JP XII Physical&Inorganic Chemistry (13) - Prev Chaps + Inorg. Chem + Electrochemistry PDF

PHY./INO.
CHEMISTRY
TARGET : JEE (Main + Advanced) 2016
Course : VIJETA (JP) NO. 20 & 21
This DPP is to be discussed in the week (22-06-2015 to 27-06-2015)
DPP No. # 20 (JEE-MAIN)

Total Marks : 60 Max. Time : 40 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.20 (3 marks, 2 min.) [60,40]
1. The virial equation for 1 mole of a real gas is written as

 A B C 
PV = RT 1  V  2  3  .....to higher power of n
 V V 
W here A,B and C are known as virial cofficients. If Vander waal's equation is written in virial form , then
what will be the value of A.
1 eksy okLrfod xSl ds fy, fofj;y lehdj.k fuEu gSA
 A B C 
PV = RT 1  V  2  3  ..... n 
 V V 
;gk¡ A,B rFkk C fofj;y fLFkjkad gSA ok.Mj okWy lehdj.k dks ;fn fofj;y lehdj.k ds :i esa fy[kk tk;s rks A dk eku
gksxkA
b a a RT  b
(A) a – (B) RT – (C*) b – (D)
RT b RT a
2. W hat is the correct increasing order of liquifiability of the gases shown as in above graph ?
mijksDr oØ esa fn[kk;s vuqlkj xSlksa ds nzohdj.k dh lqxerk dk c<rk gqvk lgh Øe gSA
(A*) H 2 < N 2 < CH 4 < CO 2 (B) CO2 < CH 4 < N 2 < H 2

(C) H 2 < CH 4 < N 2 < CO2 (D) CH 4 < H 2 < N 2 < CO2
Sol. Order of Vander waals constant CO 2 > CH 4 > N 2 > H 2
 ease of liqufication CO 2 > CH 4 > N 2 > H 2
okW.Mj okWYl fLFkjkadksa dk Øe CO2 > CH4 > N2 > H2
 nzohdj.k dh lqxerk CO2 > CH4 > N2 > H2
3. CaCN 2 has :
(A*) 2  bonds , 2  bonds (B) 3  bonds , 1  bond
(C) 1  bond , 2  bonds (D) 3  bonds , 2  bonds
CaCN 2 es a gksr s gS %
(A*) 2  ca /k , 2  ca/k (B) 3  ca/k , 1  ca /k
(C) 1  ca/k , 2  ca /k (D) 3  ca/k , 2  ca/k
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4. Which of the following statements is correct ?
(A) N2F3+ is planar at each nitrogen atom. (B) In N3H, the H – N – N bond angle is exactly of 120°.
(C) The shape of N(SiMe3)3, is trigonal planar. (D*) (A) and (C) both.
fuEu esa ls dkSulk dFku lgh gS ?
ukbVªkstu ijek.kq ij N2F3+ leryh; gSA
(A) izR;sd (B) N3H esa] H – N – N cU/k dks.k ,dne 120° ik;k tkrk gSA
(C) N(SiMe3)3 dh vkd`fr f=kdks.kh; leryh; gSA (D*) (A) rFkk (C) nksuksaA
Sol. (A) (B) (C)
5. The species that do not contain peroxide ions are :

(A*) PbO2 (B) H2O2 (C) SrO2 (D) BaO2
Lih'kht tks ijkWDlkbM vk;u ugha j[krh gS %
(A*) PbO2 (B) H2O2 (C) SrO2 (D) BaO2
Ans. (A)
Sol. Only H2O2 (hydrogen peroxide), BaO 2 (Barium peroxide) and SrO2 (Strontium peroxide) contain peroxide
ions. So (A) is the correct choice.
g y- dsoy H2O2 ¼gkbMªkstu ijkWDlkbM½] BaO2 ¼csfj;e vkWDlkbM½ o SrO2 ¼LVªkWfU'k;e ijkWDlkbM½ ijkWDlkbM vk;u j[krs
gSA vr% (A) lgh fodYi gSA
6. A solution of sodium metal in liquid ammonia is strongly reducing due to the presence of
(A) sodium atoms (B) sodium hydride
(C) sodium amide (D*) solvated electrons
fuEu esa ls fdldh mifLFkfr ds dkj.k] lksfM;e /kkrq dk nzo veksfu;k esa foy;u] çcy vipk;d gksrk gS %
(A) lksfM;e ijek.kq (B) lksfM;e gkbMªkbM (C) lksfM;e ,ekbM (D*) foyk;fdr bysDVªku
W
Ans. (D)
Sol. (D) The free ammoniated electrons make the solution of Na in liquid NH3 is a very powerful reducing agent.
The ammonical solution of an alkali metal is rather favoured as a reducing agent than its aqueous solution
because in aqueous the alkali metal being highly electropositive quite stable, provided no catalyst
(transition metal) is present.
g y- (D) eqDr veksfu;ke; bysDVªkWu] nzo NH3 esa Na foy;u dks çcy vipk;d cuk nsrs gSA {kkj /kkrq dk veksfu;ke;
foy;u blds tyh; foy;u dh vis{kk vipk;d dh rjg O;ogkj djrk gSA D;ksafd tyh; foy;u esa {kkj /kkrq mPp
fo?kqr/kukRed gksrh gS blds dkj.k ;g vf/kd LFkk;h gksrh gSA bl vfHkfØ;k esa dksbZ Hkh mRçsjd ¼laØe.k /kkrq½ ç;qDr
ugha gksrs gSaA
7. Molecular formula of Glauber`s salt is :
(A) MgSO4.7H2O (B) CuSO4.5H2O (C) FeSO4.7H2O (D*) Na2SO4.10H2O
Xykscj yo.k dk v.kqlw=k gS %

