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FIITJEE COMMON TEST

PHYSICS, CHEMISTRY & MATHEMATICS


BATCHES – Two Year CRP (1820) C-LOT
CPT3-1 PH-III CODE : SET-A PAPER - 1
Time Allotted: 3 Hours Maximum Marks: 234
 Please read the instructions carefully. You are allotted 5 minutes
specifically for this purpose.
 You are not allowed to leave the Examination Hall before the end of
the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the
answer OMR sheet before attempting the paper. Wrong CODE or no CODE will
give wrong results.
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Three Parts: Part A, B & C.
5. Rough spaces are provided for rough work inside the question paper. No additional
sheets will be provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers
and electronic devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking
your answers on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen
for each character of your Enrolment No. and write in ink your Name, Test Centre
and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.
(i) PART-A (01 – 10) contains 10 multiple choice questions which have One or more
than one correct answer. Each question carries +3 marks for correct answer.
There is no negative marking
(iii) PART-B (01 – 02) contains 2 Matrix Match Type questions containing statements
given in 2 columns. Statements in the first column have to be matched with
statements in the second column. Each question carries +8 marks for all correct
answer. For each correct row +2 marks will be awarded and – 1 mark for wrong
answer. There may be one or more than one correct choice. No marks will be
given for any wrong match in any question.
(ii) PART-C (01 – 08) contains 08 Numerical based questions with single digit integer
as answer, ranging from 0 to 9 (both inclusive) and each question carries +4 marks
for correct answer and – 2 mark for wrong answer.

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Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

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Useful Data

PHYSICS

Acceleration due to gravity g = 10 m / s2

Planck constant h = 6.6 × 10–34 J-s

Charge of electron e = 1.6 × 10–19C

Mass of electron me = 9.1 × 10–31 kg

Permittivity of free space 0 = 8.85 × 10–12 C2/N-m2

Density of water water = 103 kg/m3

Atmospheric pressure Pa = 105 N/m2

Gas constant R = 8.314 J K–1 mol–1

CHEMISTRY

Gas Constant R = 8.314 J K1 mol1


= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J

Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13,
Si = 14, P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27,
Ni=28, Cu=29, Zn=30, As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54,
Ba = 56, Pb = 82, U = 92, V = 50.

Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23,
Mg=24, Al=27, Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131,
Ba = 137, Pb = 207, U = 238.

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SECTION-I : PHYSICS
PART-A : One or More Than One Options Correct Type
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. A body of mass m is attached to a spring of spring constant k which hangs from the ceiling
of an elevator at rest in equilibrium. Now the elevator starts accelerating upwards with its
acceleration varying with time as a  pt  q, where p and q are positive constants. In the
frame of elevator
(A) the block will perform SHM for all value of p and q
(B) the block will not performs SHM in general for all value of p and q expect p = 0
(C) the block will perform SHM provided for all value of p and q expect p = 0
(D) the velocity of the block will vary simple harmonically for all value of p and q.

2. One mole of a gas is subjected to two processes AB and BC, one


after the other as shown in the figure. BC is represented by PV =
constant.
We can conclude that (where T = temperature, W = work done by
gas, V = volume and U = internal energy).
(A) TA = TB = TC (B) VA < VB, PB < PC
(C) W AB > W BC (D) TA < TB

3. For any monoatomic gas the quantities independent of the nature of the gas at the same
temperature is/are :
(A) The number of molecules in one mole
(B) The number of molecules in equal volume and pressure
(C) The translational kinetic energy of one mole
(D) The kinetic energy of unit mass
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4. An ideal gas under goes a thermodynamic cycle as shown in


figure. Which of the following graphs represents the same
cycle ?

(A) (B)

(C) (D)

5. At a certain moment, the photograph of a string on which a


harmonic wave is travelling to the right is shown. Then, which of
the following is true regarding the velocities of the points P, Q
and R on the string.

