Académique Documents
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Culture Documents
By
Prof. Dr Eng. /
Hamid M. Khatab
2007
Absolute porosity
The percentage of total void space with respect to the bulk volume
regardless of the interconnection of the pore voids. A rock may have
considerable absolute porosity and yet have no conductivity to fluid for
lack of pore interconnection.
Effective porosity
The percentage of interconnected void space with respect to the
bulk volume. It is an indication of conductivity to fluid but not necessarily
a measure of it.
Secondary porosity
Secondary porosity results from geological agents such as leaching,
fracturing, and fissuring which occur after lithification of sediments.
1– Degree of sorting
Well–sorted, moderately rounded sand grains settle in water giving
a packing of 30 to 40% porosity. In poorly sorted sediments, the smaller
grains fit into the space between the larger ones, and porosity is
considerable decreased.
2 – Compaction
It's a geological factor which reduces porosity due to overburden
pressure of the overlying sediments. Sandstones, whoever, exhibit very
little compressibility 3x10–6 whereas shales may be reduced to a small
fraction of there original sedimentation volume.
4 – Clay content
Clay may often act as cementing material. Clay is deposits of the
same time as sand grains and generally it adheres to them so that after
deposition considerable porosity still exists and the over–all porosity of
sandstone may not be lowered greatly by a small amount of clay.
6 – Mode of packing
One may get qualitative picture of the geometrical structure of
sands by consideration of packing of spheres of uniform size. This, too,
is of infinite variety. However, it will suffice to note here two basic and
extremely types, namely: the cubic and rhombohedra packing. Unit cells
of such packing are shown in fig (1).
Bulk volume
2r
3
8r 3
4 3
Solid volum r
3
p.v B.v S .v 8r 3 r
3 4 3
porosity 3
47.6%
B.v B.v 8r
4
S .V . r 3
3
8r 3 sin 60 4 r 3
3 39.5%
3
8r sin 60
1
1 cos1 2 cos
7– Rock compressibility:
Assume that:
1 dvs
Solid volume compressibility
cs
.
v s dp
v B v p v s
dvB dvp dvs
dp dp dp
v B c B c p v p c s v s
vs v
c B c s c p p
vB vB
c B c s
1
c p
c c
B s
c p c s
Solution:
Wt. of paraffin = 20.9 – 20 = 0.9 gm.
Volume of paraffin = 0.9/0.9 = 1 cm3.
Example:
If the sample of Ex.1 has been saturated (100%) by water
and; its weight in air become 21.5 gms. When it has been
immersed in water, it weights 11.6 gms; calculate B.V.
Solution:
Wt. of displaced water = 21.5 – 11.6 = 9.9 gms.
B.V. = volume of water displaced = 9.9 / 1 = 9.9 cm3.
Glass pycnometer:
A glass pycnometer with a cap which rests on a ground taper joint
and with a sample hole through the cap is filled with mercury, the cap is
pressed into its seat and the excess mercury which overflows through a
hole in the cap is collected and removed. The pycnometer is opened and
the sample is placed in the surface of the mercury and submerged by a
set of pointed rods which project from the lower side of the cap, fig (2).
Figure 2
The cap is again pressed into its seat, which causes a certain
amount of mercury equivalent to the bulk volume of the sample to
overflow. The rods which submerge the sample should be adjusted so
that the sample does not touch the sides of the pycnometer; this avoids
trapping air bubbles.
Calculate B.V.
Solution:
Weight of pycnometer + weight of Hg + weight of sample =
350+20 = 370 gms.
Weight of Hg displaced = 370 – 235.9 = 134.1 gms.
So: B.V. of sample = 134.1 / 13.546 = 9.9 cm3.
Russel volumeter
Figure 3
Ruska porosimeter
A schematic diagram is given in Fig (4)
Figure 4
Break of the well core, clean the surface of the sample to remove
the drilling mud, measure the bulk volume by any one of the procedure
described above, crush the sample to its grains, wash the grains with
suitable solvent to remove oil mud and water, and determine the volume
of the grains. It is of course necessary to dry the rock grains before their
volume is determined. The volume of the dry grains may be determined
in a pycnometer containing a suitable liquid as kerosene.
Similarly;
If oil and water are the only fluids present, the volume filled by water
plus the volume filled by oil must equal the total pore volume; thus:
Sw + So = 1
In many pools, in addition to oil and connate water, free gas is also
present. The free gas saturation is defined by:
And then:
S w + S o + Sg = 1
Figure 5
Figure 6
The thimble and the sample are then dried and weighted.
Centrifugal method
A solvent is injected into the centrifuge just of center.
Figure 7
Mud filtration
In the case of rotary drilling, the differential pressure across the well
face causes mud and mud filtrate to invade to formation immediately
adjacent to the well surface, this flushing the formation with mud and this
Pressure gradient
Pressure gradient between the surface and the formation permits
the expansion of the entrapped water, oil and gas. Thus the contents of
the core at the surface have been changed from those which existed in
the formation.