(A) MgSO4.7H2O (B) CuSO4.5H2O (C) FeSO4.7H2O (D*) Na2SO4.10H2O
Ans. (D)
Sol. Glauber`s salt is Na2SO4. 10H2O.
g y- Xykscj yo.k Na2SO4. 10H2O gSA
8. The oxidation of SO2 by O2 to SO3 is an exothermic reaction. the yield of SO 3 will be maximum if
(A) temperature is increased and pressure is kept constant.
(B*) temperature is reduced and pressure is increased.
(C) both temperature and pressure are increased.
PAGE NO.- 2
(D) both temperature and pressure are reduced.
O2 }kjk SO2 dk SO3 esa vkWDlhdj.k ,d Å"ek{ksih vfHkfØ;k gS] SO3 dh yfC/k (yield) vf/kdre gksxh ;fn µ
(A) rki esa o`f) rFkk nkc fu;r j[kk tk,A (B*) rki esa deh rFkk nkc esa o`f) dh tk,A
(C) rki rFkk nkc nksuksa esa o`f) dh tk,A (D) rki rFkk nkc nksuksa esa deh dh tk,A
Sol. Le-chatelier principle
2SO2(g) + O2(g) 2 SO3 (g)
rg = – 1
Pressure increases  Reaction goes in forward direction.
H = – Ve
Temperature decrases  Reaction goes in forward direction
9. In Galvanic cell :
(A*) Chemical reaction produces electrical energy (B) Electrical energy produces chemical reaction
(C) Reduction occurs at anode (D) Oxidation occurs at cathode
xSYosuhd lsy esa &
(A*) jklk;fud vfHkfØ;k fo|qr ÅtkZ mRiUu djrh gS (B) fo|qr ÅtkZ jklk;fud vfHkfØ;k mRiUu djrh gS
(C) ,suksM+ ij vip;u gksrk gS (D) dSFkksM+ ij vkWDlhdj.k gksrk gS
Sol. Galvanic cells are electro chemical cells which convert chemical energy into electrical energy.
10. The standard oxidation potentials, E°, for the half-reaction are as
v)Z vfHkfØ;k ds fy, ekud vkWDlhdj.k foHko E° fuEu gSA
Zn = Zn2+ + 2e– ; E° = + 0.76 V
Fe = Fe2+ + 2e– ; E° = + 0.41 V the E°cell is - rks E°lsy gksxkA
Fe+2 + Zn Zn2+ + Fe is -
(A) –0.35 V (B*) + 0.35 V (C) +1.17 V (D) – 1.17 V
Sol. Eºcell = [EºA – EºC]OP = 0.76 – 0.41 = 0.35 V.
11. From the following E° values of half cells -

v)Z lsy ds fy, E° dk eku fuEu gS&
(i) A + e–  A¯ ; E° = – 0.24 V (ii) B¯ + e–  B2– ; E° = + 1.25 V
– 3–
(iii) C¯ + 2e  C ; E° = –1.25 V (iv) D + 2e–  D2– ; E° = + 0.68 V
What combination of two half cells would result in a cell with the largest potential
dkSuls nks v)Z lsyks dk la;kstu] vf/kdre foHko okys lsy dk fuekZ.k djsxk \
(A*) (ii) and (iii) (B) (ii) and (iv) (C) (i) and (iii) (D) (i) and (iv)
(A*) (ii) rFkk (iii) (B) (ii) rFkk (iv) (C) (i) rFkk (iii) (D) (i) rFkk (iv)
Sol. Eºcell = [EºC – EºA]RP = 1.25 + 1.25 = 2.50 V.
Eºcell = [EºC – EºA]RP = 1.25 – (–1.25) = 2.50 V (Maximum value)
12. The Ni/Ni2+ and F–/F2 electrode potentials are listed as +0.25 V and –2.87 V respectively (with respect to the
standard hydrogen electrode). The cell potential when these are coupled under standard conditions is
(A) 2.62 V and dependent on the reference electrode chosen.
(B*) 3.12 V and independent of the reference electrode chosen.
(C) 3.12 V and dependent on the reference electrode chosen.
(D) 2.62 V and independent of the reference electrode chosen.
Ni/Ni2+ rFkk F–/F2 ds fy, bysDVªkWM foHko Øe'k% +0.25 V rFkk –2.87 V fn;k x;k gS (ekud gkbMªkstu bysDVªkWM ds lUnHkZ
esa) tc ;g ekud ifjfLFkfr;ksa esa la;ksftr fd, tkrs gS rks lsy foHko gksxk \
(A) 2.62 V rFkk pqus x, ekud bysDVªkWM ij fuHkZj djrk gSA (B*) 3.12 V rFkk pqus x, ekud bysDVªkWM ls Lora=k gksrk
gSA
(C) 3.12 V rFkk pqus x, ekud bysDVªkWM ij fuHkZj djrk gSA (D) 2.62 V rFkk pqus x, ekud bysDVªkWM ls Lora=k gksrk gSA
Sol. Electrode potential values depend on reference electrode chosen but not cell potential.
13. E° for some half cell reactions are given below

dqN v)Z lsy vfHkfØ;kvksa ds fy, E° uhps fn;s x;s gSaA
Sn+4 + 2e–  Sn2+ ; E° = 0.151 V
2Hg2+ + 2e  Hg2+2 ; E° = 0.92 V
PAGE NO.- 3
PbO2 + 4H+ + 2e–  Pb2+ + 2H2O ; E° = 1.45 V
based on the given data which statement is correct.
fn;s x;s vkdMksa ds vk/kkj ij dkSulk dFku lgh gSA
(A) Sn4+ is a stronger oxidising agent than Pb+4 (B*) Sn2+ is a stronger reducing agent than Hg22+
(C) Hg2+ is a stronger oxidising agent than Pb4+ (D) Pb+2 is a stronger reducing agent than Sn2+
(A) Sn4+ , Pb+4 fd rqyuk esa izcy vkWDlhdkjd vfHkdeZd gSA
(B*) Sn2+ , Hg22+ fd rqyuk esa izcy vipk;d vfHkdeZd gSA
(C) Hg2+ , Pb4+ fd rqyuk esa izcy vkWDlhdkjd vfHkdeZd gSA
(D) Pb+2 , Sn2+ fd rqyuk esa izcy vipk;d vfHkdeZd gSA
Sol. Sn2+  Sn+4 + 2e– E° = –0.15 V
Hg22+  2Hg2+ + 2e– E° = –0.92 V
Sn2+ ] Hg22+
Sn2+ ] Hg22+ fd rqyuk esa izcy vipk;d vfHkdeZd gSA
Cr2O 72 0
14. For the cell prepared from electrode A and B, electrode A : , Ered = + 1.33 V and electrode B:
Cr 3 
Fe3
, E 0red = 0.77 V, which of the following statement is not correct?
Fe2
(A) The electrons will flow from B to A (in the outer circuit) when connections are made.
(B) The standard emf of the cell will be 0.56 V.
(C) A will be positive electrode.
(D*) None of the above.
Cr2O 27  Fe3 
bysDVªkWM A o B ls cus ,d lSy ds fy,] bysDVªkWM+ A : , Eºred = + 1.33 V o bysDVªkWM+ B: ,
Cr 3  Fe 2
Eºred = 0.77 V gSA fuEu esa ls dkSulk okD; lgh ugh gS &
(A) tc la;ksftr fd;k tkrk gSA ] rks bysDVªkWu B ls A dh vksj ¼ckà; ifjiFk esa½ izokfgr gkssaxs A
(B) lsy dk ekud emf 0.56 V gksaxk A
(C) A /kukRed bysDVªkWM gksxkA
(D*) buesa ls dksbZ ughaA
Sol. Eº(Cr2O72–  Cr3+) = 1.33V (A)
Eº (Fe3+  Fe2+) = 0.77V (B)
When these two electrodes are connected, then the electrode with higher reduction potential act as cathode.
So (A) is cathode (B) is anode.
e– flow from anode to cathode in external circuit.
Eºcell = 1.33 – 0.77 = 0.56V
cathode (A) is a +ve electrode in electro chemicall cell.
15. The standard reduction potentials at 25°C for the following half reactions are given against each -
25ºC ij fuEu v)Z vfHkfØ;kvksa ds fy, ekud vip;u foHko izR;sd ds lkeus fn;k x;k gSA
Zn2+(aq) + 2e¯ Zn(s), –0.762 V
Cr3+(aq) + 3e¯ Cr(s), –0.740 V
2H+ + 2e¯ H2(g), 0.00 V
Fe3+ + e¯ Fe2+, 0.77 V
Which is the strongest reducing agent -
dkSulk izcyre vipk;d gSA
(A*) Zn (B) Cr (C) H2(g) (D) Fe3+(aq)
Ans. Higher oxidation potential, higher reducing tendency.
16. Hydrogen gas will not reduce -