(A) vP is upwards (B) vQ = – vR

(C) | vP | > | vQ | = | vR | (D) vQ = vR

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6. A car moves towards a hill with speed vc . It blows a horn of frequency f which is heared by an
observer following the car with speed v0 . The speed of sound in air is v.
v
(A) the wavelength of sound reaching the hill is
f

(B) the wavelength of sound reaching the hill is v  vc


f

(C) the beat frequency observed by the observer is  v  v0  f


 
 v  vc 

2 vc v  v0  f
(D) the beat frequency observed by the observer is
v 2  vc2

7. A metal wire of length L, area of cross-section A and Young’s modulus Y is stretched by a


variable force F such that F is always slightly greater than the elastic forces of resistance in
the wire. When the elongation of the wire is l
YAl 2
(A) the work done by F is
L
YAl 2
(B) the work done by F is
2L
YAl 2
(C) the elastic potential energy stored in the wire is
2L
(D) heat is produced during the elongation

8. A metallic wire of length l is held between two rigid supports. If the wire is cooled through a
temperature t. (T = Young’s modulus of elasticity of wire,   density,   thermal
coefficient of linear expansion). Then, the frequency of oscillation is proportional to
1 
(A) (B) Y (C) (D) t
l 

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9. A particle is suspended by two ideal strings as shown in the 7l


figure. Now mass m is given a small displacement
perpendicular to the plane of triangle formed. Choose the
correct statement(s).
5l
3 3l 3 2l
(A) The period of oscillation of the system is 2
g
M
3l
(B) The period of oscillation of the system is 2
g
(C) The period of oscillation of the system is independent of
M
(D) If the distance between the suspension points was kept
constant and the length of the strings were quadrupled then
the period of the system will be double

10. An open organ pipe of length L vibrates in its fundamental mode. The pressure variation is
maximum
(A) At the two ends (B) At the middle of Pipe
L L
(C) At distance inside the ends (D) At distance inside the ends
4 8

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PART - B : Matrix-Match Type Questions


This Section contains 2 Matrix Match Type Questions. Each question has p q r s t

four statements (A, B, C and D) given in Column I and five statements (p, q, A p q r s t

r, s and t) in Column II. Any given statement in Column I can have correct B p q r s t

matching with ONE or MORE statement(s) given in Column II. For example, if C p q r s t

for a given question, statement B matches with the statements given in q and r, D p q r s t
then for the particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.

1. For a simple harmonic wave y  2cm  sin 3t  4 x  when y and x in m, t in second.

Column-I
Column-II
(processes for ideal monoatomic
(Corresponding effects)
gas)
(A) Particle at x  0 and at t  0 is (p) Moving downwards

(B) Particle at x  and at t  0 is (q) Moving upwards
8

(C) Particle at x  0 and t  s is (r) Accelerated upwards
3
 
Particle at x  cm and at t  s
(D) 8 3 (s) Accelerated downwards
is

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2. A copper rod (initially at room


temperature 20°C) of non-uniform
cross section is placed between a
steam chamber at 100°C and ice
water chamber at 0°C. A and B are
cross sections as shown in figure.
Then match the statements in column
I with results in column II comparing
only between cross section A and B.
(The mathematical expressions in
Column I have their usual meanings in
heat transfer).
Column-I Column-II
 dQ  maximum at section A
(A) Initially rate of heat flow   will be (p)
 dt 

 dQ  maximum at section B
(B) At steady state rate of heat flow   will be (q)
 dt 

 dT  minimum at section B
(C) At steady state temperature gradient   will be (r)
 dx 

 dT  same for all section


At steady state rate of change of temperature  
(D)  dt  (s)
will be

PART – C : Single digit integer


This section contains 8 questions. The answer to each question is a single digit integer ranging
from 0 to 9 (both inclusive).

1. A point source of sound emits a constant power with intensity inversely proportional to the
square of the distance from the source. By how many decibels does the sound intensity
level drop when you move from point P1 to P2 . Distance of P2 from the source is two times
the distance of source from P1 .
2. A solid copper sphere (density and specific heat C) of radius r at an initial temperature
200 K is suspended inside a chamber whose walls are almost at 0 k. the time required for
x rc
the temperature of sphere to drop to 100 K is found to be  106 sec. The value of x is.
72 

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3. A container, closed by freely moving piston contains a mixture of hydrogen and


helium gas of total mass = 180 g. A heat of Q = 156 KJ is transferred to the gas
at constant pressure. Due to this gas performs 56 KJ of work. Determine the
ratio of mass of helium to hydrogen

4. The vibrations from an 800 Hz tuning fork set up standing waves in a string clamped at both
ends. The wave speed in the string is known to be 400 ms-1 for the tension used. The
standing wave is observed to have four antinodes. Calculate the length of the string in
metre.
5. Third overtone of a closed organ pipe of length 7 cm is in unison with fourth harmonic of an
open organ pipe. Find the length of open organ pipe, in cm.

