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Abstract: Rice husk ash (RHA) is classified as a highly reactive pozzolan. It has a very high silica content similar to that of silica
fume (SF). Using less-expensive and locally available RHA as a mineral admixture in concrete brings ample benefits to the costs,
the technical properties of concrete as well as to the environment. An experimental study of the effect of RHA blending on
workability, strength and durability of high performance fine-grained concrete (HPFGC) is presented. The results show that the
addition of RHA to HPFGC improved significantly compressive strength, splitting tensile strength and chloride penetration
resistance. Interestingly, the ratio of compressive strength to splitting tensile strength of HPFGC was lower than that of ordinary
concrete, especially for the concrete made with 20 % RHA. Compressive strength and splitting tensile strength of HPFGC
containing RHA was similar and slightly higher, respectively, than for HPFGC containing SF. Chloride penetration resistance of
HPFGC containing 10–15 % RHA was comparable with that of HPFGC containing 10 % SF.
Keywords: high performance fine-grained concrete, rice husk ash, workability, compressive strength, splitting tensile strength,
chloride penetration resistance.
301
replace SF as a partial Portland cement replacement, and the 2.2 Mixture Proportions
results show that RHA can fully substitute SF in terms of HPFGC mixtures were designed based on the absolute
calcium hydroxide consumption, autogeneous shrinkage, volume of the constituent materials (Béton de sable 1994;
compressive strength and durability of high performance Béton 1995) in which the paste volume was computed from
concrete (Bui 2001; Van et al. 2013; Feng et al. 2004; Le the void content in the sand mixture with mass ratio of
et al. 2012; Salas et al. 2009) and ultra high performance coarse to fine sand of 2.33. This ratio corresponded to the
concrete (Nguyen 2011; Nguyen et al. 2011). However, the mixture with highest granular packing density assessed
effect of RHA on properties of HPFGC needs additional experimentally. Water binder (w/b) ratio was determined
research. according to ACI 211.1 and ACI 363.2R. The designed
The objective of this study is to investigate effects compressive strength of HPFGC was fixed at 60 MPa. In
imposed by RHA blending on properties of HPFGC. this study, six mixtures were designed with a constant w/b
Blending percentages were varied. Slump, compressive and ratio of 0.33, resulting from the binder (cement, RHA)
splitting tensile strength, abrasion resistance and chloride content of 530 kg/m3 and a filler content (RHA?LSP) of
penetration resistance of concrete containing RHA were 150 kg/m3. Herein, RHA acts as a part of the binder and of
evaluated. These properties were assessed for the reference the filler. RHA was incorporated with replacement levels of
and SF containing samples as well. The knowledge obtained 5, 10, 15, and 20 % by weight. One control mixture and one
in this study can be instrumental for optimizing strength and mixture incorporating 10 % SF were prepared for compari-
durability of mortar and concrete in future applications. son purpose. The mixture proportions of HPFGC are shown
in Table 3.
Table 1 Chemical composition and physical properties of cement and mineral admixtures.
Chemical analyses (%) PC40 RHA SF LSP
SiO2 21.29 86.81 96.20 0.17
Al2O3 5.72 0.50 0.70 0.02
Fe2O3 3.30 0.87 0.30 0.04
CaO 63.18 1.04 0.00 54.88
MgO 1.10 0.85 0.10 0.45
Na2O 0.12 0.69 0.06 0.02
K2O 0.30 3.16 0.37 0.04
LOI 0.193 4.6 1.60 43.46
Density (g/cm3) 3.10 2.24 2.26 2.72
Mean particle size (lm) 16.12 8.42 0.29 18.19
Blaine SSA[BET-SSA] 0.369 [23.32] [26.43] 0.321
(m2/g)
LOI loss on ignition.
302 | International Journal of Concrete Structures and Materials (Vol.8, No.4, December 2014)
Table 2 Sieve analysis and physical properties of the fine and coarse sand.
Passing percentage (%)
Fine sand Coarse sand
Sieve size (mm)
4.75 100 100
2.36 100 94.9
1.18 99.7 72.2
0.6 89.1 38.2
0.3 42.9 14.1
0.15 1.1 0.6
Fineness modulus 1.9 2.8
3
Density (g/cm ) 2.6 2.6
Absorption (%) 2.0 1.9
moistened for 24 h. After 1 day, the specimens were de- reported in (Le et al. 2012; Van et al. 2013), RHA is a porous
moulded, and stored in water at 20 ± 2 °C until testing at 3, material with macro and meso-pores inside and on surface of
7, and 28 days. Compressive and splitting tensile strength of the particles resulting in a very large SSA. SF also has a very
concrete were determined in agreement with ASTM C39 and large SSA, significantly larger than that of cement, due to its
ASTM C496, respectively. Chloride penetration resistance very fine particles (Table 1). RHA will absorb a certain
was determined at 28 days in agreement with ASTM C1202. amount of mixing water. Using RHA or SF as replacements
The tests were carried out in triplicate and the average values for cement leads to an increase in SSA of the binder
were reported. Abrasion resistance of HPFGC was deter- (cement ? RHA/SF) thus to a decrease in free water com-
mined at 28 days following Böhme method (CEN 2003). A pared to the mixture made without RHA or SF. Conse-
dried specimen is held in contact with a cast iron disc with a quently, mixtures incorporating RHA or SF had lower
pressure of 0.6 daN/cm2. The disc rotates at 30 ± 1 rpm. For slump. This effect was more pronounced, when a higher
each specimen, the disc runs 140 revolutions. During the content of RHA was used.
