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Practice Test 3
PART A
Directions: Each set of lettered choices below refers to the numbered formulas or statements immediately
following it. Select the one lettered choice that best fits each formula or statement; ihen fill in the
corresponding oval on the answer sheet. In each set, a choice may be used once, more than once, or
not at all.
Note: For all questions involving solutions and/or chemical equations, you can assurne that the system is
in water unless otherwise stated.
Questions r5-r8
22. A precipitation reaction
Prac,tice Test 3
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PART B '"t*fi:.1
Examples:
II
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EX r. HCI is a strong acid BECAUSE HCI contains sulfur.
EX z. An atom of nitrogen is BECAUSE a nitrogen atom contains the same
electrically neutral numbei of protons and electrons.
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101. The N-N bond distance in N, is BECAUSE the atomic radius of H is smaller than the
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102. Cas-phase elements absorb or emit BECAUSE the energy levels that electrons can ::1::l
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only specific wavelengths of visible occupy in gas-phase atoms and molecules
light when excited by an electric are continuous. | :1e..1*-A
103. Elemental iodine has a higher boiling BECAUSE iodine forms stronger covalent bonds
point than elemental bromine than bromine.
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704. The boiling point of HrO is higher BECAUSE HrS has a greater molecular mass
than the boiling point of HrS than HrO
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105. The reaction of HCI (aq) and KOH (aq) BECAUSE it is a neutralization reaction between
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goes to completion a strong acid and a strong base. :f:r.r:.iiiii:
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106. Combining equal volumes of 0.2 M AgNO, BECAUSE the silver ion is rapidly reduced to silver
and 0.2 M HCI does not produce a metal, producing chlorine gas.
precipitate of AgCl
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107. When a hydrocarbon is combustedin aiq, BECAUSE air contains much more nitrogen tl-ran . .. .1,:.,.
carbon monoxide is the major product oxygen.
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l(A P tl[ N 341
Practice Tests
I II
108. If equal masses of sodium metal and BECAUSE the reaction requires twice as many atoms
chlorine gas are allowed to react, some of chlorine as sodium.
sodium will be left over after all the
chlorine is used up
109. Reactions happen faster at higher BECAUSE as temperature increases, there is also an
temperatures increase in the number of collisions with
the required activation energy for a
reaction to occur.
110. Candles can be safely stored at room BECAUSE the reaction that takes place when a
temperature/ even though their reaction candle is burned involves a decrease
with air is spontaneous at room in entropy.
temperature
111. A piece of zinc placed in a blue copper BECAUSE copper is a much more active metal
nitrate solution will displace the copper than zinc.
from the solution, producing
copper metal and a colorless Zn2*
solution
1L2. A wooden splint is set on fire and blown BECAUSE CO, gas contains oxygen.
out,leaving a hot, glowing end. When
the glowing splint is inserted into a
sample of purified CO, gas, it will
reignite into a flame
113. The sulfur in SO, is sp2 hybridized BECAUSE SO, has linear electron pair geometry.
174. The isotope Cl-37 has 17 protons, BECAUSE The atomic mass of chlorine is 35.43 amu.
17 neutrons and 77 electrons
115. At isothermal and isobaric conditions, BECAUSE Neon has a higher molar mass then
helium effuses faster than neon helium.
116. Bromine has a higher boiling point than BECAUSE Bromine has stronger dispersion forces
chlorine than chlorine.
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PART C
=':jf or
Directions: Each,of the incomplete statements or questions below is followed by five suggested-completions
on the answer
answers. Select thL one that is best for each case and fiil in oval
ti;:l
#, the corresPonding
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fli sheet.
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24. The heat caPacity for aluminum is 0.89 ]gr0C{, 26. What is the precipitate produced from the
double displacement reaction of an aqueous
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F:],
*li, a10.0 g samPle of each of the metals, which of solution of Potassium sulfate?
'4t
F:i the following would be true? (A) PbSO4
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€i: (A) Al would have the largest temperature (B) KNO3
9:1 increase. (c)
-{jt
K2Pb
?1.
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(B) Fe would have the largest temperature (D) NO2
fi increase.
,E: (E) SO3
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(C) Znwould have the largest temperature
F+
iE':' increase.
m:
f!:: (D) Fe andZnwould have the same 27. Which of the following can be classified as a
*)-: :
increase.
strong electrolYte?
