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FIITJEE PET – XIII (EXTENDED-2)

MAINS
DATE: 09.12.2017
Time: 3 hours Maximum Marks: 360
INSTRUCTIONS:

Instructions to the Candidates


1. This Test Booklet consists of 90 questions.

Use Blue/Black ball Point Pen only for writing particulars and bubbling of OMR.

2. For each correct answer 4 Marks will awarded and for each wrong answer 1 Mark will
be deducted.

3. Attempt all questions.

4. In case you have not darkened any bubble you will be awarded 0 mark for that question.

5. Use of calculator/logarithmic table is not permitted.

Don’t write / mark your answers in this question booklet.


If you mark the answers in question booklet, you will not be allowed to continue the exam.

NAME:

ENROLLMENT NO.:

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PET-XIII (EXTENDED-2)-2018-MPC-2

ax a x
1. If a  x a x = 0, then x is
a  x a x
(A) 0 (B) a (C) 3 (D) 2a

0 pq p r
2. qp 0 q  r is equal to
r p r q 0
(A) p + q + r (B) 0 (C) p – q – r (D) –p + q + r

a3  1 b 3  1 c 3  1
3. If a  b  c such that a b c = 0, then
2 2
a b c2
(A) ab + bc + ca = 0 (B) a + b + c = 0 (C) abc = 1 (D) a + b + c = 1

1 x 1 1
4. 1 1 x 1 is equal to
1 1 1 x
2 3 3
(A) x (x + 3) (B) 3x (C) 0 (D) x

5. If x, y, z are integers in AP, lying between 1 and 9, x51, y41 and z31 are three-digit numbers then the
5 4 3
value of x51 y41 z31 is
x y z
(A) x + y + z (B) x – y + z (C) 0 (D) none of these

1 1 1 1 bc a
6. If 1 = a b c , 2 = 1 ca b , then
a2 b2 c2 1 ab c
(A) 1 + 2 = 0 (B) 1 + 22 = 0 (C) 1 = 2 (D) none of these

Space for rough work

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xp  y x y
7. The determinant yp  z y z = 0 for all p  R, if
0 xp  y yp  z
(A) x, y, z are in AP (B) x, y, z are in GP (C) x, y, z are in HP (D) xy, yz, zx are in AP

x x 2  yz 1
8. The value of y y 2  zx 1 is
z z2  xy 1
(A) 1 (B) –1 (C) 0 (D) –xyz

1 x x 1
9. If f(x) = 2x x  x  1 x  x  1 , then f(100) is equal to

3x  x  1 x  x  1 x  2  x x 2  1 
(A) 0 (B) 1 (C) 100 (D) –100

2  1 0
10. If A = 8A + k I, where A =   , then k is
 1 7 
(A) 7 (B) –7 (C) 1 (D) –1

cos x  sin x 0 
11. If f(x) =  sin x cos x 0  , then f(x + y) is equal to
 0 0 1
(A) f(x) + f(y) (B) f(x) – f(y) (C) f(x) . f(y) (D) none of these

 0 c b   a2 ab ac 
 
12. If A =  c 0 a  and B = 2
ba b bc  , then AB is equal to
 b a 0   ca cb c 2 
 
(A) 0 (B) I (C) 2 I (D) none of these

 4 1 4 
If A = 3 0 4  , then A is equal to
2
13.
3 1 3 
T
(A) A (B) I (C) A (D) none of these

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x3
14.  x  2x  3
2
dx =

 x  1  x  1
(A) x2  2x  3  4sinh1  c (B) x2  2x  3  4sinh1  c
 2   2 
 x  1  x  1
(C) x2  2x  3  4sinh1  c (D) x 2  2x  3  4 sin  c
 2   2 

x2  1
15.  x4  1 dx 
1 x2  1 1 x2  1 1 x 1 1 x 1
(A) tan1 c (B) tan1 c (C) tan1 c (D) tan1 c
2 2x 2 2x 2 2x 2 2x

 x  1 dx
16.  =
 x  1 x3  x2  x
(A) 2tan1 x3  x2  x  c (B) 2tan1 x2  x  1  c
1 1
(C) 2 tan1 x  1 c (D) 2 tan1 x 2  x  c
x x

