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Article history: In this work, we report on the analysis of both vibrational and magnetic properties of heavy rare-earth
Received 22 October 2014 molybdates Gd2(Mo0.9W0.1O4)3 and Gd1.8Er0.2(MoO4)3. The crystal structures, as determined by X-ray
Received in revised form powder diffraction and the Rietveld refinement analysis, established that at room temperature both of
31 October 2014
these materials belong to orthorhombic Pba2 space group. Magnetization measurements showed that no
Available online 10 November 2014
saturation is present up to 8 T at T¼ 10 K, and the magnetic susceptibility curves show paramagnetic
Keywords: behavior down to T ¼10 K. The effective magnetic moments and possible short-range magnetic inter-
Molybdates actions between Gd3 þ ions are treated and discussed. Raman spectra of both of these molybdates are
Structure similar to that of the pure compound Gd2(MoO4)3, indicating that changes in the Raman spectra due to
Magnetic properties
the introduction of either Er or W doping are negligible at the subject dopant concentrations.
Vibrational properties
& Elsevier B.V. All rights reserved.
http://dx.doi.org/10.1016/j.jmmm.2014.10.175
0304-8853/& Elsevier B.V. All rights reserved.
L. Bufaiçal et al. / Journal of Magnetism and Magnetic Materials 378 (2015) 50–53 51
Fig. 1. Observed (dots) and calculated by Rietveld method (solid lines) XRD pat-
terns at room temperature.
3. Results and discussion Fig. 2. Magnetic susceptibility and its inverse as a function of temperature for
Gd1.8Er0.2(MoO4)3 (a) and Gd2(Mo0.9W0.1O4)3 (b).
Table 1
Main parameters obtained from the Rietveld refinement.
a
Extracted from [12].
52 L. Bufaiçal et al. / Journal of Magnetism and Magnetic Materials 378 (2015) 50–53
Fig. 4. Un-polarized Raman spectrum of (a) Gd2(MoO4)3, (b) Gd1.8Er0.2(MoO4)3 and (c) Gd2(Mo0.9W0.1O4)3.
L. Bufaiçal et al. / Journal of Magnetism and Magnetic Materials 378 (2015) 50–53 53
three tetrahedra, the MoO4 distances are very close [10], and their The authors are indebted to L.A. Boatner of the Oak Ridge National
wavenumbers are degenerate and correspond to the vibration at Laboratory for providing the samples and a careful reading of the
∼944 cm−1. paper.
4. Conclusions References
We have investigated the magnetic and vibrational properties [1] L.H. Brixner, J.R. Barkley, W. Jeitschko, in: K.A. Gschneider Jr, L. Eyring (Eds.),
of Gd1.8Er0.2(MoO4)3 and Gd2(Mo0.9W0.1O4)3. The XRD data re- Handbook on the Physics and Chemistry of Rare Earths, vol. 30, North-Holland
Publishing Company, Amsterdam, New York and Oxford, 1979.
vealed that both compounds crystallize in an Pba2 orthorhombic [2] B.K. Ponomarev, A. Zhukov, Phys. Res. Int. 2012 (2012) 276348.
structure. Magnetization curves indicate the absence of Ms up to [3] C. Guzmán-Afonso, C. González-Silgo, M.E. Torres, N. Sabalisck, A.D. Lozano-
8 T and magnetic susceptibility measurements showed para- Gorrín, J. González-Platas, E. Matesanz, Mater. Lett. 65 (2011) 2731.
magnetic behavior down to 10 K. The values of μeff for both com- [4] B.K. Ponomarev, S.A. Ivanov, B.S. Red'kin, V.N. Kurlov, Physica B 177 (1992)
327.
pounds were smaller than the expected values for Gd3 þ and Er3 þ , [5] B.K. Ponomarev, A.I. Popov, E. Steep, H. Wiegelmann, A.G.M. Jansen, P. Wyder,
and the differences are associated either to the magnetic aniso- B.S. Red'kin, Phys. Solid State 47 (2005) 1326.
tropy or to short range interactions. The values of θCW at T ∼ 0 K [6] B.K. Ponomarev, B.S. Red'kin, E. Stiep, H. Wiegelmann, A.G.M. Jansen, P. Wyder,
Phys. Solid State 44 (2002) 145.
indicate the occurrence of magnetic ordering at low temperatures, [7] B.K. Ponomarev, S.A. Ivanov, V.D. Negrii, A.P. Zhukov, B.S. Red'kin, V.N. Kurlov,
and positive θCW = 2.7 K for Gd2(Mo0.9W0.1O4)3 may be associated A.K. Zvezdin, Y.F. Popov, Ferroelectrics 151 (1994) 103.
to canted AFM or weak ferrimagnetism closely related to struc- [8] A.C. Larson, R.B. Von Dreele, General Structure Analysis System GSAS, Los
Alamos National Laboratory Report, USA, 2001.
tural symmetry.
[9] B.H. Toby, J. Appl. Cryst. 34 (2001) 210.
Raman measurements showed no modifications in the phonon [10] E.T. Keve, S.C. Abrahams, J.L. Bernstein, J. Chem. Phys. 54 (1971) 7.
distribution when Er replaces Gd and W replaces Mo. Un- [11] D. Logvinovich, A. Arakcheeva, P. Pattison, S. Eliseeva, P. Tomes, I. Marozau,
doubtedly, an assignment was possible only for the ν1 modes. The G. Chapuis, Inorg. Chem. 49 (2010) 1587.
[12] Inorganic Crystal Structure Database (ICSD), Code 9486, Version 2010/1, Fa-
reason why fewer modes are observed than formally predicted is chinformationszentrum Karlsruhe, Germany, 2010.
twofold: (i) some modes have very weak polarizability derivatives [13] R.D. Shannon, Acta Crystallogr. A 32 (1976) 751.
leading to very weak bonds which are not seen, and (ii) the cor- [14] N.W. Ashcroft, N.D. Mermin, Solid State Physics, Saunders College, Orlando,
1976 (Chapter 31).
relation field splittings may be so small that the factor group [15] H.B. Lal, V. Pratap, J. Mater. Sci. 17 (1982) 377.
components are not completely solved. [16] G. Lucazeau, D. Machon, J. Raman Spectrosc. 37 (2006) 189.
Acknowledgments