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PLSOIL 120
ORGANIC FARMING AND GARDENING
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CHAPTER 7
FERTILIZERS
If the results of testing of soil or diagnosis of plants reveal that nutrients are deficient in a soil, fertilization is
necessary for optimum plant growth. Fertilizers are chemical substances that are used to carry plant nutrients to a
soil. Fertilizers may supply one or more nutrients. Fertilizers may be manufactured or naturally occurring. Naturally
occurring fertilizers sometimes, but not always, are classified as organic fertilizers. Designation of fertilizers as
organic is a matter of definition and of acceptance and is not necessarily based on origin of the materials.
Manufactured fertilizers commonly are called chemical fertilizers. Manufactured fertilizers often are mixed to form
what is called a complete fertilizer, that is, a fertilizer with nitrogen, phosphorus, and potassium. The concentrations
of plant nutrients in a fertilizer specify its grade or analysis.

Fertilizer Grades

Grade or analysis of a fertilizer is designated by three numbers that indicate the guaranteed minimum concentrations
of available plant nutrients. Commercial fertilizers, organic or manufactured, must have the guaranteed mininum
analysis printed on the package. A grade of 10-10-10 has a guaranteed analysis 10% N, 10% P2O5, and 10% K2O,
which is specified on the container as guaranteed available nitrogen, phosphoric acid, and potash. Fertilizers that
have more than 30% total available nutrients are called high analysis fertilizers, whereas those with less than 30%
total available nutrients are called low analysis fertilizers. A 15-15-15 is a high analysis fertilizer; a 5-10-10 is a low
analysis fertilizer, and a 10-10-10 is right on the borderline. The division between high analysis and low analysis is
arbitrary. Sometimes, recommendations imply limitations on the amounts of high analysis fertilizers that must be
applied. Growers should not feel that they can apply low analysis fertilizers at substantially higher amounts than
high analysis fertilizers, when in fact only minor differences exist between the two materials. Growers should
consider most modern, mixed, chemical, multinutrient fertilizers as high analysis fertilizers.

A matter that needs explanation is the method of presentation of grades of fertilizers as amounts of N (nitrogen),
P2O5 (called phosphoric acid on the bag but chemically phosphorus pentoxide), and K2O (potash or potassium
oxide). These expressions are related to the practice of presentation of constituents of inorganic substances as
oxides. This procedure has been accepted by the fertilizer industry and is used in the expression of grades of all
fertilizers, organic or chemical, for which the manufacturer guarantees an availability of nutrients. A similar kind or
reporting of constituents is used in the expession of calcium and magnesium contents of liming materials (Chapter
8). Reports in scientific literature require that analyses be reported as actual elemental concentrations, that is, as N,
P, and K. If a grower wants to convert fertilizer grades into amounts of actual elements delivered by the fertilizer, the
following conversions should be used (Table 18). Recommendations for application of fertilizers are based on N,
P2O5, and K2O. Changes in the bases of reporting of analysis or in making recommendations are unlikely because
of the amount of confusion that would exist and the great effort in education of the public that would have to be
made to effect the changes. On the other hand, when nutrient removal by crops is presented, the amounts always are
given in amounts of actual element removed. Grower and advisers of growers, who base recommendations of
fertilization on amounts of nutrients removed, must be certain to coordinate recommendations of nutrients needed
with the amounts delivered by fertilizers.

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Table 18. Conversions of expressions of analyses as oxides into concentrations of actual plant nutrients
present.

Element Term in trade Usage Conversion factor for


actual element

Nitrogen Available N Fertilizer analyses 1.00 X N

Phosphorus Available phosphoric acid, Fertilizer analyses 0.44 X P205


P205

Potassium Available potash, K20 Fertilizer analysis 0.83 X K20

Calcium Calcium carbonate equivalent, Limestone analysis 0.4 X CaC03 (calcite) or


CaC03 0.23. X CaC03 (dolomite)

Nutrients other than the three primary macronutrients (nitrogen, phosphorus, and potassium) may be supplied by a
fertilizer, but with a few exceptions, their concentrations are specified only if a guaranteed analysis for these other
nutrients is claimed. Fertilizers with nutritients in addition to nitrogen, phosphorus, and potassium are referred to as
specialty fertilizers.

Nitrogen Fertilizers

Effects of nitrogen fertilizers on plant growth

Nitrogen is the essential element most frequently deficient in soils around the world. Most of the nitrogen in plants
is in proteins, genetic material, and chlorophyll. The amount of nitrogen accumulated by plants varies with species,
cultivar, plant part, and age of the part as well as with the nutritional status. Typical ranges of concentration are from
1.5 to 5% total nitrogen on a dry-weight basis. Nitrogen in mature grasses falls in the lower end of the range and in
young plants and legumes at the middle and higher end of the range. Although the threshhold for nitrogen deficiency
varies with kind, position, and age of tissues, leaves that have less than 1.5% total nitrogen probably are nitrogen
deficient. Nitrogen-deficient plants (Table 17) are identified by poor growth and poor color which are due basically
to the lack of production of proteins. Adequate nitrogen nutrition is associated with vigorous vegetative (roots,
stems, leaves) and reproductive (flowers, fruits, seeds) growth. Excesses of nitrogen generally lead to supraoptimal
vegetative growth and suppressions of reproductive growth. A proper total supply and balance of nitrogen with other
elements is very important in plant nutrition. Optimum and balanced fertilization with nitrogen promotes the growth
of all plant organs. Generally, nitrogen fertilization promotes shoot growth more than root growth and, in the shoots,
promotes vegetative growth more than reproductive growth. Nitrogen-fertilized plants may be soft, succulent plants
with a high content of water. This characteristic is the result of alterations in the relative contents of proteinaceous
and carbohydrate-like materials.

Nitrogen fertilization enhances protein synthesis. Photosynthetic products that might go to formation of sugars,
starches, and cell walls are directed toward protein synthesis. The thin cell walls that are associated with high water
and protein contents make leafy vegetables crisp and succulent. On the other hand, thin-walled cells of stems make
plants weak-stemmed, and these plants may fall over or lodge. Nitrogen fertilization normally delays the rate of
maturation of plants, that is, the plants are maintained in a vigorous vegetative state, and flowering is delayed.
Sometimes delays in maturity are detrimental in that crops do not have sufficient time to produce fruits or seeds
before the growing season is ended by frost. For some crops that flower and fruit over a prolonged period, such as
tomatoes and cucumbers, the period of productivity may be enhanced by a delay in maturity.

The relative responses of roots and shoots to nitrogen must be considered. Nitrogen fertilization promotes shoot
growth more than root growth, and higher than optimum amounts of nitrogen will inhibit root growth while more
markedly enhancing shoot growth. With beets, carrots, radishes, sweet potatoes, and other root crops,
overfertilization with nitrogen gives lower yields and lower quality of produce than optimum fertilization. Irish
potatoes are stems (tubers), and heavy applications of nitrogen give favorable yield responses with this crop.

Nitrogen fertilizers are potent materials. It is important to be well acquainted with the kinds of fertilizers that are

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available and with their composition and release of available nutrients. Common nitrogen fertilizers (Table 19) are
discussed in the following section.

Table 19. List and characteristics of common nitrogenous fertilizers.

________________________________________________________________________

Kind of fertilizer Type -----------Availability of nitrogen


----------

Total %N | ----------------Release of

N
z----------------

Urea Chemical 46 Rapid (water-soluble)

Ammonium nitrate Chemical 34 Rapid (water-soluble)

Ammonium sulfate Chemical 20 Rapid (water-soluble)

Diammonium Chemical 18 Rapid (water-soluble)


phosphate

Sodium nitrate Chemical 16 Rapid (water-soluble)

Calcium nitrate Chemical 15 Rapid (water-soluble)

Potassium nitrate Chemical 13 Rapid (water-soluble)

Dried blood Organic 12 Rapid (90%) y

Feather meal Organic 14 Rapid (70%)

Seed meal Organic 6 Rapid (80%)

Sewage Organic 4 Slow (10 to 50%)

Farm manures Organic 2 Slow (10 to 50%)

Composts Organic 1 to 3 Slow (10 to 50%)


________________________________________________________________________

zExpected release in first growing season.

yExpected mineralization of nitrogen in first growing season.

The chemical or manufactured fertilizers have much higher total concentrations and availability of nitrogen than the
organic fertilizers. Release (Table 19) is defined as the amount of nitrogen that is expected to be available in soluble
form from the fertilizer in one growing season. Chemical fertilizers, being water-soluble, will release all of their
nitrogen. Organic fertilizers must be mineralized before they will release their nitrogen. Mineralization is a slow,
microbiological process, the rate of which is dependent highly on the concentration of nitrogen present in the
organic material. Performance of nitrogen fertilizers is increased if they are incorporated into the soil rather than left
on the soil surface after application. Incorporation is virtually a mandatory practice with ammoniacal or organic
fertilizers, such as urea or farm manures, respectively, because of the potential of losses of nitrogen by ammonia
volatilization. Nitrate-based fertilizers are less vulnerable to losses from the surface. Washing soluble nitrogenous

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fertilizers into the soil usually is equivalent to mechanical incorporation.

