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Useful Data
PHYSICS
CHEMISTRY
Atomic No.: H=1, He=2, Li=3, Be=4, B=5, C=6, N=7, O=8, F=9, Na=11, Mg=12, Al = 13,
Si = 14, P = 15, S = 16, Cl = 17, Ar =18, K=19, Ca=20,Cr=24, Mn=25, Fe=26, Co=27,
Ni=28, Cu=29, Zn=30, As=33, Br = 35, Ag = 47, Si = 21, Sn = 50, Ti = 22,I = 53, Xe = 54,
Ba = 56, Pb = 82, U = 92, V = 50.
Atomic masses: H =1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16, F=19, Na=23,
Mg=24, Al=27, Si=28, P=31, S=32, Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn = 65.4, As = 75, Br = 80, Ag = 108, Sn = 118.7, I = 127, Xe = 131,
Ba = 137, Pb = 207, U = 238.
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SECTION-I : PHYSICS
PART-A : One or More Than One Options Correct Type
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. A body of mass m is attached to a spring of spring constant k which hangs from the ceiling
of an elevator at rest in equilibrium. Now the elevator starts accelerating upwards with its
acceleration varying with time as a pt q, where p and q are positive constants. In the
frame of elevator
(A) the block will perform SHM for all value of p and q
(B) the block will not performs SHM in general for all value of p and q expect p = 0
(C) the block will perform SHM provided for all value of p and q expect p = 0
(D) the velocity of the block will vary simple harmonically for all value of p and q.
3. For any monoatomic gas the quantities independent of the nature of the gas at the same
temperature is/are :
(A) The number of molecules in one mole
(B) The number of molecules in equal volume and pressure
(C) The translational kinetic energy of one mole
(D) The kinetic energy of unit mass
Space For Rough Work
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(A) (B)
(C) (D)
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6. A car moves towards a hill with speed vc . It blows a horn of frequency f which is heared by an
observer following the car with speed v0 . The speed of sound in air is v.
v
(A) the wavelength of sound reaching the hill is
f
2 vc v v0 f
(D) the beat frequency observed by the observer is
v 2 vc2
8. A metallic wire of length l is held between two rigid supports. If the wire is cooled through a
temperature t. (T = Young’s modulus of elasticity of wire, density, thermal
coefficient of linear expansion). Then, the frequency of oscillation is proportional to
1
(A) (B) Y (C) (D) t
l
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10. An open organ pipe of length L vibrates in its fundamental mode. The pressure variation is
maximum
(A) At the two ends (B) At the middle of Pipe
L L
(C) At distance inside the ends (D) At distance inside the ends
4 8
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four statements (A, B, C and D) given in Column I and five statements (p, q, A p q r s t
r, s and t) in Column II. Any given statement in Column I can have correct B p q r s t
matching with ONE or MORE statement(s) given in Column II. For example, if C p q r s t
for a given question, statement B matches with the statements given in q and r, D p q r s t
then for the particular question, against statement B, darken the bubbles
corresponding to q and r in the ORS.
1. For a simple harmonic wave y 2cm sin 3t 4 x when y and x in m, t in second.
Column-I
Column-II
(processes for ideal monoatomic
(Corresponding effects)
gas)
(A) Particle at x 0 and at t 0 is (p) Moving downwards
(B) Particle at x and at t 0 is (q) Moving upwards
8
(C) Particle at x 0 and t s is (r) Accelerated upwards
3
Particle at x cm and at t s
(D) 8 3 (s) Accelerated downwards
is
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dQ maximum at section B
(B) At steady state rate of heat flow will be (q)
dt
dT minimum at section B
(C) At steady state temperature gradient will be (r)
dx
1. A point source of sound emits a constant power with intensity inversely proportional to the
square of the distance from the source. By how many decibels does the sound intensity
level drop when you move from point P1 to P2 . Distance of P2 from the source is two times
the distance of source from P1 .
2. A solid copper sphere (density and specific heat C) of radius r at an initial temperature
200 K is suspended inside a chamber whose walls are almost at 0 k. the time required for
x rc
the temperature of sphere to drop to 100 K is found to be 106 sec. The value of x is.
72
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4. The vibrations from an 800 Hz tuning fork set up standing waves in a string clamped at both
ends. The wave speed in the string is known to be 400 ms-1 for the tension used. The
standing wave is observed to have four antinodes. Calculate the length of the string in
metre.
5. Third overtone of a closed organ pipe of length 7 cm is in unison with fourth harmonic of an
open organ pipe. Find the length of open organ pipe, in cm.
8. The pressure of an ideal gas varies according to the law P = P0 – AV2 where P0 and A are
positive constants. The highest temperature that can be attained by the gas is.
