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Co= 50 ppm t Absorbansi C Cawal-akhir

m= 0.05 gr 0 0.1493 4.9673 0.0000


%Removal= 136.6032211 1 0.1495 4.9773 -0.0100
3 0.1606 5.4827 -0.5155
5 0.1473 4.8791 0.0882
10 0.1365 4.3850 0.5823
15 0.1340 4.2732 0.6941
20 0.1230 3.7714 1.1959
25 0.1486 4.9359 0.0314
30 0.0000 -1.8182 6.7855
35 0.0922 2.3723 2.5950
40 0.0000 -1.8182 6.7855
50 0.0442 0.1906 4.7767
60 0.0000 -1.8182 6.7855
~ 0.0000 -1.8182 6.7855
% removal 136.6032
Co= 50 ppm t Absorbansi C Cawal-akhir
m= 0.1 gr 0 0.0143 -1.1675 0.0000
%Removal= -47.13440274 1 0.0079 -1.4572 0.2897
3 0.0327 -0.3318 -0.8356
5 0.0000 -1.8182 0.6507
10 0.0771 1.6882 -2.8556
15 0.0505 0.4755 -1.6429
20 0.0264 -0.6200 -0.5475
25 0.0228 -0.7818 -0.3856
30 0.0113 -1.3064 0.1389
35 0.0000 -1.8182 0.6507
40 0.0000 -1.8182 0.6507
50 0.0104 -1.3459 0.1785
60 0.0032 -1.6714 0.5039
~ 0.0022 -1.7177 0.5503
% removal -47.1344
Co= 150 ppm t Absorbansi C Cawal-akhir
m= 0.05 gr 0 0.6444 54.9455 0.0000
Faktor
Pengenceran= 2 1 0.6450 55.0000 -0.0545
%Removal= 38.17008604 3 0.6432 54.8364 0.1091
5 0.6753 57.7545 -2.8091
10 0.5398 45.4355 9.5100
15 0.4809 40.0818 14.8636
20 0.2967 23.3364 31.6091
25 0.6291 53.5573 1.3882
30 0.5841 49.4664 5.4791
35 0.5541 46.7364 8.2091
40 0.5616 47.4155 7.5300
50 0.6225 52.9545 1.9909
60 0.4716 39.2364 15.7091
~ 0.4137 33.9727 20.9727
% removal 38.1701
Co= 150 ppm t Absorbansi C Cawal-akhir
m= 0.1 gr 0 0.4800 20.0000 0.0000
%Removal= 34.96363636 1 0.4884 20.3818 -0.3818
3 0.4836 20.1636 -0.1636
5 0.4641 19.2773 0.7227
10 0.4854 20.2455 -0.2455
15 0.4305 17.7500 2.2500
20 0.3792 15.4182 4.5818
25 0.3366 13.4818 6.5182
30 0.4002 16.3727 3.6273
35 0.2811 10.9591 9.0409
40 0.4064 16.6536 3.3464
50 0.3057 12.0773 7.9227
60 0.4026 16.4818 3.5182
~ 0.3262 13.0073 6.9927
% removal 34.9636

90
80
70
60
50
C [ppm]

40 50 ppm
30 100 pp
150 pp
20
10
0
0 10 20 30 40 50 60 70
-10
t [menit]
10
0
0 10 20 30 40 50 60 70
-10
t [menit]

90
80
70
60
50
C [ppm]

40 0,025
30 0,05 g
0,075
20
10
0
0 10 20 30 40 50 60 70
-10
t [menit]
Cµ log (Cµ) log C Kesetimbangan
Massa Adsorben Konsentrasi C*
-0.2000 - 0.6970 0.05 50 ppm -1.8182
-10.3091 - 0.7390 0.1 50 ppm -1.7177
1.7636 0.2464 0.6883 0.05 100 ppm 33.9727
11.6455 1.0662 0.6420 0.1 100 ppm 13.0073
13.8818 1.1424 0.6308
23.9182 1.3787 0.5765
40
0.6273 -0.2025 0.6934
135.7091 2.1326 - 35
51.9000 1.7152 0.3752 30 f(x) = 0.0747864491x
135.7091 2.1326 - 25 R² = 0.8382806598
95.5336 1.9802 -0.7199 20
135.7091 2.1326 -