Chemical Fertilizers for Nitrogen

Urea (CON2H4) . Urea is the most concentrated and most commonly used dry, granular or pelleted nitrogen
fertilizer. Urea, however, is not the most widely used nitrogen fertilizer. Anhydrous ammonia (gaseous ammonia
compressed into a liquid) is used in the largest total amounts and is the most concentrated of the nitrogenous
fertilizers (80% N). Anhydrous ammonia is used widely in corn production. Special equipment is needed to apply
anhydrous ammonia; consequently, it is used infrequently in small-scale agriculture or in gardening.

Urea is sold as such for fertilization of any crop. Urea is a common product in mixed dry or liquid fertilizers used in
large-scale commercial agriculture. It is ofter a major constituent in concentrated, high-analysis, soluble, mixed
fertilizers used on greenhouse crops, gardens, and house plants. Frequently, urea is sold as a sulfur-coated or plastic-
coated material for fertilization of lawns or container-grown plants. The coatings give the urea a property of slow-
release, mimicking organic fertilizers, so that it can be applied directly to turf or mixed in containers without causing
damage to plants. The coatings can be manufactured with varying stabilities so that the availabitities of nitrogen
from the slow-release materials can be governed. Selection of the appropriate material varies with the crop being
fertilized and with the season. With container-grown crops, enough plastic-coated fertilizer may be added at planting
to carry the crop through its growth cycle.

Commercial urea is considered to be a chemical fertilizer because it is manufactured. Commercial urea is chemically
identical to urea in urine. If equal amounts of nitrogen from commercial urea or from urine were applied to a crop,
crop responses would be expected to be the same. Urea is an ammoniacal fertilizer, for the first nitrogenous product
of its breakdown in the soil is gaseous ammonia (or ionic ammonium). Phytotoxicity may be a problem if the
ammonia (or ammonium) is not oxidized rapidly to nitrate. Slow oxidation may occur in cold or wet soils. High
applications of urea may lead to ammonia (or ammonium) concentrations that are phytotoxic.

Although distinctions are made between ammonia and ammonium above, farmers and gardeners need not be
concerned with this distinction. Gaseous ammonia dissolves rapidly in water. A fertilizer of ammonia dissolved in
water is called aqua ammonia. In the field, if ammonia dissolves in water and reacts with other dissolved substances,
it forms the ammonium ion. An equilibrium exists between ammonia and ammonium, and whichever form that
dominates is dependent on the pH of the solution. In alkaline solutions, ammonia dominates, and in acidic solutions,
ammonium dominates.

Applications of urea must be incorporated into the soil. Surface-applied urea is hydrolyzed rapidly to ammonia and
carbon dioxide which react to form ammonium carbonate. Ammonium carbonate is an unstable, alkaline substance
that decomposes quickly back to ammonia and carbon dioxide. On the surface of the ground, the resulting ammonia
will be lost to the atmosphere. If pelleted urea is left on the soil surface, as much as one-third of the urea nitrogen
can be lost in a day or withinin a few days. If urea is incorporated into the soil immediately after application, losses
are nil, for soil water and colloids hold the ammonia and ammonium. If it rains or if irrigation water is applied, the
urea will be carried into the soil, and losses will be nil. Losses of urea from surface-applied liquid fertilizers are
much lower than those from surface-applied dry fertilizer.

Ammonium nitrate (NH4NO3). This fertilizer was the first solid one to be produced on a commercial scale. It
became common after World War II, when industrial plants that had been producing ammonium nitrate for blasting
or for munitions were converted into fertilizer plants. With respect to supplying nitrogen, ammonium nitrate is an
excellent fertilizer. It is a concentrated material (34% N) Half of its nitrogen comes from nitrate and half from
ammonium. This combination makes ammonium toxicity unlikely, even if the ammonium is not oxidized rapidly by
nitrification. On the other hand, ammonium nitrate is a strong oxidizing material. If it becomes contaminated with
carbonaceous materials, it may be somewhat unsafe to handle. This fertilizer should be used up and not stored
around the house or farm. Ammonium nitrate also has a tendency to absorb water and to cake even if prilled
(pelleted). Production of dry ammonium nitrate as fertilizer is declining, so that the availability of ammonium nitrate
for direct application is limited. One usually has to purchase ammonium nitrate early in the season, before supplies
stocked for sale are exhausted. Ammonium nitrate along with urea is a constituent of liquid fertilizers commonly
called UAN (urea ammonium nitrate) solutions.

Ammonium sulfate [(NH4)2SO4]. Ammonium sulfate is also a fertilizer with a long history of use, as it is a by-

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product of many industrial processes. It also is produced directly for use as a fertilizer. Today its use is limited by its
relative low analysis (21% N). Ammonium sulfate acidifies the soil, and its use in the United States is mainly on
alkaline soils. It is recommended sometimes for use on crops that are said to be acid-loving, such as rhodendrons,
azalea, and blueberries. It is used frequently in rice production. On acid soils, ammonium toxicity can be a problem
with use of ammonium sulfate, even with acid-loving crops. The grower must be careful to avoid overapplication of
ammonium sulfate because of the potential for ammonium toxicity. Ammonium sulfate has an advantage over other
nitrogen fertilizers in that it supplies sulfur as well as nitrogen.

Diammonium phosphate [(NH4)2HPO4]. This fertilizer is used primarily for its phosphorus (46% P2O5), although
it has a relative high nitrogen concentration (18% N). It is water-soluble fertilizer and is used frequently in mixed
liquid fertilizers and concentrated mixed dry fertilizers. It can be applied at any time but has good use as a starter
fertilizer.

Sodium nitrate (NaNO3). Sodium nitrate was the first commercial nitrogen fertilizer in the United States. Its origin
was ore deposits in Chile and was sold as Chilean nitrate. Today, although some is manufactured, most of the
sodium nitrate used in the United States is imported from Chile. Chilean nitrate a naturally occurring fertilizer. It is
not considered as organic because it is purified in processing and has a relatively high analysis (16% N) and
solubility in water. Sodium nitrate has a only a minor role as a nitrogen fertilizer today in the United States and is
not readily available in the marketplace. Sodium is

not a plant nutrient, and its application to soils, particularly acid, clayey soils, should be avoided. Sodium in
exchange sites of clays causes colloidal dispersion and leads to poor soil structure.

Calcium nitrate [Ca(NO3)2]. Calcium nitrate was among the first manufactured nitrogen fertilizers. Almost all of
the calcium nitrate available in the United States comes from Norway, where it was first manufactured with use of
electricity from hydroelectric power. Calcium nitrate is a high quality nitrogen fertilizer but is expensive per unit of
nitrogen. Transportation costs make this material uneconomical for use on an agronomic scale. It is not a commonly
available fertilizer in the United States but is an important source of nitrogen in Europe. Calcium nitrate absorbs
water, and this tendency limits its use as a bagged, dry fertilizer. This fertilizer supplies calcium, which is a plant
nutrient and which has favorable effects on soil structure. Clays that have a predominance of calcium on their
exchange sites can have a good, aggregated structure. Calcium nitrate is recommended as a calcium fertilizer to
control blossom-end rot on tomato.

Potassium nitrate (KNO3). Potassium nitrate provides two nutrients, nitrogen (13%) and potassium (46% K2O).
Although this fertilizer is an excellent material for use on any crop, it is expensive relative to other commercial
sources of nitrogen and potassium and is used mainly on high-value crops. It is excellent for supplemental
fertilization as side-dressings or top-dressings after plants are established and growing. The fertilizer is water-
soluble and can be applied in solutions.

Organic Fertilizers for Nitrogen

Dried blood. This organic fertilizer is mostly protein, has a high nitrogen content (12% N), and mineralizes rapidly.
Its action in the soil is much like that of a chemical fertilizer. Dried blood can be used at any time in the growing
season. Since its nitrogen becomes available rapidly, it would be a good organic source of nitrogen for supplemental
fertilization of an established crop. Since dried blood mineralizes rapidly, ammonium build up in the soil may be
rapid. Because of the possibility of ammonium injury, dried blood should be applied away from germinating seeds
and roots of young plants. Dried blood is an expensive source of nitrogen and, even if purchased in bulk, is
affordable only for use on small plots. Because of its rapid mineralization, very little of the nitrogen in the blood
would be expected to be carried over in the organic form for the next cropping season. Dried blood has little or no
value as a source of phosphorus or potassium. Dried blood should be mixed in the soil. Nitrogen will be lost rapidly
from surface applications.

Feather meal. Feathers are proteins and are a good source of nitrogen. Feather meal should be used in the same way
as dried blood. The proteins in feather meal may be slightly more resistant to mineralization than those in dried
blood, but this difference is not likely to be evident in practice. Other nutrients in feather meal are in very low
concentrations, and it should be considered only as a nitrogen fertilizer.

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Seed meals. Seed meals are the residues left after oils are extracted from seeds. Cottonseed oil meal and castor
pomace are fairly well known seed meals, which are used as organic fertilizers. Soybean oil meal is used less
frequently as a fertilizer. Cottonseed oil meal and soybean oil meal are valuable as protein supplements in animals
feeds; consequently, they are expensive as fertilizers. Castor pomace is poisonous, for the castor bean from which it
is derived has a very toxic alkaloid (ricinine). Castor pomace is not used as feed and is cheaper than the other oil
meals. Castor pomace is poisonous to humans and should be handled with care to ensure that none of its powder is
inhaled.