2x12  5x9 xp
17.  dx   c , then p – q – r =
x   
3 r
5
 x3  1 q x5  x3  1
(A) 6 (B) 8 (C) 10 (D) 14

1  cos x 
2/7 k
 x
18. If  1  cos x 9 / 7 dx  A  tan   c , then AK =
 2
11 121 49
(A) (B) (C) (D) 1
7 49 121

1  x4
19.  1 x dx 

x 2 x3 x 4 x 2 x3 x 4
(A) x    c (B) x    c
2 3 4 2 3 4
x 2 x3 x 4 x 2 x3 x 4
(C) 2x    c (D) x 2    c
2 3 4 2 3 4

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 e5log x  e4log x 
20.   e3log x  e2log x  dx =
x3 x2
c c
2
(A) x + c (B) 3x + c (C) (D)
3 2

x5
21.  x2  1 dx =

x 4 x2 x 4 x2 1
(A)
4

2
 tan1 x  c (B)
4

2 2

 log x2  1  c
x 4 x3 x 4 x3
(C)   tan1 x  c (D)   tan1 x  c
4 3 4 3

 ax ax 
22.     dx =
a  x 
 ax
x x x x
(A) 2sin1    c (B) 2a sin1    c (C) 2cos1    c (D) 2acos1    c
a a a a

e  ex dx 
xloga
23.

(A) e
x log a x
.e +c (B)
 ae 
x

c (C)
ex
c (D)
 ae   c
x

logae 1  loga loga

1  cos 4x
24.  cot x  tan x dx 
1 1 1 1
(A)  cos 4x  c (B) cos 4x  c (C) sin 4x  c (D)  cos 4x  c
4 8 4 8

Space for rough work

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 1
log  1  
 x
25.  x 1  x  dx 
log  x  1 log x 
2 2

(A)    log  x  1 log x  c


2 2
1  1
(B)  log2  1    c
2  x
1 1
(C) log  x  1  logx   c
2 2

2 2
1 1
log  x  1  logx   log  x  1 logx  c
2 2
(D)
2 2

1
26.  xlog xlog(log x) dx =
1
(A) log |log (log x)| + c (B) log |log sin x| + c (C) c (D) none of these
logsin x

1
 sec x cosec x dx =  cot x + k tan x – 2 cot x + c  k =
2 4 3
27.
3
(A) 4 (B) 3 (C) 2 (D) 1

1
28.  3  x 2  2x
dx =

 x  1  x  1  x  1  x  1
(A) sin1  c (B) cosh1  c (C) sin1  c (D) sinh1  c
 2   2   2   2 

2x  1
29.  1  5x  6x 2
dx =

1 11  12x  5  1 11  12x  5 
(A)  1  5x  6x 2  sin1  c (B)  1  5x  6x 2  sin1  c
3 6 6  7  3 6 6  7 
1 11  12x  5 
(C)  1  5x  6x 2  sin1  c (D) none of these
3 6 6  7 

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dx
30.   x  100  x  99
= f(x) + c  f(x) =

(A) 2(x + 100)


1/2
(B) 3(x + 100)
1/2
(C) 2tan1  x  99  (D) 2tan1  x  100 
31. An infinite long plate has surface charge density . As
shown in the figure, a point charge q is moved from A to B 
along two semicircular paths of radius r each. Net work
done by electric field is
q q
(A)  x1  x 2  (B)  x 2  x1  B(x1,0) A(x2,0)
2o 2o
q q
(C)  x 2  x1  (D)  2r  r 
o o

10V 1
32. Potential of the points P and Q in the circuit shown in the
figure are
(A) 6V and –2V (B) 6V and +2V
(C) –6V and –2V (D) -6V and +2V 3 D 1
P Q

33. For the given electric lines of force consider the


following statements
(A) Flux through closed surface S is zero
(B) VA  VB  0
B
(C)  E.dr
A
is negative

(D) If a point charge particle is released at point C


then its path will be straight line.

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34. What should be the value of resistance R in 0.5 W


the circuit shown in Figure so that the electric 3V

bulb consumes the rated power ?


