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GEST 79/79
4th Edition
April 2007
Euro Chlor is the European federation which represents the producers of chlorine
and its primary derivatives.
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This document has been produced by the members of Euro Chlor and should not be reproduced
in whole or in part without the prior written consent of Euro Chlor.
It is intended to give only guidelines and recommendations. The information is provided in good
faith and was based on the best information available at the time of publication. The information is
to be relied upon at the user’s own risk. Euro Chlor and its members make no guarantee and
assume no liability whatsoever for the use and the interpretation of or the reliance on any of the
information provided.
This document was originally prepared in English by our technical experts. For our members’
convenience, it may have been translated into other EU languages by translators / Euro Chlor
members. Although every effort was made to ensure that the translations were accurate, Euro
Chlor shall not be liable for any losses of accuracy or information due to the translation process.
Prior to 1990, Euro Chlor’s technical activities took place under the name BITC (Bureau
International Technique du Chlore). References to BITC documents may be assumed to be to
Euro Chlor documents.
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RESPONSIBLE CARE IN ACTION
It has been assumed in the preparation of these publications that the users
will ensure that the contents are relevant to the application selected and are
correctly applied by appropriately qualified and experienced people for
whose guidance they have been prepared. The contents are based on the
most authoritative information available at the time of writing and on good
engineering, medical or technical practice but it is essential to take account
of appropriate subsequent developments or legislation. As a result, the text
may be modified in the future to incorporate evolution of these and other
factors.
This edition of the document has been drawn up by the Storage, Transport
and Safety Working Group to whom all suggestions concerning possible
revision should be addressed through the offices of Euro Chlor.
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GEST 79 / 79
Fourth Edition
TABLE OF CONTENTS
1. OBJECTIVE 5
2. FIELD OF APPLICATION 5
3. CHOICE OF COMPRESSOR 5
3.1. Types of Compressor 5
3.2. Common Features 5
3.3. Transfer of Liquid Chlorine 6
4. DESIGN FOR SAFETY 6
4.1. Contact between Chlorine and the Lubricant 6
4.1.1. Reciprocating Compressors 6
4.1.2. Diaphragm Compressors 7
4.2. Maximum Chlorine Transfer Temperature 7
4.3. Chlorine cooling 7
4.4. Materials of Construction 8
5. ANCILLARY EQUIPMENT 8
5.1. Compressor gas inlet 8
5.2. Compressor Gas Delivery 9
5.3. Compressor by-Pass 9
6. INSTALLATION 9
7. OPERATION 10
7.1. Inspection on Commissioning a New Installation or after Maintenance 10
7.2. Starting and Transferring the Liquid Chlorine 10
7.3. Ending the Transfer 11
7.4. Prolonged Shutdown 12
7.4.1. Reciprocating Compressors 12
7.4.2. Diaphragm Compressors 12
7.5. Problems to be Avoided 12
8. APPENDIXES 13
9. REFERENCES 13
1. OBJECTIVE
2. FIELD OF APPLICATION
The use of a transfer compressor enables liquid chlorine to be transferred from
one container to another and enables a large proportion of the residual gas in the
container being emptied to be recovered. Each of these two operations is
described below. The principal advantage is that it avoids the use of an inert gas
which necessitates a subsequent venting operation to avoid any risk of excess
pressure. It can be used for transferring liquid chlorine from a transport container
to a plant stock tank.
3. CHOICE OF COMPRESSOR
Liquid ring compressors are not used for the transfer of liquid chlorine because of
the pressure normally required, the problems of achieving a reliable gas seal on
the shaft and the likelihood of entrainment of liquid (normally sulphuric acid) from
the liquid ring.
- The design gas discharge temperature shall be compatible with the material
used, taking into account the possibility of hot spots (see 4.2.).
To prevent any contact between the chlorine and the lubricating oil, it is essential
that the compressor cylinder is unlubricated, and that the piston rod passes
through a separation chamber between the cylinders and the oil sump. This
chamber must be of sufficient length to prevent any part of the piston rod coming
into contact with both the chlorine and the lubricating oil during its reciprocating
movement. In order to avoid any leakage of chlorine to the atmosphere and to
avoid contact between the piston rod and atmospheric moisture, this chamber
should be purged (gland purge) continuously at a pressure slightly greater than
atmospheric pressure by oil-free dry air or nitrogen (with a dew point of less than
minus 40°C at atmospheric pressure). This purged gas may contain traces of
chlorine and should be vented to an absorption installation.
