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Section A
Four suggested answers labelled A, B, C, and D are given for each question. Choose one
correct answer.
1
Relative abundance / %
m/e
14 16 28 44
Which of the following substance is expected to give the above mass spectrum?
[Relative atomic mass: H, 1.0; C,12.0; N, 14.0; O,16.0]
A CO2
B C3H8
C N2O
D Mixture of N2 and O2
2 The diagram below represents the unit cell of a body centred cubic structure. How many
lattice particles are there per unit cell?
A 2
B 3
C 5
D 9
A
1s 2s 2p
B
1s 2s 2p
C
1s 2s 2p
D
1s 2s 2p
962/1 [Turn over]
This question paper is CONFIDENTIAL until the examination is over CONFIDENTIAL*
Confidential* 4
4 The first ionization energies for a series of elements with increasing proton number
are as follows:
632, 661, 648, 653, 718 kJmol-1
This series of elements is:-
A Group 1
B Group 14
C Group 18
D d-block
5 Which of the following statements correctly explains the decrease in ionic radii for the
elements of Period 3 from sodium to aluminium?
A Copper
B Calcium
C Sodium
D Potassium
7 Which of the following pairs of compounds has the same molecular shape?
9 A table
The AlClbelow
3 and BCl
shows
3 the experimental results obtained for the following reaction:
B CO2 and SO2
2XO2(g) + O2(g) 2XO3(g)
C BeCl2 and H2O
D CH3+ and NH4+ Partial pressure (atm) Relative rate
XO2 O2
1.0 1.0 2a
8 The thermal decomposition of nitrogen monoxide as shown below isaa second order
0.5 1.0
reaction: p 0.5 ½a
1.0 0.5 a
2NO(g) N2(g) + O2(g)
What is the value of p in the table above?
Which of the following is true of the reaction above?
A 0.20 atm
A The unit of the rate constant is s-1.
B 0.25 atm
B The rate is quadrupled when the concentration of NO is doubled.
C 0.50 atm
C The half-life of the above reaction is independent of the initial concentration of NO.
D 0.75 atm
D A straight line graph is obtained when rate is plotted against the concentration of NO.
0.10 mol of ammonium sulphide was heated in a 2.0 dm3 flask. When equilibrium was
obtained, the total pressure in the flask was 0.63 atm. Calculate the equilibrium constant, Kp
for the above reaction.
A 0.019 atm3
B 0.037 atm3
C 0.056 atm3
D 0.074 atm3
11 For the following reaction: X2Y(g) 2X(g) + Y(g), the numerical value of Kp at
different temperatures is as follows:
12 The molecules ammonia and boron fluoride react together to form an adduct as follows:
A Ligand
B Lewis base
C Lewis acid
D Bronsted-Lowry base
13 The solubility product, Ksp for magnesium hydroxide in pure water at 250C is
2.0 x 10-11 mol3 dm-9. What is the solubility of magnesium hydroxide, when excess solid
magnesium hydroxide is shaken with 1 dm3 of 0.2 mol dm-3 potassium hydroxide solution?
14 What will be the concentration of a sulphuric acid solution if the hydroxide ion
concentration is 5.0 x 10-12 mol dm-3 at 250C?
[ Ionic product of water, Kw = 1.0 x 10-14 mol2 dm-6 at 250C]
15 When 250 cm3 of an aqueous solution of an organic acid Q of concentration 20.0 g dm-3 is
shaken with 100 cm3 of ether, the mass of Q extracted is 2.2g. After this first extraction, the
aqueous solution is again shaken with 100 cm3 of fresh ether. Calculate the mass of Q
extracted by this second extraction.
A 0.51 g
B 1.23 g
C 1.96 g
D 2.20 g
16 The standard electrode potentials of Ag+(aq)/Ag(s) and Zn2+(aq)/Zn(s) are +0.80 V and
-0.76 V respectively. Which of the following conclusions can be drawn from these data?
C Pt electrode in 1 mol dm-3 Fe3+ and 1 mol dm-3 Fe2+ against a standard hydrogen
electrode.
D Fe electrode in 1 mol dm-3 Fe3+ and 1 mol dm-3 Fe2+ against a standard hydrogen
electrode.
18 During electrolysis under suitable conditions, 0.015 mol of chromium is deposited on one of
the electrodes when 0.090 mol of electrons is passed through a chromium-containing
electrolyte.
Which of the following substances could have been the electrolyte?
A CrF4
B CrF5
C CrCl3
D Na2Cr2O7
19 The enthalpy changes for two reactions are given by the equations below,
3
2Fe(s) + O2(g) → Fe2O3(s) ∆HӨ = -822 kJ mol-1
2
1
C(s) + O2(g) → CO(g) ∆HӨ = -110 kJ mol-1
2
A +492 kJ
B +712 kJ
C -492 kJ
D -712 kJ
20 P, Q and R are Period 3 elements. The oxide of P reacts with hydrochloric acid while the
oxide of Q reacts with potassium hydroxide. The oxide of R reacts with both sulphuric acid
and sodium hydroxide. What is the order of increasing proton numbers for these elements?