6. The angular frequency of oscillation of the rolling disc of


mass m connected with a spring of stiffness k at its centre
k
m
Xk
is   . Find X .
3m

7. Two identical springs each of stiffness k are welded at a point P.


If a particle of mass m is welded at P. The period of oscillation of k
 Ym  P
the particle in the direction of x is . Find Y x
sin  k  m
k

8. The pressure of an ideal gas varies according to the law P = P0 – AV2 where P0 and A are
positive constants. The highest temperature that can be attained by the gas is.
6P0P0
Tmax  4
The value of x is.
x mR A
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SECTIONII: CHEMISTRY
PART-A : One or More Than One Options Correct Type
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. Presence of unsaturation can be tested in organic compounds with


(A) Bromine water (B) Baeyer’s reagent
(C) Tollen’s reagent (D) Grignard reagent

2. Which of the following is/are correct for SN1 reaction?


(A) The reaction intermediate is carbanion
(B) In this reaction complete inversion takes place
(C) It is favoured by polar solvents.
(D) Rate of reaction directly depends on the stability of carbocation.

3. Correct order of stability of following species is

(I) (II) (III) O (IV)


O O
(A) I > II > III > IV (B) I < II < III < IV
(C) I > II > IV > III (D) III > I > II > IV

4. Correct order of basicity of following compounds is

(I) N (II) (III)


N N
H
(A) I > II > III (B) III > I > II
(C) III > II > I (D) II > III > I

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5. Which of the following molecules is/are containing stereogenic centre(s)?


(A) Cyclopent-2- en- 1- ol (B) Cyclopent-3- en- 1- ol
(C) 2-Bromopentane (D) But-2-ene

6. Br Br Cl H CH
H H H CH 3
3
H H Br Br H
Br
CH3 H H H H
Br Cl H Br
H Br H Br H Br H
H Cl H H Cl H
H H
CH3 Cl CH3
 A  B C   D E
Which of the following is correct?
(A) A & B are non mirror images stereoisomers (B) A & C are enantiomers
(C) D & A are non superimposable mirror image (D) A & E are diastereomers

7. Which of the following reaction produces the same product?


Br2 / hv Na / ether 
(A) C H 
3 8  
(B) NaOH Electrolysis
COOH    
(C) Mg / ether CH Br
   3 
Br
COOH
(D) Red P HI 


8. Which of the following statements are correct for the following compounds when they are
treated with Lindlar’s catalyst  D2 / Pd  BaSO4  & Na / liq. NH 3 (Birch reduction?)
(I) CH 3  CH 2  C  CD (II) CH 3  CHD  C  CH
(III) CH 3  C  C  CH 2 D (IV) CH 2 D  CH 2  C  CH
(A) (I) can give trans isomers and not cis isomers
(B) (II) can give cis isomers but not trans isomers
(C) (III) can give both cis & trans isomers
(D) (IV) can give both cis & trans isomers
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9. The major product(s) formed in the reaction is/are

Conc.HNO  H SO
3 2 4
  Product(s)

(A) (B) (C) (D)

10. The gas(es) involved in the formation of photochemical smog is/are


(A) CO2 (B) SO2
(C) NO (D) hydrocarbons
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PARTB: Matrix-Match Type Questions


This Section contains 2 Matrix Match Type Questions. Each question p q r s t

has four statements (A, B, C and D) given in Column I and five A p q r s t

statements (p, q, r, s and t) in Column II. Any given statement in B p q r s t


Column I can have correct matching with ONE or MORE statement(s) C p q r s t
given in Column II. For example, if for a given question, statement B
D p q r s t
matches with the statements given in q and r, then for the particular
question, against statement B, darken the bubbles corresponding to q
and r in the ORS.
1. Match the following
Column – I Column – II
A) CH 3 COONa  2 mole  H 2O
Eleecholysis
 p) Moles of gaseous product = 1

