Spectrum Peak Pick Report 23/01/2019 15:28:51

Data Set: File_190123_ukom ida - RawData

0,1989

1
0,1500

0,1000
Abs.

0,0500

0,0000

-0,0181
450,00 500,00 550,00 600,00 650,00
nm.
[Measurement Properties] No. P/V Wavelength Abs. Description
Wavelength Range (nm.): 450,00 to 650,00 1 540,00 0,1808
Scan Speed: Fast
Sampling Interval: 2,0
Auto Sampling Interval: Disabled
Scan Mode: Single

[Instrument Properties]
Instrument Type: UV-1800 Series
Measuring Mode: Absorbance
Slit Width: 1,0 nm
Light Source Change Wavelength: 340,0 nm
S/R Exchange: Normal

[Attachment Properties]
Attachment: None

[Operation]
Threshold: 0,0010000
Points: 4
InterPolate: Disabled
Average: Disabled

[Sample Preparation Properties]

Weight:
Volume:
Dilution:
Path Length:
Additional Information:

Page 1 / 1
 Standard Table Report 23/01/2019 15:29:16

File Name:C:\Program Files\Shimadzu\UVProbe\Data\Data Pengujian\2019\Nitrit\1.

Januari\File_190123_ukom ida.pho
Standard Curve
0,3265

0,3000

0,2000
Abs.

0,1000

0,0000

-0,0297
0,0000 0,0200 0,0400 0,0600 0,0800 0,1002
Conc. (mg/l)
y = 2,96131 x + 0,00036
Correlation Coefficient r2 = 0,99989

Standard Table
Sample ID Type Ex Conc WL540,0 Wgt.Factor Comments
1 STD 1 Std-Repeat 0,0000 -0,0001 1,0000
2 STD 1-2 Std-Repeat 0,0000 -0,0000 1,0000
3 STD 1-Avg Average 0,0000 -0,0001 1,0000 Avg of preceding 2 Samples
4 STD 2 Std-Repeat 0,0040 0,0120 1,0000
5 STD 2-2 Std-Repeat 0,0040 0,0119 1,0000
6 STD 2-Avg Average 0,0040 0,0119 1,0000 Avg of preceding 2 Samples
7 STD 3 Std-Repeat 0,0150 0,0445 1,0000
8 STD 3-2 Std-Repeat 0,0150 0,0444 1,0000
9 STD 3-Avg Average 0,0150 0,0445 1,0000 Avg of preceding 2 Samples
10 STD 4 Std-Repeat 0,0301 0,0895 1,0000
11 STD 4-2 Std-Repeat 0,0301 0,0896 1,0000
12 STD 4-Avg Average 0,0301 0,0895 1,0000 Avg of preceding 2 Samples
13 STD 5 Std-Repeat 0,0601 0,1805 1,0000
14 STD 5-2 Std-Repeat 0,0601 0,1806 1,0000
15 STD 5-Avg Average 0,0601 0,1806 1,0000 Avg of preceding 2 Samples
16 STD 6 Std-Repeat 0,1002 0,2958 1,0000
17 STD 6-2 Std-Repeat 0,1002 0,2958 1,0000
18 STD 6-Avg Average 0,1002 0,2958 1,0000 Avg of preceding 2 Samples

Page 1 / 2
 Standard Table Report 23/01/2019 15:29:16

File Name:C:\Program Files\Shimadzu\UVProbe\Data\Data Pengujian\2019\Nitrit\1.

Januari\File_190123_ukom ida.pho
Standard Curve
0,3265

0,3000

0,2000
Abs.

0,1000

0,0000

-0,0297
0,0000 0,0200 0,0400 0,0600 0,0800 0,1002
Conc. (mg/l)
y = 2,96131 x + 0,00036
Correlation Coefficient r2 = 0,99989

Standard Table
Sample ID Type Ex Conc WL540,0 Wgt.Factor Comments
19

Page 2 / 2
 Sample Table Report 23/01/2019 15:29:23

File Name: C:\Program Files\Shimadzu\UVProbe\Data\Data Pengujian\2019\Nitrit\1.