The saturation values obtained directly from rock samples are used
to:
n r 4 p
Q
8 l
Where:
Q
: Flow rate, cm3/sec.
p
: Pressure lose over length, dyne/cm2.
l p
: Length over which is measured, cm.
n : Number of tubes.
Q p
A dl
Or
K P
l
The negative sign indicates that if the flow is taken as positive in the
positive direction, then the pressure decrease in that direction, so that
dP
the slope dl is negative.
A l P .V .
Vapp Vact act V act Vact .
Aapp l B .V .
This means that the actual velocity of a fluid will be the apparent
velocity divided by the porosity where the fluid completely
saturates the rock
Dimension of permeability
l
v , ML1 T 1
t
,
P F MLT 2 / A L2 , L L
KAP
Q AV
L
LT 1 K .ML1T 2 / ML1T 1 .L
K L2
Figure 10
Linear flow
Figure 11
KAdp
q
dL
KA p 2
q o
L
dl p1 dp
KA
q[ L ] [ p2 p1]
KA[ p1 p 2]
q
L
p.q=pmqm = constant
where :
p p 2
pm 1
2
And Qm is the flow rate at pm the integral is therefore;
KA p 2
qo
L
dL dp
p1
[qm p m / p ]o
L
dL [KA / ] p1
p2
dp
KA
o
L
dL p1 pdp
p2
q m pm
KA p 2 2 p1
2
L [ ]
qm pm 2
KA
.
2 p1p2
.
p p2
q m p1 p 2 2
Thus it is evident for the linear system that gas flow and liquid flow
can be calculated by the same equation provided the rate is measured
of the mean pressure of the system
Radial flow
Figure 12
K
2rhp
Q
dr
dr 2Kh
q rw
re
pw dp
pe
r
2Kh p e p w
q
ln( re / rw)
qm pm = q.p= constant
q qm pm / p
dr 2kh pe
qm pm / p rw
re
dp
r pw
dr 2Kh pe
qm pm r rw
ve
pw pdp
r
2Kh( p 2 e p 2 w )
qm
2 lv
re / rw
2Kh
pe pw
qm
en re / rw
3–Spherical flow
Figure 12
1
A 4
r 2 2 r2
2
q
k 2
r2
p
dr
dr 2 k pe
rw
re
dp
r2 q pw
1 1 2
k
pe pw
rw re q
2Kpe p w
q
1 1
r re
w
rw re
1 1
rw re
2 k
pe pw
rw
q
For compressible fluids, the same equation can be used as:
2 k
pe pw
rw
qm
KAP
Qincomp 6.323
L
Where;
2-Radial flow
Kh ( Pe Pw )
Qincomp 7.08
Ln e
r
rw
Where;
Where;
2 Kh( Pe Pw )
Qincomp
r
Ln e
rw
Where;
The foregoing flow equations were all derived on the basis of one
continuous value of permeability between the inflow and outflow face. It
is seldom that rocks are so uniform – most porous rocks will have space
variations of permeability.
Figure 13
K . A.Pt K Ap1
Qt av , Q1 1
L L1
K Ap2 K Ap3
Q2 2 and Q3 3
L2 L3
Qt L Q1 L1 Q2 L2 Q3 L 3
K av A K1 A K2 A K3A
L L1 L 2 L 3
Kav K1 K 2 K 3
L
Kav n i 1
Li / Ki
Figure 14
The total flow rate is the sum of the individual flow rates,
qt =q1+q2+q3
K av K i Ai / At
if all beds are of the same width , their areas are proportional to
their thicknesses.
k av K i Ai / hi
variable, q and h
Figure 15
q t q1 q 2 q3
7.08K av
ht
( Pe Pw ) 7.08 K1 h1 ( Pe Pw )
re r
Ln Ln e
rw rw
K av
ht K1 h K 2
h2 K 3
h3
K h
K av i i
hi
This is the same as for the parallel flow in linear beds with the same
bed width.
Example:
Calculate the average permeability of the depth
permeability data given below:
Depth, ft K, md
5012 – 13 500
5013 – 16 460
5016 – 17 5
5017 – 19 235
5023 – 24 210
5024 – 29 3
Solution:
K h
K av i i
hi
(500)(1) (460)(3) (5)(1) (235)(2) (360)(4) (210)(1) (3)(5)
11
327md
Figure 16
q, and h
Constants :
P, K and r
Variables :
2 K av h ( Pe Pw )
qt
r
Ln e
rw
2 K av h ( P1 Pw )
q1
r
Ln 1
rw
2 K av h ( P2 Pw )
q2
r
Ln 2
rw
2 K av h ( P3 Pw )
q3
r
Ln 3
rw
re r1
q Ln q Ln
rw rw
2 K av h 2 K1 h
r2 r
q Ln q Ln e
r1 r2
2 K2 h 2 K2 h
re
Ln
rw
Kav
r r r
Ln 1 Ln 2 Ln e
rw r r
1 2
K1 K2 K3
Example:
Bed 1 2 3 4
K, md 25 50 100 200
Solution:
ln re rw
Kav
(ln ri / ri 1) / Ki
ln(2000 / .05)
30.4md
ln
250 / .05 ln 500 / 250 ln 1000 / 500 ln
2000 / 1000
25 50 100 200
Example:
A well of 6 bore is drilled in to a pay of 500 md on a
spacing of 40 Ares (re = 750 ft). Assume that the mud
penetrated for a distance of one foot in to the pay and that
experiment indicates that the pay will be reduced in
permeability to a value of 10 % of its original. It is desired to
know to what average permeability the well system is reduced
by the mud penetration.