B) HCOONa  2 mole  H 2O


Elecholysis
 q) Moles of CO2 gas = 2

C) CH 3COONa 1 mole  


NaOH / CaO

r) Moles of gaseous product = 4

D) HCOONa 1 mole  


NaOH / CaO

s) Moles of H 2 gas = 1

2. Match the following


Column – I Column – II
Me H Carbocation is formed during
H2O reaction
Me C C CH2 
A) H p)
H

H H Rearrangement is involved in
1 B2 H6 ,THF proceeding of reaction by breaking of
Me C C CH2  
B) (2) H2O2 , OH  q) sigma bonds
Me

Me H Reaction is initiated by attack of


1 CH3COO 2 Hg / H2O.THF electrophile.
Me C C CH2 
C)  2 NaBH4 / OH  r)
H

H H Reaction is direct or indirect


D) HBr s) hydration of alkenes.
H2C C C CH2  
1 eq.

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PART–C: Single digit integer


This section contains 8 questions. The answer to each question is a single digit integer ranging
from 0 to 9 (both inclusive).

1. CH3
Cl 2 / hv
CH3CH2 CH CH2CH3   Product(s)
(A)
Total number of products formed by monochlorination of (A) is

2. Find out number of compounds which are more acidic than benzoic acid, from following.

COOH COOH COOH COOH


O

H C OH , H 2 C 2 O 4 , , , , H 2 CO 3 , CCl 3 COOH
,

CH 3 NO 2 N(CH 3 ) 2 CF 3

3. Examine the structural formula shown below and find out how many compounds undergo
electrophilic nitration more rapidly than fluorobenzene?

4. The total number of isomeric alkenes, that can be hydrogenated to form 2-methylpentane,

is……

5. How many of the following on reductive ozonolysis will give only glyoxal?

Ethene, ethyne, benzene, o-xylene, 1,3-butadiene, m-xylene, p-xylene,

cyclobuta -1,3-diene, cyclooctatetraene

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6. How many of the following can exhibit tautomerism?

O
NO2
NH

, , , ,

O O NH

CHO
O O

, , CH3NO , , HCHO
O
O

CH3COCH2COOC2H5

7. An aromatic hydrocarbon having molecular formula C16H16 shows following reactions


(i) It decolourise both Br2/CCl4 and cold alkaline KMnO4
(ii) Oxidation with hot KMnO4 gives dicarboxylic acid. C6H4(COOH)2 which upon treatment
with Br2/Fe gives only one monobromo substitution product.
Total number of benzylic hydrogen atoms in the given hydrocarbon is…..

8. O-
A=

Total number of resonance structures of ( A) is .....

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SECTION-III : MATHEMATICS
PART-A : One or More Than One Options Correct Type
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.

1. The number of selection of four letters taken from the word COLLEGE must be
(A) 22
(B) 18
(C) Coefficient of x 4 in the expansion of (1  x  x 2 )2 (1  x)3
(D) 32

2. A party of 6 persons consist of 2 Indians, 2 Americans and 2 Englishmen. The number of


ways they sit such that no two men of same nationality are next to one another
(A) in a row is 240 (B) at a round table is 32
(C) in a row is 120 (D) at a round table is 16

z z 
3. If z1, z2, z3 are any three roots of the equation z6 = (z + 1)6, then arg  1 3  can be equal to
 z 2  z3 
 
(a) 0 (b)  (c) (d) 
4 4

Z1
4. Let Z1 and Z2 are two non-zero complex number such that |Z1 + Z2| = |Z1| = |z2|, then
Z2
may be :
(a) 1  (b) 1  2 (c)  (d)  2

 
11
5. The integer just below 53  7  2  711 is
(A) divisible by exactly 4 prime factors (B) divisible by exactly 3 prime factors
(C) is divisible by 7 (D) has 53 as its only two digit prime factor

