EH2207YY

DESIGN PROJECT 1 (SEPTEMBER 2017)

PRODUCTION OF 212,499 METRIC TONNES OF METHANOL PER YEAR

CHAPTER 4: ENERGY BALANCE

GROUP MEMBERS

MUHAMMAD AMIR ASYRAF BIN ABD MANAP 2015655852

MIRDZA FAROUK BIN MURHAN MUKHOYIDDIN 2015636698
NUR IZYAN IZZATI BINTI AMIRUDDIN 2014235224
NABIHAH BINTI AZRON 2014479476
NURAIN SYAFIQAH BINTI MAHAZIR 2014422778
NURUL NAZAHA BINTI SHAMSURI 2015635412

SUPERVISOR
MADAM NURUL ASYIKIN BINTI MD ZAKI

FACULTY OF CHEMICAL ENGINEERING

UNIVERSITI TEKNOLOGI MARA
UITM SHAH ALAM
TABLE OF CONTENTS
CHAPTER 4: ENERGY BALANCE
4.0 Introduction 4-1
Process Flow Diagram 4-4
4.1 Energy Equation 4-5
4.1.1 First Law of Thermodynamics 4-5
4.1.2 Enthalpy 4-6
4.2 Equation Relate to Energy Balance 4-7
i. Equation for Reactive Process 4-7
ii. Equation for Non-Reactive Process 4-7
iii. Equation for Heat Capacity 4-7
4.3 Thermodynamics Properties 4-8
i. Physical Properties 4-8
ii. Specific Heat Capacity Constants for Liquid 4-8
iii. Specific Heat Capacity Constant for Gas 4-8
iv. Heat of Vaporisation 4-9
v. Heat of Formation 4-9
4.4 Energy Balance Calculation 4-10
i. Procedure of Energy Balance 4-10
ii. General Assumptions for Manual Calculation 4-10
Compressor (C-101& C-102) 4-11
Cooler/Heater (E-101, E-102, E-103, E-104 & E-105) 4-20
Heat Exchanger (E-106) 4-38
Reactor (R-101) 4-39
Separator (S-101) 4-44
Flash Drum (S-102) 4-47
Distillation Column (T-101) 4-51
Distillation Column (T-102) 4-53
Table of Summary of Energy Balance and Error Percentage 4-55
4.5 Conclusion 4-56
4.6 References 4-56
 CHAPTER 4

ENERGY BALANCE

4.0 Introduction

This energy balance calculation is for the production of 125,000 metric tonnes of
Methanol per year. The methanol production is from produced from the syngas that supplied
by the supplier. The syngas can be catalytically converted into methanol via overall exothermic
reaction at medium temperatures of 150-270˚C. The formation of methanol from synthesis gas
is taking place according to the following equation. There are two equation for the methanol
synthesis, equation (1) the methanol is produced from carbon monoxide and hydrogen while
equation (2) the methanol is produces from carbon dioxide and hydrogen.

CO + 2H2 CH3OH ∆H˚298= -90.8 kJ/mol (1)

CO2 + 3H2 CH3OH + H2O ∆H˚298= -49.6 kJ/mol (2)

The process flow diagram shown below is the process flow for the methanol production
from syngas. The temperatures and pressure conditions for every equipment are shown at every
stream in the process flow diagram. The temperature and pressure operating condition for the
methanol synthesis reactor is 150˚C and 50 atm. The highest temperature in this process is 180
˚C, the outlet stream of the reactor. There are many equipment involve in this methanol
production plant such as compressor, cooler, heater, mixer, heat exchanger, reactor, separator,
flash drum and distillation tower

The syngas enters the process in the stream 1 at 50˚C and 25 atm. The syngas is mostly
contain hydrogen, carbon monoxide and carbon dioxide, but it also contains small amount of
methane, nitrogen and water. The inert gas components that present in the syngas must be
purged out from the system. The syngas is then compressed in two-stage compressor system in
order to achieved 50 atm, the optimum condition to produced methanol are found to be reactor
pressure at 50 atm. The production methanol from syngas may occur at low or high pressure.
The high pressure process operates normally at 200 atm while the low pressure process operates

1
at 50-100 atm (Amin, Hassan, Das, Yeasmin, Rahman & Hossain, n.d). The low pressure
process of producing methanol has such economical and operational advantages (Klier, 1982).

After the syngas is compressed in the first compressor (C-101), the syngas will flow in
to the cooler (E-101) to be cooled from 71 ˚C to 68 ˚C before entering the second compressor
(C-102). The syngas need to be cooled down first before entering the second compressor to
make sure that the temperature of the syngas do not increase drastically after being compressed
in the compressor. The function of the compressor is to compress the gas and to increase the
pressure of gas. When the pressure increase, the temperature also increase.

The compressed gas at stream 4 will be mixed with the recycle stream (stream 12) from
the separator (S-101) in the mixer (M-101). The gas will be cooled in E-102 from 78 ˚C to 31
˚C before it entering the heat exchanger (E-106). The gas will be heated to 150 ˚C in E-106
before entering the reactor. The gas leaving stream the E-106 at 150 ˚C and 50 atm and will
enter the reactor (R-101). The operating condition for the reactor are set to be 150 ˚C and 50
atm.

The stream leaving from the reactor (stream 8) are at 180 ˚C and 48 atm and will be
flow into the heat exchanger to cooled down the temperature from 180 ˚C to 140 ˚C. Then, it
is cooled until the temperature is 41 ˚C and partially condensed in a water-cooler heat
exchanger (E-103).

Stream 10 enter the separator (S-101) at 41 ˚C and 48 atm. The gases component will
be separated from the methanol and water mixture. The mixture of methanol and water will
flow at the bottom stream (stream 13) while the gas will flow at the above stream and recycled
back into the process.

The liquid from the S-101 (stream 13) contains significant amount of light components
and inert components. If this stream is fed directly to the distillation column, these lights
components would build up in the condenser. Either a low temperature or high pressure needed
in the condenser, it may require the use of expensive refrigeration. Therefore, a flash drum (S-
102) is used to vent the light components and the inert from the liquid before feeding into the
distillation column. The inert are allowed to build up so that the losses of the reactants
(hydrogen, carbon monoxide and carbon dioxide) are kept small. The flash drum operated at
0.2 atm.

2
 The liquid from the flash drum (stream 16) is flow into the distillation column (T-101)..
The column will separate methanol and water. The top product (stream 17) of the distillation
column is methanol with purity about 98.9% while the bottom product (stream 18) is water.
The temperature of the top stream is 52 ˚C while the temperature of the bottom stream is 71
˚C. The bottom product from the distillation column will be flow into the second distillation
column for further purification.

3
 Syngas 50
25 R-101
1 68 150 180
29.7 C-102 31
50 48.5
50
C-101 7 8
3 77 77
71
32.5 6
32.5
30 E-101 E-106
2
4 5
140
50 9 48.5
M-101 E-102
47.8

12
40
48.8 E-103
11 40
10 48.8

E-104
30
0.24
S-101
15 Vent gas

40 38
48.8 47
S-102 51
13 14 0.64

KEY
17 MeOH
E-105 60
Stream number 30 0.95
Temperature (° C) 0.24
19 MeOH
Pressure (atm) 16 T-101
PFD and Stream Table 71
0.9
Stream 1 2 3 4 5 6 7 8 9 10
T-102
Mass flowrate (kg/h) 50667.48607 50667.48607 50667.48607 50667.48607 50667.48607 50667.48607 50667.48607 50486.63402 50486.63402 50486.63402
Mole flowrate (Kmol/h)) 4993 4993 4993 4993 4993 4993 4993 3970.034 3970.034 3970.034 18
Temperature (°C) 50 71 68 77 77 31 150 180 140 40
Pressure (atm) 25 30 29.7 32.5 32.5 50 50 48.5 48.5 48.8
Stream 11 12 13 14 15 16 17 18 19 (MeOH) 20 (Water)
Mass flowrate (kg/h) 20187.95341 20187.95341 30486.10459 30486.10459 1077.81980 29395.53457 14581.37770 14816.23938 11848.83718 2967.14745 99
Mole flowrate (Kmol/h)) 2219.000 2219.000 1030.000 1030.000 41.160 988.401 456.300 532.200 370.3 161.900 1
Temperature (°C) 40 50 40 38 30 30 51 71 60 99
20 Water
Pressure (atm) 48.8 47.8 48.8 47 0.24 0.24 0.64 0.9 0.95 1

4
4.1 Energy Equation

4.1.1 First Law of Thermodynamics

The First Law of Thermodynamic stated that the energy cannot be created or destroyed,
but it can be converted from one form to another form with the interaction of heat, work and
internal energy. The general equation for the First Law of Thermodynamics for closed system
can be express as in Equation 4.1

∆𝐸𝑇 = 𝑄 − 𝑊 (Equation 4.1)

Where:

∆ET = the total energy change transfer to the system

Q = heat transfer to system from its surrounding
W= work done by the system on its surrounding

The total energy changes (∆ET) that are being transferred to the system consist of
internal energy (∆U), kinetic energy (∆Ek), and potential energy (∆EP). For the whole
calculation, the kinetic and potential energy can be neglected because the system is not
accelerating and not rising or falling, thus the Equation 4.2 turn to Equation 4.3

∆𝑈 + ∆𝐸𝑘 + ∆𝐸𝑝 = 𝑄 − 𝑊 (Equation 4.2)

∆𝑈 = 𝑄 − 𝑊 (Equation 4.3)

Work done on or by a system is accomplished by the movement of the system boundary

against a resisting force or the passage of an electrical current or radiation across the system.
If there are no moving parts or electrical currents or radiation at the system, then work done is
equal to zero, thus the Equation 4.3 can be simplified to Equation 4.4.