Solution:
The reduced permeability =0.1x500=50md
Example:
A well of 40 acres spacing with a 6 ft bore produce 50
bb1/day of fluid from a pay of 50 md permeability before
acidizing and 90 bb1/day after acidizing. If the acid had been
injected to penetrated 15 ft into the formation, from these data
can you calculate the permeability increase which would have
had to occur in the acidized section to produce the observed
increase in the production rate.
Solution:
Channels
Considering Poiseulle's equation for fluid conductivity in capillary
tubes,
r 4 P
Q
8 L
A r 2
r 2 P
Q A
8 L
P
Q A
K
L
r2
K
8
r2
K 9
12.5 106 r 2
8(9.869) 10
Example:
Consider a cube of reservoir rock one foot on the side and
having a matrix permeability of 10 md. If a liquid of one cp.
viscosity flows linearly through the rock, under a pressure
gradient one psi per ft, the rate of flow will be:
Solution::
Q 1.127(0.01) 11 0.01127bbl / day
If a circular opening 0.01 ft diameter traverses the same rock , then the
total flow rate can be considered to be the above value (Q1) value plus the rate
of flow through the circular opening (Q2)
0.005 1
2
Q2 1. 127[80 10
.005] 0.00122
6 2
bb1 / day
144 1
Qt 0.01127 0.00122 0 .012491 bb1 / day
Example:
A core of very low permeability (0.01 md). It contains
fracture of (0.005") wide and 1 ft in lateral extent per square
foot if the core. Assume that the fracture is in the direction in
which flow is desired.
Solution:
KiAi
Qaw
Ai
0.00001
144 12 0. 005
54.4 106
0.00512 0.005
2
562md
144
Figure 17
The tested samples are usually cut with a diamond drill from the
well cores in a direction parallel to the bedding plane of the formations.
Fig18 samples are mounted in such a way that the sides of the
samples are sealed, and a fluid pressure differential can be. Applied
Q/A p1 p 2 / L
K
for viscous flow condition : the data should plot a straight line
passing through the origin. Turbulence is indicated by curvature of the
plotted points.
The slope of the straight line portion is equal to (k/μ) from which the
absolute permeability (k) can be computed.
In case of using liquids in stead of air. Data are taken only at one
flow rate .
Figure 18
Figure 19
Figure 20
This is said due to the gas slippage. The gas slippage is a function
of the mean pressure and the type of rock. The phenomena of gas
slippage occurs when the diameter of the capillary openings approach
the mean free path λ
.
The mean free path of a gas is a function of the molecular size and
the kinetic energy.
4C
K g K l (1 )
r
Where;
Kg
: Gas permeability
b
K g K l (1 )
Pm
Where;
Pm Kg
: Mean flowing pressure of the gas at which was
1
Pm
observed,
1
b ,
b : Constant for a given gas and rock, r
Figure 21
Note that for each gas a straight line is obtained for the observed
permeability as a function of the reciprocal of the mean pressure of the
test.
The data obtained with lowest molecular, (H2), weight gas yield the
straight line with greater slope, indicative of a greater slippage effect.
Kl
b
The slope of the straight line, m, is equal .
The constant b depends on the mean free path λof the gas and
the size of the openings in the porous medium.
2-Clay content
Many clays act as cementing minerals or are as part of the rock
matrix. These minerals or are as part of the rock matrix. These minerals
are usually very complex in molecular structure and posses the ability to
attract and hold +ve ions such as hydrogen , sodium or calcium. These
Figure 22
Fig (32) shows such a decrease in flow rate with fresh water flow
thus permeability determination with fresh water on a core containing
clays will be less than that in the natural state.
3-Reactive liquids
alter
5-Grain size
It was found that the rate of fluid flow is proportion al to the square
of the grain diameter , hence the finer sand the smaller the permeability.
6-Mode of packing:
The effect of packing as a factor which influence permeability can
be introduced as:
K = 10.2 d2 / c
Hexagonal 26 52.5
30 52.5
40 20.3
cubic 45 23.7
It was note that Darcy's low for flow in porous media. was
predicated upon the condition that the porous media was entirely
saturated with the flowing fluid such a circumstance does not often exist
in nature , particular in petroleum reservoir. Gas or oil is usually fauna
coexistent with water and frequently gas, oil and water may occupy
together the pores of reservoir.