1 20
6. In the expansion of (x2 + 1 + )
x2
(A) number of terms = 321 (B) number of terms = 41
(C) coefficient of x38 = 40 (D) coefficient of x38 = 20

Space For Rough Work

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 
n
7. If 5  2 6  I  f where I  N, n  N and 0  f < 1, then I equals to
1 1
(A)   f (B)    f (C) I is an even integer (D) I is an odd integer
1 f f

8. In a triangle ABC, Tan A and Tan B satisfy the equation 3x 2  4x  3  0 , then


(A) a2 + b2 > c2 (B) a2 + b2 + ab > c2
2 2 2
(C) a + b – ab < c (D) None

9. In an acute angled triangle ABC, if tan A, tan B, tan C are in H.P then
1
(A) Maximum of cot B is
3
1
(B) Minimum of cot B is
3
(C) cot A is a root of x – 2x cot B + 1 = 2cot2 B
2

(D) cot A is a root of x2 – 2x cot B + 1 = cot2 B

10. A tower subtends angles α, 2α, 3α respectively at points A, B and C all lying on a horizontal
AB
line through the foot of the tower. Then 
AC
(A) 4cos2α (B) 1 + 2Cos2α
(C) 2 + 2Cos2α (D) 4cos2α – 1

PART - B : Matrix-Match Type Questions


This Section contains 2 Matrix Match Type Questions. Each question has p q r s

four statements (A, B, C and D) given in Column I and five statements (p, q, A p q r s

r, s) in Column II. Any given statement in Column I can have correct matching B p q r s

with ONE or MORE statement(s) given in Column II. For example, if for a given C p q r s

question, statement B matches with the statements given in q and r, then for D p q r s
the particular question, against statement B, darken the bubbles corresponding
to q and r in the ORS.
Space For Rough Work

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1. Match the following and write the correct pairs.


Column I Column II
(A) If x, y, z  N then number of ordered triplet (x, y, z) 19
(p)
satisfying xyz = 243 is
(B) The number of terms in the expansion of (x + y + z)6 is (q) 28
(C) If x  N, then number of solutions of x2 + x – 400  0 is (r) 21
(D) If x, y, z  N, then number of solution of x + y + z = 10 (s) 36

Codes:
P Q R S
(A) 1 2 4 3
(B) 3 2 1 4
(C) 4 2 3 1
(D) 2 1 3 4

2. Match the following and write the correct pairs.

Column I Column II
(A) 1 (p) The minimum value of |z| |+ |z - 1| + |2z - 3|
(B) 2 z4
(q) | z |, if (z  4) is purely imaginary
z4
(C) 4 (r) Minimum value of ||z - 1| if |z - 3| - |z + 1|| = 2
(D) -1 |p|
The value of , where p is product of all the roots of
(s) 2
the equation z = (1 + i)5/7
The value of    , where  is an imaginary constant
(t)
such that z2  z    0 has a real root
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PART–C : Single digit integer


This section contains 8 questions. The answer to each question is a single digit integer ranging
from 0 to 9 (both inclusive).
1. If x + y + z = 10, where x, y, z  N. Then the number of solutions of unordered triplet (x, y, z)
such that no two variables are equal _________.

2. If n! has exactly (20) zeroes at the end, then number of such possible numbers is _____

3. Number of arrangement of a, b, c, d in which neither a, b nor c, d come together is


___________

4. If  is the imaginary cube root of unity, then the number of pairs of integers (a, b) such that
| a  b | 1 is _____

5. If , ,  are the roots of x3 – 3x2 + 3x + 7 = 0 and w is a complex cube root of unity, then
 1  1  1
  is _______
 1  1  1

