Chemistry Concepts

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2017

Course : VIJETA (JP) Date : 20-04-2015 NO. 05 & 06
TEST IN FORMATI ON
DATE : 17.05.2015 PART TEST (PT) - 01 (ADVANCED)
Syllabus : Solution & Colligative Properties, Solid State, Thermodynamics, Ionic equilibrium, s-Block
Element. (All ChemInfos and Handouts till date)
This DPP is to be discussed in the week (20-04-2015 to 25-04-2015)

DPP No. # 05 (JEE-ADVANCED)
Total Marks : 64 Max. Time : 38 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Multiple choice objective ('–1' negative marking) Q.6 to Q.11 (4 marks, 2 min.) [16, 08]
Comprehension ('–1' negative marking) Q.12 to Q.14 (3 marks, 2 min.) [09, 06]
Match the Following (no negative marking) Q.15 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.16 to Q.19 (4 marks, 2 min.) [16, 08]
1. 4.4 g of an ideal gas (mol.wt = 44) at 300 K and 10 atm is allowed to expand isothermally against a constant
external pressure of 1 atm. Taking 1 L-atm = 100 J, heat absorbed by the gas is :
300 K rFkk 10 atm ij 4.4 xzke vkn'kZ xSl (v.kqHkkj = 44) dks 1 atm fu;r ckÐ; nkc ds fo:) lerkih; :i ls izlkfjr
fd;k tkrk gSA 1 L-atm = 100 J ysdj] xSl }kjk vo'kksf"kr Å"ek fuEu gS %
(A) 200.5 J (B) 212.5 J (C*) 221.4 J (D) 242.4 J
nRT 4 .4 0.082  300
Sol. Vi = = × = 0.246 litre
P 44 10
Pi Vi 10  0.246
Vf = P = = 2.46 litres
f 1
q = – W = P(Vf – Vi) = 1 (2.46 – 0.246) × 100 = 221.4 J.
2. In which case van’t Hoff factor is maximum ?

(A) KCl, 50% ionised (B) K2SO4, 40% ionised (C) SnCl4, 20% ionised (D*) FeCl3, 30% ionised
fdl ifjfLFkfr esa okUV gkWQ dkjd vf/kdre gS
(A) 50% vk;fur KCl (B) 40% vk;fur K2SO4 (C) 20% vk;fur SnCl4 (D*) 30% vk;fur FeCl3
Sol. i = 1 + (n–1) 
(A) For KCl, i = 1 + 0.5 = 1.5
(B) For K2SO4, i = 1 + 2  0.4 = 1.8
(C) For SnCl4, i = 1 + 4  0.2 = 1.8
(D) For FeCl3, i = 1 + 3  0.3 = 1.9
3. Which of the following increases with dilution at a given temperature?

fn;s x, rki ij fuEu esa ls fdlesa ruqrk ds lkFk o`f) gksrh gSA
(A*) pH of 103M acetic acid solution (B) pH of 103 M aniline solution
(C*) degree of dissociation of 103M acetic acid (D*) degree of dissociation of 10–3M aniline
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Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
PAGE NO.- 1
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(A*) 103M ,lhfVdvEy dh pH (B) 103 M ,uhyhu
ds foy;u dh pH
3 –3
(C*) 10 M ,lhfVd vEy ds fo;kstu dh ek=kk (D*) 10 M ,uhyhu ds fo;kstu dh ek=kk
Sol. Degree of dissocation of WA & WB will increase.
[H+] in WA and [OH–] in WB will decrease so pH of WA and pOH of WB will increase.
gy % WA rFkk WB ds fo;kstu dh ek=kk] esa o`f) gksxhA
WA esa [H ] rFkk WB esa [OH–] esa deh gksxh blfy,] WA dh pH rFkk WB dh pOH esa o`f) gksxhA
+
4. Two liquids X and Y are perfectly immiscible. If X and Y have molecular masses in ratio 1:2, the total vapour
pressure of a mixture of X and Y prepared in weight ratio 2:3 should be (P X0 = 400 torr, PY0 = 200 torr)
nks nzo X rFkk Y iw.kZr;k vfeJ.kh; gS ;fn X rFkk Y dk eksyj nzO;eku vuqikr 1 : 2 gS] rks vuqikr 2 : 3 esa cuk;k x;k X
rFkk Y ds feJ.k dk dqy ok"i nkc fuEu gksuk pkfg,A (PX0 = 400 torr, PY0 = 200 torr)
(A) 300 torr (B) 466.7 torr (C*) 600 torr (D) 700 torr
Sol. For immiscible solution = PT = PA0 + PB0 = 400 + 200 = 600.
5. A mixture of two immiscible liquids at a constant pressure of 1 atm boils at a temperature

(A) equal to the normal boiling point of more volatile liquid
(B) equal to the mean of the normal boiling points of the two liquids
(C) greater than the normal boiling point of either of the liquid
(D*) smaller than the normal boiling point of either of the liquid.
1 atm fu;r nkc ij nks vfeJ.kh; nzoksa ds ,d feJ.k dk DoFkukad %
(A) vf/kd ok"i'khy nzo ds lkekU; DoFkukad ds cjkcj gksrk gSA
(B) nks nzoksa ds lkekU; DoFkukadksa ds ek/; ds cjkcj gksrk gSA
(C) nksuksa nzoksa ds lkekU; DoFkukad esa ls fdlh ,d ls vf/kd gksrk gSA
(D*) nksuksa nzoksa ds lkekU; DoFkukad esa ls fdlh ,d ls de gksrk gSA
Sol. The vapour pressure of a mixture of two immiscible liquids is the sum of their vapour pressures in the pure
states, independent of their relative amounts. Hence, B.Pt. of the mixture will be less than that of either of the
liquids, remaining constant throughout.
6. I. Orbital angular momentum of the electron having n = 5 and having value of the azimuthal quantum number
h
as lowest for this principle quantum number is .

h
I. n = 5 rFkk bl eq[; Dok.Ve la[;k ds fy, f}xa'kh Dok.Ve la[;k dk eku U;wure ysus ij d{kh; dks.kh; laosx gksrk gSA