∆𝑈 = 𝑄(Equation 4.4)

5
 The internal energy of a system is depends on the chemical composition, state of
aggregation (solid, liquid or gas) and the temperature of the system materials. It is independent
of pressure for ideal gases system and nearly independent of pressure for solids and liquid. If
there is no temperature changes, phase changes or no chemical reaction occur in a system and
if the change in pressure is less than a few atmosphere, then the internal energy is zero, thus
the Equation 4.3 become Equation 4.5.

0 = 𝑄 − 𝑊 (Equation 4.5)

The First Law of Thermodynamic equation for open system resembles the equation
for closed system (Equation 4.2):

∆U̇ + ∆Ėk + ∆Ėp = Q̇ - Ẇ (Equation 4.6)

Where:

∆U̇ = the rate transfer of internal energy (kJ/s)

∆Ėk = the rate transfer of kinetic energy (kJ/s)
∆Ėp = the rate transfer of potential energy (kJ/s)
Q̇ = the rate heat transfer to system from its surrounding
Ẇ= the rate work done by the system on its surrounding

4.1.2 Enthalpy

Enthalpy is a measurement of energy in a thermodynamic system. When a process

occurs at constant pressure, the heat evolved (either being released or absorbed) is equal to the
change in the enthalpy. Enthalpy is state of function which depends on the state of function of
temperature (T), pressure (P) and internal energy (U). Enthalpy is usually expressed as the
change in the enthalpy (∆H) for a process between initial and final state

∆𝐻 = ∆𝑈 + ∆𝑃𝑉 (Equation 4.7)

Where H is the enthalpy, U is the internal energy, P is the pressure and V is volume. For the
liquid system, PV is neglect. Substitute Equation 4.7 into Equation 4.4

𝑄 = ∆𝐻 (Equation 4.8)
Equation 4.8 also can be written as:
For closed system, 𝑄 = ∑𝑛𝑖 ,𝑜𝑢𝑡 Ĥ𝑖 ,𝑜𝑢𝑡 − ∑𝑛𝑖 ,𝑖𝑛 Ĥ𝑖 ,𝑖𝑛

6
For open system, Q̇ = ∑ṅI ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

Where:
ni = molar of the i component (mol)
ṅi = molar flowrate of the i component (mol/s)
Ĥi = Specific enthalpy of i component (kJ/mol)

4.2 Equation Relate to Energy Balance

i. Equation for Reactive Process:

a) Heat of reaction method (preferable when there is a single reaction for which
∆Ĥ˚𝑟 is known).

𝑄 = ∆𝐻 = 𝜉∆Ĥ˚𝑟 + ∑𝑛𝑖 ,𝑜𝑢𝑡 Ĥ𝑖 ,𝑜𝑢𝑡 − ∑𝑛𝑖 ,𝑖𝑛 Ĥ𝑖 ,𝑖𝑛

∆Ĥ˚𝑟 = ∑ |𝑣𝑖 |∆Ĥ˚𝑓𝑖 − ∑ |𝑣𝑖 |∆Ĥ˚𝑓𝑖

𝑝𝑟𝑜𝑑𝑢𝑐𝑡𝑠 𝑟𝑒𝑎𝑎𝑐𝑡𝑎𝑛𝑡𝑠

b) Heat of formation method (preferable for multiple reactions and single reaction
for which ∆Ĥ𝑟 is not readily available).
Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in
𝑇2

Ĥi = ∆ Ĥ˚𝑓𝑖 + ∫ 𝐶𝑃𝑖 𝑑𝑇
𝑇1

Where:
∆ Ĥ˚𝑓𝑖 = standard heat of formation of i specie
∆Ĥ˚𝑟 = standard heat of reaction

ii. Equation for Non-Reactive Process

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in
iii. Equation for Heat Capacity
𝑇2

Ĥ = ∫ (𝐴 + 𝐵𝑇 + 𝐶𝑇 2 + 𝐷𝑇 3 ) 𝑑𝑇
𝑇1

7
4.3 Thermodynamics Properties

All the thermodynamics properties were taken from Elementary Principles of

Chemical Processes, 2005.

i. Physical Properties
Compound Mol. Wt. SG Melting Point Boiling Point
(g/mol) (20⁰/4⁰) (Tm) (Tb)
Carbon monoxide 28.01 - -205.1 -191.5
Carbon Dioxide 44.01 - -56.6 -78
Hydrogen 2.016 - -259.19 -252.76
Methane 16.04 - -182.5 -161.5
Nitrogen 28.02 - -210.00 -195.8
Water 18.016 1.004⁰ 0.00 100.0
Methanol 32.04 0.792 -97.9 64.7
Table 4.3.1: Compounds Physical Properties

ii. Specific Heat Capacity Constants for Liquid

Compound A B C D
Water 75.4x10-3 - - -
Methanol 75.86x10-3 16.83x10-5 - -
Table 4.3.2: Specific Heat Capacity Constants for Liquid

iii. Specific Heat Capacity Constants for Gas

Compound A B C D
Water 33.46x10-3 0.6880x10-5 0.760x10-8 -3.593x10-12
Methanol 42.03x10-3 8.301x10-5 -1.87x10-8 -8.03x10-12
Carbon monoxide 28.95x10-3 0.4110x10-5 0.3548x10-8 -2.220x10-12
Carbon Dioxide 36.11x10-3 4.233 x10-5 -2.887x10-8 7.464x10-12
Hydrogen 28.84x10-3 0.00765x10-5 0.3288x10-8 -0.8698x10-12
Methane 34.31x10-3 5.469x10-5 0.3661x10-8 -11.00x10-12
Nitrogen 29.00x10-3 0.2199x10-5 0.5723x10-8 -2.871x10-12
Table 4.3.3: Specific Heat Capacity Constants for Gas

8
iv. Heat of vaporisation

Compound Heat of vaporisation Hv (kJ/mol)

Carbon Dioxide 304.2
Carbon Monoxide 6.042
Hydrogen 0.904
Nitrogen 5.577
Methane 8.179
Water 40.656
Methanol 35.27
Note: The enthalpy of formation is referred at 25 ˚C and 1 atm

Table 4.3.4: Compounds Heat of Vaporization

v. Heat of formation

Compound Heat of formation Hf (kJ/mol)

Water (l) -285.84
Water (g) -241.83
Methanol (l) -238.61
Methanol (g) -201.2
Carbon monoxide -110.52
Carbon Dioxide -393.5
Hydrogen 0
Methane -74.85
Nitrogen 0
Note: The enthalpy of formation is referred at 25 ˚C and 1 atm

Table 4.3.5: Compounds Heat of Formation

9
4.4 Energy Balance Calculation

Before starting on the energy balance calculation, the method of the calculation
should be known and some assumptions should be made for ease of calculation.

i. Procedure of Energy Balance:

1. Perform all the required material calculations.
2. Write the appropriate form of the energy balance and delete any of the
terms that are either zero or negligible for the given process system.
3. Choose the reference state-phase, temperature, and pressure for each
species involved in the process.
4. For an open system, construct a table with columns for inlet and outlet
steam component flow rates and specific enthalpies relative to the chosen
reference states.
5. Calculate all required values and insert the values in the appropriate places
in the table.
6. Solve the energy balance for whichever variable is unknown.

ii. General Assumptions for Manual Calculations:

1. The system is assumed to be an open system.

2. The system operated at steady state.
3. There are no moving parts in the system (no shaft work, Ws = 0)
4. The linear velocities of all stream are identical (no kinetic energy, ΔEk = 0)
5. The elevation are at constant height (no potential energy, Δep = 0)
6. Effect of pressure on total enthalpy is negligible if the change of pressure,
ΔP is lower than 50 atm.
7. The system is ideal solution system.
8. All the gas in the system is assumed to be ideal gas.
9. Heat of mixing is negligible (Hmix= 0)

