How to add libraries to this version of Kontakt:

You have to open the Kontakt 5.6.0 standalone app (or 5.6.5)
and add the library in it. If the library doesn't appear on the
left panel, don't worry about it. Just close the app.

Open this new Kontakt 6 version, and if you can't see that
library there, then you have to do the following steps (in
case there is a .nicnt file in the library's folder) but first
close Kontakt, then:

1. check the SNPID number of the library, go to the folder of

the library and open the .nicnt file (with TextEdit or any
similar program), you will find a line like this:
<SNPID>P74</SNPID>
(in this case P74 was the ID code of Metropolis Ark 3)
2. go to your hard drive > Library > Application Support >
Native Instruments > Service Center, and look for the .xml
file with the name of that desired library, open it with
TextEdit and you will see that the SNPID number there is 000
which indicates that Kontakt somehow hasn't been able to
add it properly. Change that three zeros with the ID code you
found in the .nicnt of that library, then save and close
TextEdit. And you're ready to use the library in the new
Kontakt.
During this process Kontakt app should not be opened!

You can find the 5.6.0 standalone app in Applications >

Native Instruments > Kontakt folder after installing this new
version.

If you encounter the problem where Kontakt prompts you

after you try to load the instrument that "This instrument
belongs to a library that is currently not installed", in this
case delete the library's .xml file from:
your_hard_drive > Library > Application Support > Native
Instruments > Service Center
And also delete the com.native-instruments.{library's
name}.plist file from:
your_hard_drive > Library > Preferences
Then try to add the library again in Kontakt 5.6.0 and follow
the SNPID workaround from above again.

If you can't open Kontakt 5.6.0 app, use Permissions Reset

app to reset it.