Q L
Ko o o
A p
Effective permeability to oil ,
Q L
Kg g g
Ap
Effective permeability to gas ,
And
Q L
Kw w w
Ap
Effective permeability to water ,
Relative permeability
Figure 23
a) Rapid fall in
permeability to
wetting – phase
(Krw) as the
wetting phase
saturation first
Interpretation
Figure 24
Figure 25
To the wetting phase (Krw = 0). Thus the total fluid capacity
of the tubes would be decreased.
There are many instances when not two fluids but three fluids exist
in rock simultaneously as oil, water and gas.
Figure 26
Point 1 2 3 4 5
So 20 20 40 60 40
Sw 20 40 40 20 60
Sg 60 40 20 20 0
Figure 27
Figure 28
Figure 29
Figure 30
1-Rock wettability
Figure 31
The relative
permeability values are
affected by the change in
fluid distribution brought
about by different wetting
characteristics.
Figure 32
Figure 33
Curve 2 : Dolomite.
Figure 34
Kg
Ko
The two most useful permeability ratios are ( ). The relative
Kw
Ko
permeability to gas with respect to that to oil and ( ), the relative
permeability to water with respect to that to oil, it is understand that both
quantities in the ratio are determined simultaneously on a given system.
The relative permeability ratio may vary in magnitude from zero to
infinity.
Consider a system flowing gas and oil. At high oil saturation, the
Kg
Kg Ko
flow of gas is zero, and hence, is zero.
Kg Ko
As the gas saturation increases, increase but decrease
Kg
Ko
and therefore increase. When the oil saturation becomes
Kg
Ko Ko
sufficiently low, approach zero and the value of approach
Kg
Ko
infinity. Fig (35) is a typical plot of versus the oil structure. To
Kg
Ko
give linearity, was plotted against oil structure saturation or
liquid saturation on a semi–log paper, Fig (36). It has become common
usage to express the central straight line portion of the relationship in the
analytical form:
Kg
log( ) log a b
So
Ko
Where;
1-Laboratory method:
Figure 36
A small core is
choose and prepared
for the test. It is
mounted in a
2-Field determination
Due to Darcy's equation for gas and oil, the relative permeability
ratio can be defined by the following equation:
Kg Pg
Qg A ( g )( L)
Qo K P
A( o )( o L )
g
Figure 37
Qo Qg
If the and are expressed at reservoir condition and if it is
Pg Po
assumed the pressure drops ( and ) are the same,
Qg
R p rs
Qo
K
R p g o o rs
g
Ko g
K g g
g
( Rp rs )
K o o
o
Np
S o (1 )( o )(1 S wi )
N Boi
Example:
Given the following data:
Solution:
Kg
For each pressure step calculate So and K using equations;
o
K g g
g
( R r )
K o o
o p s
And,
Np
S o (1 )( o )(1 S wi )
N Boi
Kg
At So = 0.648 , K = 0.01
o
Kg
e bS o
a
Ko
e 0 .516b
0.1 a
And,
e 0 .648b
0.01 a
So,
ln10 0.132b
Kg
ln( ) ln a b
So
Ko
ln(0.1) ln a 8.988
ln( a) 8.988 (2.3) 6.688
a 803
Relative permeability data are essential to all flow work in the field
of reservoir engineering. Just a few of its uses are mentioned
engineering. Just a few of its uses are mentioned here.
Consider two immiscible fluids (water and oil, fluid commonly found
in petroleum reservoirs). A water molecule which is within the body of
the water will uniformly attached in all directions, by an attractive force,
by other molecules and thus the resultant force on the molecule will be
zero
Figure 39
A water molecule at the interface has force acting upon it from the
oil lying immediately above the interface and water molecules lying
below the interface. The resulting forces are unbalanced and give
rise to interfacial tension.
Figure 40
Surface tension
The forces that are active at the interface between two immiscible
liquid faces
Figure 43
At wo cos
wo cos 90 0
Figure 45
The rise in height, Fig (46) is due to the attractive force (adhesion
tension) between the liquid and tube that tends to pull liquid upward.
This total upward force is balanced by the weight of the liquid column
It is noticed from the shape of the interface between the two phases
in the tube that the pressure in the liquid phase beneath the interface (A)
is less than above the interface.
Figure 46
Fig (47) shows the condition of two liquid phases compared with
case of liquid and gaseous phase.
Figure 47
At the point B' within the capillary the tube pressure is the same as
that. At the point B outside the capillary, which pressure is atmospheric.
At the point A' just under the meniscus with in the capillary, the
pressure is equal to that at B' within the capillary minus the head of
water.
Now, at the point A, just above the meniscus within the capillary, the
pressure is the same as that at B.
PA PA'
Where;
Pw Pnw
and are the wetting phase pressure (water) and the non
w
wetting–face pressure (air), and is the water density.