(A) 12
(B) 4.5 4
(C) 6
R
(D) 9
6V , 0.5

35. The length of a potentiometer wire is 10 m. The distance between the null points on its wire
corresponding of two cells comes out to 60 cm. If the difference of emf’s of the cell is 0.6 V, then the
potential gradient on potentiometer wire will be
(A) 0.67 V/m (B) 0.5 V/m (C) 2.5 V/m (D) 1 v/m

36. Two bars of radius r and 2r are kept in contact as shown. An electric current I is passed through the
bars. Which one of following is correct?
(A) Heat produced in bar BC is 4 times the heat produced in bar AB
(B) Electric field in both halves is equal
(C) Current density across bar AB is double that of across BC
(D) Potential difference across AB is 4 times that of across BC

37. 600 identical cells each of emf 20V and internal resistance ‘r’ are arranged in a mixed grouping circuit
across an external resistance R = 30  such that 60 cells are in series in row and there are 10 such
rows in parallel and for this arrangement, current through R (and hence the power dissipation) is
found to be maximum. Value of r in ohms is
(A) 5  (B) 1  (C) 10  (D) 2 

38. A galvanometer having 30 divisions has a current sensitivity of 20 A / division. It has a resistance of
25 ohm. To convert it into ammeter measuring upto 1.0 A, a shunt should be connected in parallel to it
of resistance
(A) 0.001  (B) 0.015  (C) 0.025  (D) 0.035 

39. Consider the potentiometer circuit arranged as in figure. The


potentiometer wire is 500 cm long. At what distance from the
point A should the jockey touch the wire to get zero deflection in
the galvanometer ?
(A) 150 cm (B) 133.3 cm
(C) 100 cm (D) None
/4

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40. In a meterbridge, the wire consists of two parts left part of length 30 cm and of radius ‘r’ and right of
radius ‘2r’. Where well null point occur from left end, if the resistance in the left and right gaps are 5
ohms and 8 ohms respectively? Given that material of the wires is the same.
(A) 18.3 cm (B) 20.2 cm (C) 25.2 cm (D) 40 cm

41. A source of constant P.D is applied across a conductor of irregular cross section as shown. Then,

(A) Electric field intensity at “p” is more than that of Q


(B) Rate of electrons crossing per unit area of cross section at ‘P’ is more than that at Q
(C) The rate of generation of heat per unit length at P is less than that at Q
(D) The drift velocity at “P” is greater than that at Q

42. In a potentiometer experiment, two cells connected in series get balanced at 9 m length on the wire.
Now the connections of terminals of cell of lower emf are reversed, then the balancing length is
obtained at 3 m. The ratio of emf of two cells will be
(A) 3 : 1 (B) 2 : 1 (C) 4 : 1 (D) none

43. A potentiometer contains a cell of emf E0, internal resistance r0 , a series resistance Rs and a
uniform wire of length L and resistance R0 in its primary circuit. Its secondary circuit contains a cell of
r0
emf E and internal resistance . R s varies with time (t) according to R s =R 0 1+ αt 
2
  is a +ve constant  . The speed of jockey to keep the galvanometer of secondary circuit remain
undeflected is
r 
E  0  Lα
(A)
ELα
. (B)
ELα
(C)
2 d
E2r0 Lα
E0 2E 0 E 0  r0 +R 0  E 0  r0 +2R 0 

44. A meter bridge contains zero error. Its balancing length against an unknown resistance with a known
resistance of 10 in right gap and left gaps are 34.33cm and 67.67 cm respectively. The unknown
resistance is
(A) 5.1 (B) 4.9  (C) 5 Ω (D) 10 Ω

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PET-XIII (EXTENDED-2)-2018-MPC-10

45. Identify the correct statement


(A) Principle of potentiometer is balancing resistances against known resistance
(B) Sensitivity of potentiometer can be increased by increasing emf in primary circuit
(C) Potentiometer can be used to measure only “emf” but not P.D. in a circuit
(D) Potentiometer can be used for measuring internal resistance and PD in any circuit also