6P0P0
Tmax 4
The value of x is.
x mR A
Space For Rough Work
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SECTIONII: CHEMISTRY
PART-A : One or More Than One Options Correct Type
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
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6. Br Br Cl H CH
H H H CH 3
3
H H Br Br H
Br
CH3 H H H H
Br Cl H Br
H Br H Br H Br H
H Cl H H Cl H
H H
CH3 Cl CH3
A B C D E
Which of the following is correct?
(A) A & B are non mirror images stereoisomers (B) A & C are enantiomers
(C) D & A are non superimposable mirror image (D) A & E are diastereomers
8. Which of the following statements are correct for the following compounds when they are
treated with Lindlar’s catalyst D2 / Pd BaSO4 & Na / liq. NH 3 (Birch reduction?)
(I) CH 3 CH 2 C CD (II) CH 3 CHD C CH
(III) CH 3 C C CH 2 D (IV) CH 2 D CH 2 C CH
(A) (I) can give trans isomers and not cis isomers
(B) (II) can give cis isomers but not trans isomers
(C) (III) can give both cis & trans isomers
(D) (IV) can give both cis & trans isomers
Space For Rough Work
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Conc.HNO H SO
3 2 4
Product(s)
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H H Rearrangement is involved in
1 B2 H6 ,THF proceeding of reaction by breaking of
Me C C CH2
B) (2) H2O2 , OH q) sigma bonds
Me
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1. CH3
Cl 2 / hv
CH3CH2 CH CH2CH3 Product(s)
(A)
Total number of products formed by monochlorination of (A) is
2. Find out number of compounds which are more acidic than benzoic acid, from following.
H C OH , H 2 C 2 O 4 , , , , H 2 CO 3 , CCl 3 COOH
,
CH 3 NO 2 N(CH 3 ) 2 CF 3
3. Examine the structural formula shown below and find out how many compounds undergo
electrophilic nitration more rapidly than fluorobenzene?
4. The total number of isomeric alkenes, that can be hydrogenated to form 2-methylpentane,
is……
5. How many of the following on reductive ozonolysis will give only glyoxal?
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O
NO2
NH
, , , ,
O O NH
CHO
O O
, , CH3NO , , HCHO
O
O
CH3COCH2COOC2H5
8. O-
A=
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SECTION-III : MATHEMATICS
PART-A : One or More Than One Options Correct Type
This section contains 10 multiple choice questions. Each question has 4 choices (A), (B), (C)
and (D), out of which ONE or MORE THAN ONE is correct.
1. The number of selection of four letters taken from the word COLLEGE must be
(A) 22
(B) 18
(C) Coefficient of x 4 in the expansion of (1 x x 2 )2 (1 x)3
(D) 32
z z
3. If z1, z2, z3 are any three roots of the equation z6 = (z + 1)6, then arg 1 3 can be equal to
z 2 z3
(a) 0 (b) (c) (d)
4 4
Z1
4. Let Z1 and Z2 are two non-zero complex number such that |Z1 + Z2| = |Z1| = |z2|, then
Z2
may be :
(a) 1 (b) 1 2 (c) (d) 2
11
5. The integer just below 53 7 2 711 is
(A) divisible by exactly 4 prime factors (B) divisible by exactly 3 prime factors
(C) is divisible by 7 (D) has 53 as its only two digit prime factor
1 20
6. In the expansion of (x2 + 1 + )
x2
(A) number of terms = 321 (B) number of terms = 41
(C) coefficient of x38 = 40 (D) coefficient of x38 = 20
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n
7. If 5 2 6 I f where I N, n N and 0 f < 1, then I equals to
1 1
(A) f (B) f (C) I is an even integer (D) I is an odd integer
1 f f
9. In an acute angled triangle ABC, if tan A, tan B, tan C are in H.P then
1
(A) Maximum of cot B is
3
1
(B) Minimum of cot B is
3
(C) cot A is a root of x – 2x cot B + 1 = 2cot2 B
2
10. A tower subtends angles α, 2α, 3α respectively at points A, B and C all lying on a horizontal
AB
line through the foot of the tower. Then
AC
(A) 4cos2α (B) 1 + 2Cos2α
(C) 2 + 2Cos2α (D) 4cos2α – 1
four statements (A, B, C and D) given in Column I and five statements (p, q, A p q r s
r, s) in Column II. Any given statement in Column I can have correct matching B p q r s
with ONE or MORE statement(s) given in Column II. For example, if for a given C p q r s
question, statement B matches with the statements given in q and r, then for D p q r s
the particular question, against statement B, darken the bubbles corresponding
to q and r in the ORS.