II. If n = 3,  = 0, m = 0, for the last valence shell electron, then the possible atomic number may be 12 or 13.
II. ;fn vafre la;ksth dks'k bysDVªkWu ds fy, n = 3,  = 0, m = 0 gS rks laHkkfor ijek.kq Øekad 12 ;k 13 gksxkA
7
III. Total spin of electrons for the atom 25Mn is ± .
2
7
III.ijek.kq 25Mn ds fy, bysDVªkWuksa dk dqy pØ.k ± gSA
2
IV. Magnetic moment of inert gas is 0
IV. vfØ; xSl dk pqEcdh; vk?kw.kZ 'kwU; gSA
Which of the above statement (s) is/are false.
fuEu es ls dkSulk@dkSuls dFku vlR; gS &
(A*) I, II and III (B) II and III Only (C) I and IV only (D) None of these
(A*) I, II vkSj III (B) II vkSj III (C) I vkSj IV (D) buesa ls dksbZ ugha
Sol. I. For n = 5 lowest value of l = 0
h
 orbtail angular momentum = 0(0  1) =0
2
PAGE NO.- 2
II n = 3, l = 0, m = 0 coresspond to 3s
 electronic configuration can be
1s22s22p6 3s1 or 1s22s22p6 3s2
there fore atomic number may be 11 or 12.
III 5 2
25Mn – [Ar]3d 4s
there are 5 unpaired electrons
 total spin = ± 5/2
IV As intert gas has no unpaired electron hence, it’s magnetic moment will be zero.
Sol. I. n = 5 ds fy, l = 0 lcls U;wure eku gSA
h
 d{kd dks.kh; laosx = 0(0  1) 2 = 0
II n = 3, l = 0, m = 0 ls lEcfU/kr 3s d{kd gSA
 blfy, bysDVªkWfud foU;kl
1s22s22p6 3s1
;k 1s22s22p6 3s2
blfy, ijek.kq Øekad 11 ;k 12 gks ldrk gSA
III 25Mn – [Ar]3d5 4s2
;gka ij 5 v;qfXer e– gSA
 dqy pØ.k = ± 5/2
IV vfØ; xSl esa dksbZ v;qfXer e– ugha gSA blfy, bldk pqEcdh; vk?kw.kZ 'kwU; gSA
7. Which of the following molarity values of ions in a aqueous solution of 5.85 % w/v NaCl, 5.55% w/v CaCl2 and
6% w/v NaOH are correct [Na = 23, Cl = 35.5 , Ca = 40, O = 16 ]
5.85 % w/v NaCl, 5.55% w/v CaCl2 rFkk 6% w/v NaOH ds ,d tyh; foy;u esa fuEu esa ls dkSu ls vk;uksa dh eksyjrk
lgh gSaA [Na = 23, Cl = 35.5 , Ca = 40, O = 16 ]
(A*) [Cl–1] = 2M (B) [Na+] = 1M (C*) [Ca2+] = 0.5 M (D*) [OH–] = 1.5 M
Sol. Only single solution have all these
means 100 ml solution have 5.85 gm NaCl = 0.1 mole
and 5.55 gm CaCl2 = 0.05 mole
and 6 gm NaOH = 0.15 mole
(0.1 0.05  2 ) 1000 (0.1 0.15 ) 1000
[Cl–] = =2M  [Na+] = = 2.5 M
100 100
0.05
[Ca2+] =  1000 = 0.5 M  [OH–] = 1.5 M
100
mijksDr lHkh dsoy ,d gh foy;u j[krs gSa
vFkZkr~ 100 ml foy;u 5.85 gm NaCl ds 0.1 mole eksy j[krs gSa
rFkk 5.55 gm CaCl2 = 0.05 eksy
rFkk 6 gm NaOH = 0.15 eksy
(0.1 0.05  2 ) 1000
[Cl–] = =2M
100
(0.1 0.15 ) 1000

[Na+] = = 2.5 M
100
0.05
[Ca2+] =  1000 = 0.5 M [OH–] = 1.5 M.
100
8. In which of the following cases van't Hoff factor is greater than 3 (i > 3)
fuEu esa ls fdl ifjfLFkfr esa] okWUV gkWQ xq.kkad dk eku 3 (i > 3) ls vf/kd gS %
(A*) AlCl3 if  = 0.8. (B) BaCl2 if  = 0.9.
(C*) Na3PO4 if  = 0.9 (D*) K4[Fe(CN)6] if  = 0.7.
PAGE NO.- 3
Sol. (A) i = 1 + ( n – 1) 
i = 1 + (4 – 1) ´ 0.8 = 3.4
(B) For BaCl2, i = 1 + ( 3 – 1)  0.9 = 2.8
(C) For Na3PO4, i = 1 + (4 – 1)  0.9 = 3.7
(D) For K4[Fe(CN)6], i = 1 + ( 5–1)  0.7 = 3.8
9. In which of the following pairs of solutions will the values of the van't Hoff factor be the same?
(A) 0.05 M K4 [Fe(CN)6] and 0.10 M FeSO 4.
(B*) 0.10 M K4[Fe(CN)6] and 0.05 M FeSO4.(NH4)2SO4. 6H2O.
(C) 0.20 M NaCl and 0.10 M BaCl2
(D*) 0.05 M FeSO4.(NH4)2SO4.6H2O and 0.02 M KCl . MgCl2 . 6H2O
fuEu esa ls dkSuls foy;u ;qXeksa ds fy, okUVgkWQ dkjd (factor) dk eku leku gksxkA
(A) 0.05 M K4 [Fe(CN)6] rFkk 0.10 M FeSO4
(B*) 0.10 M K4[Fe(CN)6] rFkk 0.05 M FeSO4.(NH4)2SO4. 6H2O
(C) 0.20 M NaCl rFkk 0.10 M BaCl2
(D*) 0.05 M FeSO 4.(NH4)2SO4 . 6H2O rFkk 0.02 M KCl . MgCl2 . 6H2O.
Sol. Those which have same no of ions after dissociation will have same Van't Hoff factor.
K4[Fe(CN)6] & FeSO4.(NH4)2SO4.6H2O have 5 ions each.
& FeSO4.(NH4)2SO4.6H2O & KCl. MgCl2.6H2O have 5 ions each.
10. Select correct statement :