As mentioned before;
Pc w
gh
(6)
Pc ( PB o
gh ) PB ' w
gh
( w o )
gh
(8)
2 cos
Pc
gh
r (9)
1 1
Pc { }
R1 R2
(10)
Where;
R1
and
R2
are the radii of the curvature of the interface and is
R1
the interfacial tension between the two fluids. The values of and
R2
expresses the amount of fluid that is contained at the contact, or the
saturation of that fluid within the porous body if the number of such
contacts are considered. It is practically impossible to measure the
1 1 1
Rm R1 R2
(11)
R1 R2
Referring to equation (10), it is seen that if and both
decreased (i.e. the quantity of the wetting–face decreases); the
magnitude of the capillary pressure would in turn have to increase in
size. It is therefore possible to express the capillary pressure as a
function of rock saturation when two immiscible fluids are used within the
porous medium. In other words, smaller water saturation gives a greater
capillary pressure.
First, it is assumed that the reservoir rock was originally filled with
water.
Figure 49
Figure 50
There is no sharp line between oil and water level, Fig (51). The
depth internal within which the saturation (S w) changes from 100% to the
irreducible saturation (Swi ) is known as the "transition zone", thus, the
water–oil contact con not be said to exist at a definite depth, but rather
within a range of depth.
Figure 51
Figure 52
Figure 53
Procedure
The porous diaphragm must first be completely saturated with
water.
Solution:
Pc Sw
10 100
20 100
30 94.7
40 85.2
50 71.3
Figure 55
Figure 56
2 cos
J effect PB PA from
to
r A B
Figure 57
There are now two interface, the pressure drop across each
interface is the same but opposite in the direction to the other, there is
no net pressure necessary to prevent motion, the total pressure drop
between the point A and B is zero as seen by;
2 cos
2 cos
J PB PA ( ) A ( ) B 0
r r
Now if either term of this equation were modified, the net pressure
drop between point A and B would not be zero.
1 1
PB PA 2 cos ( )
rA rB
rB rA
PA PB
Figure 58
2
PB PA (cos A cosB )
r
Figure 59
Figure 60
2
PB PA (A
cosA B
cosB )
r
If B
cos B A
cosA
PA PB
A positive pressure drop from A to B would be necessary to initial
flow to the right.
1-contact angle
A contact angle of zero would indicate complete wetting by the
dense phase.
Figure 61
h
r
b
Sessile drop ratio of one indicates complete non-wetting the solid
surface by the dense phase.
Where;
PTo .a = threshold pressure of core for air to enter when core initially
saturated with oil.
Gravity force: the force tends to expel water from the rock.
It is also the force that causes oil to force water out of the rock
pores and it is opposite by the capillary force.
The laboratory capillary pressure test starts out with 100% water
saturation in the core and zero capillary.
Fig (63) shows the distinction between the free water level and the
original water oil contact.
w.a cosL 2
2 L cos L
( Pc ) lab
r r
o.w cosR 2
2 R cos R
( Pc )Re s
r r
If L R 180
Pc R Pc L R
L
Example:
Calculate the reservoir capillary pressure from the
following laboratory data:
Solution:
24
( Pc ) R ( Pc ) L R 18 6 psi
L 72
To convert the capillary pressure saturation data to height
saturation it is only necessary to rearrange the equation:
Pc
gh
144( Pc ) R ( w o ) g
h
144( Pc ) R 144 ( Pc ) R
h
( w o ) g g
Where;
h : ft, w , o : lb / ft 3 , Pc : psi
Example:
Calculate the height of the saturation plane for the last
example.
Solution:
144 ( Pc ) R 144 6
h 58 ft.
( w o ) (68 53)
Example:
Calculate the water saturation profile (depth versus Sw),
for the following laboratory capillary pressure data,
considering that the initial WOC is located at depth of
3788 ft.
Sw Pc
100 0
100 1.9
85 2.02
72 2.34
58 2.74
52 3.25
45 3.60
39 4.57
35 5.44
32 7.20
30 10.00
30 10.00
% Psi
Also given;
w 63 .8lb / ft 3
o 54.7lb / ft 3
a .w 70 dyne / cm
Solution:
( Pc ) R ( Pc ) L w .o
w.a
28
( Pc ) R ( Pc ) L 0.4( Pc ) L (1)
70
144 ( Pc ) R 144
h
( Pc ) R
w o 63.8 54.7
h 15 .82 ( Pc ) R 6.328( Pc ) L (2)
Sw ( Pc ) R h D
Example:
Calculate the water saturation profile at a well drilled into
a reservoir has he following capillary pressure data for this
cores of different perm abilities;
Solution:
After deciding the suitable capillary–saturation curve:
Calculate ( Pc ) R for each foot of depth as the previous example.
h 3800 D
( Pc ) R
15.82 15.82
Calculate ( Pc ) L .
(P ) 3800 D 3800 D
( Pc ) L c R
0 .4 0.4(15.82) 6.33
Read
S w for each ( P ) from curves P – S for each core (1,2and
c L c w
3)
Depth H ( Pc ) L Curve Sw
Example:
For the above example, estimate a capillary pressure curve
for 40 md core.
