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J Fail. Anal. and Preven.

(2009) 9:365–369
DOI 10.1007/s11668-009-9250-1

TECHNICAL ARTICLE—PEER-REVIEWED

Failure Investigation on Reheater Tube Due to Deposit and Wall


Thinning
J. Purbolaksono Æ F. Tarlochan Æ M. M. Rahman Æ
N. F. Nordin Æ B. Ahmad

Submitted: 16 October 2008 / in revised form: 4 April 2009 / Published online: 29 April 2009
Ó ASM International 2009

Abstract Failure analysis of a reheater tube showed that efficiency. Additionally, the growing scales may cause the
the failure was caused by overheating and wall thinning. tube temperatures to be higher than those originally
Finite element modeling, dimensional measurements, and specified. High temperatures and scale formation may
microscopic examinations were performed to investigate cause degradation of the tube material and eventually will
the root cause of the failure. Wall thinning, due to exces- lead to tube rupture. Tube rupture may also be caused by
sive coal-ash corrosion, and overheating, due to scale reduction in tube wall thickness as the alloy is consumed
buildup on the tube were measured, and estimations, the by scale formation and corrosion processes. It is estimated
average corrosion and scale growth rates, were made. The that 10% of all power-plant breakdowns are caused by
combination of excessive scale formation on the inner tube creep fractures of boiler tubes due to the scale formation
surfaces and wall thinning due to coal-ash corrosion on the and 30% of all tube failures in boilers and reformers are
outer tube surfaces combined to cause the failure of the caused by creep [2].
reheater tube. As reported in Ref. [3], coal-ash corrosion is caused
by the formation of complex alkali sulfates such as
Keywords Boiler material  Deposits  Failure analysis  K3Fe(SO4)3 and Na3Fe(SO4)3 at the scale/metal interface
Tube burst  Thinning  High temperature when the tube metal temperature is in the range of 566–
732 °C. Coal-ash corrosion may be accelerated when the
fuel supply or fuel type is changed and the new heat source
results in the production of an aggressive ash. Certain coals
Introduction
contain constituents which form ash deposits that are
molten at typical operating temperatures and can cause
The thermal efficiency of a boiler depends on the heat
extensive corrosion. The corrosion may lead to a significant
transfer process across the tube wall. With prolonged
concern if the wall thickness is reducing at rate of 8 mils/
exposure at elevated temperature, boiler tubes may
year or greater [4].
develop scales on the internal and/or external surfaces [1]
In this study, dimensional measurements of the failed
which will retard heat transfer and reduce the thermal
tube sample were made to obtain data of the wall thinning
and scale thickness of the tube. Average rates of the scale
formation on the inner surface and tube thinning due to
corrosion on the external surface were then estimated.
J. Purbolaksono (&)  F. Tarlochan  M. M. Rahman
Finite element models, conducted using software package
Department of Mechanical Engineering,
Universiti Tenaga Nasional, Km 7 Jalan Kajang-Puchong, of ANSYS [5], for heat transfer analysis are developed
Kajang 43009, Selangor, Malaysia according to the data obtained from visual inspection and
e-mail: Judha@uniten.edu.my dimensional measurements. Microscopic examination was
also carried to show any microstructure changes. The
N. F. Nordin  B. Ahmad
TNB Research Sdn Bhd, No. 1 Lorong Air Hitam, maximum allowable stresses of SA-213-T22 for different
Kajang 43000, Selangor, Malaysia temperatures [6] are also presented.

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366 J Fail. Anal. and Preven. (2009) 9:365–369

Visual Inspection

The boiler/reheater tube data can be seen in Table 1. Visual


inspection of the failed tube sample shown in Fig. 1a and b
revealed the following features:
1 Significant wall thinning was found. The tube metal
thickness at the distance of 30 cm and 2 m away from
the failure region were in the average of 2.5 and 5 mm,
respectively.
2 Scale thickness on the inner surface at the distance of
30 cm and 2 m away from the failure region were in
the average of 2.2 and 0.4 mm, respectively.
3 According to data from Table 1, it can be estimated
that the amount of wall thinning was approximately
1.8 mm (30 cm away from rupture region) and 1.1 mm
(2 m away from rupture region).
4 The tube was failed with wide opened (fish mouth)
burst having dimension of the rupture of 2.8 cm in
width and 5.5 mm in length.