(A*) Higher the value of k H (Henry’s law constant) at a given pressure, the lower is the solubility of the gas in
the liquid
(B) Solubility of a gas in a liquid decreases with increase in temperature and pressure
(C*) to minimise the painful effects accompanying the decompression of deep sea divers, O 2 diluted with
less soluble He gas is used as breathing gas
(D*) The solubility of a gas in a liquid is governed by Henry’s law
lgh dFku dk pquko dhft,A
(A*) fn;s x;s nkc ij k H (gSujh fu;e fu;rkad) dk mPp eku gS] mruk gh nzo esa xSl dh mPp foys;rk n'kkZrk gSA
(B) ,d nzo esa xSl dh ?kqyu'khyrk] rki o nkc esa o`f) ds lkFk de gksrh gSA
(C*) xgjk;h esa tkus okys xksrk[kksjksa ds fy, dksf'kdkvksa esa nokc ds dkj.k mRiUu nnZ dks de djus ds fy, 'olu xSl ds
:i esa de foy;'khy He xSl ds lkFk ruqd`r O2 xSl dk mi;ksx fd;k tkrk gSA
(D*) nzo esa xSl dh ?kqyu'khyrk] gSujh fu;e }kjk le>k;h tk ldrh gSA
Sol. Solublity of a gas in a liquid increases with increase in pressure and decrease in temperature.
gy . nzo esa xSl dh ?kqyu'khyrk] nkc esa o`f) rFkk rki esa deh ds lkFk c<+rh gSA
11. The value of Hºr for the given reaction cannot be calculated using which of the following informations :
CH4(g) + 2O2(g)  CO2(g) + 2H2O()
(A*) Bond enthalpies of C=O, O=O, O–H and C–H bonds.
(B) Hºƒ(CO2(g)), Hºƒ(H2O()) & Hºƒ(CH4(g))
(C*) Bond enthalpies of C–H, C=O & O–H bonds and Hºvap.(H2O())
(D*) Hºatomisation(C, graphite, s), Hºatomisation(CH4(g)),Hºƒ(H2O() and Bond enthalpies of O=O & C=O bonds.
fuEu esa ls fdu lwpukvksa dk mi;ksx djus ij uhps nh xbZ vfHkfØ;k ds fy, Hºr dk eku Kkr ugha fd;k tk ldrk gS%
(A) C=O, O=O, O–H ,oe~ C–H ca/kksa dh ca/k ,UFkSYih
(B) Hºƒ(CO2(g)), Hºƒ(H2O()) rFkk Hºƒ(CH4(g))
(C) C–H, C=O o O–H ca/kksa dh ca/k ,UFkSYih ,oe~ Hºvap.(H2O())
(D) H°ijek.ohdj.k (C,xzsQkbV]s), H°ijek.ohdj.k (CH4(g)),Hºƒ(H2O() rFkk O=O o C=O ca/kksa dh ca/k ,UFkSYih
Sol. (A) All calculations done by bond enthalpy data involves species in gaseous state only. But in question, H2O
() is there.
(C) O = O bond energy is not given.
(D) H – H bond energy is not given.
PAGE NO.- 4
g y- (A) ca/k ,UFkSYih ds vkadM+ksa }kjk dh x;h lHkh x.kuk;sa dsoy xSlh; Lih'kht ds fy, gksrh gSaA ijUrq ç'u esa H2O () fn;k
x;k gSA
(C) O = O ca/k ÅtkZ ugha nh x;h gSA
(D) H – H ca/k ÅtkZ ugha nh x;h gSA
Comperhension #
The pressure of two pure liquid A and B which form an ideal solutions are 400 mm Hg and 800 mm Hg
respectively at temperature T. A liquid containing 3 : 1 molar composition pressure can be varied. The
solutions is slowly vaporized at temperature T by decreasing the applied pressure starting with a pressure of
760 mm Hg. A pressure gauge (in mm) Hg is connected which given the reading of pressure applied.
rki T ij A rFkk B nks 'kq) nzo ds nkc Øe'k% 400 mm rFkk 800 mm Hg gSa, tks fd vkn'kZ foy;u cukrs gSA ,d nzo]
tks fd 3 : 1 eksyj laxBu j[krk gS] dk nkc ifjofrZr gks ldrk gSA foy;u rki T ij /khjs &/khjs ok"ihd`r gksrk gS tc
yxk;s x;s nkc esa deh dh tkrh gS] ;g yxk;k x;k nkc 760 mm Hg ls izkjEHk gksrk gSA yxk;s x;s nkc ds ekiu ds fy;s
,d nkcekih (mm esa) yxk;k x;k gSA
12. The reading of pressure Gauge at which only liquid phase exists.
tc dsoy nzo voLFkk mifLFkr gS] rc nkcekih dk ikB~;kad gS \
(A) 499 (B) 399 (C) 299 (D*) None
13. The reading of pressure Gauge at bubble point is
cqycqyk fcUnq ij nkc ekih dk ikB~;kad gSA
(A*) 500 (B) 600 (C) 700 (D) None
14. The reading of pressure Gauge at which only vapour phase exists is
tc dsoy ok"i voLFkk mifLFkr gS] rc nkcekih dk ikB~;kad fuEu gSA
(A) 501 (B) 457.14 (C*) 425 (D) 525
Sol. (Q.12 to Q.14)
XA = 0.75 XB = 0.05 above 500 mm Hg only liquid phase exists.
XA = 0.75 XB = 0.05 500 mm Hg ds Åij dsoy nzo voLFkk mifLFkr gksrh gSA
Pbubble point = XA P°A + XB P°B
Pcqycqfyr fcUnq = XA P°A + XB P°B
= 0.75 + 400 + 0.25 × 800 = 500 mm.
yA = 0.75, yB = 0.5
At dew point (vksl fcUnq ij)

1 y y 1 0.75 0.25 1.5  0.25
 A  B
PT PAº PBº  PT = 400 + 800 = 800
800
 PT = = 457.14 mm Hg
1.75
Below dew point only vapour phase exists.
(vksl fcUnq ds uhssps dsoy ok"i voLFkk mifLFkr gksrh gSA )
15. Column-I Column-II

(A) n-hexane + n-heptane. (p) Can be separated by fractional distillation.
(B) Acetone + chloroform (q) Maximum boiling azeotrope.
(C) Chloro-benzene and bromo-benzene (r) Cannot be separated by fractional distillation
completely.
(D) Ethanol + water. (s) Minimum boiling azeotrope.
LrEHk  LrEHk 
(A) n-gSDlsu + n-gSIVsu (p) çHkkth vklou }kjk i`Fkd~ fd;k tk ldrk gSaA
(B) ,lhVksu + DyksjksQkWeZ (q) vf/kdre fLFkj DokFkha rkiekuA
(C) Dyksjks&csathu rFkk czksekscsathu (r) iw.kZ :i ls çHkkth vklou }kjk i`Fkd ugha fd;k tk
ldrk gSaA
PAGE NO.- 5
(D) ,sFksukWy + ty (s) U;wure fLFkjDokFkh rkiekuA
Ans. [A – p] ; [B – q,r] ; [C – p] ; [D – r,s].
Sol. Hexane & Heptane solution do not form azeotrope, but have different boiling points, so can be separated by
fractional distillation. Acetione & chloroform form maximum boiling azeotrope ethanol & water form minimum
boiling azeotrope. Azeotropes cannot be separated completely by fractional distillation chlorobenzene &
bromobenzene do not form azeotrope but have different boiling points. so can be separated by fractional
distillation.
ChemINFO-1.3 Solution & Colligative Properties