Seeds meals are slower to mineralize in the soil than the nitrogen-rich animal products. Seed meals may be
incorporated into the soil at planting but application before planting is preferable. Their rate of mineralization is
moderate but not rapid enough to be considered as a fertilizer for side-dressing or other supplemental applications.
Initial decomposition of seed meals is rapid. If the seed meals are placed close to germinating seeds or seedlings,
seeds will rot, and damping-off disease of seedlings will occur. If possible, seed meals should be applied two weeks
ahead of planting to allow for their rotting and to alleviate possibilities of seeds rotting or damping-off. Seed meals
should be considered only as nitrogen fertililzers, for their contents of phosphorus and potassium are too low to be
considered practical.

Sewages. The sludge or biosolids from municipal wastewater treatment plants is a source of nitrogen. This material
has some phosphorus but is essentially void of potassium, which has been washed out in the effluent. Sewage
biosolids are commercially available. Sewage bioslids from Milwaukee have been marketed for decades. Sewage
biosolids occasionally may be available from local wastewater treatment plants. Toxic heavy metals, such as,
cadmium, nickel, copper, zinc, and lead, are suspected hazards in virtually all sewage biosolids. Although with
control of point sources of pollution, the concentrations of heavy metals in sewage biosolids is being reduced to
levels that are safe for application to farmland.

If present in biosolids, metals are adsorbed by the soil and will remain there for long periods of times.
Contamination of soils with heavy metals is a drawback to the use of sewage biosolids as nitrogen fertilizer. Because
of this hazard, sewage biosolids should be avoided or used with caution in the production of food crops. Sewage
biosolids from local treatment plants may be high in paper if the sludge is raw or undigested. This kind of material
should be composted before it is applied to the land. Some treatment plants may have facilities in which biosolids
and wood chips are composted into a product that is made available for sale to the public. Sewage biosolids is
sometimes surface-applied to turf; otherwise, it should be mixed into the soil. Ammonia loss from surface
applications will be high; particularly, since biosolids are usually made alkaline by incorporation of calcium
carbonate at the treatment plant.

Farm manures. Applications of farm manures to land are discussed more extensively in Chapter 3. In summary,
farm manures are nitrogen fertilizers ranging from 1% to 3% N on a dry weight basis and from 10 lb N/ton to 30 lb
N/ton on a wet (fresh) weight basis. Manures applied as fertilizers should be incorporated into the soil about two
weeks ahead of planting. This mode of application will conserve nitrogen against losses from ammonia
volatilization and will permit ammonium formed in the soil to be oxidized to nitrate before the crops are in the soil.
The amount of application should be about 1 lb of fresh material per square foot of land (20 tons/acre).

Composts. Use of composts is discussed in Chapter 4. In general, composts are applied in the same manner as
manures except that the lead time of two weeks ahead of planting is not necessary. Chances of damaging seeds or
seedlings from compost are much lower than from manures. Chapter 4 deals with how growers can make their own
composts. Today many composts are manufactured commercially. Some of these composts are made from farm
products, such as manures, products of food processing plants, and wood chips. Others are made from municipal
solid wastes, such as paper, yard wastes, leaves, and sewage sludge. All users of commercial composts should know
the composition of the composts with respect to plant nutrients and other elements.

Miscellaneous and specialty nitrogen fertilizers.

Many of these materials are imported or are only of local origin. Scarcity and cost limit their general use in many
cases.

Urea reacts with formaldehyde to produce a slow release fertilized (urea-form, 38% N) which is used is used in
formulation of fertilizers for turf. Isobutylidenediurea (IBDU, 32% N) also is a slow-release material commonly

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used on turf. Peanut hulls (1.5% N), cotton bolls (1% N), cocao shells (2.5% N), alfalfa hay or meal (2.5% N) are
plant-derived nitrogen fertilizers with slow to moderate rates of release of nitrogen. Wool wastes and felt have about
8% N each. These materials treated with sulfuric acid to increase their release of nitrogen are called rough
ammoniates. Fish meal and fish scrap have 5% to 10% N of which half or more will be available in a season. Guano
(excrement of birds and bats), about 10% N, is a scarce material rarely used today.

Most farmers and gardeners will use mixed or multinutrient fertilizers in all or in a portion of their programs in soil
fertility. Multinutrient fertilizers are guaranteed to have more than one of the primary macronutrients, nitrogen,
phosphorus, and potassium. Examples of such fertilizers are 5-10-10, 10-10-10, and 20-20-20. The nitrogen in these
fertilizers will be derived from at least one of the above-mentioned chemical fertilizers.

Phosphorus Fertilizers

Effects of Phosphorus Fertilizers on Plant Growth

The role of phosphorus is most prominent as a constituent of genetic material, the nucleic acids, DNA and RNA.
Phosphorus has another major function in the metabolic processes of energy transfer. Energy from respiration and
photosynthesis is stored in phosphate bonds of energy-rich compounds (e.g., ATP, adenosine triphosphate) in plants
and in animals. The phosphorus requirements of plants is about one-tenth to one-fourth the amounts of nitrogen
required.

Plants absorb phosphorus as phosphate ions (principally H2PO4-). Plants respond with increased growth or yield in
about half of the cases in which phosphorus fertilizers are applied. New land or land that has not been cropped or
fertilized recently is more likely to be phosphorus-deficient than land that has been cultivated and fertilized. The
high frequency of response of crops to fertilization with phosphorus is the reason that phosphorus is considered as a
primary macronutrient, for its accumulation in plants does not exceed that of calcium, magnesium, and sulfur, which
are considered as secondary macronutrients. The elemental phosphorus concentration of phosphorus-sufficient
plants typically ranges from 0.2 to 0.4% of the dry weight of foliage. Leaves that have less than 0.15 to 0.2% actual
P probably are phosphorus deficient. Plants grown in soil normally will have less than 0.5% actual P. Concentrations
approaching or exceeding 0.8% occur with plants grown hydroponically or in well-fertilized media in containers.

Phosphorus-deficient plants are stunted (Table 17). The stunting may at first be difficult to recognize, for the plants
may appear dark green and otherwise normal. A well-nourished plant would have to be available as a standard of
comparison to indicate optimum growth. Phosphorus is a mobile element in plants. It will move from old leaves to
young leaves and growing points and into fruits and seeds. If phosphorus becomes deficient through exhaustion of
available soil reserves, deficiencies will appear as reddening or purpling of the lower leaves, particularly on the
undersides of the leaves. These leaves may later become yellow or dead and drop off. A plant that is stunted or
otherwise exhibiting deficiencies of phosphorus deficiency is very difficult to nourish back to a state of full
nutrition. Losses of yields or quality are certain to result any time that phosphorus deficiency occurs.

The concentration of phosphorus in the soil solution is only a few tenths parts per million in unfertilized soils. Most
phosphorus salts in the soil are present as sparingly soluble phosphates of iron, aluminum, calcium, and magnesium.
Plants receive only a fraction, perhaps 20% or less, of the phosphorus that is applied in fertilizers. Soils have strong
capacities to fix phosphorus. Phosphorus fixation by soils refers refers to the precipitation of phosphate by iron and
aluminum in acid soils and by calcium and magnesium in alkaline soils. Fixation in acid soils is the more common
process in humid temperate regions.

Generally, phosphorus in soil or from fertilizers is most available to plants in the pH range of 6 to 7. An exception,
might be in the case of rock phosphate for which availability of phosphorus is favored by acidic conditions, which
help to dissolve the rock. An abundance of organic matter in the soil helps to limit fixation and to keep phosphorus
in solution. Organic matter forms complexes (chelates) with iron and aluminum ions and lessens their reaction with
phosphates, thereby lessening precipition. The acids from the decay of organic matter also help to dissolve rock
phosphate or other difficultly soluble phosphorus fertilizers.

Because of fixation, phosphorus builds up in soils, and after many years of fertilization, use of phosphorus fertilizers
may not be necessary. Soil tests are accurate in determining if this condition of enrichment exists. Also, because of
fixation and the relatively low solubility of most phosphorus fertilizers, overfertilization with phosphorus may occur

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but is unlikely. The problems that occur with overfertilization with phosphorus fertilizers may be imbalances that
render minor elements unavailable to plants.

Chemical (manufactured) and organic phosphorus fertilizers are marketed (Table 20). As a rule, the chemical
fertilizers are the superior products and are the easiest to obtain. Much more attention needs to be given to
procedures for application of organic fertilizers and to the conditions of the soil than for use of the chemical
fertilizers. Proper use of each fertilizer will be discussed below.

Chemical Fertilizers for Phosphorus

Superphosphates. Superphosphates are manufactured by treatment of rock phosphate with sulfuric acid or with
phosphoric acid. The purpose of this process is to increase the effectiveness of rock phosphate by its acidulation into
more soluble compounds. This process dates back to about 1840, when Justus von Liebig, a physical chemist in
Germany, demonstrated that the value of bones as fertilizer could be increased by treating them with sulfuric acid.
Liebig is credited with the development of the first chemical fertilizer.

Table 20. List and characteristics of some common phosphorus fertilizers.

