T 25˚C

�_� 1.0069E-14
pKw/2 pCa Ca pH Criterio No.Ec. pCb Cb
6.999 0.5 0.316227766 0.500 3151423.94 1 0.5 0.316227766
6.999 1 0.1 1.000 996567.75 1 1 0.1
6.999 1.5 0.031622777 1.500 315142.39 1 1.5 0.031622777
6.999 2 0.01 2.000 99656.78 1 2 0.01
6.999 2.5 0.003162278 2.500 31514.24 1 2.5 0.003162278
6.999 3 0.001 3.000 9965.68 1 3 0.001
6.999 3.5 0.000316228 3.500 3151.42 1 3.5 0.000316228
6.999 4 0.0001 4.000 996.57 1 4 0.0001
6.999 4.5 3.16228E-05 4.500 315.14 1 4.5 3.162278E-05
6.999 5 0.00001 5.000 99.66 1 5 0.00001
6.999 5.5 3.16228E-06 5.500 31.51 1 5.5 3.162278E-06
6.999 6 0.000001 5.958 9.97 3 6 0.000001
6.999 6.5 3.16228E-07 6.380 3.15 3 6.5 3.162278E-07
6.999 7 0.0000001 6.698 1.00 3 7 0.0000001
6.999 7.5 3.16228E-08 6.880 3.17 3 7.5 3.162278E-08
6.999 8 0.00000001 6.999 10.03 2 8 0.00000001
6.999 8.5 3.16228E-09 6.999 31.73 2 8.5 3.162278E-09
6.999 9 0.000000001 6.999 100.34 2 9 0.000000001

Corrección termodinámica de Van´t Hof

kw/50˚C 5.763423E-14
ln⁡〖� _(𝑤⁡𝑇)⁡ 〗 〖 =ln 〗〖
〖� _(𝑤⁡25˚𝐶)+ 〖∆� ° 〗 _298.15/𝑅∗(1/298.15−1/𝑇) 〗
pkw/50˚C 13.2393195

Correlación Luis Barrera

(𝑝�_𝑤)/2=7.48321213−0.0366544775∗𝑇^0.805
pkw/50˚C 13.25708652
kw/50˚C 5.532399E-14

Ecuación No.1 Criterios

[�^+⁡]_𝑠𝑙𝑛=𝐶_� 𝐶_�/�_𝑤^(1/2)>10
[ 〖��〗 ^−⁡]_𝑠𝑙𝑛=𝐶_� �_𝑤=[�^+⁡]∗[ 〖��〗 ^−⁡]
〖𝑝�〗 _𝑤=𝑝�+𝑝��
Ecuación No.2
[�^+⁡]_𝑠𝑙𝑛=𝐶_�+�_𝑤^(1/2) �_𝑤^(1/2)/𝐶_�>10

[ 〖��〗 ^−⁡]_𝑠𝑙𝑛=𝐶_�+�_𝑤^(1/2)

Ecuación No.3
[�^+⁡]_𝑠𝑙𝑛=�_𝑤^(1/2) 𝐶_�/�_𝑤^(1/2)<10

[ 〖��〗 ^−⁡]_𝑠𝑙𝑛=�_𝑤^(1/2) �_𝑤^(1/2)/𝐶_�<10

 T 50˚C
V.H �_�
pH Criterio No.Ec. pCa Ca pH Criterio No.Ec.
13.500 3151423.94 1 0.5 0.316227766 0.500 1317224.35 1
13.000 996567.75 1 1 0.1 1.000 416542.92 1
12.500 315142.39 1 1.5 0.031622777 1.500 131722.44 1
12.000 99656.78 1 2 0.01 2.000 41654.29 1
11.500 31514.24 1 2.5 0.003162278 2.500 13172.24 1
11.000 9965.68 1 3 0.001 3.000 4165.43 1
10.500 3151.42 1 3.5 0.000316228 3.500 1317.22 1
10.000 996.57 1 4 0.0001 4.000 416.54 1
9.500 315.14 1 4.5 3.16228E-05 4.500 131.72 1
9.000 99.66 1 5 0.00001 5.000 41.65 1
8.500 31.51 1 5.5 3.16228E-06 5.500 13.17 1
8.042 9.97 3 6 0.000001 5.907 4.17 3
7.620 3.15 3 6.5 3.16228E-07 6.255 1.32 3
7.302 1.00 3 7 0.0000001 6.468 2.40 3
7.120 3.17 3 7.5 3.16228E-08 6.566 7.59 3
7.001 10.03 2 8 0.00000001 6.620 24.01 2
7.001 31.73 2 8.5 3.16228E-09 6.620 75.92 2
7.001 100.34 2 9 0.000000001 6.620 240.07 2

