GRUPO

GRUPO 5:
5: TAREA
TAREAN°2
N°
MODELAMIENTO ELV PROBLEMA
MODELAMIENTO ELV PROBLEM
SISTEMA METANOL(1) -ACETONI
SISTEMA METANOL(1) -ACETON
INTEGRANTES:
INTEGRANTES:
CARRION CORDOVA DIEGO 1426115137
CARRION CORDOVA
CORONADO DIEGO
LEZMA CARLOS 142611513
1516110035
CORONADO
LLAJA TORRESLEZMA CARLOS
CAROLINA 151611003
1516110071
LLAJA TORRES
VELARDE RAMOSCAROLINA
GERSON 151611007
142612515
PAREJA MORI KEVINGERSON
VELARDE RAMOS 14261251
142612551
PAREJA
PEREZ MORIKAREN
JULCA KEVIN 14261255
132612029
PEREZ JULCA KAREN 13261202
EA N°2
REA N°2
ROBLEMA 12.6
PROBLEMA 12.6
-ACETONITRILO(2)
-ACETONITRILO(2)
1426115137
1426115137
1516110035
1516110035
1516110071
1516110071
1426125156
1426125156
1426125515
1426125515
1326120297
1326120297
WILSON
Para el sistema Metanol(1)/Acetonitrilo(2) en ELV a T=333.15 K, se tiene los datos experimentales.
Wilson
Datos experimentales Datos calculados con ecuación de ELV Λ12
Λ21
P(KPa) x1 y1 Ganma 1 Ganma 2 GE/RT GE/RTcalc
85.265 0.0000 0.0000 0.0000 1.0000 0.0000 0.0000
82.202 0.0579 0.0253 0.7238 0.9974 -0.0211 0.0450
80.481 0.0924 0.0416 0.7302 0.9967 -0.0320 0.0695
72.422 0.2482 0.1314 0.7726 0.9813 -0.0782 0.1585
65.096 0.3880 0.2457 0.8307 0.9410 -0.1092 0.2067
59.651 0.5036 0.3686 0.8798 0.8899 -0.1224 0.2228
56.833 0.5749 0.4564 0.9092 0.8524 -0.1226 0.2213
51.62 0.7676 0.7176 0.9725 0.7357 -0.0928 0.1697
50.455 0.8476 0.8238 0.9882 0.6842 -0.0679 0.1258
49.926 0.9093 0.9002 0.9960 0.6443 -0.0435 0.0819
49.72 0.9529 0.9502 0.9991 0.6166 -0.0236 0.0452
49.624 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000
G E / RTca lc-L N (G 1 )-L N (G 2 )-G E / RT X 1 X 2

OBJETIVO

1.2000

1.0000

0.8000

0.6000 X1 VS GE/RTca l c
X1 VS LN(G1)
X1 VS LN(G2)
0.4000 X1 VS GE/RTX1X2

0.2000

0.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

X1
 sistema volumen a12 a21
s experimentales. metanol(1) 40.73 504.31 196.75
Wilson acetonitrilo(2) 66.3
0.75960904
0.45631214 R(cal/molK)
Δ(GE/RT)2 Ln(Ganma1) Ln(Ganma2) Pcalc y1calc GE/RTx1x2 T(K)
0.0000 0.8186 0.0000 85.2650 0.0000 0.8182
0.0044 0.7381 0.0024 86.5323 0.0695 0.8250
0.0103 0.6919 0.0062 87.0238 0.1052 0.8290
0.0560 0.4998 0.0458 87.4067 0.2323 0.8492
0.0998 0.3503 0.1157 85.9159 0.3181 0.8707
0.1192 0.2433 0.2020 83.6749 0.3809 0.8913
0.1183 0.1853 0.2700 81.8172 0.4197 0.9055
0.0689 0.0625 0.5237 74.0008 0.5479 0.9510
0.0375 0.0285 0.6667 68.5892 0.6310 0.9737
0.0157 0.0106 0.7965 62.7556 0.7267 0.9930
0.0047 0.0030 0.9001 57.3066 0.8276 1.0078
0.0000 0.0000 1.0250 49.6240 1.0000 1.0246
0.5348323