10
COMPRESSOR (C-101 & C-102)

Stream 1
Tin = 50˚ C
Pin = 25 atm

C-101
Stream 2
Tout = 71˚ C
Pout = 30 atm

Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 1 Stream 2
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ 𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 159.776 Ĥ1 = 0.941 159.776 Ĥ7 = 1.751
CO 748.95 Ĥ2 = 0.728 748.95 Ĥ8 = 1.341
H2O 9.986 Ĥ3 = 1.885 9.986 Ĥ9 = 3.468
H2 3065.702 Ĥ4 = 0.721 3065.702 Ĥ10 = 1.327
N2 9.986 Ĥ5 = 0.727 9.986 Ĥ11 = 1.339
CH4 998.6 Ĥ6 = 0.909 998.6 Ĥ12 = 1.699
CH3OH - - - -
Table 4.4.1: Molar Flowrate and Specific Enthalpy for C-101

Path Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 50˚ C, 25 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 50˚ C, 1 atm)

Calculation:
50
Ĥ1 = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 0.941 kJ/mol

Path: Ĥ2
CO (g, 25˚ C, 1 atm) CO (g, 50˚ C, 25 atm)
Ĥ2𝑎 Ĥ2𝑏
CO (g, 50˚ C, 1 atm)

11
Calculation:
50
Ĥ2 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 0.728 kJ/mol

Path: Ĥ3
H2O (l, 25˚ C, 1 atm) H2O (l, 50˚ C, 25 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 50˚ C, 1 atm)

Calculation:
50
Ĥ3 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 1.885 kJ/mol

Path: Ĥ4
H2 (g, 25˚ C, 1 atm) H2 (g, 50˚ C, 25 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g, 50˚ C, 1 atm)

Calculation:
50
Ĥ4 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.721 kJ/mol

Path: Ĥ5
N2 (g, 25˚ C, 1 atm) N2 (g, 50˚ C, 25 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 50˚ C, 1 atm)

Calculation:
50
Ĥ5 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 + (−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.727 kJ/mol

12
Path: Ĥ6
CH4 (g, 25˚ C, 1 atm) CH4 (g, 50˚ C, 25 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 50˚ C, 1 atm)

Calculation:
50
Ĥ6 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 0.909 kJ/mol

Path: Ĥ7
CO2 (g, 25˚ C, 1 atm) CO2 (g, 71˚ C, 30 atm)
Ĥ7𝑎 Ĥ7𝑏
CO2 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ₇ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 1.751 kJ/mol

Path: Ĥ8
CO (g, 25˚ C, 1 atm) CO (g, 71˚ C, 30 atm)
Ĥ8𝑎 Ĥ8𝑏
CO (g, 71˚ C, 1 atm)

13
Calculation:
71
Ĥ8 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.341 kJ/mol

Path: Ĥ9
H2O (l, 25˚ C, 1 atm) H2O (l, 71˚ C, 30 atm)
Ĥ9𝑎 Ĥ9𝑏
H2O (l, 71˚ C, 1 atm)

Calculation:
71
Ĥ9 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 3.468 kJ/mol

Path: Ĥ10
H2 (g, 25˚ C, 1 atm) H2 (g, 71˚ C, 30 atm)
Ĥ10𝑎 Ĥ10𝑏
H2 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ10 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 1.327 kJ/mol

Path: Ĥ11
N2 (g, 25˚ C, 1 atm) N2 (g, 71˚ C, 30 atm)
Ĥ11𝑎 Ĥ11𝑏
N2 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ11 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 1.339 kJ/mol

14
Path: Ĥ12
CH4 (g, 25˚ C, 1 atm) CH4 (g, 71˚ C, 30 atm)
Ĥ12𝑎 Ĥ12𝑏
CH4 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ12 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.699 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

=
[(159976)(1.751)+(748950)(1.341)+(9986)(3.468)+(3065702)(1.327)+(9986)(1.339)+(99860
0)(1.699)] -
[(159976)(0.941)+(748950)(0.728)+(9986)(1.885)+(3065702)(0.721)+(9986)(0.727)+(99860
0)(0.909)]
= 3257153.592 kJ/h x 1h/3600s
= 904.76488 kW

Stream 3
Tin = 68˚ C
Pin = 29.7
atm
Stream 4
C-102 Tin = 77˚ C
Pin = 32.5
atm

15
Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 3 Stream 4
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 159.776 Ĥ1 = 1.635 159.776 Ĥ7 =1.986
CO 748.95 Ĥ2 = 1.253 748.95 Ĥ8 =1.517
H2O 9.986 Ĥ3 = 3.242 9.986 Ĥ9 =3.921
H2 3065.702 Ĥ4 = 1.241 3065.702 Ĥ10 =1.509
N2 9.986 Ĥ5 = 1.252 9.986 Ĥ11 =1.515
CH4 998.6 Ĥ6 = 1.586 998.6 Ĥ12 =1.930
CH3OH - - - -
Table 4.4.2: Molar Flowrate and Specific Enthalpy for C-102

Path
Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 68˚ C, 29.7 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 68˚ C, 1 atm)
Calculation:
68
Ĥ₁ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 1.635 kJ/mol

Path: Ĥ2
CO (g, 25˚ C, 1 atm) CO (g, 68˚ C, 29.7 atm)
Ĥ2𝑎 Ĥ2𝑏
CO (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ2 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.253 kJ/mol

Path: Ĥ3
H2O (l, 25˚ C, 1 atm) H2O (l, 68˚ C, 29.7 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 68˚ C, 1 atm)

16
Calculation:
68
Ĥ3 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 3.242 kJ/mol

Path:
Ĥ4
H2 (g, 25˚ C, 1 atm) H2 (g, 68˚ C, 29.7 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ4 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 1.241 kJ/mol

Path: Ĥ5
N2 (g, 25˚ C, 1 atm) N2 (g, 68˚ C, 29.7 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ5 = ∫ 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 + (−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.252 kJ/mol

Path: Ĥ6
CH4 (g, 25˚ C, 1 atm) CH4 (g, 68˚ C, 29.7 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 668˚ C, 1 atm)

Calculation:
68
Ĥ6 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.586 kJ/mol

17
Path:
Ĥ7
CO2 (g, 25˚ C, 1 atm) CO2 (g, 77˚ C, 32.5 atm)
Ĥ7𝑎 Ĥ7𝑏
CO2 (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ₇ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 1.986 kJ/mol

Path: Ĥ8
CO (g, 25˚ C, 1 atm) CO (g, 77˚ C, 32.5 atm)
Ĥ8𝑎 Ĥ8𝑏
CO (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ8 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.517 kJ/mol

Path: Ĥ9
H2O (l, 25˚ C, 1 atm) H2O (l, 77˚ C, 32.5 atm)
Ĥ9𝑎 Ĥ9𝑏
H2O (l, 77˚ C, 1 atm)

Calculation:
77
Ĥ9 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 3.921 kJ/mol

Path: Ĥ10
H2 (g, 25˚ C, 1 atm) H2 (g, 77˚ C, 32.5 atm)
Ĥ10𝑎 Ĥ10𝑏
H2 (g, 77˚ C, 1 atm)

18
Calculation:
77
Ĥ10 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 1.509 kJ/mol

Path: Ĥ11
N2 (g, 25˚ C, 1 atm) N2 (g, 77˚ C, 32.5 atm)
Ĥ11𝑎 Ĥ11𝑏
N2 (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ11 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 1.515 kJ/mol

Path: Ĥ12
CH4 (g, 25˚ C, 1 atm) CH4 (g, 77˚ C, 32.5 atm)
Ĥ12𝑎 Ĥ12𝑏
CH4 (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ12 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.930 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (8061198.5 – 6632860.976) kJ/mol

= 396.76042 kW

19
COOLER/HEATER (E-101, E-102, E-103, E-104, E-105)

Stream 2 Stream 3
Tin = 71˚ C Tout = 68˚ C
Pin = 30 atm Pout = 29.7 atm

E-101
Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 2 Stream 3
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ 𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 159.776 Ĥ1 = 1.751 159.776 Ĥ7 = 1.635
CO 748.95 Ĥ2 = 1.341 748.95 Ĥ8 = 1.253
H2O 9.986 Ĥ3 = 3.468 9.986 Ĥ9 = 3.242
H2 3065.702 Ĥ4 = 1.327 3065.702 Ĥ10 = 1.241
N2 9.986 Ĥ5 = 1.339 9.986 Ĥ11 = 1.252
CH4 998.6 Ĥ6 = 1.699 998.6 Ĥ12 = 1.586
CH3OH - - - -
Table 4.4.3: Molar Flowrate and Specific Enthalpy for E-101

Path Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 71˚ C, 30 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ₁ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 1.751 kJ/mol