Januari\File_190123_ukom ida.pho
Sample Graph
0,0673

0,0600

0,0400
Conc. (mg/l)

0,0200

0,0000

-0,0068
3 5 10 15 20 21
Sequence No.
Sample Table
Sample ID Type Ex Conc WL540,0 Comments
1 BM Unk-Repeat -0,0011
2 BM-2 Unk-Repeat -0,0011
3 BM-Avg Average -0,0005 -0,0011 conc = <MDL (0,004 mg/L)
4 LFB Unk-Repeat 0,0441
5 LFB-2 Unk-Repeat 0,0441
6 LFB-Avg Average 0,0148 0,0441 %LFB = (0,0148/0,0150)*100%= 98,67%
7 CV Unk-Repeat 0,1807
8 CV-2 Unk-Repeat 0,1808
9 CV-Avg Average 0,0609 0,1807 %CV= (0,0609/0,0601)*100% = 101,33 %
10 Sampel sumur Unk-Repeat -0,0014
11 Sampel sumur-2 Unk-Repeat -0,0014
12 Sampel sumur-Avg Average -0,0006 -0,0014 conc = <LoQ (0.015 mg/L)
13 Sampel A Unk-Repeat 0,0878 % = (0,0295/0,0301) * 100 % = 98,01 %
14 Sampel A-2 Unk-Repeat 0,0878 % = (0,0293/0,0301)*100% = 97,34%
15 Sampel A-Avg Average 0,0295 0,0878 % rata-rata = 97,68%
16 Sampel B Unk-Repeat 0,0872 Selisih = 0,0002 mg/L
17 Sampel B-2 Unk-Repeat 0,0872 Rata-rata = 0,0294 mg/L
18 Sampel B-Avg Average 0,0293 0,0872 %RPD = 0,68%

Page 1 / 2
 Sample Table Report 23/01/2019 15:29:23

File Name: C:\Program Files\Shimadzu\UVProbe\Data\Data Pengujian\2019\Nitrit\1.

Januari\File_190123_ukom ida.pho
Sample Graph
0,0673

0,0600

0,0400
Conc. (mg/l)

0,0200

0,0000

-0,0068
3 5 10 15 20 21
Sequence No.
Sample Table
Sample ID Type Ex Conc WL540,0 Comments
19 CV 2 Unk-Repeat 0,1815
20 CV 2-2 Unk-Repeat 0,1815
21 CV 2-Avg Average 0,0612 0,1815 %CV = (0,0612/0,0601)*100% = 101,83%
22

Page 2 / 2
 REKAMAN HASIL PENGUJIAN NITRIT

Tanggal Pengujian : 23/01/2019

I. Kenormalan Larutan Na2C2O4 (E)

_Na2C2O4 =( × ×1000)/( × ( )))

gram Berat
Purity Volume (mL) N Na2C2O4 (E)
Na2C2O4 Equivalen
1,6770 0,9987 66,9995 500 0,0500

II. Penentuan Normalitas KMnO4 (C)

〖 〗_4= /(( − )×0,067)

gram Volume KMnO4 (mL)

N KMnO4 (C)
Na2C2O4 awal akhir Terpakai Rata-rata
0,00 29,40 29,40
0,100 A 29,40
0,00 29,40 29,40 0,0508
0,00 B 0,00 0,00 0,00 0,00
III. Standardisasi Larutan Induk Nitrit (A)

Volume Larutan Kadar Larutan

Volume KMnO4 (B mL) Volume Total (D
Induk yang Induk (A) Na-
mL) Na2C2O4
awal akhir Terpakai Rata-rata dititar (F mL) NO2
0,00 4,90 54,90
54,90 20 50 251
0,00 4,90 54,90

Konsentrasi Larutan Kerja Nitrit (NO2-N)

N1 x V1 = N2 x V2
251 x 4 = N2 x 100 N2 = 10,0240 mg/L
10,0240 x 10 = N2 x 100 N2 = 1,0024 mg/L
10,0240 x 4 = N2 x 100 N2 = 0,4010 mg/L
10,0240 x 3 = N2 x 100 N2 = 0,3007 mg/L
10,0240 x 2 = N2 x 100 N2 = 0,2005 mg/L
10,0240 x 1 = N2 x 100 N2 = 0,1002 mg/L
1,0024 x 6 = N2 x 100 N2 = 0,0601 mg/L
1,0024 x 3 = N2 x 100 N2 = 0,0301 mg/L
1,0024 x 2 = N2 x 100 N2 = 0,0200 mg/L
0,3007 x 5 = N2 x 100 N2 = 0,0150 mg/L
0,2005 x 2 = N2 x 100 N2 = 0,0040 mg/L

FR-14.1-PVM-D, R:0, Halaman: 1 dari 1