Overview of the tests methods used for water determination in and
factors affecting their precision and accuracy. Crude is mixed with water immiscible solvent (xylene).The mixture is boiled (refluxed) forcing water and solvent overhead Condenser condenses solvent and water into trap .Trap returns solvent to crude while retaining water. This test method covers the determination of water in volume in and other bituminous materials by the ,petroleum products, tars. distillation method. NOTE 1—Volatile water-soluble material, if present, may be measured as water. The specific products considered during the develop NOTE —With some types of oil, satisfactory results may be obtained. The values stated in SI units are to be regarded as the standard. The values in parentheses are for information only. This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate. safety and health practices and determine the application- ability of regulatory limitations prior to use. For specific hazard statements, see Section . The material to be tested is heated under reflux with a water-immiscible solvent, which co-distills with the water in the sample. Condensed solvent and water are continuously separated in a trap, the water settling in the graduated section of the trap and the solvent returning to the still. Objective:
1-To separate water from crude oil .
2- To know how to use distillation to separate water in crude oil. 3- to find the percentage of water in sample of crude oil .
Apparatus & Materials:
The apparatus, shown in Fig. 1, consists of 1-A glass distillation flask —a 1000-mL (or 500ml) round-bottom, glass, distillation flask 2-A 5-mL calibrated, graduated water trap with 0.05-mL graduations connected to the distillation flask. 3-A 400-mm condenser fitted with the Trap. 4-A drying tube filled with desiccant (to prevent entrance of atmospheric moisture) is placed on top of the condenser. 5-An electric heating mantle that can uniformly distribute heat to the entire lower half of the flask. 6-Solvent: different solvents can be used Toluene, xylene or a mixture of both or naphtha. The solvent is miscible with oil but immiscible with water. 7- A sample of crude oil. Procedure: 1-Measure (100 ml) of the crude oil sample in a graduated cylinder and transfer it to the distillation flask . 2-Add 100 ml solvent to the flask in three stages 50 ml, 25ml and 25ml using the graduated cylinder of step one (total solvent volume 100 )ml). 3-Use glass beads or other boiling aids to reduce bumping distillation Flask. 4-Assemble the apparatus making sure all connections are vapor and liquid-tight 5-Insert a drying tube containing an indicating desiccant into the end the condenser to prevent condensation of atmospheric moisture of inside.