Space For Rough Work
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)19
Codes:
P Q R S
(A) 1 2 4 3
(B) 3 2 1 4
(C) 4 2 3 1
(D) 2 1 3 4
Column I Column II
(A) 1 (p) The minimum value of |z| |+ |z - 1| + |2z - 3|
(B) 2 z4
(q) | z |, if (z 4) is purely imaginary
z4
(C) 4 (r) Minimum value of ||z - 1| if |z - 3| - |z + 1|| = 2
(D) -1 |p|
The value of , where p is product of all the roots of
(s) 2
the equation z = (1 + i)5/7
The value of , where is an imaginary constant
(t)
such that z2 z 0 has a real root
Space For Rough Work
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2. If n! has exactly (20) zeroes at the end, then number of such possible numbers is _____
4. If is the imaginary cube root of unity, then the number of pairs of integers (a, b) such that
| a b | 1 is _____
5. If , , are the roots of x3 – 3x2 + 3x + 7 = 0 and w is a complex cube root of unity, then
1 1 1
is _______
1 1 1
6
5
6. The remainder when 20 C2k 1 is divided by 11 is
k 1
(A) 3 (B) 4 (C) 5 (D) 10
21
7. The number of values of x satisfying 2sinx - 42 cos x 6 in x ϵ 0, is ______.
2
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SECTION – I (PHYSICS)
ANSWKER KEY
SECTION – II (CHEMISTRY)
SET-A
SECTION – III (MATHS)
PART-A PART-A PART-A
1. C,D 1. AB 1. B,C
2. C,D 2. CD 2. A,B
3. A,B,C 3. D 3 A,B
4. A,C 4. C 4. C,D
5. C,D 5. ACD 5. A,C
6. B,D 6. ACD 6. B,D
7. B,C 7. A,B,C,D 7. A,D
8. A,B,C,D 8. A,B,C 8. B,C
9. B,C 9. B 9. B,C
10. B 10. CD 10. B,D
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)22
2. C,D
PV = nRT V T (at const. P)
TB TA
WAB P0 2V0 V0 P0 V0
WBC RT ln 3 / 2 2P0 V0 In 3 In 2
= 2 P0V0 (2.303) (0.477 – 0.30)
= 0.8142 P0V0 < W AB
3. A,B,C
(a) No. of molecules in 1 mole = 6.023 × 1023
PV
(b) No. of moles are same n =
RT
(c) Translational KE of N – moles
3 3
= NRT RT / mole
2 2
(d) Unit mass contains different No. of moles.
different no. of molecules and hence different KE.
4. A,C
Using PV = nRT
(A)
(C)
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5. C,D
6. B,D
7. B,C
e 2Y
W U Vol.
2
2
1 l YAl 2
Y AL
2 L 2L
8. A,B,C,D
Conceptual based
9. B,C
Sol. y 2 5l x 2 7l
2
x 7l x
2
7l x
2
3 2l
x 4l y 3l y
3l
T 2 5l 3 2l
g
10. B
Consider, Pressure diagram from fundamental mode
Obviously, P is max at middle
PART – B
1. A–q,B–r,C–p D–s
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)25
PART – C
1. 6
2. 7
dQ dT
mc
dt dt
E AT 4
dT
mc
dt
4 4
A T 0 AT
4
dT A
dt
T4 mc
100 t
A
200
T 4 dT
mc
dt
0
3 100
T A
t
3 200
mc
100
mc 1
t
3A T 3 200
4 3
3 r c
1 1
3 4r 2 1003 2003
7 rc
106 sec .
72
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3. 5
m = m H e + m H 2 = 180 g. W g = 56 KJ. Q = 150 KJ.
mH2 = m1
mHe = m2
E Q W Q Wg 100KJ
PV N1 N2 kT
f f
E 1 N1 2 N2 kT
2 2
f f Wg
E 1 N1 2 N 2
2 2 N1 N2
2E f1N1 f2N2 200 5N1 3N2
Wg N1 N2 56 N1 N2
Let N 1 / N 2 = x
25 5 x 3
7 x 1
25x + 25 = 35x + 21 10x = 4
x = 0.4
m1 m
NA 0.4 2 NA
M1 M2
m2
m1 0.4 M1
M2
m 2 = 5m 1
4. 1
5. 8
6. 2
Let the speed of the disc be v at any displacement x.
Then, the total mechanical energy of the disc + spring system is
1 2 1 2 1
E U K = kx mv I C 2
2 2 2
v mR 2
Where for rolling and I C
R 2
1 3
E kx 2 mv 2
2 4
dE 3 dv
Differentiating both sides with x, we have kx mv
dx 2 dx
vdv dE
Where a and 0
dx dx
2 k
a x
3m
2k
Since, a 2 x, we have
3m
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)27
7. 2
F
keff numerically
x
Let us find x (static deformation of the system).