(A) heated cupric oxide (B) heated feric oxide
(C) heated stannic oxide (D*) heated aluminium oxide
PAGE NO.- 4
   
[ E Sn 4 /Sn 2  0.15V ; E Cu 2 /Cu  0.167 V ; E Fe3 / Fe2  0.771V ; E Al 3 / Al  1.67 V ]
gkbMªkstu xSl fdls vipf;r ugha djsxh&
(A) xeZ D;wfizd vkWDlkbM dks (B) xeZ Qsfjd vkWDlkbM dks
(C) xeZ LVsfud vkWDlkbM dks (D*) xeZ ,Y;qfefu;e vkWDlkbM dks

[ E Sn 4 /Sn 2  0.15V ; E Cu 2 /Cu  0.167 V ; E Fe3 / Fe2  0.771V ; E Al 3 / Al  1.67 V ]
Sol. EHº  / H = 0 V..

2
Hydrogen gas will reduce those metals which have reduction potential greater than H 2 gas.
17. Four colourless salt solutions are placed in separate test tubes and a strip of copper is dipped in each.
Which solution finally turns blue ? (use data from electrochemical series)
pkj jaxghu yo.k foy;uks dks i`Fkd µ i`Fkd ij[kuyh esa j[kk x;k gS rFkk izR;sd esa dkWij dh iryh iV~Vhdk Mqcks;h tkrh
gS dkSulk foy;u vUrr% uhyk gks tkrk gS (fo|qr jklk;fud Js.kh ls vk¡dM+ks dks iz;qDr dhft, )
(A) Pb(NO3)2 (B*) AgNO3 (C) Zn(NO3)2 (D) Cd(NO3)2
Sol. Cu will reduce to those metal which have higher reduction potential than Cu.
So, Ag+ has higher potential.
18. Red hot carbon will remove oxygen from the oxide XO and YO but not from ZO. Y will remove oxygen from
XO. Use this evidence to deduce the order of activity of the three metals X, Y, and Z putting the most active
first -
yky rIr dkcZu vkWDlkbM XO rFkk YO ls vkWDlhtu dks i`Fkd djrk gS ysfdu ZO ls ugha] Y, XO ls vkWDlhtu dks i`Fkd
djrk gS bl rF; dks iz;qDr dj rhu /kkrqvksa X, Y, rFkk Z dh fØ;k'khyrk ds Øe dks fu/kkZfjr dhft, rFkk vf/kd fØ;k'khy
dks igys fyf[k, \
(A) XYZ (B*) ZYX (C) YXZ (D) ZXY
Sol. As carbon can reduce XO and YO but not ZO, SRP of X and Y are more than carbon. Y can reduce XO,which
means SRP of X is more than Y. Hence the order of SRP is
SRP of X > SRP of Y > SRP of C > SRP of Z.
More active metal has lesser SRP.
So the order of activity of metals is
Z>Y>X Ans.
19. W hich statement about standard reduction potentials is correct


(A*) EH / H2 = Zero at all temperature

(B) ED  / D2 = zero at 298 K
(C) A redox reaction is feasible if sum of SRP of oxidant and that of reductant is a positive quantity
(D) K 2Cr2O7 (acid) is stronger oxidising agent than KMnO 4 (acid)

[Given : EMnO–4 / Mn2  = 1.51 V ; E Cr O 2 – / Cr 3  = 1.33 V]
2 7
ekud vip;u foHko ds fy, dkSulk dFku lgh gS&


(A*) E H / H = fdlh Hkh rki ij 'kwU;

2
(B) ED  / D = 'kwU; (298 K rki ij)

2
(C) ,d jsMkDl vfHkfØ;k gksrh gS ;fn vkWDlhdkjd ds SRP rFkk vipk;d ds SRP dk ;ksx ,d /kukRed ek=kk gS
(D) K2Cr 2O 7 ( vEy) ( KMnO 4 ( vEy) dh rqyuk esa izcyre vkWDlhdkjd vfHkdeZd gSA
 
[Given : EMnO –4 / Mn2  = 1.51 V; E Cr2O 27 – / Cr 3  = 1.33 V]
Sol. (A) It is a convention that SRP of standard hydrogen electrode is zero at all tempertures.
(B) is incorrect.
(C) the difference should be +ve quantity.
PAGE NO.- 5
(D) KMnO4 is stronger oxidising agent (SRP values).
20. The temperature defining the standard electrode potential is
(A) 298 K (B) 273 K (C) 373 K
(D*) any temperature can be selected but it must remain constant and species must be in their standard
states.
ekud bysDVªkWM foHko dks ifjHkkf"kr djus ds fy, rki gSA
(A) 298 K (B) 273 K (C) 373 K
(D*) fdlh Hkh rkieku dk p;u fd;k tk ldrk gS ysfdu ;g fu;r jguk pkfg, rFkk Lih'kht viuh ekud voLFkk
esa gksuh pkfg,A
Sol. Any temperature can be selected.
DPP No. # 21 (JEE-ADVANCED)

Total Marks : 76 Max. Time : 46 min.
Single choice Objective ('–1' negative marking) Q.1 to Q.8 (3 marks, 2 min.) [24,16]
Multiple choice objective ('–1' negative marking) Q.9 to Q.14 (4 marks, 2 min.) [24,12]
Subjective Questions ('–1' negative marking) Q.15 to Q.18 (4 marks, 3 min.) [16,12]
ChemINFO : 3 Questions ('–1' negative marking) Q.19 to Q.21 (4 marks, 2 min.) [12, 06]
1. Calculate H° for this reaction.