6
 5

6. The remainder when   20 C2k 1  is divided by 11 is
 k 1 
(A) 3 (B) 4 (C) 5 (D) 10

 21 
7. The number of values of x satisfying 2sinx - 42 cos x  6 in x ϵ  0, is ______.
 2 

sin  sin3 sin9 K


8. If K1 = tan27θ – tanθ and K2 =   then the value of 1 is
cos 3 cos 9 cos 27 K2

Space For Rough Work

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FIITJEE COMMON TEST


BATCHES : Two Year CRP (1820)-C LOT
PHASE TEST-III: PAPER-1
JEE ADVANCED LEVEL Paper Code

SECTION – I (PHYSICS)
ANSWKER KEY
SECTION – II (CHEMISTRY)
SET-A
SECTION – III (MATHS)
PART-A PART-A PART-A
1. C,D 1. AB 1. B,C
2. C,D 2. CD 2. A,B
3. A,B,C 3. D 3 A,B
4. A,C 4. C 4. C,D
5. C,D 5. ACD 5. A,C
6. B,D 6. ACD 6. B,D
7. B,C 7. A,B,C,D 7. A,D
8. A,B,C,D 8. A,B,C 8. B,C
9. B,C 9. B 9. B,C
10. B 10. CD 10. B,D

PART – B PART–B PART – B


1. A–q, 1. A - q,r,s 1. A-r,
B–r, B - q,r B-q,
C–p C-p C-p,
D–s D - p,s D-s

2. A–p,r, 2. A - p,q,r,s 2. A-rt,


B–s, B - r,s B-p,
C–q; C - r,s C-qs,
D–s D - p,r D-t

PART – C PART–C PART – C


1. 6 1. 8 1 4
2. 7 2. 5 2. 5
3. 5 3. 6 3. 8
4. 1 4. 5 4. 6
5. 8 5. 4 5. 3
6. 2 6. 4 6. 3
7. 2 7. 6 7. 5
8. 3 8. 9 8. 2

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HINTS & SOLUTIONS


SECTION-I : PHYSICS
PART-A
1. C, D
Sol. In the frame of elevator
d 2x
mg  ma  kx  m 2
dt
2
d x k  m  g  a
 2   x  
dt m k 
2
d x k  m  g  pt  a  
Or 2
  x  
dt m k 
There is a term involving t on RHS., this does not represent SHM unless p = 0
Differentiating again wrt time
d 3x k  dx mp  d 2v k  mp 
     or   v 
dt 3
m  dt k  dt 2
m k 
Thus the velocity of the block will vary simple harmonically.

2. C,D
PV = nRT  V  T (at const. P)
 TB  TA
WAB  P0  2V0  V0   P0 V0
WBC  RT ln  3 / 2   2P0 V0 In 3  In 2
= 2 P0V0 (2.303) (0.477 – 0.30)
= 0.8142 P0V0 < W AB

3. A,B,C
(a) No. of molecules in 1 mole = 6.023 × 1023
PV
(b) No. of moles are same n =
RT
(c) Translational KE of N – moles
3 3
= NRT  RT / mole
2 2
(d) Unit mass contains different No. of moles.
 different no. of molecules and hence different KE.

4. A,C
Using PV = nRT
(A)

(C)

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5. C,D

6. B,D

7. B,C
e 2Y
W U   Vol.
2
2
1 l  YAl 2
   Y  AL 
2 L 2L

8. A,B,C,D
Conceptual based

9. B,C

Sol. y 2   5l   x 2 7l
2

x 7l  x
 
2
  7l  x 
2
 3 2l
 x  4l  y  3l y
3l
 T  2 5l 3 2l
g

10. B
Consider, Pressure diagram from fundamental mode
Obviously, P is max at middle

PART – B
1. A–q,B–r,C–p D–s

2. A–p,r, B–s,c; C–q D–s


Initially temperature greatest at A will be more and also area is more at A. So the rate of flow
of heat is maximum at A.
At steady state, rate of flow of heat is constant at all sections as all sections are connected
in series.
 dQ   dT 
As    KA  – dx 
 dt   
dT 1

dx A
dT
At steady state, the temperature at each at every section is constant. Hence = 0 at each
dt
section.