Path:
Ĥ2
CO (g, 25˚ C, 1 atm) CO (g, 71˚ C, 30 atm)
Ĥ2𝑎 Ĥ2𝑏
CO (g, 71˚ C, 1 atm)
Calculation:
71
Ĥ2 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.341 kJ/mol

20
Path:
Ĥ3
H2O (l, 25˚ C, 1 atm) H2O (l, 71˚ C, 30 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 71˚ C, 1 atm)

Calculation:
71
Ĥ3 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 3.468 kJ/mol

Path:

Ĥ4
H2 (g, 25˚ C, 1 atm) H2 (g, 71˚ C, 30 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ4 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 1.327 kJ/mol

Path: Ĥ5
N2 (g, 25˚ C, 1 atm) N2 (g, 71˚ C, 30 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ5 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 + (−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 1.339 kJ/mol

21
Path:
Ĥ6
CH4 (g, 25˚ C, 1 atm) CH4 (g, 71˚ C, 30 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 71˚ C, 1 atm)

Calculation:
71
Ĥ6 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.699 kJ/mol

Path:
Ĥ7
CO2 (g, 25˚ C, 1 atm) CO2 (g, 68˚ C, 29.7 atm)
Ĥ7𝑎 Ĥ7𝑏
CO2 (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ₇ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 1.635 kJ/mol

Path:
Ĥ8
CO (g, 25˚ C, 1 atm) CO (g, 68˚ C, 29.7 atm)
Ĥ8𝑎 Ĥ8𝑏
CO (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ8 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.253 kJ/mol

22
Path:
Ĥ9
H2O (l, 25˚ C, 1 atm) H2O (l, 68˚ C, 29.7 atm)
Ĥ9𝑎 Ĥ9𝑏
H2O (l, 68˚ C, 1 atm)

Calculation:
68
Ĥ9 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 3.242 kJ/mol

Path:
Ĥ10
H2 (g, 25˚ C, 1 atm) H2 (g, 68˚ C, 29.7 atm)
Ĥ10𝑎 Ĥ10𝑏
H2 (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ10 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 1.241 kJ/mol

Path: Ĥ11
N2 (g, 25˚ C, 1 atm) N2 (g, 68˚ C, 29.7 atm)
Ĥ11𝑎 Ĥ11𝑏
N2 (g, 68˚ C, 1 atm)

Calculation:
68
Ĥ11 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 1.252 kJ/mol

23
Path: Ĥ12
CH4 (g, 25˚ C, 1 atm) CH4 (g, 68˚ C, 29.7 atm)
Ĥ12𝑎 Ĥ12𝑏
CH4 (g, 668˚ C, 1 atm)

Calculation:
68
Ĥ12 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.586 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (6632860.976 – 7096920.382) kJ/mol

= - 128.90540 kW

Stream 5 Stream 6
Tin = 77˚ C Tout = 31˚ C
Pin = 32.5 Pout = 50 atm
atm
E-102
Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 5 Stream 6
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 159.776 Ĥ1 = 1.986 159.776 Ĥ8 =0.224
CO 748.95 Ĥ2 = 1.516 748.95 Ĥ9 =0.174
H2O 9.986 Ĥ3 = 3.921 9.986 Ĥ10 =0.452
H2 3065.702 Ĥ4 = 1.500 3065.702 Ĥ11 =0.173
N2 9.986 Ĥ5 = 1.515 9.986 Ĥ12 =0.174
CH4 998.6 Ĥ6 = 1.930 998.6 Ĥ13 =0.215
CH3OH - Ĥ7 = 39.18 - Ĥ14 =0.483
Table 4.4.4: Molar Flowrate and Specific Enthalpy for E-102

24
Path:
Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 77˚ C, 32.5 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ₁ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 1.986 kJ/mol

Path:
Ĥ2
CO (g, 25˚ C, 1 atm) CO (g, 77˚ C, 32.5 atm)
Ĥ2𝑎 Ĥ2𝑏
CO (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ2 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.516 kJ/mol

Path:
Ĥ3
H2O (l, 25˚ C, 1 atm) H2O (l, 77˚ C, 32.5 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 77˚ C, 1 atm)

Calculation:
77
Ĥ3 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 3.921 kJ/mol

Path:
Ĥ4
H2 (g, 25˚ C, 1 atm) H2 (g, 77˚ C, 32.5 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g, 77˚ C, 1 atm)

25
Calculation:
77
Ĥ4 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 1.500 kJ/mol

Path: Ĥ5
N2 (g, 25˚ C, 1 atm) N2 (g, 77˚ C, 32.5 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ5 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 + (−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 1.515 kJ/mol

Path:
Ĥ6
CH4 (g, 25˚ C, 1 atm) CH4 (g, 77 C, 32.5 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 77˚ C, 1 atm)

Calculation:
77
Ĥ6 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 1.930 kJ/mol

Ĥ7
Path: CH3OH (g, 77˚ C, 32.5 atm)
CH3OH (l, 25˚ C, 1 atm)

Ĥ7𝑎 Ĥ7𝑏

CH3OH (l, 64.7˚ C, 1 atm) CH3OH (g, 64.7˚ C, 1 atm)

Ĥ𝑣

26
Calculation:
64.7 77
Ĥ7 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡 + Ĥ𝑣 + ∫64.7 42.93 𝑥 10−3 +
8.301 𝑥 10−5 𝑇 + (−1.87 𝑥 10−8 ) 𝑇 2 + (−8.03 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 3.311 kJ/mol + 35.27 kJ/mol + 0.599 kJ/mol

= 39.18 kJ/mol

Path:
Ĥ8
CO2 (g, 25˚ C, 1 atm) CO2 (g, 31˚ C, 50 atm)
Ĥ8𝑎 Ĥ8𝑏
CO2 (g, 31 ˚C, 1 atm)

Calculation:
30
Ĥ₈ = ∫ 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡
25

= 0.224 kJ/mol

Path:
Ĥ9
CO (g, 25˚C, 1 atm) CO (g, 31˚C, 50 atm)
Ĥ9𝑎 Ĥ9𝑏
CO (g, 31˚C, 1 atm)
Calculation:
31
Ĥ9 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 0.174 kJ/mol

Path:
Ĥ10
H2O (l, 25˚ C, 1 atm) H2O (l, 31˚C, 50 atm)
Ĥ10𝑎 Ĥ10𝑏
H2O (l, 31˚C, 1 atm)
Calculation:
31
Ĥ10 = ∫ 75.4 𝑥 10−3 𝑑𝑡
25

= 0.452 kJ/mol

27
Path:
Ĥ11
H2 (g, 25˚ C, 1 atm) H2 (g, 31˚ C, 50 atm)
Ĥ11𝑎 Ĥ11𝑏
H2 (g, 31˚ C, 1 atm)
Calculation:
31
Ĥ11 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.173 kJ/mol

Path:
Ĥ12
N2 (g, 25˚C, 1 atm) N2 (g, 31˚C, 50 atm)
Ĥ12𝑎 Ĥ12𝑏
N2 (g, 31⁰C, 1 atm)

Calculation:
31
Ĥ12 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.174 kJ/mol

Path:
Ĥ13
CH4 (g, 25˚ C, 1 atm) CH4 (g, 31˚ C, 50 atm)
Ĥ13𝑎 Ĥ13𝑏
CH4 (g, 31˚ C, 1 atm)
Calculation:
31
Ĥ13 = ∫ 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 0.215 kJ/mol

Ĥ14
Path: CH3OH (l, 25 ˚C, 1 atm) CH3OH (l, 31 ˚C, 50 atm)
Ĥ14𝑎 Ĥ14𝑏
CH3OH (l, 31 ˚C, 1 atm)
Calculation:
31
Ĥ14 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 0.483 kJ/mol

28
Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (917423.806 – 8032858.232) kJ/mol

= -1976.50956 kW

Stream 9 E-103 Stream 10

Tin = 140˚ C Tout = 40˚ C
Pin = 48.5 atm Pout = 48.8 atm

Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 9 Stream 10
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ 𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 131.011 Ĥ1 = 4.529 131.011 Ĥ8 = 0.562
CO 269.962 Ĥ2 = 3.371 269.962 Ĥ9 = 0.436
H2O 27.790 Ĥ3 = 47.686 27.790 Ĥ10 = 1.131
H2 2024.717 Ĥ4 = 3.320 2024.717 Ĥ11 = 0.433
N2 11.910 Ĥ5 = 3.361 11.910 Ĥ12 = 0.436
CH4 1000.449 Ĥ6 = 4.467 1000.449 Ĥ13 = 0.541
CH3OH 508.164 Ĥ7 = 42.437 508.164 Ĥ14 = 1.220
Table 4.4.5: Molar Flowrate and Specific Enthalpy for E-103

Path: Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 140˚ C, 48.5 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 140˚ C, 1 atm)

