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SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 1
system remains in thermal and Eg: - The expansion of a gas in a
mechanical equilibrium with the metallic cylinder placed in a large
surroundings throughout the process. reservoir of fixed temperature is an
example of isothermal process.
(ii) Isobaric Process Melting of ice at its normal melting
In an isobaric process, pressure is point, vaporization of a liquid at its
constant throughout the process. normal boiling point etc. are other
If heat is applied, the piston moves up. examples.
A part of heat supplied is used
increase the internal energy and the Work done during an isothermal
other part are used to do the work. process
Q U W.
Q nC P T Suppose a system of gas is
C P Molar specific heat capacity expanding from an initial volume V1
at cons tan t pressure. to a final volume V2 during an
isothermal process.
(iii) Isochoric Process
The work done for the small change in
In an isochoric process, volume is
volume ‘dV’ is given by
constant throughout the process.
dW PdV
V 0
The total workdone,
W PV 0
V2
Q U W V1
dW
The heat sup plied is completely V2
Q nC V T nRT
P
C V molar specific heat capacity V
nRTV2
at cons tan t volume. W V1 V dV
V2 1
(iv) Isothermal process nRT dV
V1 V
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 2
x n 1
During an adiabatic process, no We have, x n dx
n 1
heat enters or leaves the system. In an V2
adiabatic process all of the quantities V 1
W k
P, V and T changes. 1 V1
Equations for Adiabatic Process
k V2
Cp V1
PV Constant, = 1 V1
Cv k
1
V21 V11
or TV C ons tan t 1
or P V 1 Cons tan t 1
kV21 kV11
1
Eg: - Sudden burst of an inflated But k P1V1 P2 V2
balloon or a tyre tube, propagation of
1
sound through air. W P2 V2 .V21 P1V1 .V11
1
[During a sudden expansion no intake
1
of heat takes place. So the work for P2 V2 P1V1
the expansion is done using the 1
internal energy of the system. So the but P1 V1 nRT1 and P2 V2 nRT2
internal energy of the system 1
decreases and hence temperature
W nRT2 nRT1
1
decreases. Thus during an adiabatic nR
expansion cooling is produced.] T2 T1
1
nR
Work done during an adiabatic T1 T2
process 1
The work done during an adiabatic nR
change of an ideal gas from the state W T1 T2
1
(P1, V1, T1) to the stateP 2,V2, T2) is
given by, Problem1: Three moles of an ideal
V2 gas kept at a constant temperature of
W dW 300 K are compressed from the
V1
V2 volume of 10 litres to 5 litres.
PdV Calculate the work done to compress
V1
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 3
Problem4: A thermos flask contains
coffee. It is violently shaken.
Considering the coffee as a system
answer the following:
Ans:
Ans:
Ans:
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 4
Problem6: A gas expands
adiabatically so that 50 J of work is
obtained. What is the change in
temperature in the above process if
the working substance is a
monoatomic gas? (R=8.314J/molK)
Ans:
Cyclic Process
In a cyclic process, the system
returns to its initial state.
U 0, for a cyclic process.
Then Q W
Heat Engines:
It consist of:
i. A very hot body of large specific heat
capacity called the source.
ii. A working substance. Eg: a
mixture of fuel vapour and air in a
Problem7: A thermodynamic system
petrol or diesel engine or steam in a
performs work without taking heat
steam engine.
from an external source.
iii. An insulating stand
a) Which process is involved in this iv. A cold body of large specific
case? heat capacity called sink.
b) What is the source of energy for
Schematic representation of a heat
this work?
engine is given below.
c) By what factor does the pressure
of the system decrease if the
volume is doubled (γ=1.4).
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 5
W and other part Q2 is given to the or W = Q1 - Q2
sink.
The coefficient of performance of a
Efficiency of a heat engine () refrigerator
W Q1 Q 2 Q
1 2 Q2 Q2
Q1 Q1 Q1 =
W Q1 Q 2
Q2
1
Q1 A heat pump is a device to pump heat
into a portion of space (room).
For Q 2 0, =1
i.e., 100% efficiency for heat engine, Coefficient of performance of a heat
which is never possible. pump
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 6
Explanation: - This statement says (P2, V2, T1) by absorbing a heat Q1
that the transfer of heat from a cold from the source at T1 K. The work
object to a hot object will not takes done by the gas during this process.
place if no work is supplied. Thus the
coefficient of performance cannot be Step 2 3: Adiabatic expansion
infinite. of the gas from (P2 , V2 , T2 ) to
Reversible and irreversible (P3 ,V3 ,T1 ). Work done bythe gas
processes during this process,
nR
A process is reversible if it can
W23 T1 T2
be reversed such that both the 1
system and surroundings return to
Step 3 4: Isothermal compression
their initial states, with no other
change anywhere else in the of the gas from (P3 ,V3 ,T2 ) to (P4 ,V4 ,T2 ).
universe. Heat released (Q2 ) by the gas during
Spontaneous processes of nature this compression is equal to the work
are irreversible. The idealised done on the system.
reversible process is a quasi –static V
process with no dissipative factors W34 nRT2 log 4 = Q2
such as friction, viscosity etc. V3
Step 4 1: Adiabatic compression of
Carnot engine the gas from (P4 , V4 , T2 ) to (P1 ,V1 ,T1 ).
A reversible heat engine Work done on the gas
nR
operating between two temperatures is W3 4 T2 T1
called a Carnot engine. Nicolas Sadi 1
Carnot introduced this ideal heat The total work done by the gas in
engine whose cycle of operation is one complete cycle,
called Carnot cycle. W = W1 2 W2 3 W3 4 W4 1
V nR
W nRT1 log 2 T1 T2
V1 1
V nR
nRT2 log 4 T2 T1
V3 1
V nR
nRT1 log 2 T1 T2
V1 1
V nR
nRT2 log 3 T1 T2
V4 1
V V3
The operation of the engine is W nRT1 log 2 nRT2 log
V1 V4
completed in four stages:
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 7
The efficiency () of the carnot engine Problem8: a) Which law of
Q
1 2
thermodynamics is used to explain the
Q1 working of a heat engine?
V3
nRT2 log ( ) b) What are the sink, source and
V4
1 (1)
V2 working substance of a domestic
nRT1 log ( )
V1 refrigerator?
Since step 2 3 is an adiabatic process, Ans:
T2 V2 1
T1V2 1 T2 V3 1
T1 V3 1
1
T V
2 2
T1 V3
1
V T
2 ( 2 ) 1 (2)
V3 T1
Similarly step 4 1 is an adiabatic process,
T2 V11
T2 V4 1 T1V11
T1 V4 1
1
T V
2 1
T1 V4
1 Problem9: (a) What is the working
V T 1 substance of an ideal heat engine?
1 2 (3)
V4 T1
From (2) and (3) (b) Calculate the maximum
V1 V2 V V efficiency of a heat engine
or 3 2 (4)
V4 V3 V4 V1 working between steam point
Substituting (4) in (1) and ice point. Can you design
an engine of 100% efficiency?
T2
1
T1 Ans:
Carnot’s Theorem: -
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 8
Problem10: An ideal heat engine
utilizes a perfect gas. The source is at
450 K and sink is at 320 K. If the
engine takes 3600J per cycle from the
source, calculate the efficiency of the
engine.
Ans:
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 9
Problem12: A Carnot engine working
between 5270C and 1270C has a work
output of 800J per cycle. How much
heat is supplied to the engine from the
source per cycle?
Ans:
SAJU K JOHN, M.Sc. Physics, NET, Doctoral Research Fellow at NIT Calicut 10