Daily Self-Study Dosage for mastering Chemistry
Non ideal solution

A non-ideal solution is defined as the one which does not obey Raoult’s law. These are divided into two types.
1. Non-ideal positive deviation solution
2. Non-ideal negative deviation solution.
Positive deviation solution Negative deviation solution
(i) PT  X APA0  XBPB0 (i) PT  X APA0  XBPB0
(ii) The inter molecular interaction is weaker as (ii) The inter molecular interaction is more than the
interaction found in any one of the pure interaction found in any of the pure components
components.
(iii) There is decrease in volume on mixing and

(iii) There is increase in volume on mixing and evolution of heat takes place on mixing
absorption of heat. Vmix  ve Hmix   ive
Vmix  positive Hmix  positive
Smix   ive Gmix   ive
Smix   ive Gmix   ive Ex. H2O + HCOOH, H2O + CH3COOH
Ex. H2O + CH3OH, C2H5OH + Hexane H2O + HNO3, CHCl3 + CH3OCH3
C2H5OH + Cyclohexane, CHCl3 + CCl4
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
16. Identify the mixture that shows negative deviation solutions

(A) Benzene + (CH3)2CO (B*) (CH3)2CO+ C6H5NH2
(C) CHCl3 + C6H6 (D) (CH3)2CO + CS2
17. At 550C, ethanol has a vapour pressure of 168 mm, and the vapour pressure of methyl cyclohexane is 280
mm. A solution of the two in which the mole fraction of ethanol is 0.68, has a total vapour pressure of 376 mm.
This solution is formed from its components with
(A) The evolution of heat (B*) The absorption of heat.
(C) Neither absorption nor evolution of heat
(D) Nothing can be predicted on the basis of given information
PAGE NO.- 6
18. Total vapour pressure of mixture of 1 mole of A PA0  150 mm and 2 mole of B PB0  240 mm is 200 mm. In
this case :
(A) There is a positive deviation from Raoult’s law.
(B*) There is a negative deviation from Raoult’s law
(C) There is no deviation from Raoult’s law.
(D) Molecular masses of A & B are also required for calculating deviation.
19. Identify the mixture showing positive deviation of non-ideal solution.

(A*) CH3COCH3 + CS2 (B) Hexane + Heptane
(C) Chlorobenzene + Bromo benzene (D) Acetone + Chloroform

Daily Self-Study Dosage for mastering Chemistry
Non ideal solution

,d vukn'kZ foy;u dks og gS tks jkÅYV fu;e dk ikyu ugha djrk gSA bUgs nks çdkj ls foHkkftr djrs gSa
1. vukn'kZ /kukRed fopyu foy;u
2. vukn'kZ _.kkRed fopyu foy;u
/kukRed fopyu foy;u _.kkRed fopyu foy;u
(i) PT  X APA0  XBPB0

(i) PT  X APA0  XBPB0
(ii) fdlh ,d 'kq+) vo;o esa vUrjfØ;k dh vis{kk vUrj
(ii) fdlh ,d 'kq+) vo;o esa vUrjfØ;k dh vis{kk vUrj
vkf.od vUrjfØ;k vf/kd gksrh gS
vkf.od vUrjfØ;k nqcZy gksrh gS
(iii) ;gk¡ feJ.k ij vk;ru esa o`f+) gksrh gS o Å"ek dk (iii) fefJr djus ij ;gk¡ feJ.k ij vk;ru esa deh gksrh
vo'kks"k.k gksrk gSA gS o Å"ek dks fu"dklu gksrk gSA
V  H  V  ve H   ive
S   ive G   ive S   ive G   ive
Ex. H2O + CH3OH, C2H5OH + gSDlsu Ex. H2O + HCOOH, H2O + CH3COOH
C2H5OH + lkbDyksgSDlsu, CHCl3 + CCl4 H2O + HNO3, CHCl3 + CH3OCH3
16. og feJ.k igpkfu;s tks _.kkRed fopyu dk foy;u n'kkZrk gS %

(A) csUthu + (CH3)2CO (B*) (CH3)2CO+ C6H5NH2
(C) CHCl3 + C6H6 (D) (CH3)2CO + CS2
17. 550C, ij ,FksukWy ds fy, ok"i&nkc 168 mm gS o esfFky lkbDyksgSDlsu ds fy, ok"i&nkc 280 mm gSA bu nks foy;uksa
esa ftlesa ,FksukWy dk eksy&fHkUUk 0.68 gS o dqy ok"i nkc 376 mm gSA ;g foy;u fuEu ds lkFk blds vo;oksa ls curk
gSA
(A) Å"ek ds fu"dklu
(B*) Å"ek ds vo'kks"k.k
(C) u rks Å"ek ds vo'kks"k.k vkSj uk gha Å"ek ds fu"dklu lsA
(D) nh xbZ tkudkjh ds vk/kkj ij buesa ls fdlh dks crk;k ugha tk ldrk gSA
PAGE NO.- 7
18. 1 eksy A PA0  150 mm o 2 eksy B PB0  240 mm ds feJ.k dk dqy ok"i nkc 200 mm gSaA bl fLFkfr esa
(A) jkÅYV fu;e ls /kukRed fopyu gksrk gSA
(B*) jkÅYV fu;e ls _.kkRed fopyu gksrk gSA
(C) jkÅYV fu;e ls dksbZ fopyu ugha gksrk gSA
(D) fopyu dks tk¡pus ds fy, A o B ds v.kqHkkjksa dh Hkh vko';drk gksrh gSA
19. ml feJ.k dks igpkfu, tks vukn'kZ foy;u ds /kukRed fopyu dks n'kkZrk gSA
(A*) CH3COCH3 + CS2 (B) gSDlsu + gsIVsu
(C) DyksjkscsUthu + czksekscsUthu (D) ,lhVksu + DyksjksQkWeZ
DPP No. # 06 (JEE-ADVANCED)

Total Marks : 75 Max. Time : 46 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.5 (3 marks, 2 min.) [15, 10]
Multiple choice objective ('–1' negative marking) Q.5 to Q.10 (4 marks, 2 min.) [20, 10]
Integer type Questions ('–1' negative marking) Q.11 to Q.14 (4 marks 3 min.) [16, 12]
Match the Following (no negative marking) Q.15 (8 marks, 6 min.) [08, 06]
ChemINFO : 4 Questions ('–1' negative marking) Q.16 to Q.19 (4 marks, 2 min.) [16, 08]
1. For the given process on an ideal gas, which of the following statements is true :
,d vkn'kZ xSl ds fn, x, izØe ds fy;s fuEu esa ls dkSulk dFku lR; gS %
(A) Work done by the gas during complete cycle is 6P0V0.