nh xbZ vfHkfØ;k ds fy, H° dk eku Kkr dhft,]
C2H2 (g) + 2H2 (g)  C2 H6 (g)
Hcombustion, kJ mol–1  H , k J m o l –1
C2H2 (g) C 2 H 2 (g ) – 1300

– 1300
H2(g) – 286 H 2 (g ) – 286
C2H6 (g) – 1560 C 2 H 6 (g ) – 1560
(A*) – 312 kJ (B) – 26 kJ (C) + 26 kJ (D) + 312 kJ

Sol. H°rxn = (H°C)R – (H°C)P
= [– 1300 – 2 × 286] – 1560 = – 312.5 kJ
2. S1 : (a)NH3 > (a)H2 O [(a) is Vanderwaal's constant]

S2 : Pressure of the real gas is more than the ideal gas for same temperature and volume of the container.
S3 : Compresssibilty factor for H2 (g) is never less than unity at any temperature.
S4 : The value of critical temperature (T C) is greater for H2O than O2.
S1 : (a)NH3 > (a)H2 O [(a) okUMWjoky fLFkjkad gS]
S2 : ik=k es leku rki rFkk vk;ru ds fy, okLrfod xSl dk nkc] vkn'kZ xSl dh rqyuk esa vf/kd gksrk gSA
S3 : fdlh rki ij H2 (g) ds fy, laihM~;rk&xq.kkad] dHkh Hkh bdkbZ ls de ugha gksrk gSA
S4 : O2 dh rqyuk esa H2O ds fy, ØkfUrd rki (TC) dk eku vf/kd gksrk gSA
(A) T F F T (B*) F F F T (C) F T T F (D) T T T F
3. In a half-cell contaning [Tl3+] = 0.1 M and [Tl+] = 0.01M, the cell potential is –1.2496 V for the reaction
Tl+  Tl3+ + 2e– . The standard reduction potential of the T+3 /T+1 couple at 25°C is
,d v)Z&lsy ftlesa [Tl3+] = 0.1 M rFkk [Tl+] = 0.01M mifLFkr gS] vfHkfØ;k Tl+  Tl3+ + 2e– ds fy, lsy foHko
–1.2496 V gSA 25°C ij T+3 /T+1 ;qXe ds fy, ekud vip;u foHko gksxk \
(A) 144 V (B) 0.61 V (C) 2.44 V (D*) 1.22 V
Sol. T3+ + 2e–  T+ ECell = + 1.2496 V
0.0591 0.01
ECell = 1.2496 V = EºCell – log
2 0. 1
PAGE NO.- 6
EºCell = 1.22 V.
4. The standard electrode potential for the reactions,
Ag+(aq) + e¯ Ag(s)
Sn2+(aq) + 2e¯ Sn(s)
at 25°C are 0.80 volt and –0.14 volt, respectively. The emf of the cell Sn|Sn 2+ (1 M) ||Ag+ (1M)|Ag is-
(A) 0.66 volt (B) 0.80 volt (C) 1.08 volt (D*) 0.94 volt
Ag+(aq) + e¯ Ag(s)
Sn2+(aq) + 2e¯ Sn(s)
vfHkfØ;kvksa ds fy, ekud bysDVªkWM foHko 25°C ij Øe'k% 0.80 oksYV rFkk –0.14 oksYV gSA Sn|Sn2+ (1 M) ||Ag+ (1M)|Ag
lsy ds fy, E.M.F. gksxkA
(A) 0.66 oksYV (B) 0.80 oksYV (C) 1.08 oksYV (D*) 0.94 oksYV
0.0591 [ Zn2  ] 0.0591 1

Sol. Ecell = Eºcell – log . = 0.8 – (– 0.14) – log 2 = 0.94 V..
2 [ Ag ]2 2 1
5. Given that (at T = 298 K)

Cu(s) | Cu2+ (1.0 M) || Ag+ (1.0 M) | Ag(s) Eºcell = 0.46 V
Zn(s) | Zn2+ (1.0 M) || Cu2+ (1.0 M) | Cu(s) Eºcell = 1.10 V
Then Ecell for
Zn | Zn2+ (0.1 M) || Ag+ (1.0 M) | Ag at 298 K will be
(A*) 1.59 V (B) 1.53 V (C) 2.53 V (D) cannot be calculated due to insufficient data
(T = 298 K ij) fn;k x;k gS

Cu(s) | Cu2+ (1.0 M) || Ag+ (1.0 M) | Ag(s) EºlSy = 0.46 V
2+ 2+
Zn(s) | Zn (1.0 M) || Cu (1.0 M) | Cu(s) EºlSy = 1.10 V
rc 298 K ij Zn | Zn2+ (0.1 M) || Ag+ (1.0 M) | Ag ds fy, ElSy gksxk
(A*) 1.59 V (B) 1.53 V (C) 2.53 V (D) vk¡dMs vi;kZIr gksus ds dkj.k x.kuk ugha dh tk ldrh gSA
Sol. Eo – Eo  0.46 V
Ag / Ag Cu2 / Cu
o
(+) E – Eo  1.1V
Cu2 / Cu Zn2 / Zn
___________________________
Eo – Eo  1.56 V
Ag / Ag Zn2 / Zn
Zn/Zn2+ (0.1M) || Ag+ (1.0M) | Ag Eºcell = 1.56
0.059
Ecell = Eºcell – log Q.
n
Cell reaction :
Zn Zn2+ + 2e–
+ (Ag+ + e– Ag) × 2
___________________________
Zn + 2Ag+ Zn2+ + 2Ag
[ Zn2 ] (0.1) 0.059 0.059

Q= = = 0.1  Ecell = Eºcell – log 0.1 = 1.56 – × – 1 = 1.59V Ans.
[ Ag  ] 2 (1) 2 2 2
6. What is the value of the reaction quotient, Q, for the cell -

Ni(s) | Ni(NO3)2 (0.190M) | | KCl(0.40M)| Cl2(g, 0.10 atm) |Pt(s)
lsy Ni(s) | Ni(NO3)2 (0.190M) | | KCl(0.40M)| Cl2(g, 0.10 atm) |Pt(s) ds fy, vfHkfØ;k xq.kkad Q dk eku D;k gksxk\
(A*) 3 x 10–1 (B) 1.3 x 10–1 (C) 8.0 x 10–2 (D) 3.0 x 10–2
2+ –
Sol. Ni (s) + Cl2  Ni (aq) + 2Cl .
[Ni2 ] [Cl– ]2 (0.19 ) (0.4 )2