Since the particle is in equilibrium,
F 2 Fs sin
By Pythagoras theorem, x 2 y 2 l 2
Taking differentials of both sides, we have 2 x x 2 y y 2l l
Since y is constant, y 0
x
l x
l
F
2k sin 2
x
keff 2k sin 2
2m
Substituting keff , we have T
sin k
8. 3
PV = nRT
P = P 0 – AV 2
(P 0 – AV 2 )V = nRT
dT
P 0 – 3 AV 2 = nR
dV
dT
For Tmax 0
dV
P0
V
3A
2P0 P0
Tmax
3nR 3A
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)28
CHEMISTRY
7. Br CH3 CH3
(C)
Mg / ether
CH 3 Br
SN 2
Br MgBr
COOH
(D)
Red P/HI
8. Lindlar catalyst provides cis-addition while Birch reduction gives trans-addition product
PART-B
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)29
PART-C
1. CH3 CH3
CH3CH2 CH-CH2CH2Cl , CH3CH2 CH-CH-CH3
(d & l forms) Cl
( 4 isomers)
CH3 CH2Cl
CH3 CH2-C-CH2-CH3 and CH3CH2 CH-CH2CH3
Cl
2. In the presence of activating groups, acidic strength decreases. H2CO3 is less acidic than
C6H5COOH
3. O O
4.
5. ,
C2H2(ethyne), benzene
O O
6. NH
O
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)30
7.
C16H16 is H3C CH=CH CH3
8. O O
O O
(III) (IV)
(I) (II)
O O O
O O O
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MATHEMATICS
1. B,C
LS 2
C, O, G 3 different letters
ES 2
(1) Four different letters = 5C4 5
(2) 2 like 2 different 2C1 4C2 12
(3) 2 alike , 2 alike = 1 =1
_________
18
2. A,B
Required no of linear permutation as per condition
= 6! C53
1 ! . 2 ! 3 C2 4 ! 2 !
2
3 C3 3 ! 2 !
3
= 240 {using inclusion exclusion}
Required no of circular permutation 5! (3C14! 2! 3C2 3! (2!)2 + 3C3 2! (2!)3) = 32
3 A,B
AB
Given equation z6 = (z + 1)6
| z 6 || (z 1)6 |
| z || z 1|
z z
Roots are collinear 1 3 0 or
z 2 z3
4. C,D
5. A,C
11
53 7 I f (0 < f < 1) and I is an integer
53 7
11
f
2
= 2 71 53 11 int eger as pCr is divisible by p 1 r p – 1 if p is prime.
6. B,D
let x² = t
1 n 1
n
7. A,D
n
Let 5 2 6 ƒ1 where 0 < f/ < 1
I + f + f/ = even integer
f + f/ = 1 or f/ = 1 – f
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)32
n
I + f = 52 6
1
n
I 52 6 f f
5 2 6
n
1
I f
1 f
8. B,C
9. B,C
10. B,D
PART – B
1. A-r,B-q,C-p,D-s
(A) xyz = 35
number of solution (x, y, z) is 3 + 5 – 1C5 = 21.
(C) x2 + x – 400 0
x(x + 1) 400
solutions are 1, 2, 3, …, 19.
Number of solutions = 19.
(D) x + y + z = 10
number of solutions = coefficient of x10 in (t + t2 + … + t8)3
3
10
1 t8
3
= coefficient of x in t
1 t
= coefficient of x7 in (1 + 3C1 t + 3C2 t2 + …) = 9C7 = 36.
PART – C
1 4
x + y + z = 10
1 2 7
3 1 6
4 1 5
2 3 5
Total ways = 4.
2. 5
n
Number of zeroes = x = 5i
i1
n n n
x < i since i < i
i1 5 5 5
n 1
x<
5
5i1
i 1
n 5
x<
5 4
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IT2020Two Year CRP (1820)- C LOT- PH-III (PAPER-1) (CPT3-1)-(PCM) JEE ADV. (SET-A)33
n > 4x n > 80
80 80
If n = 80, x = + = 16 + 3 = 19
5 25
85 85
n = 85, x = + = 20
5 25
90 90
n = 90, x = + = 21
5 25
n {85, 86, 87, 88, 89}
3. 8
Required number of arrangements
= 4! C 3! 2! C
2
1
2
2 2! 2!
2
8.
4. 6
We have | a b | 1
(a b)(a b) 1 a 2 ab b 2 1
(a b)2 ab 1
5. 3
x3 – 3x2 + 3x + 7 = 0
(x 1)3 8
1 ; 1 2w, 1 2w 2
1 1
= w 2 2w 2 w 2 3w 2
w w
1 1 1
1
1 1 1
6. 3
6 6
5 20 1
C2k 1
2
20
C1 20C3 ..... 20C19
k 1
= 2108 25 23 11 3 1 8
21 21
7. 5
2
1 2 2
2
sin x 3 cos x 3 0
1 2 2
possible only if, sin x , cos x (2n quadrant).
3 3
8. 2
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