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ia.i
lb:,
temPerature increase. (B) Co HrzOo
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(C) CaCl,
li.:.. 2 NO2 (g) -+ NrO* (g)
?irr,'
(D) H2O
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25. What is the heat of reaction for the above (E) NO3
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reaction given the heat of formation, AH',
t+:,
of NO2 (g) is 34 kllmole and NrOn (g) is
trir:
f{i"
t!.. 10. kJlmole? 28. How many grams of potassium chloride, KCl,
;* must be added to make 500. mL of 1.00M KCI
ii.
$:. (A) -s8 kJ solution?
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(B) -48 kJ
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{i (A) 1.00 g
i.,, (c) 10 kJ
(B)
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18.6 g
(D) 48 kl
l.r, G) 37.3 e
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i|: (D) 7a.se
,i' G) 1,ae g
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The above reaction is classified as a 2 frr(g) + O, (g) -->zSOe (g) AHo=-198 kJ
: .1:j
(A) Decomposition
32. Given the above thermochemical reactions, .{{
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what is the heat of reaction for the formation
(B) Double Displacement of SO3 (g) provided below?
.:,,,
(C) Neutralization S(s) + 3/2O2(g) -+ SO, (g)
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(D) Oxidation-reduction :.,.:
(A) -495 kJ .:l;
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(E) Single Displacement -
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(B) -3e6 kJ :i5
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(A) H2 {d + O, (g) -+ HrO (l)
, JJ. Which of the following compounds would be
:l
(B) NaOH (aq) + HCI (aq) -+ NaCl (aq) +
a white, crystalline solid? =
H2O (1)
(A) 3o72kl t
(A) CS2 :j
(B) 1536 k] ,::j
(B) Hi
(c) 0
(c) H2s
(D) *1536 kl
(D) H2O
(E) 1o72kl
(E) Mgo
344 ry39
Praetice Test 3
35. Whieh,of the following elements would have 39. Quartz, SiOr, has a high melting point and
the largest atomic radius? is insoluble in most solvents. lAlhich type of
force best accounts for the physical properiies
(A) CI of quartz?
(B) F
(A) Hydrogen bonding
(C) Li
(B) Covalent bonding
(D) Ne
(C) Ionic bonding
(E) Na
(D) P bonding
(E) Dispersion forces
36. Which atom would require the shortest wave-
length photon to remove a single electron?
40. Which of the following atoms would have the
(A) Mg largest ionic radii?
(B) Si
(A) F
(C) P
G) O-2
(D) S
(C) Na+
(E) C1
(D) Mg*2
(E) Al+3
.a/. Which of the elernents below is most likely to
form compounds in which it has an incomplete
octet? 41. Which of the following elements would have
the lowest first ionization energy?
(A) B
(A) Fluorine
(B) C
(B) Oxygen
(C) N
(C) Nitrogen
(D) O
(D) Carbon
(E) F
(E) Boron
43. Whicn-ofthefollowingis themostappropriate 46. Whichof the following species has a molecular
definition of the noinal boiling poi"t of u shape most similar to that of ammonia, NH3?
liquid?
(A) BH3
(A) The temperature at which the Iiquid
(B) H2O
boils.
(B) The pressure at which the liquid boils at
(c) H"o*
100 EC. (D) CH4
(C) The ternperature at which the liquid's (E) NH4*
vapor pressure is 1 atm.
(D) 100 EC. A-+28
(E) Dependent upon the pressure above the 47. The initial rates method was used to study
liquid. the reaction above. Determine the rate
expression and calculate the rate constant for
the reaction.
44. Sodium-24, a radioactive isotope used
medically in blood studies, decays by beta
lAl(mol/L) rate (mol/L.s)
decay and has a half-life of 15.0 hours. What is
the product of the radioactive decay of Na-24? 0.250 3.40 x 102
0.500 1.36 x 103
(A) F-20 1.00 5.44 x 103
(A) CO2
(B) NO3-
(c) Po43*
(D) SO2
(E) sonz-
l
GO ON TO THE NEXT PAGE
:
: 347
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Practice Tests
53. HCI (aq) + Zn (s) -+ ZnCIr(aq) + H, (g) 56. How many moles of potassium ions are
In the reaction above, which term best
present in 2.50 L of 0.200 M potassium
sulfate?
describes the role of HCI (aq)?