Kind of fertilizer Type -------Availability of phosphorus----------

Total % P2O5 |---------Release of P-----------

Ammoniated Chemical 46+ Rapid (water -soluble)


phosphates

Triple Chemical 46 Rapid (moderately water-


superphosphate soluble)

Ordinary Chemical 20 Rapid (moderately water-


superphosphate soluble)

Rock phosphate Organic 30 Very slow

Colloidal rock Organic 20 Very slow


phosphate

Bonemeal Organic 24 Slow


________________________________________________________________________

The product of the reaction of sulfuric acid and rock phosphate is ordinary superphospate. This material is a mixture
of phosphates, mostly monocalcium phosphate, a fairly water-soluble material, and gypsum. Ordinary
superphosphate has the chemical formula, Ca(H2PO4)2.CaSO4. Triple superphosphate is produced by treatment of
rock phosphate with phosphoric acid. The end product is mostly monocalcium phosphate, Ca(H2PO4)2; hence, triple
superphosphate, missing the gypsum of ordinary superphosphate, is about 46% P2O5 compared to 20% P2O5 for
ordinary superphosphate. The availability of phosphorus does not differ between the two superphosphates. About
85% of the phosphorus is water-soluble in these fertilizers. The name triple superphosphate dates back to the time
when ordinary superphosphate was 16% P2O5 and triple superphosphate was 48% P2O5. Triple superphosphate
sometimes is called concentrated superphosphate. Strictly speaking concentrated superphosphate is another product
with about 54% P2O5 and is used mainly in mixed nutrient fertilizers.

Because of its lower analysis, ordinary superphosphate is declining in importance. More than twice as much
ordinary superphosphate would have to be applied to supply the same amount of total phosphorus carried in triple
superphosphate. Costs of transportation make it more economical to ship the more concentrated material. About
one-third of the fertilizer phosphorus used in the United States is supplied by triple superphosphate. Triple
superphosphate or concentrated superphosphate is common in dry, bulk blends of mixed fertilizers.

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Superphosphates may be applied directly to the soil. Modern superphosphates are pelleted or prilled materials.
These materials can be incorporated by broadcasting and mixing in the soil or by placing in a band along side of
rows of seeds or transplants. All of the phosphorus fertilizer should be applied at one time at planting. Most
recommendations for applications of superphosphates specify that they be broadcasted and disked in or drilled in
about 2 inches below and 2 inches to the side of the seed row. Banding usually allows for more efficient use of
phosphorus but may require more labor and care or special implements than broadcasting.

Because of precipitation by fixation, phosphorus is not very mobile in soils and will not move more than a
centimeter or so (about a half inch) from a pellet. With banding, the concentrated placement, which is not reacted
with the soil, helps to provide a constant supply of phosphorus. A one-time large application helps to ensure that
young, sparsely rooted seedlings in cold soils of the spring season are able to obtain adequate phosphorus.

Superphosphates are 17% to 22% calcium. Supplying the phosphorus requirement of plants with either of these
fertilizers generally ensures adequate nutrition with calcium. Ordinary superphophate is richer in calcium than
concentrated superphosphate and also has 10% to 12% sulfur of which concentrated superphosphate is essentially
void. The absence of sulfur in concentrated fertilizers may be of concern in areas in which sulfur contents of soils
are marginal for crop production.

Ammoniated phosphates. Ammoniated phosphates are produced by reactions of ammonia and phosphoric acids.
Depending on the manufacturing process one or more chemical salts or their mixtures are produced. Ammoniated
phosphates are marketed in liquid and dry formulations. These phosphates are more soluble in water than the
superphosphates and are used frequently to make mixes of soluble fertilizers for use in greenhouses and gardens and
for houseplants. They are available also for direct application in production of agronomic and horticultural crops.
The principal ammoniated phosphates are monoammonium phosphate (NH4H2PO4), diammonium phosphate
[(NH4)2HPO4], and ammonium polyphosphate (pyrophosphate). They have concentrations of P2O5 from 46% to
62% and are equally effective in suppling phosphorus to plants.

Liquid fertilizer applied in bands or broadcasted and worked in gives the same response as dry, water-soluble
fertilizer applied in the same way. As with dry fertilizers, band application of liquid gives superior results to
broadcasted applications. Banding lessens contact between soil and fertilizer and restricts phosphorus fixation.
Monoammonium phosphate and diammonium phosphate are the most commonly used dry materials. Diammonium
phosphate is the most widely used phosphorus fertilizer in the United States.

Some care must be taken in the use of diammonium phosphate as a starter fertilizer. Diammonium phosphate, which
has loosely bound ammonia, gives an alkaline solution (pH 8 in saturated solutions), whereas monoammonium
phosphate makes an acid solution (pH 4). Application of diammonium phosphate in direct or close contact with
seeds can result in ammonium toxicity to the seeds. Although any soluble salt can damage seeds or roots by
plasmolysis, the problems of ammonium toxicity are less likely with monoammonium phosphate or ammonium
polyphosphate than with diammonium phosphate.

Liquid or dry fertilizers sold as starter fertilizers or for other uses have their constituents printed on labels of the
cartons, and users should take care to read these labels before application of the fertilizers.

Organic Fertilizers for Phosphorus

Plant and animal tissues. Phosphorus concentrations in plant materials, farm manures, and composts are too low for
these materials to be practical sources of phosphorus for the short term. The amounts of materials that need to be
applied limit the feasibility of use of these materials as phosphorus fertilizers for single applications in one season.
Long-term use of these materials may lead to build up of phosphorus in the soil, and the organic matter in these
materials makes them good amendments for application with phosphorus fertilizers. Organic matter additions to the
soils generally improve the nutritional availability of phosphorus from any source.

Phosphatic materials derived from animal bodies have much higher phosphorus concentrations than those from plant
materials and can be used directly as phosphorus fertilizers as well as being processed into the chemical fertilizers
mentioned above.

Rock phosphate [Ca10(PO4)6F2]. Rock phosphate occurs as sedimentary deposits of marine organisms. Principal

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deposits in the United States are in Florida, North Carolina, Tennessee, Wyoming, Idaho, and Montana. About 80%
of all rock phosphate mined in the United States comes from Florida and North Carolina. The products that are sold
for direct application to land come from Florida and Tennessee. Regardless of source, rock phosphate is an often
very hard, nearly inert material. It has a chemical composition similar to enamel of teeth. Since rock phosphate is of
biological origin, the phosphorus content of ores varies. At the fertilizer plant, the ore is washed to remove
impurities such as sand and clay. The washed materials go into waste ponds. Methods of pumping the washings into
the waste ponds give separation of sand and clay deposits. The clay deposits are marketed as colloidal rock
phosphate (from Florida). Material marketed as regular rock phosphate is from Tennessee.

Because of the fineness of the waste-pond colloidal phosphates, claims are made that they are superior to regular
rock phosphate. These claims should be discounted, for colloidal rock phosphate has a lower analysis (20% P2O5) as
it is regular rock phosphate (30% P2O5) diluted with clay or silt. On the other hand, regular rock phosphate should
be pulverized to at least silt-sized particles before it has much value as a fertilizer. If colloidal rock or regular rock
phosphate are not used properly, crop responses may not be any different than if no phosphorus fertilizers were
applied at all.

Rock phosphate or colloidal rock phosphate should be applied at double or quadruple the recommended rate for
superphosphates or ammoniated phosphates. If the user is close to the site of production of rock phosphates,
shipping costs may be low enough so that these amounts of application are economically reasonable.

The rock phosphates must be pulverized finely and mixed well into the soil. The soil should be about pH 5.5.
Mixing the finely divided material into an acid soil brings the rock into close contact with the soil acids so that the
rock may be solubilized. In essence, the acids of the soil acidulate the rock into a form of superphosphate. More
strongly acid soils should be limed to raise them to pH 5.5. If the soils are much below pH 5.5, so much iron and
aluminum are in solution that the dissolved phosphate is unable to move in the soil because of fixation. Organic
matter should be added in generous amounts, at least 20 tons/acre (1,000 lb/1,000 sq. ft.). Organic matter increases
the availability of phosphorus in rock in that organic acids produced during decomposition of the organic matter
help to dissolve the rock and in that the organic matter complexes (sequesters or chelates) iron and aluminum
allowing the dissolved phosphate to remain in solution. Irrigation may help in increasing the availability of
phosphorus from rock sources.

Rock phosphates can be mixed in direct contact or in close proximity to seeds, roots, or bulbs, for the low solubility
of the rock prohibits the possibility of the creation of any stresses from salinity.

Bonemeal. The product that should be used is steamed bone meal. The principal sources of bones are from slaughter
houses. Raw bones are boiled and steamed to remove fats and proteins. The fats and proteins may go to the
manufacture of gelatins and glues. The resulting bones are nearly nitrogen-free, maybe 1% N, so that steamed
bonemeal is not a nitrogen fertilizer. Raw bonemeal may have 4% N but should not be used as it has not been
steamed and sterilized. The steamed bones are ground into meal. The resulting product has 22% to 30% P2O5,
averaging about 24%. Bone meal is much superior to rock phosphate and is approaches the value of ordinary
superphosphate. The phosphorus in bones is a little less available than that in the superphosphate, for bones are
about chemically equivalent to tricalcium phosphate [Ca3(PO4)2], which is sparingly soluble compared to the
monocalcium phosphate of the superphosphate.

Bonemeal should be mixed well into soils of pH 6. Organic matter should be used generously as with the rock
phosphates. Bonemeal can be placed in direct contact with seeds, roots, or bulbs without damage to the plant tissues.
The sparingly soluble nature of the phosphorus compounds in the bonemeal prohibit any damage from salinity.