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PART – C
1. 6

2. 7
dQ  dT 
 mc   
dt  dt 
E  AT 4
 dT 
mc  
 dt 
4 4

  A T  0  AT
4

dT A
 dt
T4 mc
100 t
A

200
T 4 dT  
mc
dt 
0
3 100
T A
 t
3 200
mc
100
mc  1 
t
3A  T 3  200
4 3 
 3 r   c
   1  1 
 
3  4r 2  1003 2003 
7 rc
  106 sec .
72 

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3. 5
m = m H e + m H 2 = 180 g. W g = 56 KJ. Q = 150 KJ.
mH2 = m1
mHe = m2
E  Q  W  Q  Wg  100KJ
PV  N1  N2  kT
f f 
E   1 N1  2 N2  kT
 2 2 
f f  Wg
E   1 N1  2 N 2 
2 2  N1  N2
2E f1N1  f2N2 200 5N1  3N2
  
Wg N1  N2 56 N1  N2

Let N 1 / N 2 = x
25 5 x  3

7 x 1
25x + 25 = 35x + 21  10x = 4
x = 0.4
m1 m
 NA  0.4 2 NA
M1 M2
m2
 m1  0.4 M1
M2
m 2 = 5m 1

4. 1

5. 8

6. 2
Let the speed of the disc be v at any displacement x.
Then, the total mechanical energy of the disc + spring system is
1 2 1 2 1
E U  K = kx  mv  I C 2
2 2 2
v mR 2
Where   for rolling and I C 
R 2
1 3
E  kx 2  mv 2
2 4
dE 3 dv
Differentiating both sides with x, we have  kx  mv
dx 2 dx
vdv dE
Where  a and 0
dx dx
2 k
a x
3m
2k
Since, a   2 x, we have  
3m

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7. 2
F
 keff  numerically 
x
Let us find  x (static deformation of the system).
Since the particle is in equilibrium,
 F  2 Fs sin 
By Pythagoras theorem, x 2  y 2  l 2
Taking differentials of both sides, we have 2 x x  2 y y  2l l
Since y is constant,  y  0
x
l   x
l
F
 2k sin 2 
x
keff  2k sin 2 
 2m
Substituting keff , we have T 
sin  k

8. 3

PV = nRT
P = P 0 – AV 2
 (P 0 – AV 2 )V = nRT
 dT 
 P 0 – 3 AV 2 = nR  
 dV 
dT
For Tmax 0
dV
P0
 V
3A
2P0 P0
 Tmax 
3nR 3A

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CHEMISTRY

5. Chiral carbon and double bonded carbon are stereogenic centres

7. Br CH3 CH3

(A) CH 3  CH 2CH 3 


Br2 / hv
 CH 3  CH  CH 3 
Na
ether
 CH 3  CH  CH  CH 3

(B) COOH 


NaOH
 COONa 
Electro

lysis

(C) 
Mg / ether
 
CH 3 Br
SN 2

Br MgBr

COOH
(D) 
Red P/HI

8. Lindlar catalyst provides cis-addition while Birch reduction gives trans-addition product

9. Methyl group shows more hyperconjugation than that of iso-propyl group

PART-B

1. 2CH 3COONa  2 H 2O 


Current
 CH 3CH 3  g   2 NaOH  aq   2CO2  g   H 2  g 
2 HCOONa  2 H 2O 
Current
 2 NaOH  2CO2  2 H 2
CaO / 
CH 3COONa  NaOH   CH 4  Na2CO3 .
HCOONa  NaOH 
 H 2  Na2CO3 .

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PART-C

1. CH3 CH3
CH3CH2 CH-CH2CH2Cl , CH3CH2 CH-CH-CH3

(d & l forms) Cl
( 4 isomers)
CH3 CH2Cl
CH3 CH2-C-CH2-CH3 and CH3CH2 CH-CH2CH3

Cl

2. In the presence of activating groups, acidic strength decreases. H2CO3 is less acidic than
C6H5COOH

3. O O

CH 3 ,  NH  C  CH 3 ,  OCH 3 ,  N  CH 3  2 ,  O  C  CH 3 and  OH are

benzene ring acitvating groups for EASR.

4.