Solution:
Plot Pc vs. K for the three cores on log–log paper for each saturation
level given straight lines. For any K as 40 md, draw a horizontal line
and record Pc vs. S w that gives the new curve, Fig (64)
Figure 63
Pc Sw
1.7 100
2.5 80
4 60
2cos
Pc
r
2cos
r
pc
(1)
r 4 p
Q
8L
vi
r2
P
Q
8 L2
Q
cos
2
vi p
2 L2 ( pc ) 2
(3)
cos
2
p
vi
Qt n
2
2 L2 pc (4)
KAP
Qt
L (5)
(cos ) 2 n vi
K
2A
L i1 ( Pc ) 2
(6)
vi
As the volume of each capillary can expressed as a function of
Si vT
( ) of the total void volume of the system.
vi
S i
vT
,
v
T
A L
vi S i
vT S i
A
L
(
cos ) 2
n Si
K
2
i 1 Pc
2
i
(7)
dS nw
100
K 10 .24(
cos) 2
2
S 0
Pc
(8)
Where;
K : md.
: Fraction.
Pc
: psi.
: Dyne/cm.
: Contact angle.
Purcell assumed that the contact angle for mercury was ( = 140o)
and that the interfacial tension of Hg = 480 dyne/cm.
Pc Pc S
The integral is found by reading values of from ( – ) curve at
1
( 2
)
Pc
various saturations, calculating value of and plotting these values
as a function of corresponding saturation.
S w dS
K w 10.24(cos) 2
0 P2
c (9)
Where;
Kw
: the effective permeability to the wetting phase at any
Sw
saturation value ( ).
K nw
The effective permeability to the non-wetting phase ( ) can be
calculated in a similar fashion as equation (9) by assuming that the non-
wetting phase is contained in tubes or pores, free of the wetting phases;
100 dS
K nwt 10.24(
cos)
2
S S w Pc 2
(11)
K nwt
The relative permeability to the non-wetting phase ( ) is given
by;
100
K S S
dS P c
2
K nwt nw 100w
K dS
P c
2
0
(12)
If 0.216 , 480dyne / cm ,
140 and 23%
Calculate;
K and ( K rw vs. S w ).
Solution:
dSSw
1 dS 0 P2
S Hg Pc
Pc
2
Pc
2 K rw 100 c
dS
0 Pc 2
0 1.6 0.391 1
10 2.8 0.128 2.595 0.578
20 3.1 0.104 1.160 0.392
30 3.5 0.082 0.930 0.239
40 4.2 0.067 0.745 0.118
50 5.5 0.029 0.480 0.0405
60 12.2 0.007 0.180 0.0113
70 20 0.003 0.05 0.0032
80 30 0.001 0.020 0
6.16
Where;
K : md.
S : Percent.
: Percent.
Pc : atm.
: Dyne/cm.
K 4.75 10 6 (480 0.766)2 0.216 6.16 19 .65md
Figure 64
1) Permeability
Poiseuille (1846) derived an equation which relates the rate of flow of an
incompressible fluid of known viscosity through a horizontal straight
capillary of length (L) and radius (r) under the influence of a pressure
differential ( P ) as follows;
r4
P
Q
8L
(–1)
Where;
P ( P1 P2 ) : Dyne/cm2.
Figure 65
Where;
n r 4
P
Q
8 tL
(–2)
Figure 66
1.013 A
KP 8
n r 4
P
Q 10 Q
L 8 tL
nr 4
K 10 8
8At (-3)
Where;
P : Dyne/cm2.
n : Number of capillary tubes.
K : Darcy.
2) Porosity
Volume porosity (
v
) of this bundle of capillary tubes is
expressed as the pore-space volume per bulk volume. It is
given by;
Vp n r 2
L
t n r 2
v t
V A L A
(-4)
Surface porosity ( s ) is the cross sectional area of all
pores that are intersected by a plane surface and
expressed as a fraction of the total cross- sectional area
(A) of the rock.
n r 2 (-5)
s
A
Oil Reservoir Engineering (115)
To aid better in the understanding of fluid flow in rocks,
correlations among porosity, permeability, Surface area, pore
size and other variables have been made.
n r 2 r 2
K 108
A 8 t
By combining this equation with equation (-4);
1 r 2
K 2 108
8 t
By solving for the mean pore radius (r');
r ' 8
Kt2 10 4
(-6)
Specific surface
Unit volume may be the solid volume in which case the specific
surface is represented by (Ss). The unit value may also be pore
space, in which case the specific surface is represented by (Sp).
n( 4 r 2 )L t 3
SS
n( 4 3 r 3 )L t r
(-11)
And;
n( 4 r 2 )L t 3 1
SP
( 4
n r 3 )L t r
3 1
(-12)
r 8
Kt2 104
2
SP
And r
2 8K
t2
r 104
SP
K 2 108
2
t
2
SP
darcy (-8)
Or;
3
K 2 108
2 S S (1 ) 2
t
2
darcy (-9)
r2 P
vi
8 L
(-10)
r2 P
vi
ts L
(-11)
Where;
ts
is the shape factor, which has an average value of 2.5
(t s 2.5)
.
