Ajuste: mínimos cuadrados

P cmHg P mmhg T °C TK P abs mmHg ln P [y] T^-1 [x] LnP/T [x*y] (1/T)^2 [x^2] Vap Fusión Sublimación

ΔH [mmHg
1 39 390 48 321.15 195 5.273000 0.003114 0.016419117 9.696E-06 m c
*m^3/mol K]
2 36 360 58 331.15 225 5.416100 0.003020 0.016355429 9.119E-06 -2725.47648 45.1537132988 6.3698466E-08
ΔH [mmHg
3 33.2 332 68 341.15 253 5.533389 0.002931 0.016219814 8.592E-06 c *m^3/mol K]
4 29 290 70 343.15 295 5.686975 0.002914 0.016572855 8.492E-06 13.68377 6.1881977E-08
ΔH [mmHg
5 23 239 73 346.15 346 5.846439 0.002889 0.0168899 8.346E-06 *m^3/mol K]
6 19.9 199 75 348.15 386 5.955837 0.002872 0.017107101 8.250E-06 169.96106296
7 17.9 179 80 353.15 406 6.006353 0.002832 0.017007938 8.018E-06
Sumatorias 39.718094 0.020572 0.116572 6.05E-05

6.2

6
f(x) = - 2725.4764798565x + 13.6837732827
R² = 0.8947263097
5.8

5.6
Ln P

5.4
Linear ()
5.2

4.8
0.0028 0.00285 0.0029 0.00295 0.003 0.00305 0.0031 0.00315
T ^1 [K^1]
4.8
0.0028 0.00285 0.0029 0.00295 0.003 0.00305 0.0031 0.00315
T ^1 [K^1]
 Punto triple Temperaturas propuestas para curvas en el diagrama de fases

T P (Sublimación) Curva de Vaporacion (complemento)

P (mm de P (mm de
273.16 607.95 4.58 T (°C) T (K) P (Pa) T (°C) T (K) P (Pa)
Hg) Hg)
[K] [Pa] [mmHg] -50 223.15 4.567057472 35.87226675 0.01 273.16 4.58 607.95

-35 238.15 4.571506005 94.97595959 15 288.15 68.39088823 9317.982774

-20 253.15 4.57543095 224.0564117 20 293.15 80.36392949 10936.68908

-5 268.15 4.578919606 480.1747995 25 298.15 93.92347706 12767.81677

0 273.15 4.579997883 607.6689961 35 308.15 126.3595138 17140.87267

0.01 273.16 4.58 607.95 40 313.15 145.5255488 19720.93283
48 321.15 195 24457.64986

Diagrama de Fases mmHg vs T^-1

450
400
350
300
Presión [mmHg]

Vap exp
250 Sub
200 Vap prop
Punto Triple
150
100
50
0
200 220 240 260 280 300 320 340 360 380
Temperatura [K]
 PRÁCTICA 1
585 77993.5855
P cmHg P mmhg T °C TK P abs mmHg P abs Pa P abs Pa
1 39 390 48 321.15 195 25997.86 26373.66
2 36 360 58 331.15 225 29997.53 30344.43
3 33.2 332 68 341.15 253 33730.56 34050.47
4 29 290 70 343.15 295 39330.10 39609.54
5 23 239 73 346.15 346 46129.54 47551.07
6 19.9 199 75 348.15 386 51462.43 51654.19
7 17.9 179 80 353.15 406 54128.88 54301.36

ln P T^-1
1 5.27299956 0.00311381
2 5.4161004 0.00301978 m -2725.4764799
3 5.53338949 0.00293126 C= 13.684 mmhg
4 5.68697536 0.00291418
5 5.84643878 0.00288892 D H VAP 22659.611454 Pa m3/mol k
6 5.95583737 0.00287233
7 6.00635316 0.00283166 D H sub 28679.611454 Pa m3/mol k

ΔH fusión= 6020

ln P T^-1
10.1801211 0.00311381
10.3203681 0.00301978 m -2706.0668409
10.4355991 0.00293126 C= 18.531 pa
10.5868253 0.00291418
10.7695595 0.00288892 D H VAP 22498.239715 Pa m3/mol k
10.8523266 0.00287233
10.9023046 0.00283166 D H sub 28518.239715 Pa m3/mol k

ΔH fusión= 6020

Punto Triple C H sub 1.5343262265 MM HG

T 273.16 K
P 607.95 Pa C H fusión 1.5243495192
4.58 mmHg
Temperaturas Propuestas

sublimacion vaporacion complemento

T (°C) T (K) P (mm de Hg)P (Pa) T (°C) T (K)
-50 223.15 4.57 35.87 0.01 273.16
-35 238.15 4.57 94.98 15 288.15
-20 253.15 4.58 224.06 20 293.15
-5 268.15 4.58 480.17 25 298.15
0 273.15 4.58 607.67 35 308.15
0.01 273.16 4.58 607.95 40 313.15
48 321.15

Fusión
T (°C) T (K) P (mm de Hg)P (Pa)
-100 173.15 4.57 131.50
-90 183.15 4.57 165.23
-50 223.15 4.58 335.64
-20 253.15 4.58 493.03
-5 268.15 4.58 578.57
0.1 273.25 4.58 608.48
dens Merc 25 13533.6175
6.2

6
f(x) = - 2725.4764798566x + 13.6837732
5.8 R² = 0.8947263097

5.6

5.4

5.2

4.8
0.0028 0.0029 0.003 0.0031

169.961063 mmHg *m^3/mol K C 13.684

215.114776 mmHg *m^3/mol K C 1.5343262265

45.1537133 mmHg *m^3/mol K C 1.5243495192

168.750675 mmHg *m^3/mol K C 18.531

213.904389 mmHg *m^3/mol K C 18.967373013

45.1537133 C 9.0608462853

62.3656 Diagrama de Fases mmHg vs T

19.0384289 450
400
9.06084629 350
300
250
Axis Title
200
150
 450
400
350
300
250
Axis Title
200
150
100
50
on complemento
P (mm de Hg) P (Pa) 0
150 200 250 300 350 400
4.5800 607.95
Axis Title
68.3909 9317.98
80.3639 10936.69
93.9235 12767.82
126.3595 17140.87
145.5255 19720.93 Diagrama de Fases Pa vs T
195.0000 24457.65
60000.00

50000.00

40000.00

Axis Title 30000.00

20000.00

10000.00

0.00
150 200 250 300 350 400
Axis Title
5.4764798566x + 13.6837732827
263097

Column C
Linear (Column C)

0.003 0.0031 0.0032

Fases mmHg vs T

Vap exp
Sub
Vap prop
fusión
Punto Triple
 Vap exp
Sub
Vap prop
fusión
Punto Triple

300 350 400

tle

e Fases Pa vs T

Vap exp
Sub
Vap prop
fusión
Punto Triple

300 350 400

tle