Calculation:
140
Ĥ1 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 4.529 kJ/mol
Path:
Ĥ2
CO (g, 25˚ C, 1 atm) CO (g, 140˚ C, 48.5 atm)
Ĥ2𝑎 Ĥ2𝑏
CO2 (g, 140˚ C, 1 atm)

29
Calculation:
140
Ĥ2 = ∫25 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 3.371 kJ/mol

Ĥ3
Path: H2O (l, 25˚ C, 1 atm) H2O (g, 140˚ C, 48.5 atm)

Ĥ3𝑎 Ĥ3𝑏

H2O (l, 100˚ C, 1 atm) H2O (g, 100˚ C, 1 atm)

Ĥ𝑣
Calculation:
100 140
Ĥ3 = ∫25 75.4 𝑥 10−3 𝑑𝑡 + Ĥ𝑣 + ∫100 33.46 𝑥 10−3 + 0.6880 𝑥 10−5 𝑇 +
0.7604 𝑥 10−8 𝑇 2 + (−3.593 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 5.655 kJ/mol + 40.656 kJ/mol + 1.375 kJ/mol
= 47.686 kJ/mol
Path: Ĥ4
H2 (g, 25˚ C, 1 atm) H2 (g, 140˚ C, 48.5 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g,140 C, 1 atm)

Calculation:
140
Ĥ4 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 3.320 kJ/mol

Ĥ5
Path: N2 (g, 25˚ C, 1 atm) N2 (g, 140˚C, 48.5 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 140˚ C, 1 atm)

Calculation:
140
Ĥ5 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 3.361 kJ/mol
Path:
Ĥ6
CH4 (g, 25˚ C, 1 atm) CH4 (l, 140˚C, 48.5 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 140˚ C, 1 atm)
30
Calculation:
140
Ĥ6 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 4.467 kJ/mol

Path: Ĥ7
CH3OH (l, 25˚ C, 1 atm) CH3OH (g, 140 ˚C, 48.5 atm)

Ĥ7𝑎 Ĥ7𝑏

CH3OH (l, 64.7˚ C, 1 atm) CH3OH (g, 64.7˚ C, 1 atm)

Ĥ𝑣

Calculation:
64.7 140
Ĥ7 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡 + Ĥ𝑣 + ∫64.7 42.93 𝑥 10−3 +
8.301 𝑥 10−5 𝑇 + (−1.87 𝑥 10−8 ) 𝑇 2 + (−8.03 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 3.311 kJ/mol + 35.27 kJ/mol + 3.856 kJ/mol
= 42.437 kJ/mol

Path:
Ĥ8
CO2 (g, 25˚ C, 1 atm) CO2 (g, 40˚ C, 48.8 atm)
Ĥ8𝑎 Ĥ8𝑏
CO2 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ8 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 0.562 kJ/mol

Ĥ9
Path: CO (g, 25˚ C, 1 atm) CO (g, 40˚ C, 48.8 atm)
Ĥ9𝑎 Ĥ9𝑏
CO2 (g, 40˚ C, 1 atm)
Calculation:
40
Ĥ9 = ∫25 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.436 kJ/mol

31
Path:
Ĥ10
H2O (l, 25˚ C, 1 atm) H2O (l, 40˚ C, 48.8 atm)
Ĥ10𝑎 Ĥ10𝑏
H2O (l, 40˚ C, 1 atm)

Calculation:
40
Ĥ10 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 1.131 kJ/mol

Path: Ĥ11
H2 (g, 25˚ C, 1 atm) H2 (g, 40˚ C, 48.8 atm)
Ĥ11𝑎 Ĥ11𝑏
H2 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ11 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.433 kJ/mol

Path:
Ĥ12
N2 (g, 25˚ C, 1 atm) N2 (g, 40˚ C, 48.8 atm)
Ĥ12𝑎 Ĥ12𝑏
N2 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ12 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.436 kJ/mol
Path:
Ĥ13
CH4 (g, 25˚ C, 1 atm) CH4 (l, 40˚ C, 48.8 atm)
Ĥ13𝑎 Ĥ13𝑏
CH4 (g, 40˚ C, 1 atm)

32
Calculation:
40
Ĥ13 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.541 kJ/mol

Path:
Ĥ14
CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 38˚ C, 48.8 atm)
Ĥ14𝑎 Ĥ14𝑏
CH3OH (l, 38˚ C, 1 atm)

Calculation:
40
Ĥ14 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 1.220 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (2265860.314 – 35624635.96) kJ/h

= -9266.32657 kW

Stream 11 Stream 12
Tin = 40˚ C Tout = 50˚ C
Pin = 48.8 atm Pout = 47.8 atm

E-104
Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 11 Stream 12
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 6.657 Ĥ1 =0.562 6.657 Ĥ7 =0.9414
CO 31.066 Ĥ2 =0.436 31.066 Ĥ8 =0.7277
H2O - - - -
H2 1164.975 Ĥ3 =0.433 1164.975 Ĥ9 =0.7212
N2 11.095 Ĥ4 =0.436 11.095 Ĥ10 =0.7273
CH4 987.455 Ĥ5 =0.541 987.455 Ĥ11 =2.8516
CH3OH 19.971 Ĥ6 =1.22 19.971 Ĥ12 =2.0543
Table 4.4.6: Molar Flowrate and Specific Enthalpy for E-104

33
Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (1815510.354– 1085135.38) kJ/h

= 202.88193 kW

Stream 13 Stream 14
Tin = 40˚ C Tout = 38˚ C
Pin = 48.8 atm Pout = 47 atm
E-105
Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 13 Stream 14
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 1.03 Ĥ1 = 0.562 1.03 Ĥ6 = 0.486
CO - - - -
H2O 162.74 Ĥ2 = 1.131 162.74 Ĥ7 = 0.980
H2 2.06 Ĥ3 = 0.433 2.06 Ĥ8 = 0.375
N2 - - - -
CH4 10.3 Ĥ4 = 0.541 10.3 Ĥ9 = 0.468
CH3OH 853.87 Ĥ5 = 1.220 853.87 Ĥ10 = 1.055
Table 4.4.7: Molar Flowrate and Specific Enthalpy for E-105

34
Path: Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 40˚ C, 48.8 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 40˚ C, 1 atm)
Calculation:
40
Ĥ1 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 0.562 kJ/mol

Path:
Ĥ2
H2O (l, 25˚ C, 1 atm) H2O (l, 40˚ C, 48.8 atm)
Ĥ2𝑎 Ĥ2𝑏
H2O (l, 40˚ C, 1 atm)
Calculation:
40
Ĥ3 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 1.131 kJ/mol

Path:
Ĥ3
H2 (g, 25˚ C, 1 atm) H2 (g, 40˚ C, 48.8 atm)
Ĥ3𝑎 Ĥ3𝑏
H2 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ3 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.433 kJ/mol

Path: Ĥ4
CH4 (g, 25˚ C, 1 atm) CH4 (g, 40˚ C, 48.8 atm)
Ĥ4𝑎 Ĥ4𝑏
CH4 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ4 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.541 kJ/mol

35
Path:
Ĥ5
CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 40˚ C, 48.8
atm) Ĥ5𝑏
Ĥ5𝑎
CH3OH (l, 40˚ C, 1 atm)

Calculation:
40
Ĥ5 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 1.220 kJ/mol

Path:
Ĥ6
CO2 (g, 25˚ C, 1 atm) CO2 (g, 38˚ C, 47 atm)
Ĥ6𝑎 Ĥ6𝑏
CO2 (g, 38˚ C, 1 atm)

Calculation:
38
Ĥ6 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 0.486 kJ/mol

Path: Ĥ7
H2O (g, 25˚ C, 1 atm) H2O (g, 38˚ C, 47 atm)
Ĥ7𝑎 Ĥ7𝑏
Calculation: H2O (g, 38˚ C, 1 atm)
38
Ĥ8 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 0.980 kJ/mol

Path:
Ĥ8
H2 (l, 25˚ C, 1 atm) H2 (l, 38˚ C, 47 atm)
Ĥ8𝑎 Ĥ8𝑏
H2 (l, 38˚ C, 1 atm)
Calculation:
38
Ĥ8 = ∫ 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
25

= 0.375 kJ/mol

36
Path: Ĥ9
CH4 (g, 25˚ C, 1 atm) CH4 (g, 38˚ C, 47 atm)
Ĥ9𝑎 Ĥ9𝑏
CH4 (g, 38˚ C, 1 atm)
Calculation:
38
Ĥ9 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.468 kJ/mol
Path:
Ĥ10
CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 38˚ C, 47 atm)
Ĥ10𝑎 Ĥ10𝑏
CH3OH (l, 38˚ C, 1 atm)