The diaphragms shall be replaced periodically to avoid accidental failure. The life
of the diaphragms is very dependent on any impurities which may be present in
the chlorine and also on the general mechanical state of the compressor. The
replacement frequency must therefore be chosen to suit the circumstances of
each plant and must take into account the possible impact of any change in the
quality of the chlorine. A filter on the chlorine inlet to the compressor may extend
the life of the diaphragms (see 5.1.).
Any risk of chlorine liquefaction must be avoided, for example by controlling the
water temperature.
Any components of the compressor which come into contact with chlorine should
be fabricated from materials which are compatible with dry chlorine gas and which
have appropriate mechanical properties for the stresses and temperatures to
which they will be subjected.
For example:
5. ANCILLARY EQUIPMENT
Recommended:
A coarse filter to retain any large solid foreign bodies (not fine iron and rust
particles which may results in a chlorine-iron fire).
A heated separation chamber at a controlled temperature just above the
temperature of liquefaction of chlorine at the suction pressure. This
chamber should be as close as possible to the chlorine inlet port and is
designed to vaporise any entrained droplets of liquid chlorine which may
form in the suction pipework. This chamber should be fitted with a vent
valve connected to the absorption installation. This separation chamber
could be fitted with a liquid chlorine detector (either a low temperature alarm
or a level indicator).
Recommended:
To avoid vibration in the discharge pipework of the compressor a
capacity vessel may be necessary. This capacity vessel can also
prevent the return of any liquid chlorine which may result from
condensing chlorine gas in the discharge pipework due to its route
and the external temperature (see Section 6 below).
6. INSTALLATION
The discharge pipework between the compressor and the capacity vessel must be
designed to prevent any return of liquid chlorine to the compressor when the
external temperature is low.
7. OPERATION
For the operation of the transfer, refer to the following Euro Chlor
recommendations:
GEST 78/74 - Design Principles for Installations for Loading of
Liquid Chlorine into Road and Rail Tankers and ISO-Containers
GEST 78/73 - Design Principles for Installations for Off Loading
of Liquid Chlorine Road and Rail Tankers and ISO-Containers
Then check that all the operating conditions are at correct values:
Oil pressure.
Cooling water throughput, pressure and exit temperature.
Discharge temperature of the chlorine.
Discharge and inlet pressures.
Follow the chlorine transfer (weight or level of the 2 containers).
Note: the reciprocating compressors use dynamic seals and hence when stopped,
Cl2 will pass into the transition pieces. As such the transition pieces need to be
continually purged/pressurised to avoid this.
At the end of the transfer, a small amount of liquid chlorine is left in the “emptied”
container allowing maintaining an acceptable maximum NCl3 concentration.
After purging, the gas cylinder should be maintained under pressure with dry, oil
free air or nitrogen (dew point below minus 40°C at atmospheric pressure). It is
also recommended that the purge gas on the compressor seal should be
maintained in order to avoid corrosion, which necessitates a permanent source of
dry inert gas. To avoid any seizure of the machine it is recommended that the
compressor is periodically turned over.
The gas chamber (the space between the chlorine side of the diaphragm and the
cylinder head) should be maintained under pressure with dry, oil free air or
nitrogen (dew point should be below minus 40°C at atmospheric pressure).
8. Appendixes
Schematic P&I and installation drawing for chlorine padding with a compressor.
9. REFERENCES
GEST 76/55 - Maximum Levels of Nitrogen Trichloride in Liquid
Chlorine
GEST 78/73 - Design Principles for Installations for Off Loading
of Liquid Chlorine Road and Rail Tankers and ISO-Containers
GEST 78/74 - Design Principles for Installations for Loading of
Liquid Chlorine into Road and Rail Tankers and ISO-Containers
GEST 79/82 - Materials of Construction for Use in Contact with
Chlorine
GEST 87/133 - Over Pressure Relief of Liquid Chlorine
Installations
Vent to
absorption
or recovery
TAL PAH
PSD Water
Inert gas
TAL
Note: the "S" switches give alarm and trip the compressor
5 6
4 3
1 9
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