Bonemeal is an expensive material compared to all other commercial sources of phosphorus. Its high price limits its
use to garden-size or smaller applications. Its rate of application to soils should be about the same as that of ordinary
superphosphate.

Miscellaneous and specialty phosphorus fertilizers. Basic slag is a by-product of refining of pig iron (crude cast
iron) to steel. In the Bessemer process, pig iron and lime are heated to a molten state. The lime reacts with
phosphoric acid and other impurities and floats to the surface, where it is poured off as slag. The cooled slag is
ground to a fine powder. Slag is 8% to 12% P2O5. It is a liming material, being 70% as effective as agricultural
limestone. Slag is best suited for long-season crops in acid soils. It is not used much in the United States, with most

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of its use being in Europe.

Practically all crops that are fertilized with nitrogen and phosphorus are fertilized with multinutrient materials.
These materials may be supplemented with potassium fertilizers, usually potassium chloride, to make a complete
commercial fertilizer. Some nitrogen and phosphorus compounds are manufactured specifically for mixed fertilizers.
These materials include some of the fertilizers described above but also others such as nitric phosphates and
ammoniated superphosphates. The latter materials are mixtures of nitrogen-containing compounds and phosphorus-
containing compounds. These multinutrient fertilizers generally are as effective as the individual fertilizers,
especially for nitrogen. Some of the phosphorus-containing compounds may not be as water-soluble as some of the
individual fertilizers discussed above. It is doubtful that differences in crop response could be noted between crops
fertilized with multinutrient fertilizers and mixtures or individual applications of the phosphorus fertilizers described
above.

Potassium Fertilizers

Effects of Potassium Fertilizers on Plant Growth

Potassium is usually the most abundant cation in plants. Nitrogen is the only nutrient accumulated consistently in
quantities that exceed those of potassium. Some plants accumulate more calcium than potassium. The sufficiency
zone for potassium accumulation typically is from 1.5% to 3% actual K. With well-fertilized plants, potassium may
accumulate to levels well above 5% into what is known as the concentration range of luxury consumption.
Accumulation in the luxury range has no ill effects on plants. Accumulation above the luxury range may have ill
effects in that calcium and magnesium accumulation may be suppressed to the point of deficiency.

In spite of the requirement for large amounts of potassium, the specific function of potassium eluded scientists for
many years, mainly because all of the potassium is in plants is in ionic form and no organic compound has
potassium in any permanent combination. Recently it has been ascertained that the roles of potassium in plants are
catalytic or osmotic functions. Potassium has a role in activation of enzymes, which are proteins that catalyze
metabolic reactions. Potassium appears to impart a specific structure that makes the enzymes functional. Potassium
has a known catalytic role in protein synthesis and apparent roles in photosynthesis. The opening and closing of
stomates in leaves is regulated by turgor pressure brought about by the movement of potassium into and out of the
cells surrounding the stomates. The turgor pressure in leaves may be regulated by potassium. Growth of cells by
expansion may be due in part to the turgor pressure brought about by high concentrations of potassium in cells.
Potassium is a mobile element in plants. It will move from sites where it is needed less to sites where the demand is
greater. If potassium is depleted in the soil, the potassium that is in the plant will move from the old leaves to young
leaves. The old leaves will become deficient in potassium and will die at their edges and tip. This condition is called
firing or scorching.

Stems of potassium-deficient plants may become weak due to internal breakdown or failure of supporting cells to
develop. Although grain is not high in potassium, seeds of cereals will be unfilled or chaffy, and ears or corn will
fail to fill at the tips, producing what are called nubbins. Often fruits of potassium-deficient apple or pepper are
misshapen. Blotchy ripening of tomato has been associated with potassium deficiency. Although potassium appears
to have a role in the growth and development of fruits and seeds, they are not rich in potassium, as about two-thirds
of the potassium remains in the vegetative portions of the shoots.

About half of the soil in the United States are deficient in potassium for optimum plant growth. These soils may be
sandy or organic soils from which potassium has leached. Potassium-deficient soils also may be ones from which
the readily available potassium has been exhausted leaving behind the the difficultly available potassium, which
supplies potassium too slowly to meet the needs of crop growth. Potassium exists in the soil in several forms (Figure
15). Plants absorb potassium (K+) from only the ionic form in soil solution. Exchangeable potassium from the soil
colloids (clays and humus) is readily available, for this form enters easily into the soil solution. Nonexchangeable
potassium is fixed in the lattice structure of clays. It is trapped in the structure and is not released unless some
mechanism opens the lattice to permit the potassium to diffuse into the soil solution. The nonexchangeable fraction
is from 2% to 10% of the total soil potassium and represents a reservoir of slowly available potassium from which a
plant may draw during the growing season. The release of potassium from the nonexchangeable sites depends on the
types of clay, moisture, pH, and presence of other cations in the soil. Almost all of the potassium in the soil is in the
primary minerals or slowly available fraction. These primary minerals are feldspars and micas, which are derived

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from the weathering of rocks from the parent material. They are resistant to weathering further and are very slowly
soluble; hence, the amount of potassium released from this fraction is very small although the total amount present
is large.

Figure 15. Equilibrium relationships between forms of potassium in soils.

Previously, it was believed that soils did not have to be fertilized with potassium, for tests for total soil potassium,
which includes the primary minerals, revealed an abundance of potassium. After World War II, when the production
and consumption of commercial nitrogen and phosphorus fertilizers increased, the potassium supplying power of
many soils was exhausted. High yields brought about by fertilization with nitrogen and phosphorus placed high
demands on the soil to supply potassium. The readily available soluble and exchangeable potassium and the slowly
available nonexchangeable potassium were removed by the crops. The virtually unavailable potassium in the
primary minerals remained but was unable to supply potassium rapidly enough to meet the needs of crops. A similar
event occurred in the early agricultural history of the colonial United States. The practice of recommending that a
fish be placed in a hill of corn ultimately failed because the fish provided nitrogen and phosphorus but little
potassium. The enhanced corn production brought about by fertilization by fish soon depleted the soils of their
available potassium, and yields were diminished afterwards. Today, several potassium fertilizers are marketed
individually or in mixed carriers (Table 21).

Table 21. List and characteristics of some common potassium fertilizers

_______________________________________________________________________________

----------Potassium -----------------Characteristics---------------------------
fertilizer----------------
Availability of potassium

Kind Type Total%K20 Release of K

Potassium Chemical 60 Rapid (water-soluble)


chloride

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Potassium Chemical 52 Rapid (water-soluble)


sulfate

Potassium Chemical 21 Rapid (water-soluble)


magnesium
sulfate

Potassium Chemical 44 Rapid (water-soluble)


nitrate

Wood Organic 5-10 Rapid (water-soluble)


ashes

Seaweed Organic 6 Rapid (water-soluble)

Greensand Organic 6 Unavailable

Granite Organic 5 Unavailable


dust

Farm Organic 2 Rapid (water-soluble)


manures
_______________________________________________________________________________

The highest quality materials are chemical fertilizers. The organic farmer and gardener has difficulty in preventing
depletion of soil of its potassium, for they do not have good fertilizers in an abundant supply to replenish the
potassium removed by crops. The organic farmer and gardener depend on plants to mine the soil for available
potassium.

Chemical Fertilizers for Potassium

Potassium chloride (KCl). In the trade, this fertilizer is known as muriate of potash, with its name being derived
from muriatic acid (hydrochloric acid). It is the most widely used potassium fertilizer in the world, constituting as
much as 95% of the total consumption of potassic fertilizers. Most of the potassium chloride comes from refining of
mined products of deep salt deposits on the earth. The world's largest deposit of high-grade ore is in Saskatchewan,
Canada. The United States is a relatively minor producer, along with Germany, France, Spain, Ukraine, Israel, and
Zaire. Potassium chloride is the most inexpensive carrier of potassium on the market.

Potassium chloride is a water-soluble, concentrated fertilizer. Although it is naturally occurring, its high solubility
and high analysis prevent its acceptance as organic. It is sold for direct application to soil and is the most common
potassium carrier for mixed fertilizers.

Potassium sulfate (K2SO4). This fertilizer is manufactured by refining of ores by washing or by treatment of
potassium chloride with sulfuric acid. Potassium sulfate has a lower analysis than potassium chloride and is more
expensive. On a potassium-equivalent basis, potassium sulfate is as good as or better than potassium chloride for
production of crops. Irish potatoes, tobacco, and maybe corn are sensitive to high amounts of chloride, and
potassium sulfate is preferred by some growers of these crops. Most of the potassium sulfate used in the United
States is used by tobacco growers.

Potassium magnesium sulfate (K2SO4.2MgSO4). This material, known in the trade as sulfate of potash magnesia,
is produced by refining langbeinite ores by washing, which removes the more soluble KCl. It is a useful fertilizer in
that it supplies potassium (21% K2O), magnesium (11%), and sulfur (21%). It is sold under several registered trade
names for direct application to the soil. It is listed in some mail order catalogs as being an organic fertilizer. Its
origin at the mine is no different from that of potassium chloride or sulfate, and it is also a refined product cleaned
by washing. Perhaps, its lower analysis of potassium and somewhat slower dissolution than potassium chloride and
its contents of magnesium and sulfur permit its acceptance as organic.

