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Polymer Chemistry
Global Research and Technology Centre
Kuala Lumpur
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Polymers
Viscosity
Bentonite Extension
Fluid Loss Control
Flocculation / Deflocculation (Thinning)
Shale Inhibition
Lubricity
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The Basics
• Polymers are large molecules (macromolecules) built up
from numerous smaller molecules known as monomers.
• Polymers may be linear, branched, or cross linked.
• The size of the polymer is defined by it’s mass or by the
number of repeat units (DP) in the molecule multiplied
by the repeat unit molecular weight.
• The polymer properties depend on the type and number
of monomer/s used, the number of branches and
functional groups in the chain.
• The type and extent of any subsequent chemical
modification
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Polymer Types
X Polymerisation
Reaction
-X-X-X-X-X-X-X-
Monomer Linear Homopolymer
X-X
-X - X - X
X-X-X-X-
Branched Homopolymer
X+Y -X-Y-X-Y-X-Y-X-Y-
Alternating Copolymer
Monomers
-X-Y-Y-X-X-X-Y-X-
Random Copolymer
-X-X-X-Y-Y-Y-X-X-X-
Block Copolymer
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Polymer Types
-X-X-X-X-X-X-X-
X Polymerisation
-X-X-X-X-X-X-X-
l l
Y Y
l l
Y Y
Branched Graft Copolymer
X -X-X-X-X-X-X-X-
Monomer Add reactant (R)
-X-X-X-X-X-X-X-
l l l
R R R
Functionalised /Derivatised Polymer
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Molecular Weight (Chain Length)
Number of molecules
It is rarely possible to get all Narrow
distribution
the chain lengths exactly
the same. Hence there is
a distribution of molecular Broad
distribution
weights.
Molecular weight
MW
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Reactive Groups
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Polymer Shape
Linear
Crossed linked
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Polymer Shape
• The concentration of the groups on -ve -ve
the polymer.
• Polymers with a higher number of
charge groups will uncoil more
than polymers with only a few Low substitution.
charged groups. Chain remains coiled.
• This is because the charged groups -ve -ve -ve
base
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Polymer Shape
Multivalent cations will - - - -
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Classification of Polymers
Natural Polymers
• Starch
• Guar Gum
• Locust Bean Gum
Microbial Polymers
• Xanthan Gum (XC Polymer)
Synthetic Polymers
• Sulfonated styrene maleic anhydride copolymer
• Polyacrylates
• Polyacrylamides
• Partially hydrolyzed polyacrylamide (PHPA)
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Bentonite Extenders
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Viscosifying Polymers
solution
low molecular weight
viscosity
polymer concentration
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Viscosifiers
Guar Gum
Xanthan Gum
Welan Gum
Scleroglucan
Hydroxy Ethyl Cellulose
Carboxy Methyl Cellulose
Carboxy Methyl Ethyl Cellulose
Poly Anionic Cellulose
Styrene butadiene latexes in oil based fluids
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Filtration Control
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Filtration Controllers
Cellulosics
Low viscosity carboxy methyl cellulose
Poly anionic cellulose
CMHEC
Starch and it’s derivatives
Sodium Polyacrylates
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Filtration Controllers
High temperature copolymers and terpolymers
copolymers contain 2 monomers, terpolymers contain 3.
Many are AMPS based (2-acrylamido-2-methyl-propane
sulphonic acid).
Lignins
Pre cross-linked methyl styrene acrylate copolymer. Oil based
fluid systems.
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Flocculants
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Flocculants
• Flocculants are long chain polymers that are able to bridge
particles together.
• They assist in removing particles from the fluid by making the
overall particle size bigger, and thus easier to remove.
Flocculated clay Flocculant
Deflocculant
High M.W.
polymer acting as
bridge between
particles
Adsorption of low
M.W. polymer
creates overall
negative charges
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Deflocculants
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Thinner & Deflocculants
Lignosulphonates
Tannins
Sodium Acrylates
AMPS and it’s derivatives (high temperatures)
poly 2- acrylamido 2-methyl propane sulphonic acid
Sulphonated styrene maleic anhydride
Low Molecular weight (c. 3000)
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Shale Stabilization
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Polymer Encapsulation (PHPA)
Hydrated
Shale
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Shale Encapsulating Polymer
POLYMERS
SHALE
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HYDRO CAP – Adheres to Shale Cuttings
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Shale Control Additives
Cationic Polyamines
PAC’s
Polyhydroxy Compounds
Glycols
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Lost Circulation Materials
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Summary
Polymer types Description Examples Functions
Carboxymethyl Polysaccharide
cellulose ether linear polymer
CMC anionic-COO-
groups
High viscosity Viscosifer, fluid
High molecular wt CMC loss additive
Low molecular wt Fluid loss additive
Low viscosity CMC
Hydroxyethyl Polysaccharide
cellulose ether linear polymer HEC Viscosifier –
HEC non-ionic ether particularly for
group brines
High molecular wt
Starch Polysaccharide Corn, potatoes, Fluid loss control
highly branched tapioca, etc. in salt solutions
forms colloidal Variously
solution normally chemically 32
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non-ionic modified
Summary
Polymer types Description Examples Functions
Bacterial gums Polysaccharide Viscosifier
polysaccharide branched complex Xanthan gums particularly in salt
structure some water and where
anionic groups suspension
High molecular wt properties are
required
Natural gums Polysaccharide Guar, gum arabic Viscosifier
from trees and branched – high
shrubs molecular wt
some anionic
groups complex
structure
Lignosulphonate Water soluble Lignosulphonate Thinner,
sulphonate deflocculant, fluid
derivative of lignin loss control
– range of metal
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Summary
Polymer types Description Examples Functions
Mined lignins Metal salts of Lignite Thinner, fluid
petrified humic loss control
acid
Tannin Extracts from Quebracho Thinner
bark and wood
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