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MAINS
DATE: 09.12.2017
Time: 3 hours Maximum Marks: 360
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2. For each correct answer 4 Marks will awarded and for each wrong answer 1 Mark will
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NAME:
ENROLLMENT NO.:
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PET-XIII (EXTENDED-2)-2018-MPC-2
ax a x
1. If a x a x = 0, then x is
a x a x
(A) 0 (B) a (C) 3 (D) 2a
0 pq p r
2. qp 0 q r is equal to
r p r q 0
(A) p + q + r (B) 0 (C) p – q – r (D) –p + q + r
a3 1 b 3 1 c 3 1
3. If a b c such that a b c = 0, then
2 2
a b c2
(A) ab + bc + ca = 0 (B) a + b + c = 0 (C) abc = 1 (D) a + b + c = 1
1 x 1 1
4. 1 1 x 1 is equal to
1 1 1 x
2 3 3
(A) x (x + 3) (B) 3x (C) 0 (D) x
5. If x, y, z are integers in AP, lying between 1 and 9, x51, y41 and z31 are three-digit numbers then the
5 4 3
value of x51 y41 z31 is
x y z
(A) x + y + z (B) x – y + z (C) 0 (D) none of these
1 1 1 1 bc a
6. If 1 = a b c , 2 = 1 ca b , then
a2 b2 c2 1 ab c
(A) 1 + 2 = 0 (B) 1 + 22 = 0 (C) 1 = 2 (D) none of these
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PET-XIII (EXTENDED-2)-2018-MPC-3
xp y x y
7. The determinant yp z y z = 0 for all p R, if
0 xp y yp z
(A) x, y, z are in AP (B) x, y, z are in GP (C) x, y, z are in HP (D) xy, yz, zx are in AP
x x 2 yz 1
8. The value of y y 2 zx 1 is
z z2 xy 1
(A) 1 (B) –1 (C) 0 (D) –xyz
1 x x 1
9. If f(x) = 2x x x 1 x x 1 , then f(100) is equal to
3x x 1 x x 1 x 2 x x 2 1
(A) 0 (B) 1 (C) 100 (D) –100
2 1 0
10. If A = 8A + k I, where A = , then k is
1 7
(A) 7 (B) –7 (C) 1 (D) –1
cos x sin x 0
11. If f(x) = sin x cos x 0 , then f(x + y) is equal to
0 0 1
(A) f(x) + f(y) (B) f(x) – f(y) (C) f(x) . f(y) (D) none of these
0 c b a2 ab ac
12. If A = c 0 a and B = 2
ba b bc , then AB is equal to
b a 0 ca cb c 2
(A) 0 (B) I (C) 2 I (D) none of these
4 1 4
If A = 3 0 4 , then A is equal to
2
13.
3 1 3
T
(A) A (B) I (C) A (D) none of these
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PET-XIII (EXTENDED-2)-2018-MPC-4
x3
14. x 2x 3
2
dx =
x 1 x 1
(A) x2 2x 3 4sinh1 c (B) x2 2x 3 4sinh1 c
2 2
x 1 x 1
(C) x2 2x 3 4sinh1 c (D) x 2 2x 3 4 sin c
2 2
x2 1
15. x4 1 dx
1 x2 1 1 x2 1 1 x 1 1 x 1
(A) tan1 c (B) tan1 c (C) tan1 c (D) tan1 c
2 2x 2 2x 2 2x 2 2x
x 1 dx
16. =
x 1 x3 x2 x
(A) 2tan1 x3 x2 x c (B) 2tan1 x2 x 1 c
1 1
(C) 2 tan1 x 1 c (D) 2 tan1 x 2 x c
x x
2x12 5x9 xp
17. dx c , then p – q – r =
x
3 r
5
x3 1 q x5 x3 1
(A) 6 (B) 8 (C) 10 (D) 14
1 cos x
2/7 k
x
18. If 1 cos x 9 / 7 dx A tan c , then AK =
2
11 121 49
(A) (B) (C) (D) 1
7 49 121
1 x4
19. 1 x dx
x 2 x3 x 4 x 2 x3 x 4
(A) x c (B) x c
2 3 4 2 3 4
x 2 x3 x 4 x 2 x3 x 4
(C) 2x c (D) x 2 c
2 3 4 2 3 4
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PET-XIII (EXTENDED-2)-2018-MPC-5
e5log x e4log x
20. e3log x e2log x dx =
x3 x2
c c
2
(A) x + c (B) 3x + c (C) (D)
3 2
x5
21. x2 1 dx =
x 4 x2 x 4 x2 1
(A)
4
2
tan1 x c (B)
4
2 2
log x2 1 c
x 4 x3 x 4 x3
(C) tan1 x c (D) tan1 x c
4 3 4 3
ax ax
22. dx =
a x
ax
x x x x
(A) 2sin1 c (B) 2a sin1 c (C) 2cos1 c (D) 2acos1 c
a a a a
e ex dx
xloga
23.