Potassium nitrate (KNO3). Potassium nitrate is known also as saltpeter or nitre and is viewed as being primarily a

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nitrogen fertilizer. It is worth considering as a potassium fertilizer, because of its relatively high analyses. High costs
of production limit its widespread use. Its limited use is in some water-soluble concentrates and lawn fertilizers.

Organic Fertilizers for Potassium.

Wood ashes. Wood ashes are an excellent source of potassium. Burning of wood drives away all of the carbon and
leaves an ash that is usually more than 5% K2O. Ashes from softwoods may be lower, and ashes from hardwoods
may be higher than this analysis. After burning the potassium may be present mostly as potassium oxide, but with
time it will react with the air, and potassium carbonate will be formed. In any case, the potassium in wood ashes is
water-soluble and on a potassium-equivalent basis would be as good as any chemical fertilizer. Wood ashes are also
high in calcium oxide or carbonate and are valuable as a liming material. Wood ashes have about half the liming
equivalency of agricultural limestone. Care needs to be taken in application of wood ashes to avoid creating alkaline
soils and what is known as the over-liming effect. Dumping or prolonged disposal of wood ashes on the same site
can elevate soil alkalinity to levels that will inhibit plant growth. Reports of pH 11 in soils on which wood ashes are
dumped are common. The limiting factor in the use of wood ashes in agriculture is their limited supply.

Seaweed and other plant materials. A truly remarkable phenomenon is that algae (seaweed) grow in the ocean and
accumulate potassium and do not accumulate sodium. The concentration of sodium in sea water is nearly a hundred
times the concentration of potassium; yet potassium is accumulated, and sodium is excluded by the seaweed. One
does not have to worry about the transmission of sodium by application of seaweed to land. The kelp of seaweed can
be washed free of any sodium that adheres to their external surface. The potassium that is held in the kelp will wash
out only after the kelp is dead. The limiting factor in use of kelp is its limited supply and distribution and its high
costs. Commercially available liquid seaweed, after it is diluted for application, has little value as a source of
potassium because of its low analysis.

Essentially all vegetative plant materials are rich in potassium unless they have been grown under potassium-
deficient conditions. Plant materials may range from 1% to 9% K2O. All of their potassium would be available, for
it can be extracted from dead plants by water. Seeds and the flesh of fruits are low in potassium, but peelings, rinds,
and hulls are comparable in potassium to that of vegetative organs. On an potassium-equivalent basis, plant
materials are as good as chemical fertilizers. Low analysis and bulk limit their use as potassic fertilizers. Plant
diseases, such as mosaic virus from tobacco, may present problems in the application of plant materials on crops
that are susceptible to the diseases.

Manures. Farm manures, being of plant origin, are good sources of potassium, and if applied in quantities to meet
the nitrogen requirements of a crop will also meet its potassium requirement. Dehydrated, unleached manures have
about 2% K2O, and composted manures have about 1% K2O. Fresh manures with some bedding deliver about 10 lb
of K2O per ton. Manures or composts that are subjected to leaching from rain water will have low concentrations of
potassium, maybe no more than half that of the unleached materials.

Greensand and granite dust. Greensand is potassium glauconite , a naturally occurring mineral. It occurs in
deposits of sand-sized materials in coastal New Jersey and vicinity. Its total K2O is about 6%, but none is water-
soluble. Thus, none of the potassium is considered available. Granite contains minerals of feldspars and micas,
which are potassium-containing minerals. Finely ground granite dust from Georgia or Massachusetts is sold as a
source of potassium. These dusts are about 5% K2O, but potassium availability is nil. These materials are expensive
and would have to be used in very large quantities to improve soil fertility. Some recommendations are to apply as
much as 5 to 10 tons of granite dust or greensand per acre per year. To apply potassium in one application in these
quantities could exceed the value of the land. In most soils, weathered granite dust already exists in the primary
minerals. Further additions of granite dust may contribute little to the total potassium reserves in these soils and give
negligible increases in crop yields.

Calcium Fertilizers

Effects of Calcium on Plant Growth

Calcium is necessary for cell division and growth by expansion. The layer of pectin that is between cells is a
calcium-containing material. Calcium is needed for maintenance of membranes in cells. If calcium is deficient,
nutrient absorption by plants may be perturbed. The growing points (vegetative buds and surrounding leaves) of

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calcium-deficient plants die. Shoots will die back to the first fully expanded or mature leaf. Dieback occurs only in
conditions of severe calcium deficiency; however, a number of disorders occur in fruits and vegetables (Table 22).
Produce that has these disorders is unmarketable or inedible.

Table 22. Disorders resulting from calcium deficiency of fruits and vegetables.

________________________________________________________________________

Disorder
Fruits Vegetables
Bitter pit (apple) Blossom-end rot (tomato, pepper, watermelon)
Scald (apple)z Blackheart (celery)
Internal breakdown (apple) Internal tipburn or browning (lettuce, cabbage, brussels sprouts)
Water core (apple) Brownheart (escarole)
Cracking (cherry) Cavity spot (carrot)
Soft nose (mango, avocodo) Unfilled kernels (peanut)
Pod split (bean, pea)
______________________________________________________________________________________________

z Possibly calcium related disorder

Fertilization with Calcium

Fertilization of plants with calcium normally occurs with the application of the primary macronutrients or with
liming of soil. Many of the carriers of nitrogen and phosphorus are calcium-containing compounds (Table 23). All
liming materials contain calcium. Gypsum (calcium sulfate), which is used as an amendment to improve structure of
clayey soils, supplies calcium. Calcium sulfate is applied specifically to increase available calcium to peanuts.
Calcium chloride (CaCl2) is one of the rare materials that are applied specifically to crops to improved their status
with respect to calcium nutrition. It is used occasionally to increase the calcium supply to apple fruits.

Table 23. Fertilizers or soil amendments that contain calcium.

________________________________________________________________________

Material Use % Calcium

Calcium nitrate Nitrogen fertilizer 24

Superphosphate Phosphorus fertilizer 21

Triple superphosphate Phosphorous fertilizer 17

Bonemeal Phosphorus fertilizer 35

Wood ashes Potassium fertilizer 20

Gypsum Soil amendment 29

Calcite Lime 40

Dolomite Lime 21

Calcium chloride Calcium fertilizer 36

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________________________________________________________________________

If farm manures or composts are suppied in quantities to meet the nitrogen requirement of plants, the calcium
requirement will be satisfied also. If rock phosphate is supplied in sufficient amounts and under conditions that
supply adequate phosphorus nutrition, sufficient calcium will be available.

Plants are unable to mobilize calcium from one portion of the plant to another portion. Calcium which enters a leaf
or another organ cannot be transported to young, growing areas such as growing points or fruits. For example, old
leaves of cabbage may have an abundance of calcium, whereas young leaves at the center of the head will be
showing internal tipburn. Plants must have a constant supply of calcium from the soil to avoid deficiencies.

Calcium deficiency occurs frequently in dry weather. Blossom-end rot of tomato, pepper, and watermelon often can
be corrected by irrigation without addition of calcium to the soil. In dry weather, restricted water uptake limits
calcium absorption, for research shows that calcium enters plants passively and is distributed in plants with the flow
of water. Also in dry soils, the concentrations of soluble potassium salts may be sufficiently high relative to calcium
salts so that potassium absorption competively suppresses calcium absorption. Irrigation helps to overcome these
difficulties in calcium absorption and transport.

Generally, calcium cannot be supplied to plants by foliar sprays, for calcium that enters through the foliage will
remain in the foliage that absorbs the calcium. Foliar sprays of calcium chloride on apple has provided some success
in preventing disorders of the fruits.

Magnesium Fertilizers

Functions and Effects of Magnesium on Plant Growth

Magnesium is a constituent of chlorophyll, and magnesium activates more enzymatic reactions than any other
cation. It is a cofactor in reactions participating in photosynthesis, respiration, and protein synthesis. Magnesium in
leaves ranges from 0.15% to 1% of their dry weight. The threshhold value for sufficiency is about 0.2 to 0.3%.

Magnesium-deficient plants have mottled leaves, which are yellow, bleached, or necrotic between the veins and
green along the veins. This mottling is due to a combination of the effects that magnesium deficiency has on protein
synthesis and chlorophyll synthesis.

Fertilization with Magnesium

Soils are enriched with magnesium when they are limed (Table 24). Limestones are grouped chemically into calcite
and dolomite. Calcite is calcium carbonate, and dolomite is a 1:1 molecular mixture of calcium carbonate and
magnesium carbonate. In nature, deposits of limestone are rarely, if ever, pure deposits of calcite or dolomite;
therefore, agricultural limestones and liming materials derived from limestones are mixtures of calcite and dolomite
and have varying magnesium contents. The magnesium concentration of limestones is provided on the package in
which they are sold or on other labels for bulk sales. The concentrations of actual magnesium in limestones
commonly vary from 0.6% to 13%, averaging about 5%.

Epsom salts (magnesium sulfate, MgSO4.7H2O, 20% Mg) is water soluble. Magnesium deficiency on foliage can be
corrected by sprays of 10 g epsom salts dissolved in 20 liters (0.33 oz in 5 gal) of water. Magnesium is mobile in
plants, so it will move from one area of the plant to another. Although a complete spraying of the plants with the salt
solution is desirable, complete coverage is not mandatory, for magnesium will be transported to sites where it is
needed. Since foliar symptoms of magnesium indicate depletion of available magnesium in the soil, repeated
sprayings will be needed. Spraying should begin as soon as the deficiencies are diagnosed. Recovery of severely
stressed tissues will not occur.