Finite Element Models

Data obtained from dimensional measurements for the


inner scale and outer wall thinning of the tube sample was
used to estimate the average scale growth and wall thinning
rates. The average scale growth and wall thinning rates are
shown in Table 2. These data are based on the measure-
ments and the report that the tube failed after 99,083 h. Fig. 1 (a) Cross section of the as-received tube at 30 cm away from
rupture region. (b) Rupture region with opened wide burst (Courtesy:
Table 1 Boiler data and properties of fluid and solid materials Kapar Power Station, Malaysia)
Boiler
Fuel Pulverized coal
Load capacity 300 MW
Flue gas properties Table 2 Estimations of scale growth and wall thinning rates
Flue gas temperature 800 °C Scale growth
2
Convection coefficient 109.44 W/m C Scale thickness at 99,083 h
Inlet steam properties - Rupture region: 2.2 mm
Inlet temperature 541 °C - 2 m away from rupture region: 0.4 mm
Thermal conductivity 0.0604 W/m C Average scale growth rate:
Specific heat 2161 J/kg C - Rupture region: 2.2 mm/99,083 h = 2.22036 9 105 mm/h
Density 0.2697 kg/m3 - 2 m away from rupture region
Dynamic viscosity 0.00002834 N s/m2 0.4 mm/99,083 h = 4.03702 9 106 mm/h
Mass flow rate 18,000 kg/h Wall thinning
Water wall properties Wall thinning at 99,083 h
Tube material SA-213-T22 - Rupture region: 1.80 mm
Thermal conductivity [3] 34.606 W/m C - 2 m away from rupture region: 1.10 mm
Inner radius 0.0189 m Average scale growth rate
Outer radius 0.0254 m - Rupture region: 1.80 mm/ 99,083 h = 1.81666 9 105 mm/h
Fe3O4 iron oxide (magnetite) - 2 m away from rupture region:
Thermal conductivity [3] 0.592 W/m C 1.10 mm/ 99,083 h = 1.11018 9 105 mm/h

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J Fail. Anal. and Preven. (2009) 9:365–369 367

1/2 expansion model of 2D-axisymmetric solid

hot gas
oxide
100 mm scale tube metal

scale/metal interface

549.757 563.619 577.481 591.343 605.204

steam remaining tube 542.826 556.688 570.550 584.412 598.273


X
metal thickness
hollow
radius initial tube metal thickness Fig. 3 Estimated temperature (°C) distribution of the tube at 60,000
service hours
Fig. 2 Model of the reheater tube with inner scale on the surface
Convective coefficient of steam film for fully developed
turbulent flow in circular tube is expressed as [7]:
Finite element analyses are conducted in order to
k
determine the temperature distribution at the final stage of hs ¼ 0:023 ðReÞ0:8 ðPrÞ0:4 ðEq 1Þ
d
rupture and simulate some configurations at different times
prior to rupture. In order to represent the actual geometry where Re is Reynolds number; Pr is Prandtl number; k is
of the tube and by considering the ratio of the length to fluid conductivity; and d is the inner diameter of the tube.
radius of the tube, the model used is 100 mm in length (see The maximum elastic hoop stress in the tube wall [4] is
Fig. 2). used in order to provide a conservative estimation as
In modeling of the steady state heat transfer for the ðb2 þ a2 Þ
problem using ANSYS, the area of the model is divided rh ¼ P ðEq 2Þ
ðb2  a2 Þ
into two regions, i.e., scale region and tube region. Data for
the steam region is used to determine the convection where P is operational pressure; a and b are inner and outer
coefficient of steam film for fully developed turbulent flow radius, respectively.
in circular tube. Steam flows through the internal of tube
with an inlet temperature of 541 °C and a mass flow rate of
18,000 kg/h. The flue gas temperature is 800 °C, and the Microscopic Examination
heat transfer along the external surface between the flue gas
and the tube wall is considered as free convection heat The microscopic examination for the specimens taken from
transfer. The scale is magnetite (Fe3O4 iron oxide) and the rupture region of the failed tube was carried out to reveal
detailed material properties of steam, scale, tube, and flue any change of microstructure. Locations of the specimens
gas used are shown in Table 1. Some parameters shown in are indicated at A and B in Fig. 1b. The locations chosen are
Table 1 are taken from the actual data by courtesy of Kapar expected to obtain sufficient information in order to support
Power Plant, Malaysia. It was reported that the operational the analysis pertaining to the tube rupture.
pressure of the reheater tubes is around 40 bar or 4 MPa.
The scale and tube are modeled as two-dimensional
axisymmetric solids. In order to ensure the models have a Results and Discussion
good meshing connectivity, the meshing size control of
0.0001 is used to generate the triangular elements. Steady Estimated temperature distribution at the rupture region of
state analyses of heat transfer are carried out in order to the tube at 60,000 service hours obtained from the finite
show the influence of different scale thickness and wall element analysis is shown in Fig. 3. It can be seen that the
thinning to the temperature distribution developed in the metal temperature already relatively high. The average
tube wall. Phenomenon of heat transfer inside the boiler tube temperatures for different regions of the tube are
tube is considered as forced convection with turbulent flow, plotted in Fig. 4. The temperatures are taken from of the
while the outer surface is experiencing free convection. average of the temperatures at oxide scale/metal interface

