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400C JOURNAL OF THE ELECTROCHEMICAL SOCIETY September 1978

U.K. He was president of the Institu- strated by experiments. The experi- ters and small metal crystallites.
tion of Corrosion Technology. He was ments have been chosen to require a Chapter One of the volume deals with
chairman of a committee set up by minimum of equipment. Each experi- transition metal complexes as catalysts
the British Ministry of Technology to ment is placed in the text at the point for the addition of oxygen to reactive
inquire into all aspects of the cost of at which the principle is discussed organic substrates. It is a review de-
corrosion and protection in the U.K. rather than in a section at the end voted to presenting numerous recent
and of such measures as may be nec- of the book. The combination of dis- efforts to activate molecular oxygen by
essary to assist the dissemination of cussion and "hands on" experience coordination to metal centers in order
corrosion knowledge and to improve should make the book quite useful to to catalytically transfer oxygen to a re-
education in corrosion matters. He was the newcomer. active substrate. An impressive list of
also on the committee of the newly Several topics which are especially 524 references are cited, indicating the
formed Society for Electrochemistry in well described include batteries, con- intense interest in the field of the oxi-
the U.K. ductivity, potentiometry, galvanic cells, dation of organic substances. The ma-
His scientific work brought him many and electrolysis. A full chapter is de- jority of the work reviewed is recent,
honors. He received the Whitney Award voted to technological applications in- having first appeared in the past ten
from the National Association of Corro- cluding electro-winning, electroplating, years. The interested reader is di-
sion Engineers in 1946, the Hothersall electrochemical machining, anodizing, rected to other reviews of earlier work in
Medal of the Institute of Metal Finish- cathodic protection against rust, and this area and to reviews of subjects re-
ing in 1962, the Palladium Medal Award fuel cells. lated to these commercially important
of The Electrochemical Society in 1969, Another chapter is devoted to elec- and synthetically interesting compound-
and was the first recipient of the U.R. troanalytical methods. Electrogravi- producing catalytic oxidation reactions.
Evans Award of the Institution of Corro- metry, coulometry, coulometric titra- Chapter Two is concerned with com-
sion Science and Technology in 1976. tions, conductimetry, conductimetric paring structure and electronic relations
Dr. Hoar traveled widely, being in- titrations, potentiometry, potentiomet- between molecular clusters and small
vited on many occasions to lecture ric titrations, polarography, and am- particles and includes an attempt to
in the U.S., Australia, New Zealand, perometric titrations are briefly dis- understand very dispersed metals as
Chile, Argentina, and many European cussed. Unfortunately the text makes used in catalysis. The comparison of
countries. He was the host organizer no mention of pulse polarography, a-c very small particles (VSP) and molecular
of the Third International Conference polarography, rapid-scan voltammetry, clusters (MC) includes an analysis of
on the Passivity of Metals at Cambridge, cyclic voltammetry, or anodic stripping size range and size-range characteriza-
England, in July 1970. voltammetry (inverse voltammetry). tion, geometric aspects of the relation
In spite of the demands of his ex- The text appears to be free of mis- between VSP and MC, electronic struc-
tremely active career, Dr. Hoar found takes with the exception of several tures of VSP and MC, metal-metal bond
time to pursue many other interests. typographical errors. The most impor- characteristics in VSP and MC, and sev-
Among these were his involvement in tant of these occurs on page 40 where eral electronic behavior aspects of the
the summer theaters run by his wife, the text refers to a point "D" (which two. The intent of the chapter is to il-
Joan, as a theater manager. He was is unlabeled) in a sketch of a Wheat- lustrate the similarities between very
also renowned in the corrosion com- stone Bridge circuit. Perhaps the great- small particles and molecular clusters.
munity for his expert knowledge of est fault in the text lies in the first This goal is accomplished with the em-
good food and wine. chapter which would have been much phasis placed on the structural and
The remarks made by Prof. Stuart more readable had the first page been electronic similarities.
devoted to telling the reader the topics Chapter Three reviews recent ad-
Leach upon the conferring of the first
to be covered in the remainder of the vances in catalytic asymmetric hydro-
U.R. Evans Award provide a measure
book and to defining electrochemistry. silylation of olefins, carbonyl com-
of the loss that will be felt by those
Since this text is liberally sprinkled pounds including keto esters, and ]mino
both within and without the corrosion
with industrial examples of the use of compounds using transition metal com-
community. He said, "Dr. Hoar has
electrochemistry, it can be highly rec- plexes of chiral phosphine ligands. Par-
made a major contribution to the estab-
ommended as an introduction to elec- ticular emphasis is placed on the asym-
lishment and administration of bodies
trochemistry to persons intending to metric reduction of prochiral carbonyl
concerned with corrosion prevention. He
become industrial electrochemists, and compounds which has received exten-
has made a major contribution to edu-
to practicing engineers seeking an in- sive recent interest and has provided
cation in corrosion prevention. He has
troduction to electrochemistry. This an effective reduction method for or-
made a major contribution to increasing
book is well suited to individual study ganic syntheses.
the corrosion awareness of our admin-
istrators and industrialists." and provides the opportunity for con- The volume is a fine collection of re-
siderable practical experience. The text views of the three specialized aspects
Along with these major contributions,
cannot be recommended to accom- of homogeneous catalysis considered. It
his friendliness, his quick wit, and should find a wide range of interested
his marvelous sense of humor, which pany those electrochemistry courses
normally taught in chemistry depart- readers concerned with catalytic behav-
enlivened many an international meet- ior and reactions.
ing, will be surely missed. ments in the United States and cer-
tainly cannot be recommended as a T. A. Roth
text for a course in electroanalytical Kansas State University
methods. Manhattan, Kansas
BOOK Rs EWS Robert D. Braun
University of Southwestern Louisiana "Trends in Electrochemistry," edited by
Lafayette, Louisiana J. O'M. Bockris, D. A. J. Rand, and
"Experimental Approach to Electrochem- B. J. Welch. Published by Plenum
istry," by N. J. Selley. Published by "Aspects of Homogeneous Catalysis," A Press, New York and London (1977).
John Wiley & Sons, New York (1977). Series of Advances, Vol. 3, edited by 408 4- xi pages; $35.00.
219 pages, price unavailable. R. Ugo. Published by D. Reidel Pub-
lishing Company, DordrechtHolland/ "Trends in Electrochemistry" is an
"Experimental Approach to Electro- Boston (1977). 240 4- viii pages; exciting collection of 22 plenary lectures
chemistry" is intended as an introduc- $39.50. and invited papers from the Fourth Aus-
tion to electrochemistry. Each chapter tralian Electrochemistry Conference,
ends with a summary followed by a The volume is a group of three which had the theme, "Electrochemistry
problem set. The problems are well reviews of the literature devoted to for a Future Society" and was held at
chosen to illustrate the topics dis- three different aspects of homogeneous The Flinders University of South Aus-
cussed in the chapter. Most of the catalysis: asymmetric synthesis; metal- tralia in February 1976. Ten of the
principles of electrochemistry which catalyzed homogeneous oxidation; and papers are by authors resident in Aus-
are described in the text are demon- relations between molecular metal clus- tralia, and the remainder by authors

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