Diagrama de Flood pH vs pC a 25˚C

14.0 14.0

12.0 12.0

10.0 10.0

8.0 8.0
pCa
pCb
pH

6.0 pKw/2 pH 6.0

4.0 4.0

2.0 2.0

0.0 0.0
0 1 2 3 4 5 6 7 8 9 10 0
pC
 T 50˚C
5.76342300798648E-14 L.B
pCb Cb pH Criterio No.Ec. pKw/2 pCa Ca
0.5 0.316227766 12.739 1317224.35 1 6.6197 0.5 0.316227766
1 0.1 12.239 416542.92 1 6.6197 1 0.1
1.5 0.031622777 11.739 131722.44 1 6.6197 1.5 0.031622777
2 0.01 11.239 41654.29 1 6.6197 2 0.01
2.5 0.003162278 10.739 13172.24 1 6.6197 2.5 0.003162278
3 0.001 10.239 4165.43 1 6.6197 3 0.001
3.5 0.000316228 9.739 1317.22 1 6.6197 3.5 0.000316228
4 0.0001 9.239 416.54 1 6.6197 4 0.0001
4.5 3.16228E-05 8.739 131.72 1 6.6197 4.5 3.16228E-05
5 0.00001 8.239 41.65 1 6.6197 5 0.00001
5.5 3.16228E-06 7.739 13.17 1 6.6197 5.5 3.16228E-06
6 0.000001 7.333 4.17 3 6.6197 6 0.000001
6.5 3.16228E-07 6.985 1.32 3 6.6197 6.5 3.16228E-07
7 0.0000001 6.771 2.40 3 6.6197 7 0.0000001
7.5 3.16228E-08 6.673 7.59 3 6.6197 7.5 3.16228E-08
8 0.00000001 6.620 24.01 2 6.6197 8 0.00000001
8.5 3.16228E-09 6.620 75.92 2 6.6197 8.5 3.16228E-09
9 0.000000001 6.620 240.07 2 6.6197 9 0.000000001

Diagrama de Flood pH vs pC a 50˚C (V.H.) D

14.0 14.0

12.0 12.0

10.0 10.0

8.0 8.0
pCa
pCb
pH

pH

6.0 pKw/2 6.0

4.0 4.0

2.0 2.0

0.0 0.0
0 1 2 3 4 5 6 7 8 9 10 0 1
pC
 T 50˚C
L.B �_� 5.5323988640696E-14
pH Criterio No.Ec. pCb Cb pH Criterio No.Ec.
0.500 1344445.67 1 0.5 0.316227766 12.757 1344445.67 1
1.000 425151.05 1 1 0.1 12.257 425151.05 1
1.500 134444.57 1 1.5 0.031622777 11.757 134444.57 1
2.000 42515.11 1 2 0.01 11.257 42515.11 1
2.500 13444.46 1 2.5 0.003162278 10.757 13444.46 1
3.000 4251.51 1 3 0.001 10.257 4251.51 1
3.500 1344.45 1 3.5 0.000316228 9.757 1344.45 1
4.000 425.15 1 4 0.0001 9.257 425.15 1
4.500 134.44 1 4.5 3.16228E-05 8.757 134.44 1
5.000 42.52 1 5 0.00001 8.257 42.52 1
5.500 13.44 1 5.5 3.16228E-06 7.757 13.44 1
5.908 4.25 3 6 0.000001 7.349 4.25 3
6.259 1.34 3 6.5 3.16228E-07 6.999 1.34 3
6.475 2.35 3 7 0.0000001 6.782 2.35 3
6.574 7.44 3 7.5 3.16228E-08 6.683 7.44 3
6.629 23.52 2 8 0.00000001 6.629 23.52 2
6.629 74.38 2 8.5 3.16228E-09 6.629 74.38 2
6.629 235.21 2 9 0.000000001 6.629 235.21 2

Diagrama de Flood pH vs pC a 50˚C (L.B.)

14.0

12.0

10.0

8.0
pCa
pCb
pH

6.0 pKw/2

4.0

2.0

0.0
0 1 2 3 4 5 6 7 8 9 10

pC
pKw/2
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285
6.6285