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368 J Fail. Anal. and Preven. (2009) 9:365–369

640

630
Average metal temperature °C

620

610

600

590 Rupture region


2 m away from rupture region
580
Oxidation might become excessive [1]
570

560

550
50,000 60,000 70,000 80,000 90,000 100,000
Service hours

Fig. 4 The average tube temperatures for different regions of the


tube at the corresponding service hours

30
Rupture region

25 Maximum allowable stress [6]


Hoop Stress, MPa

20

15
Hoop stress start
exceeding the
10 allowable stress
at about 85,000
service hours
5

Fig. 6 (a) Photomicrograph of the tube metal at location of A (see


0
590 600 610 620 630 640 650 Fig. 1b). (b) Photomicrograph of the tube metal at location of B
(Courtesy: Kapar Power Station, Malaysia)
Average Metal Temperature °C

Fig. 5 Hoop stresses in service at rupture region of the tube and the
allowable stresses for SA-213-T22 tube at the corresponding average The results of the microscopic examinations as shown in
tube temperatures Fig. 6a and b indicated that the tube metal at locations of A
and B (see Fig. 1b) shows complete spheroidization with
and outer surface of the tube. It can be seen from Fig. 4 that uniform dispersion of carbide particles. It is clear that the
at 60,000 h the average tube temperature at rupture region failed tube had operated at high temperature for a long time
has already exceeded 600 °C. At this temperature, thermal as shown by the change of microstructure.
oxidation may become excessive. At the higher metal tube It is obvious that a severe condition had been occurred
temperature ash deposits might also become corrosive as a in the tube over a prolonged period of time due to scale
result of the molten fly ash deposits. It can be seen from formation on the inner surface which results in temperature
Fig. 5 that the hoop stress at the rupture region start increase, and outer wall thinning which increases the hoop
exceeding the maximum allowable stress values for stress. Additionally the metal is weakened by microstruc-
SA-213-T22 tube for the last 14,000 h. The interaction ture deterioration (Fig. 6a and b). Results obtained from
between the significant outer wall thinning due to coal-ash the finite element analysis are well supported by the find-
corrosion and scale formation on the inner surface in the ings from the microscopic examinations.
metal tube is identified as the governing factor for the
failure problem. The interaction leads to the overheating
and excessive stresses in the tube and eventually results in Conclusions
the tube rupture.
The microscopic examinations were carried out in order Finite element modeling supported by dimensional mea-
to support the findings obtained from finite element analyses. surements and microscopic examinations for investigating

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J Fail. Anal. and Preven. (2009) 9:365–369 369

the failed reheater tube due to overheating and wall thin- References
ning were presented. It was found that the major
contributor which resulted in the failure of the reheater tube 1. Port Robert, R.D., Herro, M.H.: The NALCO Guide to Boiler Failure
Analysis. Nalco Chemical Company, McGraw-Hill Inc (1991)
was interaction between the excessive scale formation on 2. Jones, D.R.H.: Creep failures of overheated boiler, superheater and
the inner surface and outer wall thinning due to coal-ash reformer tubes. Eng. Fail. Anal. 11, 873–893 (2004)
corrosion. The tube had consequently operated at higher 3. French, D.N.: Metallurgical Failures in Fossil Fired Boilers. A
temperature and had operational stress exceeding the Wiley-Interscience Publication, Wiley, New York (2000)
4. Clark, K.J., Paterson, S.R., Rettig, T.W.: Remaining Life Assess-
maximum allowable stress values for a prolonged period ment of Superheater and Reheater Tubes. Aptech Engineering
of time. Services, Inc, CA, USA (1988)
5. ANSYS Multiphysics Version 11.0, ANSYS, Inc. Southpointe 275
Acknowledgments The authors wish to thank the Ministry of Sci- Technology Drive Canonsburg, PA 15317
ence Technology and Innovation, Malaysia for financial supports 6. ASME International electronic stress table. Table 1A: The max-
through the research project of IRPA 09-99-03-0033 EA001 and imum allowable stress values for ferrous materials. Section II,
Sciencefund 04-02-03-SF0003. The authors would also like to thank Part D of the ASME boiler and pressure vessel code, Copy RightÓ
Universiti Tenaga Nasional, TNB Research Sdn. Bhd and Kapar 1998 ASME International
Power Station Malaysia for permission of utilizing all the facilities 7. Incropera, F.P., DeWitt, D.P.: Introduction to Heat Transfer,
during conducting this study. 3rd edn. Wiley, New York (1996)

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