process, the specimen is progressively rotated through 90o,
and sand with maximum particle size of 2 mm is spread on 3.2 Compressive Strength and Splitting Tensile
the disc. The abrasion index (g/mm2) is calculated by Strength
dividing the mass loss of each specimen by its abraded area. 3.2.1 Compressive Strength
In Fig. 2, compressive strength of HPFGC containing
RHA/SF and control HPFGC at 3, 7 and 28 days is shown.
3. Results and Discussion Incorporating RHA increased compressive strength of
HPFGC compared to control concrete regardless of ages,
3.1 Workability except for mixture containing 20 % RHA at 3 days. A
Slump data of the fresh concrete are presented in Fig. 1. It highest value of 62.3 MPa was obtained for compressive
can be seen that the control mixture had highest slump strength at 10 % RHA blending, and the lowest value of
compared to mixtures containing RHA and SF. Increasing 54.0 MPa for the control sample. As seen in Fig. 2, the
RHA content resulted in a lower slump of fresh concrete. As optimum content of RHA tended to be higher at later age,
International Journal of Concrete Structures and Materials (Vol.8, No.4, December 2014) | 303
140 diminishes at further maturation because of cement hydra-
tion, and causes a prolonged hydration (Nguyen et al. 2011).
120 The internal curing by RHA could be an important reason
for the improvement of compressive strength at later age of
100 HPFGC containing high RHA content, e.g. the HPFGC
Slump (mm)
10
3.2.2 Splitting Tensile Strength
0 It is found that the trend in splitting tensile strength was
REF 5% RHA 10% RHA 15% RHA 20% RHA 10% SF
almost similar with that of compressive strength (Fig. 3).
Fig. 2 Compressive strength of HPFGC. Generally up to a replacement level of 15 %, splitting tensile
strength of RHA containing HPFGC was higher than that of
i.e. 10 % RHA at 3 days, 15 % RHA at 7 days and 10–20 % the control sample. The highest value of 6.49 MPa was
RHA at 28 days, and may be 15–20 % RHA at later ages, obtained for splitting tensile strength at 10 % RHA
e.g. 56 and 90 days as found in (Le et al. 2012). replacement, and the lowest value of 5.12 MPa was obtained
The positive effect of RHA on compressive strength will for the control sample. HPFGC proportioned with 20 %
be due to the high pozzolanity of RHA resulting from the RHA had lower splitting tensile strength with respect to the
large SSA and the high silica content. RHA reacts inten- control sample. It is well documented that splitting tensile
sively with the water and the calcium hydroxide generated strength is mainly governed by aggregate-paste bond (Nazari
from the hydration of cement to produce additional C–S–H and Riahi 2011; Parra et al. 2011). RHA incorporation
(Bui 2001; Nguyen et al. 2011; Safiuddin et al. 2011). The refined the transition zone between cement matrix and
additional C–S–H itself is the main strength-contributing aggregate, and reduced the amount of large calcium
compound, and also fills in the capillary pores to improve hydroxide crystals and ettringite due to additional C–S–H
the microstructure of the paste matrix and transition zone in phases generated from pozzolanic reaction, as mentioned in
concrete resulting in enhancement of compressive strength. the previous section.