(A) e
x log a x
.e +c (B)
ae
x
c (C)
ex
c (D)
ae c
x
1 cos 4x
24. cot x tan x dx
1 1 1 1
(A) cos 4x c (B) cos 4x c (C) sin 4x c (D) cos 4x c
4 8 4 8
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PET-XIII (EXTENDED-2)-2018-MPC-6
1
log 1
x
25. x 1 x dx
log x 1 log x
2 2
2 2
1 1
log x 1 logx log x 1 logx c
2 2
(D)
2 2
1
26. xlog xlog(log x) dx =
1
(A) log |log (log x)| + c (B) log |log sin x| + c (C) c (D) none of these
logsin x
1
sec x cosec x dx = cot x + k tan x – 2 cot x + c k =
2 4 3
27.
3
(A) 4 (B) 3 (C) 2 (D) 1
1
28. 3 x 2 2x
dx =
x 1 x 1 x 1 x 1
(A) sin1 c (B) cosh1 c (C) sin1 c (D) sinh1 c
2 2 2 2
2x 1
29. 1 5x 6x 2
dx =
1 11 12x 5 1 11 12x 5
(A) 1 5x 6x 2 sin1 c (B) 1 5x 6x 2 sin1 c
3 6 6 7 3 6 6 7
1 11 12x 5
(C) 1 5x 6x 2 sin1 c (D) none of these
3 6 6 7
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PET-XIII (EXTENDED-2)-2018-MPC-7
dx
30. x 100 x 99
= f(x) + c f(x) =
10V 1
32. Potential of the points P and Q in the circuit shown in the
figure are
(A) 6V and –2V (B) 6V and +2V
(C) –6V and –2V (D) -6V and +2V 3 D 1
P Q
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PET-XIII (EXTENDED-2)-2018-MPC-8
35. The length of a potentiometer wire is 10 m. The distance between the null points on its wire
corresponding of two cells comes out to 60 cm. If the difference of emf’s of the cell is 0.6 V, then the
potential gradient on potentiometer wire will be
(A) 0.67 V/m (B) 0.5 V/m (C) 2.5 V/m (D) 1 v/m
36. Two bars of radius r and 2r are kept in contact as shown. An electric current I is passed through the
bars. Which one of following is correct?
(A) Heat produced in bar BC is 4 times the heat produced in bar AB
(B) Electric field in both halves is equal
(C) Current density across bar AB is double that of across BC
(D) Potential difference across AB is 4 times that of across BC
37. 600 identical cells each of emf 20V and internal resistance ‘r’ are arranged in a mixed grouping circuit
across an external resistance R = 30 such that 60 cells are in series in row and there are 10 such
rows in parallel and for this arrangement, current through R (and hence the power dissipation) is
found to be maximum. Value of r in ohms is
(A) 5 (B) 1 (C) 10 (D) 2
38. A galvanometer having 30 divisions has a current sensitivity of 20 A / division. It has a resistance of
25 ohm. To convert it into ammeter measuring upto 1.0 A, a shunt should be connected in parallel to it
of resistance
(A) 0.001 (B) 0.015 (C) 0.025 (D) 0.035
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PET-XIII (EXTENDED-2)-2018-MPC-9
40. In a meterbridge, the wire consists of two parts left part of length 30 cm and of radius ‘r’ and right of
radius ‘2r’. Where well null point occur from left end, if the resistance in the left and right gaps are 5
ohms and 8 ohms respectively? Given that material of the wires is the same.
