1.

Calculate the mass of 6.022 × 1023 molecule of Calcium carbonate (CaCO3) 29. The density of a particular crystal of LiF is 2.65 g/cc. X-ray analysis shows that
2. Calculate the mass of 12.044 × 1023 carbon atoms. Li+ and F– ions are arranged in a cubic array at a spacing of 2.01 Å. From these data
3. Calculate the number of oxygen atoms in 1 mole of O2. calculate the apparent Avogadro constant. [Li = 6.639u, F = 18.998u (1 Å = 10-
8
4. Calculate the number of Cu atoms in 0.635g of Cu. cm)]
5. Calculate the number of molecules in 11.2 liters of SO2 gas at NTP. 30. To 50 mL of 0.5 M H2SO4, 75 mL of 0.25 M H2SO4 is added. What is the
6. An atom of some element X weighs 6.644 × 10-23 g. Calculate the number of gram- concentration of the final solution if its volume is 125 mL?
atoms in 40 kg of it. 31. It is found that in 11.2 liters of any gaseous compound of phosphorus at NTP, there
7. An atom of some element X weighs 6.644 × 10-23 g. Calculate the number of gram- is never less than 15.5 g of P. Also, this volume of the vapour of phosphorus itself
atoms in 40 kg of it. at NTP weighs 62 g. What should be the atomic mass and molecular mass of the
8. Calculate the volume occupied by 1 mole atom of (i) monoatomic gas, and (ii) phosphorus?
diatomic gas at NTP. 32. A polystyrene, having the formula Br3C6H3(C3H8)n, was prepared by heating
9. Calculate the volume of 20g H2 at NTP. styrene with tribromobenzoyl peroxide in the absence of air. If it was found to
10. What is the volume occupied by 6.022×1023molecules of any gas at NTP? contain 10.46% bromine by weight, find the value of n.
11. the number of atoms in 5.6 liters of a (i) monoatomic, and (ii) diatomic gas at NTP. 33. It has been estimated that 93% of all atoms in the entire universe are hydrogen
12. Calculate the number of sulphate (SO42-) ions in 100 mL of 0.001 M H2SO4 solution. and that the vast majority of those remaining are helium. Based on only these two
13. Calculate the number of atoms in 100 u of He. elements, estimate the mass percentage composition of the universe.
14. If a mole were to contain 1× 1024 particles, what would be the mass of (i) one mole 34. The molecular weight of haemoglobin is about 65,000 g/mol. Haemoglobin
of oxygen, and (ii) a single oxygen molecule? contains 0.35% Fe by mass. How many iron atoms are there in a haemoglobin
15. Calculate the standard molar volume of oxygen gas. The density of O2 gas at NTP molecule?
is 1.429g/L. 35. At room temperature, the density if water is 1.0 g/mL and the density of ethanol
16. Calculate the mass of 1 mole He gas. The density of He gas at NTP is 0.1784g/L. is 0.789g/mL. What volume of ethanol contains the same number of molecules as
17. A metal M of atomic mass 54.94 has a density of 7.42g/cc. Calculate the apparent are present in 175 mL of water?
volume occupied by one atom of the metal. 36. A sample of ethane has the same mass as 10.0 million molecules of methane. How
18. Calculate the number of moles, and number if atoms of H, S, and O in 5 mole of many C 2H 6 molecules does the sample contain?
H2SO4. How many grams of CaWO4 would contain the same mass of tungsten that is
19. Calculate the number of oxygen atoms and its mass in 50 g of CaCO3. present in 569g of FeWO4? (W=184)
20. Calculate the number of atoms of each element in 122.5 g of KClO3. 37. 0.75 mole of solid ‘A4’ and 2 moles of gaseous O2 are heated in a sealed vessel,
21. Calculate the total number of electrons present in 1.6 g of CH4. completely using up the reactants and producing only one compound. It is found
22. Find the charge of 1 g-ion of N3- in Coulombs. that when the temperature is reduced to the initial temperature, the contents of
23. Find the charge of 27 g of Al3+ ions in coulombs. the vessel exhibit a pressure equal to half the original pressure. What conclusions
24. Equal masses of oxygen, hydrogen and methane are taken in a container in can be drawn from these data the product of the reaction?
identical conditions. Find the ratio of the volumes of the gases. 38. Find the number of atoms in 48 g of ozone at NTP.
25. If the components of the air are N2, 78%; O2, 21%; Ar, 0.9% and CO2, 0.1% by 39. What is the ratio of the volumes occupied by 1 mole of O2 and 1 mole of O3 in
volume, what would be the molecular mass of air? identical conditions?
26. The atomic masses of two elements (A and B) are 20 and 40 respectively. x g of A 40. Calculate the mass of 5 moles of CaCO3 in g.
contains y atoms, how many atoms are present in 2x g of B? 41. Calculate the volume occupied by 11.2 g of the gas at NTP. Given that the vapour
27. Oxygen is present in a 1-liter flask at a pressure of 7.6 × 10-10 mm of Hg at 0oC. density of a gas is 11.2.
Calculate the number of oxygen molecules in the flask. 42. Calculate the number of oxygen atoms in 0.2 mole of Na2CO3.10H2O.
28. Calculate approximately the diameter of an atom of mercury, assuming that each 43. Calculate the number of moles of CuSO4 contained in 100mL of 1 M
atom is occupying a cube of edge length equal to the diameter of the mercury CuSO4 solution. Also, find the number of SO4-2 ions in it.
atom. The density of mercury is 13.6 g/cc. 44. Find the total number of nucleons present in 12g of 12C atoms.