89

84

79

74
P(KPa)

69 Y1 VS P
X1 VS P
64 Y1ca lc VS Pca l c
X1 VS Pca lc
59

54

49
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

X1,Y1
1.987
333
NRTL
Para el sistema Metanol(1)/Acetonitrilo(2) en ELV a T=333.15 K, se tiene los datos
experimentales NRTL
Datos experimentales Datos calculados con ecuación de ELV τ12 0.51944244
τ21 0.47544777
P(KPa) x1 y1 Ganma 1 Ganma 2 GE/RT GE/RTcalc (ΔGE/RT)2
85.265 0.0000 0.0000 0.0000 1.0000 0.0000 0.0000 0.0000
82.202 0.0579 0.0253 0.7238 0.9974 -0.0211 0.0502 0.0051
80.481 0.0924 0.0416 0.7302 0.9967 -0.0320 0.0771 0.0119
72.422 0.2482 0.1314 0.7726 0.9813 -0.0782 0.1716 0.0624
65.096 0.3880 0.2457 0.8307 0.9410 -0.1092 0.2185 0.1074
59.651 0.5036 0.3686 0.8798 0.8899 -0.1224 0.2303 0.1244
56.833 0.5749 0.4564 0.9092 0.8524 -0.1226 0.2254 0.1211
51.62 0.7676 0.7176 0.9725 0.7357 -0.0928 0.1651 0.0665
50.455 0.8476 0.8238 0.9882 0.6842 -0.0679 0.1198 0.0352
49.926 0.9093 0.9002 0.9960 0.6443 -0.0435 0.0766 0.0144
49.72 0.9529 0.9502 0.9991 0.6166 -0.0236 0.0418 0.0043
G E / RTca l-L N (G 1 )-L N (G 2 )-G E / RT X 1 X 2

49.624 1.0000 1.0000 1.0000 0.0000 0.0000 0.0000 0.0000

OBJETIVO 0.5527

100.000

90.000

80.000

Pcal
1.0000

0.9000
70.000
0.8000

0.7000

0.6000 60.000
0.5000 X1 vs GE/RTca l
X1 vs LN(G1)
0.4000
X1 VS LN(G2) 50.000
0.3000 X1 VS GE/RTX1X2

0.2000

0.1000 40.000
0.0000 0.20
0.0000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000

x1
 sistema volumen b12 b21
metanol(1) 40.73 343.7 314.59
acetonitrilo(2) 66.3
G12 0.85654725
G21 0.8678547 R(cal/molK) 1.987
LN(Ganma1) LN(ganma2) GE/RTx1x2 Pcal ycalc T(K) 333
0.9204 0.0000 0.9204 85.265 0.000
0.8162 0.0031 0.9199 87.077 0.075
0.7573 0.0079 0.9198 87.777 0.111
0.5199 0.0566 0.9195 88.548 0.234
0.3456 0.1379 0.9201 87.100 0.312
0.2284 0.2321 0.9212 84.789 0.370
0.1681 0.3027 0.9221 82.813 0.408
0.0509 0.5423 0.9257 74.165 0.540
0.0221 0.6636 0.9276 68.231 0.630
0.0079 0.7662 0.9293 62.119 0.732
0.0021 0.8437 0.9306 56.724 0.835
0 0.9321 0.9321 49.624 1.000

100.000

90.000

80.000
Pcal

70.000
X1 VS Pca l
Y1cal vs Pca l
60.000

50.000

40.000
0.0000 0.2000 0.4000 0.6000 0.8000 1.0000
x1,Y1 cal
α
0.2981
 MARGULES
Para el sistema metanol(1)/acetonitrilo(2) en ELV a T=308.15 K, se tiene los datos MARGULES EXPER
experimentales