Potassium magnesium sulfate (11% Mg) is used primarily as a potassium fertilizer. Fertilization of a crop with
potassium magnesium sulfate to meet the potassium requirement will satisfy the magnesium needs. Manures and
composts contain sufficient magnesium so that crops supplied with an ample supply of nitrogen from these materials
will have adequate magnesium nutrition. Talc, the mineral in soapstone, is used occasionally as an organic source of
magnesium.

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Table 24. Fertilizers or soil amendments that contain magnesium.

________________________________________________________________________

Material Use Percent


magnesium

Dolomite Lime 13

Magnesium sulfate Magnesium fertilizer 20

Potassium magnesium sulfate Potassium fertilizer 11

Wood ashes Potassium fertilizer 5

Talc (soapstone) Magnesium fertilizer 19

________________________________________________________________________

Sulfur Fertilizers

Functions and Effects of Sulfur on Plant Growth

Sulfur is needed for protein synthesis in that it is a component of the amino acids, cysteine and methionine. Sulfur is
a constituent of several vitamins that have important roles in plant metabolism. The characteristic odor and taste of
plants in the mustard family (radish, turnips, cabbage, caulflower, broccoli, mustard, and others) and of onions and
garlic are due to sulfur-containing compounds. Since sulfur is needed for protein synthesis, symptoms of its
deficiency resemble those of nitrogen deficiency with the exception that the symptoms of sulfur deficiency appear
first on the young leaves rather than on the old leaves. Sulfur is not as mobile in the plant as nitrogen, and sulfur in
the old leaves cannot be transported rapidly enough to the young leaves to prevent deficiency after the available
sulfur in the soil has been depleted. Normal leaf tissue has from 0.15% to 0.5% actual sulfur, about the same
concentration as for phosphorus. Deficiencies may occur if the concentration in leaves falls below 0.15%.

Fertilization with Sulfur

Most of the sulfur in soils of humid regions is in the organic matter. In dry areas, sulfur may be precipitated in the
soil as gypsum (calcium sulfate). The annual raindown of sulfur (5 to 15 lb S/acre) meets part of the sulfur
requirements of crops. Sulfur additions to the soil may be made in the process of fertilizing the soil with the other
macronutrients (Table 25). Applications of sulfur to land with fertilizers is diminishing, for many of the modern,
high-analysis fertilizers are free of sulfur. Urea, ammonium nitrate, ammonium phosphates, triple superphosphate,
and potassium chloride which are used in formulation of concentrated fertilizers contain no sulfur. Ammonium
sulfate, ordinary superphosphate, and potassium sulfate are used infrequently for direct application to the land or in
the manufacture of mixed fertilizers. Limestones add virtually no sulfur. Sometimes elemental sulfur or aluminum
sulfate are used to acidify soil.

Possibly, in heavily cropped soils in the future, sulfur deficiency may become common because of the lack of return
of sulfur back to the land.

Table 25. Fertilizers or soil amendments that contain sulfur.

________________________________________________________________________

Material Use Percent


sulfur

Ammonium sulfate Nitrogen fertilizer 24

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Potassium sulfate Potassium fertilizer 18

Potassium magnesium sulfate Potassium fertilizer 21

Ordinary superphosphate Phosphorus fertilizer 8

Gypsum Soil amendment 23


________________________________________________________________________

Rock phosphate provides essentially no sulfur other than that which might be present as a contaminate. Organic
farmers and gardeners supply sulfur through applications of farm manures and composts. Fertilization to satisfy the
nitrogen needs of a crop with farm manures or composts also will meet its sulfur requirement.

Micronutrients

Because plants accumulate small amounts of iron, copper, zinc, manganese, molybdenum, boron, and chlorine, these
elements are called micronutrients. Sometimes these nutrients are called minor elements or trace elements. These
names refer to the the small amounts that are required and to the infrequent occurrence of deficiencies of these
elements. Most growers normally do not apply specialty fertilizers for micronutrients and rely on the soil to provide
ample supplies of these nutrients. In most cases, this practice is acceptable. Chlorine deficiency has never been
observed in nature, but deficiencies of the other micronutrients occur sporadically and warrant some attention.
Deficiencies of minor elements are not easy to diagnose, expert advice should be sought before applying of
fertilizers to supply minor elements.

Iron, zinc, copper, and manganese

Deficiencies of the metallic micronutrients (iron, copper, zinc, manganese) except molybdenum may occur in
alkaline soils, in heavily leached soils, and in organic soils. Carbonates, hydroxides, and phosphates of these
elements are sufficiently insoluble in alkaline soils at pH 7.5 or above that availability of these nutrients is reduced
to the level of deficiency. In acid, sandy soils, these elements may be leached to the level of deficiency. In organic
soils (peats, mucks), they may be held so tightly in organic complexes that they are unavailable or, in some cases,
may be leached to deficient levels.

Iron deficiency develops first on the youngest leaves and may advance to older leaves but seldom appears on fully
mature leaves. Symptoms are characterized by interveinal (early stages) or uniform light-green or yellow color or
even bleaching to white leaves. Leaves may die so that the plant dies back, or even the whole plant may die. Iron
deficiency is a world-wide problem in alkaline soils. The deficiency under this condition is referred to as lime-
induced chlorosis. Acidifying the soil with organic matter, sulfur, or ammonium sulfate may premit sufficient native
soil iron to dissolve to provide adequate nutrition (Table 26).

Table 26. Approximate amount of soil amendment to apply to lower pH one unit.

____________________________________________________________________

Application l lb/100 sq ft

Material Sands Loams Clays

Sulfur 2 3 4

Aluminum 12 18 24
sulfate (alum)

Organic matter 50 75 100


_____________________________________________________________________

Applying soluble iron salts to alkaline soils gives no relief or only temporary relief from iron deficiency. Chelated or

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sequestered iron compounds (Table 27) may be applied to the soil or as a foliar spray. The best success is achieved
by application to the soil (Table 28). Iron chelates protect the iron from fixation as hydroxides, carbonates, or
phosphates and help to keep the iron in solution.

Table 27. List of iron chelates.

________________________________________________________________________

Name of compound Condition of use

Common Scientific

FeEDTA Iron ethylenediamine tetraacetate Acid soils

FeHEEDTA Iron hydroxyethyl- Neutral soils

ethylenediamine triacetate

FeDTPA Iron diethylene triamine Neutral soils

pentaacetate

FeEDDHA Iron ethylenediamine di-(o- Alkaline soils


hydroxyphenylacetic acid)
________________________________________________________________________

Table 28. Application of iron chelates to correct deficiencies in soils.

________________________________________________________________________

Kind of crop --------------------------Application of chelate--------------------------------

Amount Method

Trees 0.25 lb to 0.5 Apply under crown with enough water to carry to
lb/tree roots

Shrubs 1 oz/shrub Same as for trees

Vegetables 1 oz/100 sq ft Dissolve in water and apply to base of plants

Flowers 1 oz/100 sq ft Same as for vegetables

Lawns 1 oz/100 sq ft Spray across surface

Potted plants 0.1 oz/pot Apply with water


___________________________________________________________________________________

Foliar feeding of iron is of questionable value for most plants. Iron does not enter into the leaves readily, and high
concentrations of iron salts or chelates applied foliarly in solution may be toxic. If a grower wants to employ foliar
spraying, the concentration of iron in the sprays should be in the range of 10 ppm to 50 ppm (mg/kg). The spray
should be applied over the plant to the point of runoff.

Plants with sufficient nutrition have from 100 to 200 ppm iron in their foliage. Deficient concentrations occur in the

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range of 25 to 50 sometimes up to 100 ppm with some vegetables.

Zinc deficiency in most plants affects the termninal growth first. Early stages appears as interveinal chlorosis which
produces mottling of leaves of trees. Acute deficiency appears as little leaf, rosetting, or dieback. Corn shows white
striping or banding on the lower half of leaves. Plants with sufficient zinc nutrition have from 30 to 200 ppm
(mg/kg) in their foliage. Deficient levels of zinc vary with species but are 5 to 25 ppm, with the lower end of this
range being woody plants such as fruit trees and the upper limit being herbaceous plants.

For trees, shrubs, fruit-bearing trees, and field or garden crops, zinc can be applied as foliar sprays of zinc sulfate
(0.1 to 0.3% solution of compound by weight) or zinc chelate (ZnEDTA, ZnHEEDA). These chelates are
comparable to those of iron (Table 27), except they have zinc as the complexed metal. Zinc sulfate can be applied to
the soil of garden and field crops at amounts of 10 to 20 lb/acre (0.25 to 0.5 lb/1,000 sq ft). Most of the soil-applied
zinc remains about where it is applied as its mobility in soil is low, but the mobility is sufficient to provide zinc to a
crop. Zinc chelates (about 1 lb/tree) may be applied to the soil around trees to provide adequate zinc nutrition for 2
or 3 years.

Excesses of zinc may occur with repeated applications. Symptoms of excess zinc resemble iron deficiency.
Applications of lime or phosphates help lower the solubility of zinc and its absorption by plants. A problem of
excessive phosphate nutrition of plants is suspected to be zinc deficiency.