46. Circuit shown in figure is an arrangement which can be used to


measure the resistance R though the reading may not be linear. In the
circuit “G” is a galvanometer, R0 is a known resistance and R is the
resistance which is to be measured. If A and B are short circuited by a
resistance-less wire; (G) gives full scale deflection. Then to read a
resistance “R” directly from (G), its scale should be like:

(A) (B) (C) (D)

47. An electrical circuit is given. Calculate the current flowing in the


V
resistor of 400 , if voltmeter resistance is 400
1 1 400
(A) A (B) A 100
60 3 100 200
20 10 100
(C) A (D) A
3 3 10V

48. In the figure shown, the potentiometer wire of length E1 =10V


r1=1
L  100cm and resistance 9 is joined to a cell of
emf E1  10V and internal resistance r1  1 . Another
cell of emf E2  5V and internal resistance r2  2 is A
C
B
connected as shown. The Galvanometer G will show no
G
deflection when the length AC is
(A) 50 cm (B) 55.55 cm
(C) 45.55 cm (D) None E2=5V
r2 =2

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49. In the shown meter-bridge arrangement if AC corresponding to


null deflection of the galvanometer is x , what would be it’s value
if the radius of the wire AB is doubled ? R1 R2

(A) x (B)x/2
(C) 4x (D) 2x G

A C B
x

50. Current in the wire varies according to equation I  15sin50t where I is in ampere, t is in second
and  50t  is in radian. How much net charge will passed a cross-section of the wire in the interval
t  0 to t  40 ms :
(A) 0.080 C (B) 0.80 C (C) 0.030 C (D) Zero

51. Figures show two squares, X and Y, cut from a sheet of metal, of uniform thickness t. X and Y have
sides of length L and 2 L, respectively. The resistance RX and RY of the square are measured
R
between the opposite faces shaded in the first figure. What is value of X ?
RY

1 1
(A) (B) (C) 1 (D) 2
4 2

52. In potentiometer experiment a cell of emf 1.5 V connected in the secondary circuit gives a balancing
length of 165 cm of the wire. If a resistance of 5  is connected parallel to the cell, the balancing
length of the wire is 150 cm. The internal resistance of the cell is
(A) 5  (B) 1.5  (C) 1  (D) 0.5 

53. A cell of emf E volt with negligible internal resistance is connected to a


wire whose cross-section changes. The wire has three sections of equal
length. The middle section has a radius a whereas the radius of the
outer two sections is 2a. The ratio of the potential difference across the
section AB to the potential difference across the section CA is

1 1
(A) 5 (B) 4 (C) (D)
2 4

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54. Read the following statement carefully


Y : The resistivity of semiconductor decreases with increase of temperature.
Z : In a conducting solid, the rate of collisions between free electrons and ions increases with increase
of temperature.
Select the correct statement from the following
(A) Y is true but Z is false
(B) Y is false but Z is true
(C) both Y and Z are true
(D) Y is true and Z is the correct reason for Y

55. The galvanometer G in the following circuit reads


zero. Find the value of R. Batteries are resistance
less.

(A) 100  (B) 50  (C) 250  (D) None

56. The resistance of a metallic conductor increases with temperature due to (free electrons are the
charge carriers):
(A) change in carrier density
(B) change in the dimensions of the conductor
(C) decrease in average speed of the carrier
(D) increase in the rate of collisions between the carriers and the vibrating atoms of the conduct

57. Two resistances connected in parallel across a cell of negligible internal resistance, use 4.5 times the
power that they would use, when in series across the same cell. If one of the resistances is 8 ohm,
the other can be
(A) 8  (B) 12  (C) 16  (D) 36 

58. Two identical batteries each of emf E = 2V and internal resistance r = 1 are available to produce
heat in an external circuit with variable resistance ‘R’. What is the maximum rate of production of heat
that can be obtained in the external circuit?
(A) 1 W (B) 2 W (C) 4 W (D) 8 W

59. How many 60 W lamps may be safely run on a 230 V circuit fitted with a 5 A fuse? (The fuse would
melt when the current passing through it exceeds 5(A). Lamps are connected in parallel to mains.
(A) 2 (B) 19 (C) 20 (D) 4