(cis and trans-forms)

5. ,
C2H2(ethyne), benzene
O O

and cyclooctatetraene give glyoxal, H - C - C - H

6. NH
O

, , CH3NO and CH3COCH 2COOC 2H5 show tautomerism

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7.
C16H16 is H3C CH=CH CH3

8. O O
O O

(III) (IV)
(I) (II)

O O O

(VII) (VI) (V)

O O O

(III) (VIII) (IX)

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MATHEMATICS

1. B,C
LS  2
C, O, G  3 different letters
ES  2
(1) Four different letters = 5C4  5
(2) 2 like 2 different 2C1  4C2  12
(3) 2 alike , 2 alike = 1 =1
_________
18

2. A,B
Required no of linear permutation as per condition
= 6!   C53
1 ! . 2 !  3 C2 4 !  2 !
2
3 C3 3 !  2 !
3

= 240 {using inclusion exclusion}
Required no of circular permutation 5!  (3C14! 2!  3C2 3! (2!)2 + 3C3 2! (2!)3) = 32

3 A,B
AB
Given equation z6 = (z + 1)6
| z 6 || (z  1)6 |
| z || z  1|
z z 
Roots are collinear   1 3   0 or 
 z 2  z3 
4. C,D

5. A,C
 
11
53  7  I  f (0 < f < 1) and I is an integer

 53  7 
11
 f

I  f  f /  2  11 C1         711   int eger


10 8 2 0
53 71  11C3 53 73  ......  11C9 53 79  11C11 53
 
 f – f/ = 0
 
11
 The integer just below ( 53  7  2  711 is I – 2 × 711

 
2
= 2  71  53  11  int eger  as pCr is divisible by p  1  r  p – 1 if p is prime.

6. B,D
let x² = t
1 n  1
n

Coefficient of x2n – 2 in (x2 + 1 + 2


) is coefficient t n– 1
in  t  1   = coefficient of t
2n – 1
in
x  t 
(t² + t + 1)n = nC1.
No. of terms is 2n + 1
Now put n = 20.

7. A,D
 
n
Let 5  2 6  ƒ1 where 0 < f/ < 1
I + f + f/ = even integer
f + f/ = 1 or f/ = 1 – f

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 
n
I + f = 52 6

  1
n
I 52 6 f  f
5  2 6 
n

1
 I f
1 f

8. B,C

9. B,C

10. B,D

PART – B
1. A-r,B-q,C-p,D-s
(A) xyz = 35
number of solution (x, y, z) is 3 + 5 – 1C5 = 21.

(B) Number of terms = 6 + 3 – 1C3 – 1 = 28.

(C) x2 + x – 400  0
x(x + 1)  400
solutions are 1, 2, 3, …, 19.
Number of solutions = 19.

(D) x + y + z = 10
number of solutions = coefficient of x10 in (t + t2 + … + t8)3
3
10
 1  t8 
3
= coefficient of x in t  
 1 t 
= coefficient of x7 in (1 + 3C1 t + 3C2 t2 + …) = 9C7 = 36.

2. A-rt, B-p, C-qs, D-t

PART – C
1 4
x + y + z = 10
1 2 7
3 1 6
4 1 5
2 3 5
Total ways = 4.

2. 5

n
Number of zeroes = x =   5i 
i1

n n n
x <  i since  i  < i
i1 5 5  5

n 1
x<
5
 5i1
i 1

n 5
x< 
5 4

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 n > 4x  n > 80
 80   80 
If n = 80, x =   +   = 16 + 3 = 19
5   25 
 85   85 
n = 85, x =   +   = 20
5   25 
 90   90 
n = 90, x =   +   = 21
5   25 
 n  {85, 86, 87, 88, 89}

3. 8
Required number of arrangements
= 4!   C  3! 2! C
2
1
2
2  2!  2!
2
  8.
4. 6
We have | a  b | 1
 (a  b)(a  b)  1  a 2  ab  b 2  1
 (a  b)2  ab  1

5. 3
x3 – 3x2 + 3x + 7 = 0
 (x  1)3  8
   1 ;   1  2w,   1  2w 2
1 1
=   w 2  2w 2  w 2  3w 2
w w
 1  1  1
   1
 1  1  1

6. 3
6 6
 5 20  1 
  C2k 1   
2
 20
C1  20C3  .....  20C19 


 k 1 
= 2108   25   23  11 3  1  8
21 21

= (11I – 1)× 8 = 11I + 3

7. 5
2
1  2 2
2

 sin x  3    cos x  3   0
   
1 2 2
possible only if, sin x  , cos x  (2n quadrant).
3 3

8. 2

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