(A) 18.3 cm (B) 20.2 cm (C) 25.2 cm (D) 40 cm
41. A source of constant P.D is applied across a conductor of irregular cross section as shown. Then,
42. In a potentiometer experiment, two cells connected in series get balanced at 9 m length on the wire.
Now the connections of terminals of cell of lower emf are reversed, then the balancing length is
obtained at 3 m. The ratio of emf of two cells will be
(A) 3 : 1 (B) 2 : 1 (C) 4 : 1 (D) none
43. A potentiometer contains a cell of emf E0, internal resistance r0 , a series resistance Rs and a
uniform wire of length L and resistance R0 in its primary circuit. Its secondary circuit contains a cell of
r0
emf E and internal resistance . R s varies with time (t) according to R s =R 0 1+ αt
2
is a +ve constant . The speed of jockey to keep the galvanometer of secondary circuit remain
undeflected is
r
E 0 Lα
(A)
ELα
. (B)
ELα
(C)
2 d
E2r0 Lα
E0 2E 0 E 0 r0 +R 0 E 0 r0 +2R 0
44. A meter bridge contains zero error. Its balancing length against an unknown resistance with a known
resistance of 10 in right gap and left gaps are 34.33cm and 67.67 cm respectively. The unknown
resistance is
(A) 5.1 (B) 4.9 (C) 5 Ω (D) 10 Ω
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PET-XIII (EXTENDED-2)-2018-MPC-10
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PET-XIII (EXTENDED-2)-2018-MPC-11
(A) x (B)x/2
(C) 4x (D) 2x G
A C B
x
50. Current in the wire varies according to equation I 15sin50t where I is in ampere, t is in second
and 50t is in radian. How much net charge will passed a cross-section of the wire in the interval
t 0 to t 40 ms :
(A) 0.080 C (B) 0.80 C (C) 0.030 C (D) Zero
51. Figures show two squares, X and Y, cut from a sheet of metal, of uniform thickness t. X and Y have
sides of length L and 2 L, respectively. The resistance RX and RY of the square are measured
R
between the opposite faces shaded in the first figure. What is value of X ?
RY
1 1
(A) (B) (C) 1 (D) 2
4 2
52. In potentiometer experiment a cell of emf 1.5 V connected in the secondary circuit gives a balancing
length of 165 cm of the wire. If a resistance of 5 is connected parallel to the cell, the balancing
length of the wire is 150 cm. The internal resistance of the cell is
(A) 5 (B) 1.5 (C) 1 (D) 0.5
1 1
(A) 5 (B) 4 (C) (D)
2 4
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56. The resistance of a metallic conductor increases with temperature due to (free electrons are the
charge carriers):
(A) change in carrier density
(B) change in the dimensions of the conductor
(C) decrease in average speed of the carrier
(D) increase in the rate of collisions between the carriers and the vibrating atoms of the conduct
57. Two resistances connected in parallel across a cell of negligible internal resistance, use 4.5 times the
power that they would use, when in series across the same cell. If one of the resistances is 8 ohm,
the other can be
(A) 8 (B) 12 (C) 16 (D) 36
58. Two identical batteries each of emf E = 2V and internal resistance r = 1 are available to produce
heat in an external circuit with variable resistance ‘R’. What is the maximum rate of production of heat
that can be obtained in the external circuit?
(A) 1 W (B) 2 W (C) 4 W (D) 8 W
59. How many 60 W lamps may be safely run on a 230 V circuit fitted with a 5 A fuse? (The fuse would
melt when the current passing through it exceeds 5(A). Lamps are connected in parallel to mains.
(A) 2 (B) 19 (C) 20 (D) 4
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60. To get maximum current through a resistance of 2.5 , one can use m rows of cells, each row having
n cells. The internal resistance of each cell is 0.5 . What are the values of n and m if the total
number of cells is 45?