Calculation:
38
Ĥ10 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 1.055 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (1065639.03 – 1231931.5) kJ/h

= -46.19235 kW

37
Heat Exchanger (E-106)

Stream 8
Tin = 180˚ C
Pin = 48.5 atm

Stream 6 Stream 7
Tin = 31˚ C Tout = 150˚ C
Pin = 50 atm Pout = 50 atm
E-106

Stream 9
Tout = 140˚ C
Pout = 48.5
atm
Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 6 Stream 8 Stream 7 Stream 9
ṅin Ĥ𝑖𝑛 ṅin Ĥ𝑖𝑛 ṅ𝑜𝑢𝑡 Ĥ𝑜𝑢𝑡 ṅ𝑜𝑢𝑡 Ĥ𝑜𝑢𝑡
(kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol)
CO2 159.776 0.224 131.011 6.2156 159.776 4.9453 131.011 4.529
CO 748.950 0.174 269.962 4.5588 748.950 3.6674 269.962 3.371
H2O 9.986 0.452 27.790 49.076 9.986 48.033 27.790 47.686
H2 3065.702 0.173 2024.717 4.4776 3065.702 3.6094 2024.717 3.32
N2 9.986 0.174 11.910 4.5403 9.986 3.6551 11.910 3.361
CH4 998.6 0.215 1000.449 6.1911 998.6 4.8896 1000.449 4.467
CH3OH 0 0.483 508.164 44.665 0 42.983 508.164 42.437
Table 4.4.8: Molar Flowrate and Specific Enthalpy for FEHE

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= [(19999920.9+35624635.96) – (917423.806 + 41420622.12) kJ/h

= 3690.69747 kW

38
REACTOR (R-101)

R-101

Stream 7 Stream 8
Tin = 150˚ C Tout = 180˚ C
Pin = 50 atm Pout = 48.5 atm

Reference state: C(s), O2 (g), H2 (g), N2 (g) at 25˚C and 1 atm

Compound Stream 7 Stream 8
ṅin (kmol/hr) Ĥ𝑖𝑛 (kJ/mol) ṅ𝑜𝑢𝑡 (kmol/hr) Ĥ𝑜𝑢𝑡 (kJ/mol)
CO2 159.776 Ĥ1 = -388.555 131.011 Ĥ8 = -387.284
CO 748.950 Ĥ2 = -106.853 269.962 Ĥ9 = -105.961
H2O 9.986 Ĥ3 = -237.807 27.790 Ĥ10 = -236.764
H2 3065.702 Ĥ4 = 3.609 2024.717 Ĥ11 = 4.478
N2 9.986 Ĥ5 = 3.655 11.910 Ĥ12 = 4.450
CH4 998.6 Ĥ6 = -69.96 1000.449 Ĥ13 = -68.659
CH3OH 0 Ĥ7 = -195.617 508.164 Ĥ14 = -193.935
Table 4.4.9: Molar Flowrate and Specific Enthalpy for R-101
Path: Ĥ1
CO2 (g, 25˚ C, 1 atm) CO2 (g, 150˚ C, 50 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 150˚ C, 1 atm)

Calculation:
150
Ĥ1 = ∆ Ĥ˚𝑓 + ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 +
7.464 𝑥10−12 𝑇 3 𝑑𝑡
= -393.5 kJ/mol + 4.945 kJ/mol
= -388.555 kJ/mol

Path:
Ĥ2
CO (g, 25˚ C, 1 atm) CO (g, 150˚ C, 50 atm)
Ĥ2𝑎 Ĥ2𝑏
CO (g, 150˚ C, 1 atm)

39
Calculation:
150
Ĥ2 = ∆ Ĥ˚𝑓 + ∫25 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 +
(−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -110.52 kJ/mol +3.667 kJ/mol
= -106.853 kJ/mol

Ĥ3
Path: H2O (l, 25˚ C, 1 atm) H2O (g, 150˚ C, 50 atm)

Ĥ3𝑎 Ĥ3𝑏

H2O (l, 100˚ C, 1 atm) H2O (g, 100˚ C, 1 atm)

Ĥ𝑣

Calculation:
100 150
Ĥ3 = ∆ Ĥ˚𝑓 + ∫25 75.4 𝑥 10−3 𝑑𝑡 + Ĥ𝑣 + ∫100 33.46 𝑥 10−3 + 0.6880 𝑥 10−5 𝑇 +
0.7604 𝑥 10−8 𝑇 2 + (−3.593 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -285.84 kJ/mol + 5.655 kJ/mol + 40.656 kJ/mol + 1.722 kJ/mol
= -237.807 kJ/mol

Path: Ĥ4
H2 (g, 25˚ C, 1 atm) H2 (g, 150˚ C, 50 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g, 150˚ C, 1 atm)

Calculation:
150
Ĥ4 = ∆ Ĥ˚𝑓 + ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0 kJ/mol +3.609 kJ/mol
= 3.609 kJ/mol

Path: Ĥ5
N2 (g, 25˚ C, 1 atm) N2 (g, 150˚ C, 50 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 150˚ C, 1 atm)

40
Calculation:
150
Ĥ5 = ∆ Ĥ˚𝑓 + ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0 kJ/mol +3.655kJ/mol
= 3.655 kJ/mol

Path: Ĥ6
CH4 (g, 25˚ C, 1 atm) CH4 (g, 150˚ C, 50 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 150˚ C, 1 atm)
Calculation:
150
Ĥ6 = ∆ Ĥ˚𝑓 + ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 +
(−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -74.85 kJ/mol +4.890 kJ/mol
= -69.96 kJ/mol

Ĥ7
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (g, 150˚ C, 50 atm)

Ĥ7𝑎 Ĥ7𝑏

CH3OH (l, 64.7˚ C, 1 atm) CH3OH (g, 64.7˚ C, 1 atm)

Ĥ𝑣
Calculation:
64.7 150
Ĥ7 = ∆ Ĥ˚𝑓 + ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡 + Ĥ𝑣 + ∫64.7 42.93 𝑥 10−3 +
8.301 𝑥 10−5 𝑇 + (−1.87 𝑥 10−8 ) 𝑇 2 + (−8.03 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -238.6 kJ/mol + 3.311 kJ/mol + 35.27 kJ/mol + 4.402 kJ/mol
= -195.617 kJ/mol
Path: Ĥ8
CO2 (g, 25˚ C, 1 atm) CO2 (g, 180˚ C, 48.5 atm)
Ĥ8𝑎 Ĥ8𝑏
CO2 (g, 180˚ C, 1 atm)
Calculation:
180
Ĥ8 = ∆ Ĥ˚𝑓 + ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 +
7.464 𝑥10−12 𝑇 3 𝑑𝑡
= -393.5 kJ/mol + 6.216 kJ/mol

41
 = -387.284 kJ/mol

Path:
Ĥ9
CO (g, 25˚ C, 1 atm) CO (g, 180˚ C, 48.5 atm)
Ĥ9𝑎 Ĥ9𝑏
CO (g, 180˚ C, 1 atm)
Calculation:
180
Ĥ9 = ∆ Ĥ˚𝑓 + ∫25 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 +
(−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -110.52 kJ/mol +4.559 kJ/mol
= -105.961 kJ/mol
Ĥ10
Path: H2O (l, 25˚ C, 1 atm) H2O (g, 180˚ C, 48.5 atm)

Ĥ10𝑎 Ĥ10𝑏

H2O (l, 100˚ C, 1 atm) H2O (g, 100˚ C, 1 atm)

Ĥ𝑣
Calculation:
100 180
Ĥ10 = ∆ Ĥ˚𝑓 + ∫25 75.4 𝑥 10−3 𝑑𝑡 + Ĥ𝑣 + ∫100 33.46 𝑥 10−3 + 0.6880 𝑥 10−5 𝑇 +
0.7604 𝑥 10−8 𝑇 2 + (−3.593 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -285.84 kJ/mol + 5.655 kJ/mol + 40.656 kJ/mol + 2.765 kJ/mol
= -236.764 kJ/mol

Path:
Ĥ11
H2 (g, 25˚ C, 1 atm) H2 (g, 180˚ C, 48.5 atm)
Ĥ11𝑎 Ĥ11𝑏
H2 (g, 180˚ C, 1 atm)
Calculation:
180
Ĥ11 = ∆ Ĥ˚𝑓 + ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0 kJ/mol +4.478 kJ/mol
= 4.478 kJ/mol

42
Path:
Ĥ12
N2 (g, 25˚ C, 1 atm) N2 (g, 180˚ C, 48.5 atm)
Ĥ12𝑎 Ĥ12𝑏
N2 (g, 180˚ C, 1 atm)

Calculation:
180
Ĥ12 = ∆ Ĥ˚𝑓 + ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0 kJ/mol +4.540 kJ/mol
= 4.540 kJ/mol

