5%
i.

v
1,600 402.73 495.73 1.4890 2,096.9 31.568 0.3032 0.2581
1,700 428.69 526.20 1.5166 3,860.g 17.977 0.3060 0.2608 1.173
1,800 454.90 556.93 1.5303 5,235.1 13.872 0.3084 0.2633 1.171
1,900 481.35 587.89 1.5441 7.098.7 10.683 0.3107 0.2656 1.170

2,600 671.60 809.76 1.6262 43,774. 2.2463 0.3221 0.2770 1.163

2,700 699.33 842.00 1.6366 55,083. 1.8435 0.3233 0.2781 1.162
2,800 727.24 874.43 1.6467 68,876. 1.5210 0.3244 0.2793 1.162
2,900 755.34 907.04 1.6565 85,636. 1.2608 0.3255 0.2803 1.161
3000 783.48 939.70 1.666 1 105 844. 1.0505 0.3265 0.2813 1.161

4,200 1,126.2 1,336.6 1.7646 937,850. 0.1597 0.3347 0.2895 1.156

4,400 1,184.3 1,403.7 1.7787 1,280,900. 0.1219 0.3356 0.2905 1.155
4,600 1,242.5 1,470.9 1.7922 1,730,000. 0.0940 0.3365 0.2914 1.155
4,800 1,300.g 1,538.3 1.8053 2,3 10,700. 0.0732 0.3374 0.2922 1.155
5.000 1,359.4 1,605.9 1.8179 3,052,700. 0.0575 0.3382 0.2930 1.154

Propiedades generadas con el programa GASPROPS, Wiley Professional Software, Wiley, Nueva York, 1984.

668