DATOS EXPERIMENTALES
P(kPa) x1 x2 y1 y2 Gamma1 Ln(Gamma1) Gamma2 Ln(Gamma2)
85.265 0.0000 1 0.0000 1 1 0
82.202 0.0579 0.9421 0.0253 0.9747 0.7238233241 -0.3232079438 0.9974371739 -0.0025661
80.481 0.0924 0.9076 0.0416 0.9584 0.730168268 -0.3144802673 0.9967239305 -0.0032814
72.422 0.2482 0.7518 0.1314 0.8686 0.7726313643 -0.2579532338 0.9813348482 -0.0188415
65.096 0.3880 0.612 0.2457 0.7543 0.8306842299 -0.1855055444 0.9409708985 -0.0608431
59.651 0.5036 0.4964 0.3686 0.6314 0.8798235247 -0.1280339317 0.889856008 -0.1166956
56.833 0.5749 0.4251 0.4564 0.5436 0.9092056804 -0.0951839394 0.8523503192 -0.1597577
51.62 0.7676 0.2324 0.7176 0.2824 0.9724643651 -0.0279218468 0.7356576788 -0.3069904
50.455 0.8476 0.1524 0.8238 0.1762 0.988196433 -0.0118737821 0.6841547573 -0.3795711
49.926 0.9093 0.0907 0.9002 0.0998 0.9960171622 -0.0039907904 0.6442867948 -0.4396113
49.72 0.9529 0.0471 0.9502 0.0498 0.9990956106 -0.0009047986 0.616550649 -0.4836148
49.624 1.0000 0 1.0000 0 1 0

Tabla de los parámetros de Margules

Margules
A12= -0.3832
A21= -0.5532

Datos experimentales Datos del modelo

x1 x2 GE/RT GE/RTcalc ∆(GE/RT)^2 Ln(Gamma1) Gamma1 Ln(Gamma2) Gamma2 Pcal
0 1 0 0 0 -0.3832 0.6816765503 0 1 85.265
0.0579 0.9421 -0.0211313 -0.02143955 0.000000095 -0.3575824403 0.6993650407 -0.0007807294 0.9992195753 82.2749028
0.0924 0.9076 -0.0320362 -0.03345332 2.008172E-06 -0.3415348551 0.7106786964 -0.0020884727 0.9979137066 80.4837079
0.2482 0.7518 -0.0781891 -0.07937714 1.411526E-06 -0.2642822526 0.7677568077 -0.018332385 0.981834631 72.3939989
 0.388 0.612 -0.1092121 -0.10665574 0.000006535 -0.1929351053 0.8245354804 -0.0519557453 0.9493708801 65.4159406
0.5036 0.4964 -0.1224056 -0.11719692 2.713023E-05 -0.1366172589 0.8723040288 -0.0974949085 0.90710696 60.1932389
0.5749 0.4251 -0.1226342 -0.11753521 0.000026 -0.1045707386 0.9007110801 -0.1350682037 0.873656323 57.3629196
0.7676 0.2324 -0.0927774 -0.09163764 0.000001299 -0.0347922232 0.9658060675 -0.2793938408 0.7562420056 51.7742667
0.8476 0.1524 -0.0679109 -0.06811254 4.067678E-08 -0.0155934037 0.984527544 -0.3602071813 0.6975317956 50.4745081
0.9093 0.0907 -0.0435016 -0.04435269 7.243957E-07 -0.0056957091 0.9943204807 -0.431902739 0.6492725225 49.8879978
0.9529 0.0471 -0.0236404 -0.02446913 6.867251E-07 -0.0015688285 0.9984324015 -0.4877747776 0.613991142 49.6783601
1 0 0 0 0 0 1 -0.5532 0.5751065218 49.624

Tabla de Gráficas
P-x1-x1 Chart Title
P(kPa) x1 y1cal
Psat2 85.265 0 0
82.202 0.0579 0.024423442
80.481 0.0924 0.040488255
72.422 0.2482 0.130621496
65.096 0.388 0.24268853
59.651 0.5036 0.362157643
56.833 0.5749 0.44795907
51.62 0.7676 0.710563192
50.455 0.8476 0.820424255
49.926 0.9093 0.8993511
49.72 0.9529 0.950365168
Psat1 49.624 1 1

Parámetros Termodinámicos
x1 Ln(Gamma1) Ln(Gamma2) GE/RTcalc GE/RT X1X2
0 -0.3832 0 0 -0.3832
0.0579 -0.3575824 -0.00078073 -0.021439548 -0.393043
0.0924 -0.3415349 -0.00208847 -0.033453318 -0.398908
0.2482 -0.2642823 -0.01833238 -0.079377142 -0.425394 0
0 0.2 0.4 0.6 0.8
0.388 -0.1929351 -0.05195575 -0.106655737 -0.44916
0.5036 -0.1366173 -0.09749491 -0.117196924 -0.468812 -0.1
0.5749 -0.1045707 -0.1350682 -0.117535211 -0.480933
0.7676 -0.0347922 -0.27939384 -0.091637639 -0.513692 -0.2