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60. To get maximum current through a resistance of 2.5 , one can use m rows of cells, each row having
n cells. The internal resistance of each cell is 0.5 . What are the values of n and m if the total
number of cells is 45?
(A) m = 3, n = 15 (B) m = 5, n = 9 (C) m = 9, n = 5 (D) m = 15, n = 3

Br

61. Only one bromoether is obtained from the reaction of the alkyl halide
Br
with methanol. The structure of the ether is

Br OCH3

(A) (B)
OCH3 Br
Br
Br
(C) (D)
OCH3
OCH3

62. Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so
obtained is diazotised and then heated with cuprous bromide. The reaction mixture is formed contains
(A) mixture of o–and p–bromotoluenes (B) mixture of o–and p–dibromobenzenes
(C) mixture of o– and p–bromoanilines (D) mixture of o– and m–bromotoluenes

63. Which of the following gives a precipitate with moist silver oxide
(A) CH2=CH-Cl (B) C6H5Cl
Cl Cl
(C) (D)

64. The treatment of CH3MgX with CH3CC–H produces


(A) CH3  CH  CH2 (B) CH3C  C  CH3
(C) CH3   CH2   CH3 (D) CH4

65. Which of the following reactions will yield 2, 2–dibromopropane ?


(A) CH3  C  CH  2HBr  (B) CH3CH  CHBr  HBr 
(C) CH  CH  2HBr  (D) CH3  CH  CH2  HBr 

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66. Which of the following will react easily with conc. NaOH
Cl Cl Cl
NO 2 O 2N Cl
(A) (B) (C) (D)
NO 2 NO 2 NO 2 NO 2

67. Reaction of one molecule of HBr with one molecule of 1, 3–butadiene at 40C gives predominantly
(A) 3–bromobutene under kinetically controlled conditions
(B) 1–bromo–2–buttene under thermodymically controlled conditions
(C) 3–bromobutene under thermodynamically controlled conditions
(D) 1–bromo–2–butane under kinetically controlled conditions

68. The correct order of reactivity of the following compounds towards SN1 reactions is,

I H CO CH2Br II O2N CH2Br


3

III CH2Br IV H3C CH2Br

(A) I > IV > III > II (B) II > I > III > IV (C) I > IV > II > III (D) II > III > IV > I

69. When 2-butanol is treated with SOCl2 in presence of ether the product formed will be,
(A) a recemic mixture (B) optically inactive
(C) with retention of configuration (D) with complete inversion

70. The product of the reaction given below is :

1. NBS/ hv

2. H2O / K2CO 3

OH OH

(A) (B)

CO 2H

(C) (D)

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71. The synthesis of alkyl fluorides is best accomplished by :


(A) Sandmeyer’s reaction (B) Finkelstein reaction
(C) Swarts reaction (D) Free radical fluorination

72. The major organic compound formed by the reaction of 1, 1, 1–trichloroethane with silver powder is :
(A) 2–Butyne (B) 2–Butene
(C) Acetylene (D) Ethene

73. SN1reaction is are favoured in


(A) Polar solvents
(B) Less no. of alkyl group on the carbon atom attached to the halogen atom
(C) Small alkyl groups on the carbon attached to the halogen atom
(D) None of these

74. CH3Br  Nu   CH3  Nu  Br 



The decreasing order of the rate of the above reaction with nucleophiles (Nu ) A to D is
Nu   A  PhO , B  AcO ,  C HO , D  EtO  
 
(A) D > C > A > B (B) D > C > B > A (C) A > B > C > D (D) B > D > C > A

75. Fluorobenzene (C6H5F) can be synthesized in the laboratory


(A) by heating phenol with HF and KF
(B) from aniline by diazotization followed by heating the diazonium salt with HBF 4
(C) by direct fluorination of benzene with F2 gas
(D) by reacting bromobenzene with NaF solution

76. The structure of the major product formed in the following reaction

Cl NaCN
DMF

CN Cl

(A) (B)
NC
CN I

Cl CN

(C) (D)

CN I

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77. Reaction of trans–2–phenyl–1–bromocyclopentane on reaction with alcoholic KOH produces


(A) 4–phenylcyclopentene (B) 2–phenylcyclopentene
(C) 1–phenylcyclopentene (D) 3–phenylcyclopentene