Path:
Ĥ13
CH4 (g, 25˚ C, 1 atm) CH4 (g, 150˚ C, 48,5 atm)
Ĥ13𝑎 Ĥ13𝑏
CH4 (g, 180˚ C, 1 atm)

Calculation:
180
Ĥ13 = ∆ Ĥ˚𝑓 + ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 +
(−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -74.85 kJ/mol + 6.191 kJ/mol
= -68.659 kJ/mol

Ĥ14
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (g, 180˚ C, 48.5 atm)

Ĥ14𝑎 Ĥ14𝑏

CH3OH (l, 64.7˚ C, 1 atm) CH3OH (g, 64.7˚ C, 1 atm)

Ĥ𝑣
Calculation:
64.7 180
Ĥ14 = ∆ Ĥ˚𝑓 + ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡 + Ĥ𝑣 + ∫64.7 42.93 𝑥 10−3 +
8.301 𝑥 10−5 𝑇 + (−1.87 𝑥 10−8 ) 𝑇 2 + (−8.03 𝑥10−12 ) 𝑇 3 𝑑𝑡
= -238.6 kJ/mol + 3.311 kJ/mol + 35.27 kJ/mol + 6.084 kJ/mol
= -193.935 kJ/mol

43
 Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= -2440434438.3- (-203245497.4)
= -11332.7614 kW

SEPARATOR (S-101)
Stream 11
Tout = 40˚ C
Pout = 48.8
atm

Stream 10
Tin = 40˚ C S-101
Pin = 48.8
atm

Stream 13
Tout = 40˚ C
Pout = 48.8 atm

Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 10 Stream 11 Stream 13
ṅin (kmol/hr) Ĥ𝑖𝑛 ṅout Ĥ𝑜𝑢𝑡 ṅ𝑜𝑢𝑡 Ĥ𝑜𝑢𝑡
(kJ/mol) (kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol)
CO2 131.011 Ĥ1 = 0.562 6.657 Ĥ8 = 0.562 1.030 Ĥ14 = 0.562
CO 269.962 Ĥ2 = 0.436 31.066 Ĥ9 = 0.436 - -
H2O 27.790 Ĥ3 = 1.131 - - 162.740 Ĥ15 = 1.131
H2 2024.717 Ĥ4 = 0.433 1164.975 Ĥ10 = 0.433 2.06 Ĥ16
= 0.433
N2 11.910 Ĥ5 = 0.436 11.095 Ĥ11 = 0.436 - -
CH4 1000.449 Ĥ6 = 0.541 987.455 Ĥ12 = 0.541 10.3 Ĥ17 = 0.541
CH3OH 508.164 Ĥ7 = 1.220 19.971 Ĥ13 = 1.220 853.870 Ĥ18 = 1.220
Table 4.4.11: Molar Flowrate and Specific Enthalpy for S-101

Ĥ1
Path: CO2 (g, 25˚ C, 1 atm) CO2 (g, 40˚ C, 48.8 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 40˚ C, 1 atm)
Calculation:
40
Ĥ1 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 0.562 kJ/mol

44
 Ĥ2
Path: CO (g, 25˚ C, 1 atm) CO (g, 40˚ C, 48.8 atm)
Ĥ2𝑎 Ĥ2𝑏
CO2 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ2 = ∫25 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.436 kJ/mol

Ĥ3
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 40˚ C, 48.8 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 40˚ C, 1 atm)

Calculation:
40
Ĥ3 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 1.131 kJ/mol

Ĥ4
Path: H2 (g, 25˚ C, 1 atm) H2 (g, 40˚ C, 48.8 atm)
Ĥ4𝑎 Ĥ4𝑏
H2 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ4 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.433 kJ/mol

Ĥ5
Path: N2 (g, 25˚ C, 1 atm) N2 (g, 40˚ C, 48.8 atm)
Ĥ5𝑎 Ĥ5𝑏
N2 (g, 40˚ C, 1 atm)
Calculation:
40
Ĥ5 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 + (−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.436 kJ/mol

45
 Ĥ6
Path: CH4 (g, 25˚ C, 1 atm) CH4 (l, 40˚ C, 48.8 atm)
Ĥ6𝑎 Ĥ6𝑏
CH4 (g, 40˚ C, 1 atm)

Calculation:
40
Ĥ6 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.541 kJ/mol

Ĥ7
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 38˚ C, 48.8 atm)
Ĥ7𝑎 Ĥ7𝑏
CH3OH (l, 38˚ C, 1 atm)

Calculation:
40
Ĥ7 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 1.220 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= [(1085135.38)+ 1231931.5)] – (2265860.314)

= 14.22405 kW

46
 Flash Drum (S-102) Stream 15
Tout = 30˚ C
Pout = 0.24 atm

Stream 14
Tin = 38˚ C S-102
Pin = 47 atm

Stream 16
Tout = 30˚ C
Pout = 0.24 atm

Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 14 Stream 15 Stream 16
ṅin (kmol/hr) Ĥ𝑖𝑛 ṅout Ĥ𝑜𝑢𝑡 ṅ𝑜𝑢𝑡 Ĥ𝑜𝑢𝑡
(kJ/mol) (kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol)
CO2 1.030 Ĥ1 = 0.486 0.576 Ĥ6 = 0.186 - -
CO - - 0.0823 Ĥ7 = 0.145 - -
H2O 162.740 Ĥ2 = 0.980 0.741 Ĥ8 = 0.377 162.098 Ĥ13 = 0.377
H2 2.060 Ĥ3 = 0.375 2.428 Ĥ9 = 0.144 - -
N2 - - 0.0823 Ĥ10 = 0.145 - -
CH4 10.30 Ĥ4 = 0.468 10.249 Ĥ11 = 0.179 - -
CH3OH 853.870 Ĥ5 = 1.055 27.001 Ĥ12 = 0.402 826.303 Ĥ14 = 0.402
Table 4.4.12: Molar Flowrate and Specific Enthalpy for S-102

Ĥ1
Path: CO2 (g, 25˚ C, 1 atm) CO2 (g, 38˚ C, 47 atm)
Ĥ1𝑎 Ĥ1𝑏
CO2 (g, 38˚ C, 1 atm)

Calculation:
38
Ĥ1 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 0.486 kJ/mol

Ĥ2
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 38˚ C, 47 atm)
Ĥ2𝑎 Ĥ2𝑏
H2O (l, 38˚ C, 1 atm)

47
Calculation:
38
Ĥ2 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 0.980 kJ/mol

Ĥ3
Path: H2 (g, 25˚ C, 1 atm) H2 (g, 38˚ C, 47 atm)
Ĥ3𝑎 Ĥ3𝑏
H2 (g, 38˚ C, 1 atm)
Calculation:
38
Ĥ3 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.375 kJ/mol

Ĥ4
Path: CH4 (g, 25˚ C, 1 atm) CH4 (g, 38˚ C, 47 atm)
Ĥ4𝑎 Ĥ4𝑏
CH4 (g, 38˚ C, 1 atm)

Calculation:
38
Ĥ4 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.468 kJ/mol

Ĥ5
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 38˚ C, 47 atm)
Ĥ5𝑎 Ĥ5𝑏
CH3OH (l, 38˚ C, 1 atm)
Calculation:
38
Ĥ5 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 1.055 kJ/mol

Ĥ6
Path: CO2 (g, 25˚ C, 1 atm) CO2 (g, 30˚ C, 0.24 atm)
Ĥ6𝑎 Ĥ6𝑏
CO2 (g, 30˚ C, 1 atm)
Calculation:
30
Ĥ6 = ∫25 36.11 𝑥 10−3 + 4.233 𝑥 10−5 𝑇 + (−2.887 𝑥 10−8 )𝑇 2 + 7.464 𝑥10−12 𝑇 3 𝑑𝑡

= 0.186 kJ/mol

48
 Ĥ7
Path: CO (g, 25˚ C, 1 atm) CO (g, 30˚ C, 0.24 atm)
Ĥ7𝑎 Ĥ7𝑏
CO2 (g, 30˚ C, 1 atm)
Calculation:
30
Ĥ7 = ∫25 28.95 𝑥 10−3 + 0.4110 𝑥 10−5 𝑇 + 0.3548 𝑥10−8 𝑇 2 + (−2.220 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.145 kJ/mol

Ĥ8
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 30˚ C, 0.24 atm)
Ĥ8𝑎 Ĥ8𝑏
H2O (l, 30˚ C, 1 atm)
Calculation:
30
Ĥ8 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 0.377 kJ/mol

Ĥ9
Path: H2 (g, 25˚ C, 1 atm) H2 (g, 40˚ C, 48.8 atm)
Ĥ9𝑎 Ĥ9𝑏
H2 (g, 30˚ C, 1 atm)
Calculation:
30
Ĥ9 = ∫25 28.84 𝑥 10−3 + 0.00765 𝑥 10−5 𝑇 + 0.3288 𝑥 10−8 𝑇 2 +
(−0.8698 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.144 kJ/mol