(B) Work done on the gas during complete cycle is 6P0V0.
5P0 V0
(C) Work done on the gas during complete cycle is .
2
5P0 V0
(D*) Work done by the gas during complete cycle is .
2
(A) ,d iw.kZ pØ ds nkSjku xSl }kjk 6P0V0 dk;Z fd;k tkrk gSA
(B) ,d iw.kZ pØ ds nkSjku xSl ij 6P0V0 dk;Z fd;k tkrk gSA
5P0 V0
(C) ,d iw.kZ pØ ds nkSjku xSl ij dk;Z fd;k tkrk gSA
2
5P0 V0
(D*) ,d iw.kZ pØ ds nkSjku xSl }kjk dk;Z fd;k tkrk gSA
2
3
2. A monoatomic ideal gas (CV = R) is allowed to expand adiabatically and reversibly from initial volume of 8L
2
at 300 K to a volume of V2 at 250 K. The value of V2 is : (Given (4.8)1/2 = 2.2)
3
,d ,dyijek.kfod vkn'kZ xSl (CV = R) dks :)ks"e rFkk mRØe.kh; :i ls 300 K rki ij izkjfEHkd vk;ru 8L ls]
2
250 K ij vfUre vk;ru V2 rd izlkfjr gksus fn;k tkrk gSA rc V2 dk eku gksxk % (fn;k x;k gS % (4.8)1/2 = 2.2)
(A*) 10.5 L (B) 23 L (C) 8.5 L (D) 50.5 L
PAGE NO.- 8
Sol. TV–1 = constant (fu;rkad)
5 2
=  –1=
3 3
 300 × (8)2/3 = 250 × (V2)2/3  (V2)2/3 = 4.8
 V2 = (4.8)3/2  4.8 × 2.2 = 10.5 L
3. Three solutions are prepared by adding 'w' gm of 'A' into 1kg of water, 'w' gm of 'B' into another 1 kg of
water and 'w' gm of 'C' in another 1 kg of water (A, B, C are non electrolytic). Dry air is passed from
these solutions in sequence (A  B  C). The loss in weight of solution A was found to be 2
gm while solution B gained 0.5 gm and solution C lost 1 gm. Then the relation between molar masses
of A, B and C is :
rhu foy;u 1kg ty esa 'A' ds 'w' xzke] vU; 1kg ty esa 'B' ds 'w' xzke] rFkk vU; 1kg ty esa 'C' ds 'w' xzke dks
feykdj cuk;s tkrs gaSA (A, B, C fo|qr vu~vi?kV~; gS)A bu foy;uksa ls 'kq"d ok;q fuEu Øe (A  B 
C) esa izokfgr dh tkrh gSA foy;u A ds nzO;eku esa deh 2 xzke ik;h x;h tcfd B dk 0.5 xzke c<+rk gS rFkk foy;u
C ds nz O;eku es a 1 xz ke dh deh gksr h gSa A A, B rFkk C ds eks yj nzO ;ekuks a ds e/; lEca /k gks xkA
1 1 1
(A) M A : M B : M C = 4 : 3 : 5 (B) MA : MB : MC = : :
4 3 5
(C*) MC > MA > M B (D) M B > M A > M C
Sol. The loss in weight should be proportional to vapour pressure above that solution :
So, PSA  2gm
PSB  1.5gm
PSC  2.5 gm
So, maximum vapour pressure is above C solution hence, it is having minimum lowering and hence
minimum mole fraction (hence minimum number of moles of solute) So max. molar mass of substance.
Sol. ok"i nkc] Hkkj esa gkfu ds lekuqi krh gksxk
PSA  2gm
PSB  1.5gm
PSC  2.5 gm
pwafd C foy;u dk ok"inkc vf/kdre gS] vr% blesa U;wure deh vk;h gksxh blfy, bldk eksy izHkkt U;wure gksxk
rFkk blfy, bldk v.kqHkkj vf/kdre gksxkA
4. A solution of 0.2 mole KI ( = 100%) in 1000 g water freezes at T 1 0C. Now to this solution 0.1 mole Hg2 is
added and the resulting solution freezes at T 2 0C. Which of the following is correct :
(A) T1 = T2 (B) T1 > T2 (C*) T1 < T2 (D) Cannot be predicted.
1000 g ty esa 0.2 eksy K ( = 100%) dk foy;u T1 0C ij terk gSaA vc bl foy;u esa 0.1 eksy Hg2 Mkyk tkrk
gS rFkk ifj.kkeh foy;u T2 0C ij terk gSA rks fuEu esa ls dkSulk lR; gSA
(A) T1 = T2 (B) T1 > T2 (C*) T1 < T2 (D) dqN ugha dgk tk ldrkA
Sol. 2KI + Hg2  K2[Hg4].1. 0.1 mole of which of the following when added to 1 L water, the aqueous solution
obtained will have the lowest freeing point?
1L ty esa fuEu ls fdldk 0.1 eksy feykus ij izkIr foy;u dk fgekad U;wure gksxkA
(A) C6H5NH3Cl (B) K3[Fe(CN)6] (C*) K4[Fe(CN)6] (D) Al(NO3)3.
Sol. Greater the number of ions greater will be lowering in freezing point.
5. Which of the following compound has bond angles of 120° only, either in cationic or anionic species ?
fuEu esa ls fdl ;kSfxd esa ;k rks /kuk;fud ;k _.kk;fud Lih'kht+ esa] cU/k dks.k 120° gS \
(A*) N2O5 (s) (B) PCl5 (s) (C) I2Cl6 () (D) XeF6(s)
PAGE NO.- 9
Sol. N2O5(s) — NO+2 + NO3– (trigonal planar, so bond angle 120°)
(f=kdks.kh; leryh;] vr% cU/k dks.k 120°)
sp sp2
PCl5(s) — PCl4+ + PCl6–
sp3 sp3 d2
XeF6(s) — XeF+5 + F–
sp3d2
I2Cl6(l) — ICl2+ + ICl4–
sp3 sp3d2
6. Consider the following statements with regard to magnesium sulphate :