Axis Title
0.8476 -0.0155934 -0.36020718 -0.068112543 -0.527292
0.9093 -0.0056957 -0.43190274 -0.044352687 -0.537781 -0.3

0.9529 -0.0015688 -0.48777478 -0.024469129 -0.545193

-0.4
1 0 -0.5532 0 -0.5532

-0.5

-0.6
Axis Title
ARGULES EXPERIMENTAL

metodo de lo
GE/RT GE/RTx1x2 x1 GE/RTx1x2 0
0 0 0.2 0.4
0
-0.0211313 -0.3873916 0.0579 -0.3873916 y= ax+ b -0.1
-0.0320362 -0.3820101 0.0924 -0.3820101 a= -0.17
-0.0781891 -0.4190269 0.2482 -0.4190269 b= -0.3832 -0.2
-0.1092121 -0.4599257 0.388 -0.4599257
-0.1224056 -0.4896478 0.5036 -0.4896478 -0.3
-0.1226342 -0.5017973 0.5749 -0.5017973
-0.4
-0.0927774 -0.520081 0.7676 -0.520081 f(x) = - 0.1700160598x - 0.3
R² = 0.9401406261
-0.0679109 -0.5257307 0.8476 -0.5257307
-0.5
-0.0435016 -0.5274611 0.9093 -0.5274611
-0.0236404 -0.5267291 0.9529 -0.5267291 -0.6
0 1

y1cal GE/RTx1x2
0
0.02442344 -0.393043
0.04048826 -0.398908
0.1306215 -0.425394
 0.24268853 -0.44916
0.36215764 -0.468812
0.44795907 -0.480933
0.71056319 -0.513692
0.82042426 -0.527292
0.8993511 -0.537781
0.95036517 -0.545193
1

Chart Title
.4 0.6 0.8 1 1.2

Axis Title
 metodo de los minimos cuadrados
0
0 0.2 0.4 0.6 0.8 1 1.2

-0.1

-0.2

-0.3

-0.4
f(x) = - 0.1700160598x - 0.383150736
R² = 0.9401406261
-0.5

-0.6
Para el sistema Metanol(1)/Acetonitrilo(2) en ELV a T=308.15 K, se tiene los datos
experimentales
Datos experimentales MARGULES WILSON NRTL

P(KPa) x1 y1 P y1 P y1 P
85.265 0.0000 0.0000 85.2650 0.0000 85.2650
82.202 0.0579 0.0253 86.9436 0.0736 87.5000
80.481 0.0924 0.0416 87.6197 0.1107 88.3850
72.422 0.2482 0.1314 88.5012 0.2382 89.6410
65.096 0.3880 0.2457 87.2283 0.3210 88.4120
59.651 0.5036 0.3686 85.1055 0.3806 86.2410
56.833 0.5749 0.4564 83.3016 0.4171 84.3370
51.62 0.7676 0.7176 75.4801 0.5392 75.7080
50.455 0.8476 0.8238 69.8966 0.6202 69.5740
49.926 0.9093 0.9002 63.7614 0.7157 63.1230
49.72 0.9529 0.9502 57.9432 0.8187 57.3400
49.624 1.0000 1.0000 49.6240 1.0000 49.6240
NRTL MARGULES WILSON NRTL

y1 ΔP^2 ΔP^2 ΔP^2

0.0000 7270.1202 0.0000 0.0000
0.0790 6757.1688 22.4828 28.0688
0.1170 6477.1914 50.9610 62.4732
0.2400 5244.9461 258.5407 296.4940
0.3160 4237.4892 489.8387 543.6359
0.3700 3558.2418 647.9316 707.0281
0.4050 3229.9899 700.5868 756.4700
0.5310 2664.6244 569.3044 580.2317
0.6190 2545.7070 377.9758 365.5362
0.7210 2492.6055 191.4183 174.1608
0.8270 2472.0784 67.6210 58.0644
2462.5414 0.0000 0.0000
SUMA 49412.7041 3376.6610 3572.1631
RAIZ CUADR 222.290 58.109 59.768