(A) m = 3, n = 15 (B) m = 5, n = 9 (C) m = 9, n = 5 (D) m = 15, n = 3
Br
61. Only one bromoether is obtained from the reaction of the alkyl halide
Br
with methanol. The structure of the ether is
Br OCH3
(A) (B)
OCH3 Br
Br
Br
(C) (D)
OCH3
OCH3
62. Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so
obtained is diazotised and then heated with cuprous bromide. The reaction mixture is formed contains
(A) mixture of o–and p–bromotoluenes (B) mixture of o–and p–dibromobenzenes
(C) mixture of o– and p–bromoanilines (D) mixture of o– and m–bromotoluenes
63. Which of the following gives a precipitate with moist silver oxide
(A) CH2=CH-Cl (B) C6H5Cl
Cl Cl
(C) (D)
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66. Which of the following will react easily with conc. NaOH
Cl Cl Cl
NO 2 O 2N Cl
(A) (B) (C) (D)
NO 2 NO 2 NO 2 NO 2
67. Reaction of one molecule of HBr with one molecule of 1, 3–butadiene at 40C gives predominantly
(A) 3–bromobutene under kinetically controlled conditions
(B) 1–bromo–2–buttene under thermodymically controlled conditions
(C) 3–bromobutene under thermodynamically controlled conditions
(D) 1–bromo–2–butane under kinetically controlled conditions
68. The correct order of reactivity of the following compounds towards SN1 reactions is,
(A) I > IV > III > II (B) II > I > III > IV (C) I > IV > II > III (D) II > III > IV > I
69. When 2-butanol is treated with SOCl2 in presence of ether the product formed will be,
(A) a recemic mixture (B) optically inactive
(C) with retention of configuration (D) with complete inversion
1. NBS/ hv
2. H2O / K2CO 3
OH OH
(A) (B)
CO 2H
(C) (D)
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72. The major organic compound formed by the reaction of 1, 1, 1–trichloroethane with silver powder is :
(A) 2–Butyne (B) 2–Butene
(C) Acetylene (D) Ethene
76. The structure of the major product formed in the following reaction
Cl NaCN
DMF
CN Cl
(A) (B)
NC
CN I
Cl CN
(C) (D)
CN I
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78. Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of
(A) insolubility (B) instability
(C) inductive effect (D) steric hindrance
79. Me
SOCl2
Ph C—OH inC
5H5N
H
Which statement is true for the above reaction?
(A) Retention of configuration (B) Inversion of configuration
(C) Inversion and Retention both (D) None
80. The nucleophilicities of CH3 ,NH2 ,OH and F decrease in which order ?
(A) CH3 NH2 OH F (B) OH NH2 CH3 F
(C) NH2 OH CH3 F (D) CH3 OH F NH2
82. Which of the following will not undergo nucleophilic aromatic substitution ?
D
Cl
Cl
(A) (B)
D
D
Cl Cl
D CH3 CH3 CH3
(C) (D)
CH3 CH3
(A) I, II and III (B) II and IV (C) III and IV (D) only IV
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83.
O
Ph2 Cu Li
Product :
H3 O
Identify the structure of product :
O Ph
HO
(A) (B)
Ph
OH Ph OH
(C) (D)
Ph Ph
OH
(C) (D)
OH
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86. Which of the following is the correct order of reactivity of arylhalies towards nucleophilic substitution
reactions.
F Cl Br I F Cl Br I
Cl F Br I Br I Cl F
87. The order of relative reactivity of the given halides towards SN 2 reaction is
(A) Ph CH2Cl PhCHCl(CH3 ) PhCCl(CH3 )2 (B) PhCH2Cl PhChCl(CH3 ) PhCCl(CH3 )2
(C) PhCHCl(CH3 ) PhCH2Cl PhCcl(CH3 )2 (D) PhCHCl(CH3 ) PhCCl(CH3 )2 PhCH2Cl
90. The compound C2H4Cl2 has following number of isomers and they can be distinguished by the
reaction with
(A) 2, Aq KOH (B) 2, Alc KOH
(C) 3, Bromine water (D) 3. Alc KOH
FIITJEE (Hyderabad Classes) Limited. 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Ph: 040-66777000 – 03 Fax: 04066777004
FIITJEE Limited. 22–97, Plot No.1, (Opp. Patel Kunta) Huda Park, Vijaynagar Colony, Kukatpally, Hyderabad. 500 072. Ph : 040–64601123
FIITJEE Limited. Plot No. 39A, (Opp. Sashi Hospital), Gaddiannaram, Dilsukhnagar, Hyderabad, 5000036. Ph: 040–64569509.
PET-XIII (EXTENDED-2)-2018-MPC-19
FIITJEE (Hyderabad Classes) Limited. 5-9-14/B, Saifabad, (Opp. Secretariat) Hyderabad. 500 063. Ph: 040-66777000 – 03 Fax: 04066777004
FIITJEE Limited. 22–97, Plot No.1, (Opp. Patel Kunta) Huda Park, Vijaynagar Colony, Kukatpally, Hyderabad. 500 072. Ph : 040–64601123
FIITJEE Limited. Plot No. 39A, (Opp. Sashi Hospital), Gaddiannaram, Dilsukhnagar, Hyderabad, 5000036. Ph: 040–64569509.