1. It is sparingly soluble in water.
2. Its solubility in water is less than calcium sulphate.
3. When heated to 900 °C, it gives magnesium oxide.
Which of the above statements is/are correct?
(A) 1 and 3 (B) 2 only (C*) 3 only (D) 2 and 3
Sol. MgSO4 is more soluble than CaSO 4 in water and MgSO4 gives MgO on heating to 900ºC.
fuEu dFkuksa dks eSXuhf'k;e lYQsV ds lanHkZ esa voyksdu dhft,&

1. ;g ty esa vYi foys; gksrk gSA
2. bldh ty esa foys;rk dSfY'k;e lYQsV ls de gksrh gSA
3. tc bls 900°C ij xeZ djrs gS rks ;g eSfXuf'k;e vkWDlkbM nsrk gSA
fuEu esa ls dkSulk dFku lgh gS@gaS&
(A) 1 rFkk 3 (B) dsoy 2 (C*) dsoy 3 (D) 2 rFkk 3
Sol. MgSO4 is more soluble than CaSO 4 in water and MgSO4 gives MgO on heating to 900ºC.
MgSO4 ty esa CaSO4 ls vfèkd foys; gksrk gS o MgSO4 900°C ij xeZ djus ij MgO nsrk gSA
7. An ideal gas at initial pressure Pi and volume Vi undergoes reversible expansion to the same volume V f
either isothermally or adiabatically. Which of the following statement(s) is (are) correct ?
Where the symbols have their usual meaning.
(A*) |Pf (adiabatic) < Pf (isothermal)| (B*) |W(adiabatic)| < |W(isothermal)|
(C*) |Tf (adiabatic) < Tf (isothermal)| (D*) |q(adiabatic)| < |q(isothermal)|
izkjfEHkd nkc Pi vk;ru Vi ij ,d vkn'kZ xSl ;k rks lerkih; ;k :)ks"eh; ij leku vk;ru Vf ds lkFk mRØe.kh; :i
ls izlkfjr gksrs gSA fuEufyf[kr dFkuksa esa ls dkSu dFku lgh gS@gSa \ tgk¡ izrhd Loa; dk lkekU; vFkZ j[krs gSA
(A*) |Pf (:)ks"eh;) < Pf (lerkih;)| (B*) |W(:)ks"eh;)| < |W(lerkih;)|
(C*) |Tf (:)ks"eh;) < Tf (lerkih;)| (D*) |q(:)ks"eh;)| < |q(lerkih;)|
Sol.
bls vkjs[k }kjk Li"V fd;k tkrk gSA

|Pf (:)ks"eh;) < Pf (lerkih;)|
|W(:)ks"eh;)| < |W(lerkih;)|
|Tf (:)ks"eh;) < Tf (lerkih;)|
|q(:)ks"eh;)| < |q(lerkih;)|
PAGE NO.- 10
8. For free expansion of an ideal gas (expansion against vacuum) adiabatically, which of the following will have
zero value :
,d vkn'kZ xSl ds :)ks"e :i ls eqDr izlkj ds fy, ¼fuokZr ds fo:) izlkj½] fuEu esa ls fdu jkf'k;k¡ dk eku 'kwU; gksxk%
(A*) W (B*) q (C*) U (D*) H
Sol. Adiabatic process. So, q = 0.
Expansion against vacuum. So, Pext = 0. Therefore, W = 0.
So, from Ist law, U = 0. So, T = 0. So, H = 0.
Ssys > 0, since expansion of gas occurs.
Sol. :)ks"e izØe%] vr%] q = 0.
fuokZr ds fo:) izlkj] blfy, Pext = 0. vr%] W = 0.
blfy,] izFke fu;e ls, U = 0. blfy,, T = 0. blfy,, H = 0.
Ssys > 0, pwafd xSl dk izlkj gksrk gSA
9. Which is the correct relation between osmotic pressure of 0.1 M NaCl solution & 0.1 M Na2SO4 solution :
0.1 M NaCl foy;u rFkk 0.1 M Na2SO4 foy;u ds ijklj.k nkc ds chp lgh lEcU/k dkSulk gS&
(A) the osmotic pressure of Na2SO4 is less than NaCl solution
(B*) the osmotic pressure of Na2SO4 is more than NaCl solution
(C*) the osmotic pressure of Na2SO4 is 1.5 times that of NaCl solution
(D) the osmotic pressure of NaCl is 1.5 times that of Na2SO4 solution
(A) Na2SO4 dk ijklj.k nkc] NaCl foy;u dh vis{kk de gksrk gSA
(B*) Na2SO4 dk ijklj.k nkc] NaCl foy;u dh vis{kk vf/kd gksrk gSA
(C*) Na2SO4 dk ijklj.k nkc] NaCl foy;u dh vis{kk 1.5 xquk gksrk gSA
(D) NaCl dk ijklj.k nkc] Na2SO4 foy;u dh vis{kk 1.5 xquk gksrk gSA
10. For the depression of freezing point experiment involving non-volatile solute. The correct statement(s) is/are:
(A*) Vapour pressure of pure solvent is more than that of solution
(B) Vapour pressure of pure solvent is less than that of solution
(C) Only solute molecules solidify at the freezing point
(D*) Only solvent molecules solidify at the freezing point
fgekad fcUnq ds vou;u iz;ksx ds fy, , fuEu esa ls dkSulk@dkSuls dFku lgh gS /gSa :
(A*) 'kq ) foyk;d dk ok"inkc ,foy;u fd rq yuk esa vf/kd gksr k gS A
(B) 'kq ) foyk;d dk ok"inkc ,foy;u fd rq yuk esa de gksr k gSA
(C) fgeka d fcUnq ij dso y foy; ds v.kq] Bks l esa ifjofrZ r gks rs gSA
(D*) fgekad fcUnq ij ds oy foyk;d ds v.kq Bks l esa ifjofrZ r gks rs gSA
Sol. From Roult’s Law.
jkmYV fu;e ls
11. 20g of a binary electrolyte (molecular weight = 100) are dissolved in 500 g of water. The freezing point of the
solution is – 0.74°C ; Kf = 1.86 K moIality–1, Calculate percentage degree of dissociation of electrolyte.
500g ty esa ,d f}yd oS|qr vi?kV~; ds 20g (vkf.od Hkkj = 100) dks ?kksyk tkrk gSaA foy;u dk fgekad – 0.74°C ;
Kf = 1.86 K eksyjrk–1 gSA oS|qr vi?kV~; dk izfr'kr fo;kstu Kkr djksA
Ans. 0
Sol. Tf = 2Kf m
0.74 = 2 × 1.36 × 0.4  2 = 0.9945  1
i = 1 +   1   0
12. Consider the following trends in properties of hydrogen halides :