KP
viupp 10 8
L
(-12)
Q Vapp
Aapp Vact
Aact
A L
t PV
Vapp Vact act Vact Vact
Aapp L
t BV t t
VDarcy V pois.
t
K
P 8 r2P
10
L
ts L t
r2
K 108
ts t
As;
t s 2.5
r2
K 108
2.5
t (-13)
K 2 108
2.5
tSP
(-14)
Or;
3
K 108
2.5
t (1 ) 2
SS 2
(-15)
2.5t 2t 2
t 1.25 (-16)
Grain shape ts
Spherical 1.00
Well-rounded 1.02
Worn 1.07
Sharp (sub rounded) 1.17
Angular 1.27
ts
Introducing the shape factor ( ) into Kozeny's equation we
obtained for unconsolidated granular material.
K 108
2.5
ts
tSP 2
darcy (-17)
3
K 108
2.5
ts
tS S 2 (1 ) 2
darcy (-18)
SP SS
Where and are respectively the specific surface based on
the pore volume and the soil volume, obtained by the relation
1
SP
( r ), previously defined.
Consider the box like container, Fig (68) is completely filled with
salty water and resistivity Rw ohm-meters.
Figure 67
Let the length of the box be L meters, and its cross sectional area
be A meters2.
L
R Rw
A (1)
L
E I
R I
Rw
A
P
q A
K
L (3)
Now consider that the box is completely filled with clean sand and
saturated to 100% with salt water of the same resistivity as before, Fig
(69). The resistance of the box will be increased by a factor called the
resistivity formation factor "F" which is always larger than one.
Figure 68
A new and smaller current (I') will now flow such that;
L
E I '
Ro
A (4)
I ' I Ro Rw Ro
As , then , where is the resistivity of a unit
volume of the box that is completely filled with the porous medium and
Rw
fully saturated with a conductive fluid of a resistivity .
R
F o
Rw
(5)
a
F m
(6)
0.81
F 2
in sands, and
F 2
in compacted sands.
0.62
F 2 .15
(7)
The Humble formula and the Archie formula for several vales of
( m ) are represented graphically in Fig (3).
When oil and gas, which are non conductors of electricity, are
present, with in a porous medium together with a certain amount of salty
RT
Resistivity of a partially saturated porous medium ( ) depends
not only on the value of ( S w ) but also on its distribution within the pore
space.
Porosity type.
RT
Fig (69) shows how the ratio Ro varies as a function of saturation.
Figure 69
Curve (3) is for oil-wet sand in which case the value of (n) is
available with saturation and the degree of wetting.
Sw
The general formula which relates connate water saturation ( )
RT
and the true resistivity ( ) is Archie formula which may be written in
the following forms;
Ro FRw n
S w n n m / RL
Rw
Rt Rt
(8)
Tortuosity determination
For consolidated rocks where the porosity may be represented by
tortuous capillaries of actual length (Lt) and ending in number (n) in a
L
R Ro
A (9)
L
t
Rw
n(r2 ) (10)
L
t2
R Rw
A
L Lt2
Ro Rw
A
A
t2
Ro Rw
t2
Ro F
Rw
t 2 F
(12)
(1 S wi )
t 2 F
(13)
te
The concept of effective tortuosity ( ) takes in another aspect
Sw i
when partial water saturation ( ) prevails, for in this situation the non-
wetting phase is non conductive of electricity. An effective tortuosity can
then be written as;
( S w S wi )
t e Fe
2
Where;
Fe
: Effective formation value
F
Fe
The ratio is written as:
I Sw
When is the resistivity index at the partial water saturation ( ),
also the following relationship can be written;
2
F Ro t S w S wi
Fe Rt te 1 S wi
(14)
r 8
Kt2
(1 S wi ) 10 4
(15)
Figure 70
Where;
(1 S wi ) n(
R2 r 2 )L
t
(1 S wi )
R2
r
2
n t (17)
But;
8K t2
r
2
10 8
(1 S wi )
(15)
(1 S wi )
R2
8K
t2 10 8
n
t
(1 S wi )
2
(1 S wi ) 2
n
t3
8
K
R210 8
Fh
Fh 2
(1 S wi )2
n
t3 (18)
Where;
Sw
At partial saturation in the wetting-phase fluid ( ), an effective
Fhe
hydraulic formation factor ( ), may be expressed as;
2 ( S w S wi ) 2
Fhew
ne w (te w ) 3
(19)
Where;
ne w
: is the number of capillaries occupied by the wetting-phase.
te w
: is their tortuosity.
2 (1 S w ) 2
Fhenw
nn w (t n w ) 3
(20)
Where;
nn w
: is the number of capillaries occupied by the non wetting-
phase.
tn w
: is their tortuosity.
S w S wi
1 S is
The ratio called the free wetting-phase saturation
wi
S wf
( ), and when substituting in equation (23) and equation (23) we
have;
3
n
t
K rw
S
2
ne
t ew wf
w
(24)
And
nnw
t ew (25)
The formulas (24) and (25) are fully general and are valid whether
the saturation changes are by imbibition or by drainage. They are not
new
useful without elimination of the number of capillaries involved ( n ,
nnw tew tnw
and ) and the tortuosity coefficients ( t , and ) from them in
order to obtain practical relative permeability formulas.