(A) 0.0800 mol
(A) Brsnsted acid
(B) 0.160 mol
(B) Oxidizing agent
(C) 0.400 mol l'
(C) Reducing agent
(D) 0.500 mol
(D) Precipitate
(E) i.00 mol :
(E) Cathode
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concentrations of both magnesium and .;'l
phosphate are essentially 0.
l
55. Hydrochloricacid, HCI (aq), is a verycommon (B) Magnesium nitrate is the limiting
laboratory reagent for many purposes: as an
reactant.
acid, an oxidizing agent, and a source of
Cl- ions. Which of the following reagents will (C) Sodium phosphate is the limiting
react with 0.20 M HCI to give a precipitate? reactant.
Assume equal volumes of solutions. (D) Since nitrate ion is a spectator ion, the
concentration of nitrate ion in the final
(A) 0.20 M lead nitrate, Pb(NOg)z
solution will be the same as in the
(B) 0.10 M barium hydroxide, Ba(OH), original magnesium nitrate solution.
(C) 0.20 M sodium acetate, NaCHTCOO (E) NarPOn and Mg(NOr), react in a
(D) Silver metal, Ag (s) 1:1 ratio.
....NarPOn (aq) + ....Mg(NO), (aq) -+ 60. The combustion of octane, CsH16, has
....Mgr(POn)2 (s) + ....NaNO, (aq) Mo."u"tior, <0 and N'rua.dor, >0. Which of the
following statements is FALSE regarding the
58. Equal volirmes of 0.10 M sodium phosphate
combustion of octane?
and 0.10 M magnesium nitrate are mixed
according to the unbalanc.ed reaction equation (A) The reaction is spontaneous at room
above. When the reaction is complete, what temperature.
is the concentration of sodium ions in the
(B) The reaction is spontaneous at all
solution?
temperatures.
(A) -0 M, because all the sodium ions will (C) The reaction products are carbon dioxide
precipitate and water vapor.
(B) 0.05 M (D) The reaction is a redox process.
(c) M
0.10 (E) The reaction is endothermic at room
(D) 0.15 M temperature.
(E) 0.30 M
67. For a given reaction, which of the following
values can be determined from the value
59. Determine the heat of reaction for the
of AG'?
combustion of sulfur dioxide
zSOr(g) + O, (g) -+ 2SOr(g) I. Cell potential, E'
IL Activation energy, Ea
given the following thermochemical III. Equilibrium constant, K"o
equations:
(A) I and II only
L Sr (s) + 8 O, (g) + 8 SOle) NL=-2374.6k1
tr. Sr (s) + 12Or(g) +
8 rcg(g) AH = -3165.8kJ (B) I and III only
(C) III only
(A) -5540.4 kl
(D) I, II, and III
(B) -1385.1 kJ
(E) None of these
(Q) -191.2k1
:! (D) -1e7.8 kl
62. Calcium hydroxide, Ca(OH)2, has a lower
'1..
1i (E) -791,2k1 solubility in water than some of the other
*;.
*:.
il: Group II hydroxides (Krp = 4.0 x 10-6 at 25eC).
In a saturated solution of calcium hydroxide
at this temperature, what is the concentration
:rj.
of calcium ions?
i,d.
(A) 2.0 x 10{
i...
*. (B) 2.0 x 10-3
1
+_:
t:
(c) 1.0 x 1o-2
(D) 1.3 x 10-2
G) 1.6 x 10-2
;
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{:. GO ON TO THE NEXT PAGE
349
: :.;.
Praetice Tests
66. For each pair of chemicals below, the amounts 69. Apossiblemechanismforthereactionof carbon
shown are dissolved, togethel, in water to monoxide with nitrogen dioxide is
make 1.0 L of solution. IAlhich mixture will 2 NOr(g) -+ NOr(g) + NO(g) (slow)
form a buffer solution?
NOr(g) + CO(g) -+ NOr(g) + COr(g) (fast)
(A) 0.2 mol of HCl and 0.1 mol of KrSO,
Which of the following could be the rate law
(B) 0.2 mol of NaOH and 0.4 mol of HF for this reaction?
(C) 0.1 mol of HBr and 0.1 mol of Ba(OH)t (A) Rate = klNO,l
(D) 0.4 mol of HCl and 0.2 mol of NH,
(B) Rate = klNOzl2
(E) 0.2 mol of NaOH and 0.4 mol of HCI
(c) Rate = ktNo3l tCOl
67. What would be appropriate units for the rate (D) Rate = ktNo3ltcollNo2l2
constant of a second-order reaction?
(E) Rate = ktNOltNO3l/[NO2]2
(A) s-1
I(APLAN 351
Answer
P,rac*,i,ce TEgt,B
3s2 ryt,9
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