Ĥ10
Path: N2 (g, 25˚ C, 1 atm) N2 (g, 30˚ C, 0.24 atm)
Ĥ10𝑎 Ĥ10𝑏
N2 (g, 30˚ C, 1 atm)
Calculation:
30
Ĥ10 = ∫25 29.00 𝑥 10−3 + 0.2199 𝑥 10−5 𝑇 + 0.5723 𝑥 10−8 𝑇 2 +
(−2.871 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 0.145 kJ/mol

Ĥ11
Path: CH4 (g, 25˚ C, 1 atm) CH4 (l, 30˚ C, 0.24 atm)
Ĥ11𝑎 Ĥ11𝑏
CH4 (g, 30˚ C, 1 atm)

49
Calculation:
30
Ĥ6 = ∫25 34.31 𝑥 10−3 + 5.469 𝑥 10−5 𝑇 + 0.3661 𝑥 10−8 𝑇 2 + (−11.00 𝑥10−12 ) 𝑇 3 𝑑𝑡

= 0.179 kJ/mol

Ĥ12
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 30˚ C, 0.24 atm)
Ĥ12𝑎 Ĥ12𝑏
CH3OH (l, 30˚ C, 1 atm)
Calculation:
30
Ĥ12 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 0.402 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (13099.33+393284.752) – 1065639.03) kJ/h

= -183.12637 kW

50
Distillation Column (T-101) Stream 17
Tout = 51˚ C
Pout = 0.64 atm

Stream 16
Tin = 30˚ C T-101
Pin = 0.24 atm

Stream 18
Tout = 71˚ C
Pout = 0.9 atm

Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 16 Stream 17 Stream 18
ṅin Ĥ𝑖𝑛 ṅ out Ĥ𝑜𝑢𝑡 ṅ 𝑜𝑢𝑡 Ĥ𝑜𝑢𝑡
(kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol)
CO2 - - - - - -
CO - - - - - -
H2O 162.098 Ĥ1 = 0.377 2.7378 Ĥ3 = 1.960 159.66 Ĥ5 = 3.468
H2 - - - - - -
N2 - - - - - -
CH4 - - - - - -
CH3OH 826.303 Ĥ2 = 0.402 453.5622 Ĥ4 = 2.139 372.54 Ĥ6 = 3.861
Table 4.4.13: Molar Flowrate and Specific Enthalpy for T-101

Ĥ1
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 30˚ C, 0.24 atm)
Ĥ1𝑎 Ĥ1𝑏
H2O (l, 30˚ C, 1 atm)
Calculation:
30
Ĥ1 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 0.377 kJ/mol
Ĥ2
Path:
CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 30˚ C, 0.24 atm)
Ĥ2𝑎 Ĥ3𝑏
Calculation: CH3OH (l, 30˚ C, 1 atm)
30
Ĥ2 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 0.402 kJ/mol

51
 Ĥ3
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 51˚ C, 0.6 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 51˚ C, 1 atm)
Calculation:
51
Ĥ3 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 1.960 kJ/mol

Ĥ4
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 51˚ C, 0.6 atm)
Ĥ4𝑎 Ĥ4𝑏
CH3OH (l, 51˚ C, 1 atm)
Calculation:
51
Ĥ4 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 2.139 kJ/mol

Ĥ5
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 71˚ C, 0.9 atm)
Ĥ5𝑎 Ĥ5𝑏
H2O (l, 71˚ C, 1 atm)
Calculation:
71
Ĥ5 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 3.468 kJ/mol

Ĥ6
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 71˚ C, 0.9 atm)
Ĥ6𝑎 Ĥ6𝑏
CH3OH (l, 71˚ C, 1 atm)
Calculation:
71
Ĥ6 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 3.861 kJ/mol

Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (975535.6338 + 1992077.82) – 393284.752

= 715.09131 kW

52
Distillation Column (T-102) Stream 19
Tout = 60˚ C
Pout = 0.95 atm

Stream 18
Tin = 71˚ C T-102
Pin = 0.9 atm

Stream 20
Tout = 99˚ C
Pout = 1 atm

Reference state: CO2, CO, H2, N2, CH4 (gas, 25˚ C, 1 atm), H2O (liquid, 25˚ C, 1atm)
Compound Stream 18 Stream 19 Stream 20
ṅin Ĥ𝑖𝑛 ṅout Ĥ𝑜𝑢𝑡 ṅ𝑜𝑢𝑡 Ĥ𝑜𝑢𝑡
(kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol) (kmol/hr) (kJ/mol)
CO2 - - - - - -
CO - - - - - -
H2O 159.66 Ĥ1 = 3.468 1.1109 Ĥ3 = 2.639 158.3544 Ĥ5 =
5.5796
H2 - - - - - -
N2 - - - - - -
CH4 - - - - - -
CH3OH 372.540 Ĥ2 = 3.861 368.1891 Ĥ4 = 2.905 3.54561 Ĥ6 = 3.861
Table 4.4.13: Molar Flowrate and Specific Enthalpy for T-101

Ĥ1
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 71˚ C, 0.9 atm)
Ĥ1𝑎 Ĥ1𝑏
H2O (l, 71˚ C, 1 atm)
Calculation:
71
Ĥ1 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 0.377 kJ/mol
Ĥ2
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 71˚ C, 0.9 atm)
Ĥ2𝑎 Ĥ3𝑏
CH3OH (l, 71˚ C, 1 atm)
Calculation:
71
Ĥ2 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

53
 = 3.861 kJ/mol

Ĥ3
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 60˚ C, 0.95 atm)
Ĥ3𝑎 Ĥ3𝑏
H2O (l, 60˚ C, 1 atm)
Calculation:
60
Ĥ3 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 2.639 kJ/mol

Ĥ4
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (l, 60˚ C, 0.95 atm)
Ĥ4𝑎 Ĥ4𝑏
CH3OH (l, 60˚ C, 1 atm)
Calculation:
60
Ĥ4 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡

= 2.905 kJ/mol

Ĥ5
Path: H2O (l, 25˚ C, 1 atm) H2O (l, 99˚ C, 1 atm)

Calculation:
99
Ĥ5 = ∫25 75.4 𝑥 10−3 𝑑𝑡

= 5.5796 kJ/mol

Ĥ6
Path: CH3OH (l, 25˚ C, 1 atm) CH3OH (g, 99˚ C, 1 atm)

Ĥ6𝑎 Ĥ4𝑏

CH3OH (l, 64.7˚ C, 1 atm) CH3OH (g, 64.7˚ C, 1 atm)

Ĥ𝑣
Calculation:
64.7 99
Ĥ6 = ∫25 75.86 𝑥 10−3 + 16.83 𝑥 10−5 𝑇 𝑑𝑡 + Ĥ𝑣 + ∫64.7 42.93 𝑥 10−3 +
8.301 𝑥 10−5 𝑇 + (−1.87 𝑥 10−8 ) 𝑇 2 + (−8.03 𝑥10−12 ) 𝑇 3 𝑑𝑡
= 3.311 kJ/mol + 35.27 kJ/mol + 1.701kJ/mol
= 40.282 kJ/mol

54
Q̇ = ∆Ḣ = ∑ṅi ,out Ĥi,out − ∑ṅi ,in Ĥi ,in

= (1072521.001 + 1026378.42) – 1992077.82

= 29.67266 kW

Table 4.4 14: Summary of Energy Balance.

Equipment Q calc (kW)
C-101 904.76489
C-102 396.76042
E-101 -128.90539
E-102 -1976.50956
E-103 -9266.32657
E-104 202.88194
E-105 -46.19235
FEHE 3690.69747
R-101 -11332.7614
S-101 14.22405
S-102 -183.12637
T-101 715.09131
T-102 29.67266

55
4.5 Conclusion

From the calculation the value of heat transfer, Q for equipment was not same. This
happens due to the different inlet and outlet components and the needs of energy used. The
heat transfer with positive value represents the heat absorb which is as endothermic reaction.
Then negative value represent heat release and as exothermic reaction.

REFERENCES

Amin, D. R., Hassan, I., Das, A., Yeasmin, R., Rahman, T., & Hossain, T. (n.d.). Simulation
of Methanol Production from. 1-14.
Felder, R. M. (2005). Elementary Principles of Chemical Processes. United States of
America: John Wiley & Sons, Inc.
Klier, K. (1982). Methanol Synthesis. Advances in Catalyst, 243-310.
Luyben, W. L. (2010). Design and Control of a Methanol Reactor/Column Process. Industrial
Engineering Chemical, 6150-6163.

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