* Imbibition direction
When the wetting phase is increased from the irreducible saturation
S wi
( ), all the capillary acquire simultaneously a movable wetting-phase
saturation. Hence, we have;
n = new =
nnw
(26)
t
K rw ( )3
2
S wf
t ew
(27)
*Drainage direction
When The wetting-phase saturation is decreased because of the
injection of a non-wetting phase starting with too per cent wetting-phase
saturation, the largest capillaries are originally occupied by non wetting
fluid, then the next largest, and so on
n = new =
nnw
(29)
new
It is no longer possible to eliminate ( n and ) from equation (24)
t
tew
and after substitution of ( ) from equation (14);
n t 3
K rw(drainage) ( )( )
S wf 2
new tew
(24)
n Ro 3 2 1
K rw (drainage) ( )( ) S wf 2
new Rt
(30)
K rw (drainage)
From laboratory investigation, it has been shown that (
K rw (imbibition )
and ) show very little deviation from one another and that
such deviation may be considered to be due to errors of measurements.
n = new (31)
t = tew (32)
Therefore;
K rnw(imbibition) (1 S wf ) 2
(33)
1 S wf
The expression ( ) represents the free non wetting-phase
saturation. Considering the trapped non wetting-phase saturation,
S nwt S wf
( ), the term ( ) may be expressed as;
S S
S wf w wi
1 S wi Snwt
(34)
K rnw
Hence, the formula for ( ) should have the form;
2
S w Swi
K rnw(imbibition )
1 S S
1
wi nwt
(35)
Sw Snw S wi
Let , and represent the specific surface of wetting, non
wetting and irreducible wetting-phase on a pore-volume basis. The
Sw Snw S wi
volume of the pores having a surface , and are the
S w S nw Swi
reciprocal of , and .
1 1 1
S wi S w S nw
(35)
2 2 2
r r r
S wi wi Sw w Snw nw
and and (36)
8 K nwtnw 2
rnw 10 4
(1 S w )
(38)
8K t2
rwi 104
(1 S wi )
(38)
rw tew K rw
rwi t S wf
(39)
And;
rnw t K rnw
nw
rwi t (1 S wf )
(39)
t Krw t
ew Swf nw K rnw (1 S ) 1
t t wf
t
K rnw K rw 2 S wf 2
tnw 1 1 1 1
2 (1 Swf ) 2 1 ew
t t
t tew 1
K rnw 2
1 1 1
t
(1 S wf ) 21
t rw
K 2
S wf
2
nw
3
1
2
t
K rnw 2
1
t
(1 S wf )
1
2 ew
1
t
t
t
t
S wf
2
Swf
1
2
nw
ew
2
t
2
1
tew 2
K rnw
1
t (1 S wf )
1 S wf 2
nw
t
2
t
2 1
Ro 4
K rnw 2 S wf 4
1 1
t (1 Swf ) 1
nw Rt
t tnw
(41)
Hence, the formula for the relative permeability to the non wetting
phase in the drainage direction is;
Ro
Sw
Rt
1
K rw S w3
S wf 2
(Drainage or imbibition) (44)
1 1
K rnw(drainage ) (1 Swf )(1 S wf 4
Sw 2 )2
(45)
2
S w S wi
K rnw(imbibition )
1
1 Swi S nwt (46)
Example:
Given the following data:
Sw 20 30 40 50 60 70 80 90
Solution:
1) For imbibition direction
According to equation (28) and equation (34);
Ro 3 2 1
Krw ( ) S wf 2 ,
Rt
and
2
Sw S wi
K rnw
1
1 S S
wi nwt
Sw Ro S wf 3 1 Ro 3 2
Ro 2 1
Rt R
S wf 2
K rw S wf 2 ( )
t Rt
Sw S wf 1 Swf Krw (1 S wf ) 2
2
Ro
1
1
1
4
S
1 Swf
4 o
4
Sw 1 Swf 1 R
4
R K rnw 1 S wf R
t
wf
t
20 1.000 0.000 0.000 1.000
30 0.875 0.595 0.525 0.417
40 0.750 0.707 0.637 0.226
50 0.625 0.782 0.724 0.119
60 0.500 0.840 0.795 0.056
70 0.375 0.890 0.856 0.021
80 0.250 0.930 0.910 0.006
Example:
K rnw(imb) (1 S ef )2
1 1
K rnw(drainage ) (1 Sef )(1 Swf 4
S w 2 )2
Solution:
(1) Imbibition direction
K rw(imb) (1 S wf ) 2
1
Sw Sw 3 Swf 2 K rw (imb dra ) S wf
Sw S
wf
1
4 Sw
1
2 1 S wf
1
4
Sw
1 2
2 K rnw
Fig (71) shows the above K rw and the K rnw obtained for
the example.