Another reason is that the finer RHA particles can fill the Generally speaking, shrinkage will be stimulated at higher
empty spaces between the cement particles leading to higher cement contents (De Schutter et al. 2008). This may lead to
density of the paste matrix (Safiuddin et al. 2011). Moreover, crack formation along the aggregate-paste interface and, as a
the increase in compressive strength of concrete made with consequence, to a lower tensile splitting strength (Nguyen
RHA at more matured conditions is also due to the internal et al. 2011). As discussed previously, RHA particles absorb a
curing of RHA in the cement paste. RHA with porous certain amount of mixing water into their pores. It has been
structure may absorb free water during mixing leading to proposed that at later age, the absorbed water released from
lower w/b ratios of RHA mixtures. This amount of water is inside of the pores to the surrounding cement matrix will
released from the pores, when the relative humidity in paste cause the relative humidity in the interior not to drop,
304 | International Journal of Concrete Structures and Materials (Vol.8, No.4, December 2014)
resulting in significantly less autogeneous shrinkage due to splitting tensile strength than ordinary concrete at equal
self-desiccation (Nguyen 2011). compressive strength. In this study, sand was used as the
The decrease in splitting tensile strength of 20 % RHA main aggregate, possibly resulting in the reduction in wall
HPFGC compared to the control sample may be due to effect in the cement paste in the vicinity of the aggregate
abundance of RHA particles that can be emphasized as surfaces and the reduction in thickness of the interface
porous micro-aggregate. Those weaken the matrix and hence transition zone (Nguyen 2011; Ollivier et al. 1995). Conse-
reduce the split strength of concrete. quently, the splitting tensile strength of the HPFGC was
Figure 3 also shows that splitting tensile strength of improved.
samples containing 10 and 15 % RHA was comparable with
that of sample containing 10 % SF, irrespective of ages. The 3.3 Mechanical Abrasion Resistance
higher splitting tensile strength of the SF sample compared Abrasion index of HSPC determined at 28 days is shown
to the control sample can also be explained by refinement of in Fig. 4. The higher abrasion index, the lower mechanical
the transition zone due to the pozzolanic and filler effect. abrasion resistance is. The result shows that mechanical
This is consistent with another study (Bhanja and Sengupta abrasion resistance of HPFGC was very high. RHA con-
2005). taining HPFGC had a lower abrasion index, indicating better
abrasion resistance than that of the control sample. The
3.2.3 Ratio of Compressive Strength to Splitting lowest value for the abrasion index of 0.0006 g/mm2 was
Tensile Strength found for the 10 % RHA blend. It is generally known that
In Table 4, the ratio of compressive to splitting tensile compressive strength is one of the most important factors
strength is presented. The ratio of RHA HPFGC was higher influencing the abrasion resistance of concrete (Horszczaruk
than that of the SF sample regardless of the RHA content. 2005). This is supported by the outcomes of this study (see
Only the ratio of HPFGC containing 20 % RHA was higher Figs. 2 and 4). The abrasion index of 10 % SF concrete was
than that of control sample. The highest ratio amounted similar to those of 10 and of 15 % RHA samples. It is
11.10 at a RHA content of 20 %. closely related to the results of compressive strength above.
In this study, the ratio of compressive to splitting tensile
strength of HPFGC was in the range of 9.6–11.0. Whereas 3.4 Chloride Penetration Resistance
the ratio of ordinary concrete is in the range of 10.5–15.2 Charge passed of HPFGC at 28 days is displayed in Fig. 5.
(Shetty 2003). This indicates HPFGC to have higher It can be seen that RHA or SF incorporation substantially
decreased the charge passed of concrete, indicating an
8.0 increase in resistance to chloride penetration. Increasing
3 days 7 days 28 days RHA replacement percentage decreases charge passed. The
7.0
lowest value of charge passed was obtained for 20 % RHA
Splitting tensile strength (MPa)
6.0 sample as 261 coulombs, and the highest value was found for
the control sample as 2,782 coulombs. For concrete mixed
5.0 with 10 % SF, the value of charge passed was also signifi-
cantly lower than that of the control concrete, and similar to
4.0
those of the concretes mixed with 15 and 20 % RHA.
3.0 The chloride penetration resistance of mortar and concrete
is one of the most essential aspects concerning the durability
2.0
of concrete structures. The reinforcement steel bar in con-
1.0 crete starts to corrode due to depassivation, when the chlo-
ride concentration of mortar or concrete exceeds a certain
0.0 threshold (Alonso et al. 2000; Thomas 1996). The incor-
REF 5% RHA 10% RHA 15% RHA 20% RHA 10% SF
poration of a pozzolan is generally accepted to improve the
Fig. 3 Splitting tensile strength of HPFGC. resistance to chloride penetration and reduce the chloride-
International Journal of Concrete Structures and Materials (Vol.8, No.4, December 2014) | 305
0.0010 these properties. Based on the experimental results in the
0.0009 present study, the following conclusions can be drawn.
0.0008 (1) Workability of HPFGC containing RHA decreases at
Abrasion index (g/mm2 )
2000
of the sample containing 10 % SF, irrespective of ages.
(5) Addition of RHA provides a dramatic improvement in
chloride penetration resistance of HPFGC. The
1500
increase in RHA replacement level increases the
chloride penetration resistance. The resistance to
1000
chloride penetration of concretes mixed with 15 and
20 % RHA is similar to that of concrete mixed with
500 10 % SF.
0
REF 5% RHA 10% RHA 15% RHA 20% RHA 10% SF
Acknowledgments
Fig. 5 Chloride penetration of HPFGC.
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