A P<Q<R
B Q<R<P
C P<R<Q
D R<P<Q
A The reactivity of the Group 14 elements increases when going down the group.
B The boiling point of the Group 14 tetrachlorides increases when going down
the group.
C The oxides of the Group 14 elements becomes more acidic with increase in
proton number.
D The +2 oxidation state of the Group 14 elements becomes more stable when
going down the group.
24 When excess of aqueous ammonia is added to aqueous copper (II) ion, the
[Cu(NH3)4]2+ species is formed. Which of the following statements is true?
25 The scheme below shows the reactions between potassium iodide with hot
concentrated sulphuric acid, and with aqueous silver nitrate, as well as the solubility
of the precipitate Y in concentrated aqueous ammonia.
Conc. H2SO4
heat Vapour X
KI(s)
AgNO3(aq) Conc. NH3
Precipitate Y Product
Which of the following is correct with regards to the colour of vapour X, colour of
the precipitate Y, and the solubility of Y in concentrated ammonia?
A Lead
B Copper
C Silicon
D Chromium
CH2ClCH=C(CH3)CH(Cl)CONH2
A 2
B 3
C 4
D 6
H
H
Br
H
C H+
Br -
C C C
CH3 +
CH3 CH3 CH3 CH3
H H
A Nucleophilic addition
B Nucleophilic substitution
C Electrophilic addition
D Electrophilic substitution
30 The equations below show the products formed in two separate experiments.
Cl Cl Cl
NO2
I + HNO3 H2SO4 +
II + Cl2
AlCl3
+ HCl
:
Cl
A CH3CH2CH2OH
B CH3CH2COOH
C CH3CH (OH)CH3
D CH3CH=CHCH3
32
33 Which
Which of
of the
the following
following reagents
compoundscanreacts
be used to hydrogen
with convert C2cyanide
H5OH totoCform
2H5Cl?
an optically active
compound?
A Chlorine gas
A Sodium
B HCHO chloride
C
B Sulphur
CH 3CHO dichloride oxide
D
C Dilute
CH3COhydrochloric
2CH3
acid
D CH3CH2COCH2CH3
(i) It is neutral.
(ii) It gives an orange precipitate with2,4 dinitrophenylhydrazine.
(iii) It evolves hydrogen chloride when treated with PCl5 in the cold.
A COCH3
B
OCH3
C=O
C CH2OH
C=O
D CH2OH
OCH2CO2H OCH2CH2OH
CH3 Cl
Cl Cl
MCPA 2,4-D
Which of the following reagents will be able to distinguish MCPA from 2,4-D ?
A Sodium
B Na2CO3(aq)
C acidified AgNO3
D Fehling’s solution
A C6H5COCH3
B C6H5OCOCH3
C C6H5CH2COCl
D C6H5CH2OCOCH3
37 Which of the following statements explains why C6H5NH2 is a weaker base than
CH3NH2?
A Amide
B Amino
C Hydroxyl
D Carbonyl
D H H
| │
―C=O + H2NNH― → ―C=NNH― + H2O
40 Which of the following pairs of polymer and repeating unit matches correctly?
A Polypropene ―CH2CH2CH2―
D Polystyrene ―CHCH2CHCH2―
│ │
Section B
For each of the questions in this section one or more of the three numbered statements 1 to 3
may be correct. Decide whether each of the statements is or is not correct. The responses A to D
should be selected on the basis of the following.
A B C D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2, and 3 are
correct. correct. correct.
41 Which statements about an element X with the electronic configuration: 1s2 2s2 2p6
3s2 3p6 3d6 4s2 is /are true?
42 Which of the following molecules can receive a pair of electrons to form a dative
bond?
1 AlCl3
2 NH3
3 C2H5OH
44 A mixture of phenylamine (boiling point 184oC) and water is heated until the mixture
boils. Which of the following statements is / are true?
A B C D
1 only is correct. 1 and 2 only are 2 and 3 only are 1, 2, and 3 are
correct. correct. correct.
45 The discharge at the cathode of 1.00 mol of gold ions from an aqueous solution of a
gold salt requires 2.90 x 105 C of electricity.
Which of the following conclusions can be drawn from the above statement?
[Faraday constant, F = 9.65 x 104C]
46 The first step in the Ostwald process for the manufacture of nitric acid is the
oxidation of ammonia. The typical conditions used are 4 to 10 atm and 1000 K.
47 Which of the following statements is / are true of the complex ion [Fe(C2O4)3]3-?
48 Which of the following statements about the reaction between bromine and ethene
is / are correct?
1 CH3CH2OH
2 C6H5CH2OH
3 C6H5OH
1 CH3CH2CH2CH(OH)CH3
2 CH2CH(OH)CH3
3 (CH3)3C—OH