Q= PCl2 = = 0.304.
0. 1
PAGE NO.- 7
7. The dissociation constant for [Ag(NH3)2]+ into Ag+ and NH3 is 10–13 at 298 K. If E 0Ag Ag
= 0.8 V, then E0 for
the half cell [Ag(NH3)2]+ + e–  Ag + 2NH3 will be
298K ij [Ag(NH3)2]+ dk Ag+ rFkk NH3 ds fy, fo;kstu fu;rkad 10–13 gSA ;fn E 0Ag  Ag
= 0.8 V gks] rks v)Z lsy
[Ag(NH3)2]+ + e–  Ag + 2NH3 ds fy, Eº gksxkA
(A) 0.33 V (B) – 0.33 V (C) – 0.033 V (D*) 0.033 V
Sol. [Ag(NH3)2]+ + e–  Ag+ + 2 NH3 Kd = 10–13
G1º = RT ln Kd
Ag+ + e–  Ag G3º = – 1 × F × 0.8
[Ag(NH3)2]+ + e–  Ag + 2NH3 G3º = G1º + G2º

– 1 × F × Eº = – RT ln k d – 1 × F × 0.8
RT 8.314  298
Eº = – ln k d + 0.8  × 2.303 × (–13) + 0.8
F 96500
Eº = 0.0313 V.
8. You are given the following cell at 298 K with Eºcell = 1.10 V
Zn(s) | Zn2+ (C1) || Cu++ (C2) | Cu(s)
where C1 and C2 are the concentration in mol/lit then which of the following figures correctly correlates Ecell as
a function of concentrations..
C1
x-axis : log C and y-axis : Ecell
2
Eºcell = 1.10 V ds lkFk 298 K ij fuEu lSy fn;k tkrk gSA

Zn(s) | Zn2+ (C1) || Cu++ (C2) | Cu(s)
tgk¡ C1 rFkk C2 eksy@yhVj esa lkUnzrk gS rc lkUnzrk ds Qyu ds :i esa Ecell ds lkFk lgh rjg ls dkSu lacaf/kr gSA
C1
x-v{k : log C rFkk y-v{k : Ecell
2
(A) (B*) (C) (D)
Sol. Zn(s)  Zn2+ + 2e–

Cu2+ + 2e–  Cu(s)
Zn(s) + Cu2+  Zn2+ + Cu(s)

0.0591 C1
Ecell = Eºcell – log C
2 2
0.0591
Since slope is –ve i.e. –
2
pw¡fd <ky _.kkRed gSA
PAGE NO.- 8
9.* a (dm 6 bar mol–2) b (dm3 mol–1)
Gas A 6.5 0.055
Gas B 2 0.01
then which statements is/are INCORRECT : (Where symbols used here have their usual meanings)
(A*) VC (A) < VC (B) (B) PC (A) < PC (B)
(C) TC (A) < TC (B) (D*) Boyle temperature of A > Boyle temperature of B.
a (dm 6 bar mol–2) b (dm3 mol–1)
xSl A 6.5 0.055
xSl B 2 0.01
rc fuEu esa ls dkSulk@dkSuls dFku ¼lEcU/k½ lgh ugha gS@gSa % (tgk¡ ij mi;ksx esa fy;s x;s fpUg vius lkekU; vFkZ j[krs gSa)
(A*) VC (A) < VC (B) (B) PC (A) < PC (B)
(C) TC (A) < TC (B) (D*) A dk ckW;y rki > B dk ckW;y rki
Sol. VC = 3b  (VC)A < (VC)B
a
PC =  (PC)A  (PC)B
27b 2
8a
TC =  (TC)A  (TC)B
27bR
a
Tb =  (Tb)A > (Tb)B (Tb is Boyle temperature) (Tb ckW;y rkieku gS)
bR
10.* In which of the following molecules central atom involve expansion of octet ?
fuEu esa ls fdu v.kqvksa esa dsUnzh; ijek.kq esa v"V~d dk izlkj gksrk gS \
(A*) PCl5 (B*) SO4– – (C) NH3 (D*) ClO3–
Sol. (C) In NO3– molecule, nitrogen can not expand its octet due to non availability of vacant d-orbital. In (A), (B),
(D) central atom expand octet by exciting electron in outermost vacant d-orbital.
Sol. (C) NO3– v.kq esa] ukbVªkstu esa v"Vd dk izlkj ugh gksrk gS D;ksafd fjDr d- d{kd miyC/k ugha gksrk gSA (A), (B), (D) esa
dsUnzh; ijek.kq esa v"Vd dk izlkj bysDVªkWu dks ckáre fjDr d-d{kd mRrsftr djds fd;k tkrk gSA
11.* Which statement(s) is/are correct ?
(A*) Polarising power refers to cation.
(B*) Polarisability refers to anion.
(C*) Small cation is more efficient to polarise anion.
(D*) Molecules in which cation having pseudo inert gas configuration are more covalent.
dkSulk dFku lR; gS \

(A*) /kzqo.k lkeF;Z] /kuk;u ls lEcfU/kr gSA
(B*) /kzqoh;rk] _.kk;u ls lEcfU/kr gSA
(C*) NksVk /kuk;u] _.kk;u dks vf/kd izHkkoh /kqzoh; cukrk gSA
(D*) v.kq ftuesa /kuk;u Nn~e vfØ; xSl foU;kl j[krk gS] vf/kd lgla;kstd gksrk gSA
Sol. Factual according to Fajan's Rule.
Qt+ku fu;e ds vuqlkjA
12.* When zeolite, which is hydrated sodium aluminium silicate, is treated with hard water the sodium ions are
exchanged with
(A) H+ ions (B*) Ca2+ ions (C) SO42 – ions (D*) Mg2+ ions
tc ft;ksykbV] tks fd lksfM;e ,Y;qfefu;e lhfydsV gS dks dBksj ty ds lkFk mipkfjr djrs gS rc lksfM;e vk;uks
dk fofue; dkSuls vk;uks ls gksrk gSA
(A) H+ ions (vk;u) (B*) Ca2+ ions (vk;u) (C) SO42 – ions (vk;u) (D*) Mg2+ ions (vk;u)
Ans. (B, D)
Sol. Na2 AI2 Si2 O8 . xH2O + Ca2+  CaAI2 Si2 O8 . xH2O + 2Na+
Na2 AI2 Si2 O8 . xH2O + Mg2+  MgAI2 Si2 O8 . xH2O + 2Na+
PAGE NO.- 9
13.* Highly pure dilute solution of sodium in liquid ammonia :
(A*) shows blue colour. (B*) exhibits electrical conductivity.
(C) produces sodium amide. (D) produces hydrogen gas.
Na dk nzo veksfu;k esa vR;Ur 'kq) ruq foy;u %
(A*) uhyk jax n'kkZrk gSA (B*) oS|qr pkydrk iznf'kZr djrk gSA
(C) lksfM;e ,ekbM cukrk gSA (D) gkbMªkstu xSl mRiUu djrk gSA
Sol. M + (x + y) NH3  [M (NH3)x]+ + [e(NH3)y]–