1. Acidic strength : HF < HCl < HBr < HI
2. Thermal stability : HF > HCl > HBr > HI
3. Dipole moment : HF < HCl < HBr < HI
4. Reducing power : HF > HCl > HBr > HI
Find number of correct trends.
PAGE NO.- 11
gkbMªkstu gSykbM ds xq.kèkeksZ esa fuEu izo`fÙk dk voyksdu dhft,&
1. vEyh; lkeF;Z : HF < HCl < HBr < HI
2. rkih; LFkkf;Ro : HF > HCl > HBr > HI
3. f}èkzqo vkèkw.kZ : HF < HCl < HBr < HI
4. vipk;d {kerk : HF > HCl > HBr > HI
lgh izo`fr dh la[;k Kkr djks A
Ans. 2
13. A membrane permeable only to water separates a 0.01 M solution of sucrose from a 0.001 M one. On which
solution must pressure be applied to bring the system into equilibrium? Find this pressure if the T= 300 K.
Report your answer as (pressure × 100)
dsoy ty ds fy, ikjxE; ,d f>Yyh] ,d 0.001 M lqØksl ds tyh; foy;u dks 0.01 M foy;u ls i`Fkd djrh gS] buesa
ls fdl foy;u ij nkc yxkuk pkfg, fd] fudk; lkE; esa vk tk;sA og nkc Kkr dhft;s] ;fn T = 298 K gksA
vius mÙkj dks (nkc × 100) ds :i esa O;Dr djksA
Ans. 22
Sol. Pressure will be applied to higher conc. side.
 = P1 – P2
= (C1 – C2) × RT
= (10–2 – 10–3) × 0.082 × 300 = 0.2214 atm.
0.22 × 100 = 22
14. Calculate the osmotic pressure of a decinormal solution of cane sugar at 27°C.
27°C rki ij xUus dh 'kdZjk ds MslhukWjey foy;u ds ijklj.k nkc dh x.kuk dhft;s \
Ans. 2.46 atm
n
Sol. = molar concentration = 0.1 M  R = 0.082 litre atm K–1 mol–1 , T = 300 K
V
n
 we have P = RT  = 0.1 x 0.082 x 300 = 2.46 atm
V
15. Match the Column

Column-I Column-II
(A) 0.1 M Al2(SO4)3 (p) Solution with highest boiling point.
(B) 0.1 M AlPO4 (q) Van't Hoff factor is greater than 1.
(C) 0.1 M urea. (r) Solution with lowest osmotic pressure.
(D) 0.1 M MgCl2 (s) Solution with lowest freezing point.
LrEHk -I LrEHk -II
(A) 0.1 M Al2(SO4)3 (p) mPpre DoFkukad dk foy;uA
(B) 0.1 M AlPO4 (q) okWUV gkWQ dkjd 1 ls vf/kdA
(C) 0.1 M urea. (r) U;wure ijklj.k nkc dk foy;uA
(D) 0.1 M MgCl2 (s) U;wure fgekad dk foy;uA
Ans. [A – p,q,s] ; [B – q] ; [C – r] ; [D – q]
PAGE NO.- 12
Daily Self-Study Dosage for mastering Chemistry Immiscible Liquid
Immiscible Liquid
When a volatile liquid is added to another volatile liquid, which are completely immiscible with each other, each
liquid will behave independent of the other and will exert its own vapour pressure. The more dense liquid (A) will form
lower layer and less dense liquid (B) is passed into liquid (A). The total vapour pressure of the system will be the
sum of vapour pressure of both the volatile liquids.
 Ptotal = PA + PB = PA0 + PB0 (as XA & XB = 1)

The boiling point of a liquid system is the temperature at which its vapour pressure becomes equal to the external
atmospheric pressure. The total vapour pressure of a mixture containing immiscible volatile liquids is greater than
either of the pure constituents, thus the mixture will boil at a temperature, which is lower than the boiling point of
either of the pure constituents.
This forms the basis of steam distillation, in which one of the volatile liquids is water.
This composition of the vapour above the liquid mixture can be calculated using
Dalton’s law of partial pressures.

PA = PA0 = PTotal XA’ .......(i)
PB = PB0 = PTotal XB’ .......(ii)
XA' and XB' represents the mole fraction of A and B in the vapour phase.
PTotalXB ' PB WB PB  MB