Copper deficiency is not diagnosable until symptoms become advanced. The terminal growth is the first to be
affected, but often symptoms are nonspecific. Small or abnormally large leaves, dark green or chlorotic leaves,
necrotic spotting, rosetting, witches' brooms, or dieback may develop depending on species. Bark of trees may
become rough. Heads of lettuce or cabbage may fail to form. Plants typically have 5 to 25 ppm (mg/kg) copper in
their foliage. Deficiencies appear in foliage with less than 4 ppm copper.

Copper is applied as copper sulfate (CuSO4.5H2O) at 5 to 25 lb/acre to mineral soils and at 100 lb/acre to organic
soils. In orchards, 1 or 2 lb copper sulfate applied to the soil under each tree is sufficient. Foliar sprays used to
control diseases are valuable emergency treatments. For example, plants respond quickly to the copper in Bordeaux
mixture (5 to 10 lb copper sulfate and an equal amount of calcium hydroxide in 100 gallons of water).

Single applications of copper produce residual effects that last for many years, for copper is held tightly to the
organic matter in all soils and is not subject to leaching. Also, the amount of copper removed with a harvested crop
is small, being of the order of 1 lb/acre per year. Repeated applications of copper to meet the nutritional
requirements of plants are not needed. Excesses of copper may produce stunting of plants or symptoms resembling
the chlorosis of iron deficiency. Virtually all of the copper applied to soils remains in the top few inches of the
ground where it may build up to toxic concentrations. Excesses of copper in soil are associated usually with copper-
containing compounds applied to control diseases.

Manganese deficiency appears as chlorosis on new flushes of growth and closely resembles iron deficiency. In
severe cases with fruit trees and broadleafed vegetables, light green areas become grey, white, or necrotic; entire
leaves become dull yellow green, and twigs may dieback. Corn develops yellow and green striping over the full
length of the leaves. Manganese concentrations in plants vary with species, but generally the range of sufficiency is
from 25 to 500 ppm (mg/kg) manganese in the foliage with the deficiency threshhold being 10 to 25 ppm.

Foliar sprays of manganese sulfate often are more successful than soil fertilization. A Bordeaux-like mixture of a
5% by weight of manganese sulfate and an equal amount of calcium hydroxide in water makes a satisfactory spray
for foliar application to fruit trees. Ground applications of 2 to 4 lb manganese sulfate per tree are effective in the
second season after application.

Molybdenum. Plants need molybdenum for the metabolism of nitrogen. Nitrate assimilation requires molybdenum.
Fixation of nitrogen by free-living microorganisms or by those living in symbiosis with plants such as legumes
requires molybdenum. Molybdenum-deficient legumes may appear, and may in fact be, nitrogen deficient because
they are unable to fix atmospheric nitrogen. Legumes or nonlegumes may appear nitrogen deficient because they are
unable to assimilate nitrate. Deficiency symptoms appear when concentrations in foliage are under 0.1 ppm
molybdenum (0.1 mg/kg). Marginal scorching and rolling and cupping of leaves occurs. Whiptail of cauliflower and
yellow-spot of citrus are easily recognizable disorders. Symptoms rarely appear on grasses. Although plants require

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minute amounts of molybdenum, toxicity from molybdenum is rare, and plants may accumulate molybdenum to
several 100 ppm with no toxic effects.

Unlike the other metallic elements, the availability of molybdenum increases with rise in pH. Below about pH 5.5,
the solubility of molybdenum is so low that it is deficient for growth of some crops. Except for the rare soils that are
naturally low in molybdenum, liming of the soil to above pH 5.5 will allow for release of soil-borne molybdenum to
sufficient levels. Notable historical cases of molybdenum deficiency occurred with cauliflower grown in unlimed
fields previously cropped to potatoes with soil at pH 5.3 to control scab disease.

Fertilization with molybdenum is rare. Seeds from plants grown in normal areas often contain enough molybdenum
to meet the needs of a crop. Ammonium or sodium molybdate salts may be applied at 2 oz to 1 lb per acre to the soil
or foliage of crops. Because of the small amounts applied, molybdenum fertilizer is diluted with sawdust, sand, or
another fertilizer. Since molybdenum deficiency frequently occurs in association with phosphorus and sulfate
deficiency, molybdenized superphosphate is a frequently used carrier that provides molybdenum, phosphorus, and
sulfur. Except in acid soils below pH 5.5 in which molybdenum is rendered unavailable quickly, a single application
of molybdenum will last for several years. Economics and convenience dictate whether liming of soil or foliar
fertilization will be employed. In a gardening situation, liming is probably the better practice.

Boron. Deficiencies of boron occur more frequently than deficiencies of any other micronutrient with the possible
exception of iron. Celery, cauliflower and other cole crops, apple, pear, alfalfa, clovers, and beets commonly express
deficiencies of boron and are considered to be good indicator crops for identifying boron-deficient soils. Boron-
deficient soils include acid leached sandy soils, acid leached organic soils, mineral soils low in organic matter, and
soils with high pH. Most of the boron in soils of humid regions is in the soil organic matter and that which is not in
organic matter is water soluble and subject to leaching. In organic soils, much of the boron is leached and depleted
after the decay of the fresh organic matter into the more stable peat or peat-like matter. The solubility of boron is
low in alkaline soils with free calcium carbonate. Soils that are derived from igneous rock or from rocks of marine
deposits are naturally low in boron.

In early stages of development, boron deficiency is not identifiable by visual diagnosis. Tissue analysis is necessary
to detect incipient deficiencies. Acute deficiency has characteristic symptoms, and generally by the time of their
appearance, the crop is lost. Many disorders of fruits and vegetables result from boron deficiency and result in a
totally unmarketable crop or undesirable product. Boron deficiency affects zones of cell division. The terminal buds
and young leaves die. Rosetting and witches' brooms may occur. Plants may appear bushy because of all of the
lateral branches that develop. These lateral branches later die back. Leaves and stems become thickened and brittle.
Fruits, stems, tubers, and roots may fleck, crack, dry rot, or be blackened and water-soaked.

Table 29. Disorders caused by boron deficiency in plants.

________________________________________________________________________

Crop Disorder

Apple Cracking; corking; brown lesions with bitter taste

Beets (table & sugar) Crown rot; heart rot and dry rot of roots

Cauliflower, cabbage, broccoli Hollow stem; brown curd of cauliflower

Celery Cracked stem

Tomato Open locule; internal browning, and darkened, dried covering


of fruits

Turnip and rutabaga Brown heart


___________________________________________________________

Some of these disorders are identified readily from external symptoms, but some of the diseases such as brown

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heart of turnip may not be detected until the roots are cut.

Plants with sufficient boron nutrition have between 25 and 100 ppm (mg/kg) in their leaves. Concentrations below
20 ppm are in the deficient zone. Concentrations above 200 ppm are associated with symptoms of excessive boron
nutrition. Plants are sensitive to toxicity from boron, as is evident from the narrow range of concentrations between
deficient and excessive nutrition. Moderate care needs to be taken in rotation of crops that have a high requirement
for boron with crops that have are sensitive to boron toxicity. Fertilization of a crop with a high boron requirement
may lead to excesses of boron in the soil for the succeeding crop. Generally, however, boron fertilizers are soluble
and will leach from the root zone so that the possibility of toxic carry over of boron from one season to another is
unlikely.

If boron deficiency is not noted, boron-containing fertilizers do not need to be applied. If deficiency symptoms are
apparent or were detected in a previous crop, the following amounts of boron are recommended (Table 30).

Table 30. Suggestions for application of boron to selected crops.

__________________________________________________________

Crop Application,

lb boron/acre

Alfalfa 1 to 4

Apples 1 to 3

Beets 1 to 2

Broccoli 2 to 4

Cabbage 1 to 3

Cauliflower 2 to 4

Citrus 1 to 2

Clovers 1 to 2

Corn 1 to 2

Strawberries 1 to 2

Tomato 1 to 2
__________________________________________________________

Boron may be sprayed on foliage or applied to the soil. Soil-applied boron remains effective longer that foliarly
applied boron. Some fertilizers and methods of application are listed in Table 31.

The spray materials are applied directly to the foliage of the crop. Boric acid is water soluble. Solubor (U. S. Borax
and Chemical Corporation) is partially dehydrated pentaborate specially formulated for application in solution. The
materials of lower solubility are used for direct application to soil. The common practice, because of the low
amounts of materials needed, is to mix borax or coarse granules of borates with sand or with fertilizer for soil
application. Boron frits are fragments of borosilicate sintered glass. The fragments have a large surface area and are
relatively insoluble for slow, steady release of boron to the soil and plant roots. Finely granulated borates are
blended with fertilizers which are use provide macronutrients. For example, a 0-10-40 WB could be used to provide
potassium. A typical blend might have 0.45% boron. If this fertilizer were used to provide, 100 lb of K2O per acre,
250 lb of the fertilizer would be applied and would deliver 1.13 lb of boron per acre, as well as 25 lb of P2O5.

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Table 31. Fertilizers for application of boron to crops.

________________________________________________________________________

Fertilizer Boron (%) Application

Borax 11 Soil

Boric acid 17 Spray or soil

Boron frits 10 to 17 Soil

Sodium tetraborate

hydrate 14 Soil

anhydrous 20 Soil

Sodium pentaborate 18 Soil

Solubor 20 Spray
________________________________________________________________________

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