The electrical conductivity is due to the solvated ions and blue colour is due to solvated electrons.
gy M + (x + y) NH3  [M (NH3)x]+ + [e(NH3)y]–
oS/kqr pkydrk foyk;dhd`r vk;uks ds dkj.k izkIr gksrh gS rFkk uhyk jax foyk;dhd`r bysDVªkWu ds dkj.k izkIr gksrk gSA
14.* The standard reduction potentials of some half cell reactions are given below :
PbO2 + 4H+ + 2e– Pb2+ + 2H2O E0 = 1.455 V
– + – 2+
MnO4 + 8H + 5e Mn + 4H2O E0 = 1.51 V
4+ – 3+
Ce + e Ce E0 = 1.61 V
+ –
H2O2 + 2H + 2e 2H2O E0 = 1.71 V
Pick out the correct statement :
(A*) Ce+4 will oxidise Pb2+ to PbO 2
(B*) MnO- will oxidise Pb2+ to PbO
4 2
(C*) H2O2 will oxidise Mn+2 to MnO-4 (D) PbO2 will oxidise Mn+2 to MnO-4
dqN v)Z lsy vfHkfØ;kvksa ds ekud vip;u foHko uhps fn, gSa &
PbO2 + 4H+ + 2e– Pb2+ + 2H2O E0 = 1.455 V
MnO4– + 8H+ + 5e– Mn2+ + 4H2O E0 = 1.51 V
Ce4+ + e– Ce3+ E0 = 1.61 V
H2O2 + 2H + 2e–
+
2H2O E0 = 1.71 V
lgh dFku dks pqfu;s &
(A*) Ce+4 , Pb2+ dks PbO2 esa vkWDlhd`r djsxk (B*) MnO-4 , Pb2+ dks PbO2 esa vkWDlhd`r djsxk
(C*) H2O2 , Mn+2 dks MnO-4 esa vkWDlhd`r djsxk (D) PbO2 , Mn+2 dks MnO-4 esa vkWDlhd`r djsxk
Sol. From given SRP values.
15. Depression of freezing point of 0.01 molal aqueous CH 3COOH solution is 0.02046°. 1 molal aqueous urea
solution freezes at – 1.86°C. Assuming molality to be equal to molarity, calculate pH of CH 3COOH solution.
0.01 eksyy tyh; CH3COOH foy;u ds fgekad fcUnq dk voueu 0.02046° gSA ,d eksyy tyh; ;wfj;k foy;u
– 1.86°C ij terk gSA ekuk fd eksyyrk eksyjrk ds cjkcj gS rc CH3COOH foy;u dh pH Kkr fdft;sA
Ans. 3
Sol. For urea
Tf = k f × m
Tf 1.86
or kf = = = 1.86
m 1
Now for CH3COOH
Tf = i kf m
0.02046
so i= = 1.1
1.86  0.01
Now i=1+
so  = 1.1 – 1 = 0.1
Now CH3COOH CH3COO– + H+
C 0 0
C – C C C
[H+] = C = 0.01 × 0.1 = 0.001
so pH = 3.
PAGE NO.- 10
Sol. ;wfj;k ds fy,
Tf = k
Tf 1.86
;k kf = = = 1.86
m 1
vr% CH3COOH ds fy,

Tf = i kf m
0.02046
vr% i= = 1.1
1.86  0.01
rc i=1+
vr%  = 1.1 – 1 = 0.1
rc CH3COOH CH3COO– + H+
C 0 0
C – C C C
+
[H ] = C = 0.01 × 0.1 = 0.001
vr% pH = 3.
16. For aqueous solution of how many of the following compounds / mixtures, does the pH remains constant
even upon dilution :
(1) NH4Cl (2) Na2CO3
(3) A 1 : 2 molar ratio mixture of Na2S and HCl. (4) A 5 : 2 molar ratio mixture of NaOH and H3PO4.
(5) A 5 : 4 molar ratio mixture of CH3COONa and HCl. (6) NaH2PO4
(7) A 2 : 1 molar ratio mixture of HCl and NaHCO3. (8) CH3COONH4
(9) A 4 : 3 molar ratio mixture of NH4OH and HCl.
fuEufyf[kr esa ls fdrus ;kSfxdksa @ feJ.kksa ds tyh; foy;u dh pH, foy;u dks ruq djus ij Hkh fu;r jgrh gS %
(1) NH4Cl (2) Na2CO3
(3) Na2S rFkk HCl dk 1 : 2 eksyj vuqikr dk ,d feJ.k (4) NaOH rFkk H3PO4 dk 5:2 eksyj vuqikr dk ,d
feJ.k
(5) CH3COONa rFkk HCl dk 5:4 eksyj vuqikr dk ,d feJ.k (6) NaH2PO4
(7) HCl rFkk NaHCO3 dk 2 : 1 eksyj vuqikr dk ,d feJ.k (8) CH3COONH4
(9) NH4OH rFkk HCl dk 4 : 3 eksyj vuqikr dk ,d feJ.k

Ans. 5
1 1
Sol. (1) pH = (pKw – pKb – logC) ; (2) pH = (pKw + pKa + logC)
2 2 2
(3) Na2S + 2HCl  2NaCl + H2S
1
 pHWA = (pKa – logC)
2 1
PAGE NO.- 11
(4) NaOH + H3PO4  NaH2PO4 + H2O
i 5 2
f 3 0 2 2
NaOH + NaH2PO4  Na2HPO4 + H2O
i 3 2
f 1 0 2 2
NaOH + Na2HPO4  Na3PO4 + H2O
i 1 2
f 0 1 1 1
[PO 34– ]
 Buffer solution ¼cQj foy;u½  pH = pKa + log10
3
[HPO 24– ]
(5) CH3COONa + HCl  CH3COOH + NaCl
i 5 4
f 1 0 4 4
[CH3 COO – ]
 Acidic buffer ¼vEyh; cQj½  pH = pKa + log10
[CH3 COOH]
pK a2  pK a1
(6) pH =
2
(7) HCl + NaHCO3  NaCl + H2CO3
i 2 1
f 1 0 1 1
For a mixture of WA + SA, major H+ ions will come from HCl.
WA + SA ds ,d feJ.k ds fy, H+ vk;u eq[;r% HCl ls vkrs gSA
 pH = – log10[H+]HCl
1
(8) pH = (pKw + pKa – pKb)
2
(9) NH4OH + HCl  NH4Cl + H2O
i 4 3
f 1 0 3 3
[NH4 ]
 Basic buffer ¼{kkjh; cQj½  pOH = pKb + log10
[NH4 OH]
Clearly, pH of solutions 4, 5, 6, 8 and 9 is not affected by dilution.

