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Write TRUE if the statement is correct, otherwise change the underlined word(s) to make the statement
correct.
1. The van der Waals equation with respect to the ideal gas law, adjusts the measured pressure down
by adding a factor that accounts for intermolecular attractions.
2. pThe heat of fusion of a substance is always larger than its heat of vaporization.
3. AlCl3 is both a Brønsted-Lowry acid and a Lewis acid.
4. The attractive force that keeps the protons and neutrons in the nucleus is called the weak nuclear
force.
5. Dipole-dipole forces are primarily responsible for the dissolution of NaCl in water.
6. The root mean square speed of a particle is inversely proportional to its molar mass.
7. The dissolution of NaOH is highly exothermic because the lattice energy is much smaller than the
combined heats of hydration of its ions.
8. Carbon-14 decays via positron emission.
9. The air inside a hot air balloon is denser than the air surrounding it.
10. Raoult’s law dictates that the solubility of a gas in a solution is proportional to the partial pressure of
the gas above the solution.
11. Glass is an example of a molecular solid.
12. F- is a stronger base than Cl-.
13. All amphiprotic substances are amphoteric.
14. The volume of 1 mole of an ideal gas at 250C and 1 atm is 22.4 L.
15. The meniscus of mercury in a capillary tube is upwards because cohesive forces are weaker than
adhesive forces.
Multiple Choice
1. Which of the following acids has the most ionizable hydrogen atoms per molecule?
A. H3PO4
B. H3PO3
C. H3PO2
D. Each one contains the same number of ionizable H atoms.
2. Which physical property decreases with an increase in intermolecular molecular forces?
A. Boiling point
B. Enthalpy of vaporization
C. Vapor pressure
D. Viscosity
3. The kinetic theory of gases assumes all of the following EXCEPT:
A. Gases are composed of particles in random, ceaseless motion.
B. The sizes of gas particles are negligible compared to the size of the container.
C. Gas particles do not attract or repel each other.
D. When gas particles collide, kinetic energy is lost.
4. The normal boiling point and vapor pressure at 25oC are measured for liquids in two flasks. Flask A
contains pure water and flask B contains a 1.0 M aqueous NaCl solution. Which flask contains liquid
with the higher boiling point? Which flask contains the liquid with higher vapor pressure?
Higher boiling point High vapor pressure
A. Flask A Flask A
B. Flask A Flask B
C. Flask B Flask A
D. Flask B Flask B
5. A sample of He gas in a flexible container at room temperature exhibits a certain pressure. What will be
the new pressure when the absolute temperature and volume of the container are both halved? The
pressure of the He will be ____________.
A. the same
B. doubled
C. halved
D. quadrupled
6. Which of these pure substances has the highest normal boiling point?
A. CH4
B. NH3
C. SiH4
D. PH3
7. A mixture of 0.50 mol H2 gas and 1.3 mol Ar gas is sealed in a container with a volume of 4.82 L. If the
temperature of the mixture is 50.0oC, what is the partial pressure of H2 in the sample?
A. 1.5 atm
B. 2.8 atm
C. 7.2 atm
D. 9.9 atm
8. According to the phase diagram of methanol shown below, which statement is correct?
Ranking
1. Rank in order of increasing basicity 0.10 M aqueous solutions of the following solutes.
2. Rank in order of increasing vapor pressure at a given temperature the following chemical species.
3. Rank in order of increasing observed freezing point of ice when the following solutes are added at
equal molality.