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:
1 1 1
= +
𝑉𝑐𝑜𝑟𝑟 𝑉𝑚 𝑉𝑟
1119
log(𝑉𝑟 ) = 5.07 − + 0.58 log(𝑃𝐶𝑂2 ) − 0,34(𝑝𝐻𝑎𝑐𝑡𝑢𝑎𝑙 − 𝑝𝐻𝐶𝑂2 )
𝑇 + 273
𝑈 0.8
𝑉𝑚 = 2.7 × × 𝑃𝐶𝑂2
𝐷 0.2
𝐶𝑂2 = 3 𝑚𝑜𝑙 %
Total Pressure = 100bara,
𝑃𝐶𝑂2 = 3 × 0.764
𝑃𝐶𝑂2 = 2.292𝑏𝑎𝑟𝑎
𝑄 = 1500000𝑏𝑏𝑙/𝑑
𝑚3
𝑄 = 1500000 × 0.0000018
𝑠
𝑚3
𝑄 = 2.7
𝑠
𝜋𝐷 2
𝐴=
4
𝜋 × 0.592
𝐴=
4
𝜋 × 0.592
𝐴=
4
𝐴 = 0.273𝑚2
Liquid flow rate, U:
𝑄
𝑈=
𝐴
2.7
𝑈=
0.273
𝑈 = 9.89𝑚/𝑠
U = 9.89m/s
𝑈 0.8
𝑉𝑚 = 2.7 × 0.2 × 𝑃𝐶𝑂2
𝐷
9.890.8
𝑉𝑚 = 2.7 × × 2.292
0.590.2
𝑽𝒎 = 𝟒𝟑mm/yr
Corrosion Rate, 𝑉𝑐𝑜𝑟𝑟 :
1 1 1
= +
𝑉𝑐𝑜𝑟𝑟 𝑉𝑚 𝑉𝑟
1 1 1
= +
𝑉𝑐𝑜𝑟𝑟 1.867 43
𝑽𝒄𝒐𝒓𝒓 = 𝟏. 𝟕𝟗𝒎𝒎/𝒚𝒆𝒂𝒓
When PCO2 = 0.05–0.1 MPa and formation water exists, the ratio of the molal concentration
multiplied by the number of electrovalence for Ca2+ to that for HCO3− can be used for
determining the corrosion rate as follows.
The carbon dioxide corrosion of pipe includes uniform corrosion and pitting corrosion. The
corrosion products are FeCO3 and Fe3O4.
Uniform corrosion: Under certain conditions of temperature and pressure, the water in pipe
fluid or the water in natural gas may condense and is adsorbed on the pipe wall to form water
film. Carbon dioxide is dissolved into water and a water film with a low pH value is formed,
thus generating hydrogen depolarization corrosion. The reaction is as follows.
CO2+H2O→HCO3−+H+
H++e→H
Pitting corrosion: Carbon dioxide may not only cause the uniform corrosion of steel, but it
may also cause the local corrosion of steel. Local pitting corrosion, mosslike corrosion, and
mesalike pitting corrosion are typically characteristic of carbon dioxide corrosion, and the
mesalike pitting corrosion is most serious. This corrosion has a high penetrance and may
cause serious economic loss. It will lead to stopping production of oil and gas wells or even
the abandonment of the wells if maintenance and replacing string, and so on, are not done in
time during oil and gas well production. The carbon dioxide corrosion pits may often be
hemispherical deep pits with a steep edge (Figure 11-9). The reason the local filmless
mesalike pitting corrosion is generated is that the protective film that is formed on the metal
surface by corrosion products (FeCO3, Fe3O4, and so on) during corrosion reaction is often
either non-uniformly formed, or failed.