Li"V gS fd foy;u 4, 5, 6, 8 rFkk 9 dh pH, foy;u dks ruq djus ij çHkkfor ugha gksrh gSA
PAGE NO.- 12
17. Determine the heat of hydrogenation of ethylene from the following data .
fuEufyf[kr vk¡dM+ksa ds vk/kkj ij ,Fkhyhu ds gkbMªkstuhdj.k dh Å"ek Kkr dhft, %
Bond Bond energy Bond Bond energy
ca/k ca/k ÅtkZ ca/k ca/k ÅtkZ
HH 104 Kcal / mol CC 80 Kcal / mol
CH 99 Kcal / mol C=C 145 Kcal / mol
Ans.  29 Kcal / mol
Sol. C2H4(g) + H2  C2H6
H = (H)sup – (H)req
H = [145 + 104] – [80 + 2 × 99]
H =  29 Kcal / mol
18. In how many following species, the central atoms have two lone pairs of electrons ?
fuEu esa ls fdruh Lih'kht esa dsUnzh; ijek.kq nks ,dkdh bysDVªkWu ;qXe j[krk gS \
XeF4 XeF5– F2SeO2 XeF3+ XeOF4 ClOF3
ICl4– SCl2 OSF4
Ans. 5
Sol. XeF4 XeF5– F2SeO2
XeF3+ XeOF4 ClOF3
ICl4– SCl2 OSF4
PAGE NO.- 13
ChemINFO-1.15 ELECTROCHEMISTRY
Daily Self-Study Dosage for mastering Chemistry Galvanic Cell & Salt Bridge
A device used to convert chemical energy produced in a redox reaction into electrical energy is called an
electrochemical cell or simply chemical cell. These are also called galvanic cells or voltaic cells, after the name of
Luigi Galvani (1780) and Alessandro Volta (1800).
If the electrodes in a galvanic cell are not connected internally, initially the cell generates electrical energy. The
electrodes get polarized with passage of time and the cell stops working. For continuous of electrical energy, the
electrodes need to be internally connected.
A salt bridge is usually used to connect the electrodes of a galvanic cell. It is easy to construct and consists
of a gell drawn into a clean U-tube. The gel is formed by adding agar-agar into boiling water containing a inert
electrolyte like KCl. Generally, KCl is preferred because the ionic conductances of K + and Cl– are almost the
same. The gel holds the electrolyte in the tube as shown in below Fig.
Fig : Salt bridge and electrolyte

As the reactions proceed in the galvanic cell, there will be accumulation of particular ions around the electrodes.
This results in a slowdown of the electrode reactions. From the electrolyte of the salt bridge, say KCl, the K+
and Cl– ions migrate towards the end of the salt bridge K+ ions would migrate towards the reducation electrode
(cathode) while Cl– ions would migrate towards the oxidation electrode (anode). At the oxidation electrode
(anode), ions would polarize (attract) some of the oppositely charged ions towards themselves. Simultaneously,
the K+ ions would move towards the reduction electrode (cathode) and polarize the negatively charged ions
surrounding the metal. Thus, the cell works as usual. Hence, a salt bridge is helpful in the following ways.
1. It brings about internal contact between the electrodes.
2. It minimizes the liquid junction potential.
3. It minimizes polarization.
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
19. In which of the following cells salt bridge is not needed ?
(A*) Pb | PbSO4(s) | H2SO4 | PbO2 | Pb (B*) Cd | CdO(s) | KOH(aq) | NiO2(s) | Ni
(C*) Fe(s) | FeO(s) | KOH (aq.), Ni2O3(s) | Ni (D) Zn | ZnSO 4 | CuSO4 | Cu
20. The reaction 1/2 H2(g) + AgCl(s)  H(aq) + Cl–(aq) + Ag(s) occurs in the galvanic cell
(A) Ag | AgCl(s) | KCl (sol) | AgNO3 | Ag (B) Pt | H2(g) | HCl(sol) | AgNO3(sol) |Ag
(C*) Pt | H2(g) | HCl (sol) | AgCl(s) | Ag (D*) Pt | H2(g) | KCl(sol) | AgCl(s) |Ag
21. A saturated solution of KNO3 is used to make salt bridge because

(A) The velocity of K is greater than that of NO 3–.
(B) The velocity of NO3– is greater than that of K
(C*) The velocities of K and NO3– are nearly the same
(D) KNO 3 is highly soluble in water.
PAGE NO.- 14
ChemINFO-1.15 fo|qr jlk;u
Daily Self-Study Dosage for mastering Chemistry Galvanic Cell & Salt Bridge
og lSy ftls jsMkWDl vfHkfØ;k ls mRiUu jklk;fud ÅtkZ dks oS|qr ÅtkZ esa :ikUrfjr djus ds fy, iz;qDr fd;k tkrk gS ,d oS|qr
jklk;fud lSy ;k lkekU; jklk;fud lSy dgykrk gSA bUgsa Y;wxh XkSYosuh (1780) rFkk ,yslsUMªks oksYVk (1800) ds uke ds i'pkRk~
xSYosfud lSy ;k oksYVsbZd lSy Hkh dgk tkrk gSA
;fn xsYosfud lSy esa bysDVªkWM vkUrfjd :i ls tqM+s gq, ugh gS rks izkjEHk esa lSy fo|qr ÅtkZ mRiUu djrk gSA bysDVªkWM le;
xqtjus ds lkFk&lkFk èkqzohd`r gksrk gS rFkk lSy dk;Z djuk can dj nsrk gSA lrr~ fo|qr ÅtkZ ds fy, bys DVªkWMksa dk vkUrfjd :i
ls tqM+k gksuk vko';d gksrk gSA
,d yo.k lsrq izk;% xsYosfud lSy ds bysDVªkWMksa dks tksMus ds fy, iz;qDr gksrk gSA ;g vklkuh ls cuk;k tk ldrk gS rFkk ,d
LoPN U ufydk esa tSy dk cuk gksrk gSA tSy dks KCl ds leku vfØ; fo|qr vi?kV~; okys ,d mcyrs gq, ty esa vxkj&vxkj
esa feykdj cuk;k tkrk gSA lkekU;r% KCl dks izkFkfedrk nh tkrh gS] D;ksafd K+ rFkk Cl– dh vk;fud pkydrk;sa izk;% leku gksrh
gSA tSy fuEu fp=k esa n'kkZ;s vuqlkj ufydk esa bysDVªksMksa dks jksdrk gSA
Fig : yo.k lsrq rFkk oS|qr vi?kV~;