 
PTotalXA ' PAº W A PA  MA
The masses of the constituents in the vapour (distillate) will be proportional to their respective molar mass of vapour
pressure.
16. A mixture of immiscible liquids of an organic liquid and water boils at 90 0C and 732 torr pressure. The
distillate contains 73% by weight of the organic liquid. Calcualte the molar mass of the organic liquid (vapour
pressure of water at 900C is 526 torr.)
(A) 168.2 g mol–1 (B) 228.8 g mol–1 (C*) 122.2 g mol–1 (D) 62.7 g mol–1
17. When a mixture of water and chlorobenzene (mutually immiscible) is distilled at an external pressure of
740.2 mm Hg, the mixture is found to boil at 90.30C, at which temperature the vapor pressure of pure water
is 350.1 mmHg. Calculate the per cent by weight of chlorobenzene in the disillate. (Molecular weight is 112).
(A*) 0.71 (71%) (B) 0.48 (48%) (C) 0.25 (25%) (D) 0.86 (86%)
18. Two liquids X and Y are perfectly immisible. If X and Y have molecular masses in ratio 1 : 2, the total vapour
pressure of a mixture of X and Y prepared in weight ratio 2 : 3 should be :
Px0  400 torr , Py0  200 torr
(A*) 600 torr (B) 700 torr (C) 850 torr (D) 900 torr
19. An unknown compound is immiscible with water. It is steam distilled at 98.00C and P = 737 torr, P0(H2O) =
707 torr at 98.00C. This distillate was 75% by weight water. Calculate the molecular weight of the unknown.
(A*) M = 141.4 (B) M = 92.1 (C) M = 126.2 (D) M = 186.8
PAGE NO.- 13
Daily Self-Study Dosage for mastering Chemistry vfeJ.kh; nzo
vfeJ.kh; nzo
tc ,d ok"i'khy nzo dks vU; ok"i'khy nzo esa feyk;k tkrk gS] tks ,d&nwljs ds lkFk iw.kZ :i ls vfeJ.kh; gS] izR;sd nzo vU; nzo
ds lkFk Lora=k :i ls O;ogkj djrk gS o blds Lo;a dk Okk"i&nkc yxk;sxkA vf/kd ?kuRo okyk nzo (A) fupyh ijr cuk,xk o de
?kuRo okyk nzo (B) dks nzo (A) esa ls izokfgr djsaxsA rU=k ds dqy ok"inkc] nksuksa ok"i'khy nzoksa ds ok"inkc dk ;ksx gksxkA
 Pdqy = PA + PB = PA0 + PB0 (pwafd XA & XB = 1)
,d nzo dk DoFkukad og rkieku gS ftl ij bldk ok"i&nkc blds cká nkc ds cjkcj gksxkA vfeJ.kh; ok"i'khy nzo ;qDr ,d
feJ.k dk dqy ok"i&nkc] buesa ls izR;sd 'kq) vo;o ls vf/kd gksrk gSA bl izdkj feJ.k ,d rkieku ij mcyrk gS tks fd buesa
ls fdlh Hkh 'kq) vo;o ds DoFkukad ls de gksrk gSA
;g Hkkih; vklou dk vk/kkj cukrk gS] ftlesa ,d ok"i'khy nzo ty gSA
nzo feJ.k ds Åij ok"i ds bl laxBu dks fuEu dks iz;qDr dj ifjdfyr fd;k tkrk gSA
vkaf'kd nkcksa dk MkWYVu fu;e
PA = PA0 = PTotal XA’ .......(i)
PB = PB0 = PTotal XB’ .......(ii)
XA' o XB' ;gka ok"i izkoLFkk esa A o B ds eksy&fHkUu dks iznf'kZr djrs gSA
PTotalXB ' PB WB PB  MB

 
PTotalX A ' PAº WA PA  MA
ok"i ¼vklou½ esa vo;oksa dk nzO;eku] ok"inkc ds Øe'k% eksy nzO;eku ds lekuqikrh gksaxsA
16. 900C o 732 torr nkc ij ,d dkcZfud nzo o ty ds vfeJ.kh; nzo ds ,d feJ.k dks mckyk tkrk gSA vklou dkcZfud
nzo ds Hkkj dk 73% j[krk gSA dkcZfud nzo dk eksyj&nzO;eku ifjdfyr dhft, (900C ij ty dk ok"inkc 526 torr gS)
(A) 168.2 g mol–1 (B) 228.8 g mol–1 (C*) 122.2 g mol–1 (D) 62.7 g mol–1
17. tc 740.2 mm Hg, ds ,d cká nkc ij ty o DyksjkscUs thu ds ,d feJ.k dks vklfor fd;k tkrk gS] rks feJ.k dks 90.30C
ij mckyk x;k] ftl rkieku ij 'kq) ty dk ok"inkc 350.1 mmHg gSA vklou eas DyksjkcsUthu ds Hkkj dk izfr'kr
ifjdfyr dhft,A( v.kqHkkj 112).
(A*) 0.71 (71%) (B) 0.48 (48%) (C) 0.25 (25%) (D) 0.86 (86%)
18. nks nzo X o Y iw.kZ :i ls vfeJ.kh; gaSA ;fn X o Y ds fy, v.kqHkkj 1 : 2 vuqikr esa gS] rks Hkkjkuqikr 2 : 3 esa cuk;s x;s X
o Y ds ,d feJ.k dk dqy ok"i nkc fuEu gksuk pkfg, :
Px0  400 torr , Py0  200 torr
(A*) 600 torr (B) 700 torr (C) 850 torr (D) 900 torr
19. ,d vKkr ;kSfxd ty ds lkFk vfeJ.kh; gSA bldk Hkkih; vklou 98.00C ij gS o P = 737 torr, P0(H2O) = 707 torr
gSA ;g vklou ty ds Hkkj dk 75% gSA vKkr dk v.kqHkkj ifjdfyr dhft,A
(A*) M = 141.4 (B) M = 92.1 (C) M = 126.2 (D) M = 186.8
PAGE NO.- 14

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PHY./INO.

TARGET : JEE (Main + Advanced) 2017

DATE : 17.05.2015 PART TEST (PT) - 01 (ADVANCED)

This DPP is to be discussed in the week (20-04-2015 to 25-04-2015)

2. In which case van’t Hoff factor is maximum ?

3. Which of the following increases with dilution at a given temperature?

5. A mixture of two immiscible liquids at a constant pressure of 1 atm boils at a temperature

(0.1 0.15 ) 1000

10. Select correct statement :

At dew point (vksl fcUnq ij)

15. Column-I Column-II

ChemINFO-1.3 Solution & Colligative Properties

Non ideal solution

(i) PT  X APA0  XBPB0 (i) PT  X APA0  XBPB0

(iii) There is decrease in volume on mixing and

C2H5OH + Cyclohexane, CHCl3 + CCl4

16. Identify the mixture that shows negative deviation solutions

19. Identify the mixture showing positive deviation of non-ideal solution.

ChemINFO-1.3 Solution & Colligative Properties

Non ideal solution

(i) PT  X APA0  XBPB0

S   ive G   ive S   ive G   ive

16. og feJ.k igpkfu;s tks _.kkRed fopyu dk foy;u n'kkZrk gS %

DPP No. # 06 (JEE-ADVANCED)

(A) Work done by the gas during complete cycle is 6P0V0.

6. Consider the following statements with regard to magnesium sulphate :

fuEu dFkuksa dks eSXuhf'k;e lYQsV ds lanHkZ esa voyksdu dhft,&

bls vkjs[k }kjk Li"V fd;k tkrk gSA

12. Consider the following trends in properties of hydrogen halides :

15. Match the Column

 Ptotal = PA + PB = PA0 + PB0 (as XA & XB = 1)

Dalton’s law of partial pressures.

PB = PB0 = PTotal XB’ .......(ii)

PTotalXB ' PB WB PB  MB

Px0  400 torr , Py0  200 torr

PTotalXB ' PB WB PB  MB

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