78. Tertiary alkyl halides are practically inert to substitution by SN2 mechanism because of
(A) insolubility (B) instability
(C) inductive effect (D) steric hindrance

79. Me
SOCl2
Ph C—OH inC 
5H5N
H
Which statement is true for the above reaction?
(A) Retention of configuration (B) Inversion of configuration
(C) Inversion and Retention both (D) None

80. The nucleophilicities of CH3 ,NH2 ,OH and F decrease in which order ?
(A) CH3  NH2  OH  F (B) OH  NH2  CH3  F
(C) NH2  OH  CH3  F (D) CH3  OH  F  NH2

81. Correct order of leaving group tendency is :


(A) I  Br   Cl  F (B) F  Cl  Br   I
(C) Cl  F  Br   I (D) I  Cl  Br   F

82. Which of the following will not undergo nucleophilic aromatic substitution ?
D
Cl
Cl
(A) (B)
D
D
Cl Cl
D CH3 CH3 CH3

(C) (D)

CH3 CH3
(A) I, II and III (B) II and IV (C) III and IV (D) only IV

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83.
O

Ph2 Cu Li
Product :
H3 O
Identify the structure of product :
O Ph
HO

(A) (B)

Ph
OH Ph OH

(C) (D)

Ph Ph

84. In the given reaction


H3CMgBr
Product
O H / H2O

Find the product of reaction :


OH
(A) (B)

OH
(C) (D)
OH

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85. In the reaction


CH3CH2CH2Br 
NaOH
C H OH
 A 
HBr
B 
AlC KOH
 C;C is
2 5

(A) Propene (B) Propyne


(C) 1-Propanol (D) 2-Propanol

86. Which of the following is the correct order of reactivity of arylhalies towards nucleophilic substitution
reactions.
F Cl Br I F Cl Br I

(A) < < < (B) > > >

Cl F Br I Br I Cl F

(C) > > > (D) > > >

87. The order of relative reactivity of the given halides towards SN 2 reaction is
(A) Ph CH2Cl  PhCHCl(CH3 )  PhCCl(CH3 )2 (B) PhCH2Cl  PhChCl(CH3 )  PhCCl(CH3 )2
(C) PhCHCl(CH3 )  PhCH2Cl  PhCcl(CH3 )2 (D) PhCHCl(CH3 )  PhCCl(CH3 )2  PhCH2Cl

88. Ethylidene chloride on treatment with aqueous KOH gives


(A) acetaldehyde (B) ethylene glycol
(C) formaldehyde (D) none of them

89. In the reaction


PBr
  A  B   C;C is
AgCN
CH3  CH  CH2 
1.B2H6 3
2.H2O2 / OH
(A) CH3CH2CH2NC (B) CH3CH2CN
(C) CH3CH2CH2CN (D) CH3CH2COOH

90. The compound C2H4Cl2 has following number of isomers and they can be distinguished by the
reaction with
(A) 2, Aq KOH (B) 2, Alc KOH
(C) 3, Bromine water (D) 3. Alc KOH

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FIITJEE PET – XIII (EXTENDED-2)


MAINS_ANSWERS
DATE: 09.12.2017
MATHEMATICS
1. A 2. B 3. C 4. A
5. C 6. A 7. B 8. C
9. A 10. B 11. C 12. A
13. B 14. BONUS 15. BONUS 16. C
17. A 18. D 19. B 20. C
21. B 22. B 23. B 24. D
25. B 26. A 27. D 28. A
29. B OR C 30. C
PHYSICS
31. A 32. A 33. A 34. C
35. D 36. A 37. A 38. B
39. B 40. A 41. C 42. B
43. A 44. BONUS 45. BONUS 46. A
47. A 48. B 49. A 50. D
51. C 52. D 53. B 54. C
55. A 56. D 57. C 58. B
59. B 60. A
CHEMISTRY

61. B 62. A 63. C 64. D


65. A 66. D 67. B 68. A
69. C 70. A 71. C 72. A
73. A 74. A 75. B 76. D
77. D 78. D 79. B 80. A
81. A 82. D 83. A 84. C
85. A 86. B 87. A 88. A
89. A 90. A

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