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Tony Venelinov
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The experimental design was set up in a way so that the ISO11352:2012 focuses in the field of water analysis and
repeatability, reproducibility and trueness estimates are specifies methods for the measurement uncertainty
used for measurement uncertainty estimation. Trueness estimation of chemical and physicochemical methods in
was proven by measurement of three independent single laboratories based on validation data and
samples of a certified reference material on two different analytical quality control results. Experimental design
days. From these data the uncertainty of trueness and was set up in such a way that the uncertainty
method bias were calculated: components for the within-laboratory reproducibility,
s t2 ∑ u mat uRw, and the uncertainty component from method and
2
st
ut = = + 2 laboratory bias, ub, form the basis for the estimation of
nt nt nmat the measurement uncertainty:
Repeatability and intermediate precision were determined uRw = sRw
by replicate analysis and assessment of between-day 2
s
effects. This was achieved by preparation of three ub = b + b
2 + u Cref
2
e-mail: tvenelinov_fhe@uacg.bg