tSls gh xsYosfud lSy esa vfHkfØ;k,sa gksrh gS] ;gk¡ bysDVªksMksa ds pkjksa vkSj fo'ks"k vk;uksa dk laxzg.k gksxkA blds ifj.kkeLo:i bysDVªkWM
vfHkfØ;k;sa èkheh gks tkrh gSA yo.k lsrq KCl ds oS|qr vi?kV~; ls K+ rFkk Cl– vk;u yo.k lsrq ds fljs dh vksj xeu djrs gSA
K+ vk;u] vip;u bysDVªkWM (dSFkksM) dh vksj tcfd Cl– vk;u] vkWDlhdj.k bysDVªkWM (,uksM) dh vksj xeu djrs gSA vkWDlhdj.k
bysDVªkWM (,uksM) ij vk;u buds Lo;a dh vksj dqN foifjr vkosf'kr vk;uksa dks èkzqoh;d`r ¼vkdf"kZr½ djsaxAsa blds lkFk gh K+ vk;u]
vip;u bysDVªkWM ¼dSFkksM½ dh vksj xfr djsxas rFkk /kkrq ds pkjks vksj mifLFkr _.kkosf'kr vk;uksa dks /kzqoh;d`r djsxsaA bl izdkj
lSy lkekU; :i esa dk;Z djrk gSA blfy, ,d yo.k lsrq fuEu izdkjksa esa lgk;d gksrk gS&
1. ;g bysDVªkWMksa ds eè; vkUrfjd lEidZ ykrk gSA
2. ;g æo lfUèk foHko dks U;wure djrk gSA
3. ;g èkzqoh;dj.k dks U;wure djrk gSA
Memorize this theory as soon as you get the DPP. Revise it regularly and master this concept by practice.
19. fuEu es ls dkSuls lsy es yo.k lsrq dh vko';drk ugha 21. KNO3 dk lUriz foy;u yo.k lsrq cukus es iz;qDRk gksrk
gksrh gSA gS D;ksfd
(A*) Pb | PbSO 4(s) | H2SO4 | PbO2 | Pb (A) K dh xfr'khyrk NO3– dh rqyuk es vf/kd gksrh gSA
(B*) Cd | CdO(s) | KOH(aq) | NiO 2(s) | Ni (B) NO3– dh xfr'khyrk Kdh rqyuk esa vf/kd gksrh gSA
(C*) Fe(s) | FeO(s) | KOH (aq.), Ni2O3(s) | Ni
(C*) K rFkk NO3– dh xfr'khyrk yxHkx leku gksrh gSA
(D) Zn | ZnSO4 | CuSO4 | Cu
(D) KNO3 ty esa vf/kd foys;'khy gksrk gSA
20. vfHkfØ;k 1/2 H2(g) + AgCl(s)  H(aq) + Cl–
(aq) + Ag(s) xSyosfud lsy es gksrh gSA
(A) Ag | AgCl(s) | KCl (sol) | AgNO 3 | Ag
(B) Pt | H2(g) | HCl(sol) | AgNO 3(sol) |Ag
(C*) Pt | H2(g) | HCl (sol) | AgCl(s) | Ag
(D*) Pt | H2(g) | KCl(sol) | AgCl(s) |Ag
PAGE NO.- 15

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JP XII Physical&Inorganic Chemistry (13) - Prev Chaps + Inorg. Chem + Electrochemistry PDF

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PHY./INO.

TARGET : JEE (Main + Advanced) 2016

Course : VIJETA (JP) NO. 20 & 21

This DPP is to be discussed in the week (22-06-2015 to 27-06-2015)

DPP No. # 20 (JEE-MAIN)

1. The virial equation for 1 mole of a real gas is written as

(A*) H 2 < N 2 < CH 4 < CO 2 (B) CO2 < CH 4 < N 2 < H 2

Sol. (A) (B) (C)

5. The species that do not contain peroxide ions are :

Xykscj yo.k dk v.kqlw=k gS %

11. From the following E° values of half cells -

13. E° for some half cell reactions are given below

16. Hydrogen gas will not reduce -

Sol. EHº  / H = 0 V..

19. W hich statement about standard reduction potentials is correct

ekud vip;u foHko ds fy, dkSulk dFku lgh gS&

(B) ED  / D = 'kwU; (298 K rki ij)

DPP No. # 21 (JEE-ADVANCED)

1. Calculate H° for this reaction.

C2H2 (g) C 2 H 2 (g ) – 1300

(A*) – 312 kJ (B) – 26 kJ (C) + 26 kJ (D) + 312 kJ

2. S1 : (a)NH3 > (a)H2 O [(a) is Vanderwaal's constant]

0.0591 [ Zn2  ] 0.0591 1

5. Given that (at T = 298 K)

(T = 298 K ij) fn;k x;k gS

[ Zn2 ] (0.1) 0.059 0.059

6. What is the value of the reaction quotient, Q, for the cell -

[Ni2 ] [Cl– ]2 (0.19 ) (0.4 )2

the half cell [Ag(NH3)2]+ + e–  Ag + 2NH3 will be

Ag+ + e–  Ag G3º = – 1 × F × 0.8

[Ag(NH3)2]+ + e–  Ag + 2NH3 G3º = G1º + G2º

Eºcell = 1.10 V ds lkFk 298 K ij fuEu lSy fn;k tkrk gSA

(A) (B*) (C) (D)

Sol. Zn(s)  Zn2+ + 2e–

Zn(s) + Cu2+  Zn2+ + Cu(s)

dkSulk dFku lR; gS \

Sol. M + (x + y) NH3  [M (NH3)x]+ + [e(NH3)y]–

vr% CH3COOH ds fy,

vr%  = 1.1 – 1 = 0.1

(9) NH4OH rFkk HCl dk 4 : 3 eksyj vuqikr dk ,d feJ.k

(3) Na2S + 2HCl  2NaCl + H2S

NaOH + NaH2PO4  Na2HPO4 + H2O

NaOH + Na2HPO4  Na3PO4 + H2O

(5) CH3COONa + HCl  CH3COOH + NaCl

(7) HCl + NaHCO3  NaCl + H2CO3

(9) NH4OH + HCl  NH4Cl + H2O

Clearly, pH of solutions 4, 5, 6, 8 and 9 is not affected by dilution.

Sol. XeF4 XeF5– F2SeO2

XeF3+ XeOF4 ClOF3

ICl4– SCl2 OSF4

Fig : Salt bridge and electrolyte

21. A saturated solution of KNO3 is used to make salt bridge because

Fig : yo.k lsrq rFkk oS|qr vi?kV~;

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