C*
15
135.7091 2.1326 -
10

Cµ log (Cµ) log C 5


0
2.8972 0.4620 - 0 50 100 150 200 250
-5
-8.3564 - -

6.5073 0.8134 -
-28.5564 - 0.2274
-16.4291 - -0.3229 7.0
-5.4745 - -
6.0
-3.8564 - - f(x) = 1.8660491677x - 0.5399095243
1.3891 0.1427 - 5.0 R² = 1
6.5073 0.8134 - 4.0
ln (Cµ)

6.5073 0.8134 -
3.0
1.7845 0.2515 -
5.0391 0.7024 - 2.0
5.5027 0.7406 - 1.0

0.0
Cµ log (Cµ) log C 2 3 3 3
ln C*
-1.0909 - 1.7404
2.1818 0.3388 1.7391
0.3000
-56.1818 - 1.7616
190.2000 2.2792 1.6574 0.2000
297.2727 2.4732 1.6029
0.1000f(x) = 0.0074235974x - 0.0952660681
632.1818 2.8008 1.3680 R² = 0.3427212748
27.7636 1.4435 1.7288 0.0000
C*/Cµ

109.5818 2.0397 1.6943 -5.0 0.0 5.0 10.0 15.0 20.0


-0.1000
164.1818 2.2153 1.6697
150.6000 2.1778 1.6759 -0.2000
39.8182 1.6001 1.7239
-0.3000
314.1818 2.4972 1.5937
-0.4000
C*
-0.2000

-0.3000

419.4545 2.6227 1.5311 -0.4000


C*
Cµ log (Cµ) log C
1000
-3.8182 - 1.3092
900
-1.6364 - 1.3046
800
7.2273 0.8590 1.2850 700

Cµ [mg/gr adsorben]
-2.4545 - 1.3063 600
22.5000 1.3522 1.2492 500
45.8182 1.6610 1.1880 400
65.1818 1.8141 1.1297 300
36.2727 1.5596 1.2141 200
90.4091 1.9562 1.0398 100
33.4636 1.5246 1.2215 0
79.2273 1.8989 1.0820 -10 0 10 20 30 40 50 60 70
35.1818 1.5463 1.2170 C* [ppm]
69.9273 1.8446 1.1142


C* Henry Freundlich
0 0 0
1 13.3689839572 38.0689885
2 26.7379679144 44.7881239
3 40.1069518717 49.2556746
4 53.4759358289 52.6931796
5 66.8449197861 55.5238796
6 80.2139037433 57.9492481
7 93.5828877005 60.0823385
8 106.951871658 61.993469
9 120.320855615 63.7296019
10 133.689839572 65.3237845
11 147.058823529 66.8002245
12 160.427807487 68.177228
13 173.796791444 69.469001
14 187.165775401 70.6868066
15 200.534759358 71.8397377
20 267.379679144 76.8533621
25 334.22459893 80.9819573
30 401.069518717 84.519374
35 467.914438503 87.6305008
50 ppm 40 534.759358289 90.4178978
100 ppm 45 601.604278075 92.9500595
150 ppm
50 668.449197861 95.2751856
55 735.294117647 97.4285834
60 802.139037433 99.4369525
60 70 65 868.983957219 101.321012
60 70

0,025 gr
0,05 gr
0,075 gr

60 70
Kesetimbangan
Cµ ln C* ln (Cµ) C*/Cµ
135.7091 - 4.91051 -0.013398
5.5027 - 1.70524 -0.312159
419.4545 3.52556 6.03896 0.0809926
69.9273 2.56551 4.24746 0.1860114

Kesetimbangan Linier
slope (kD) = 0.0748
R^2 = 0.7493

150 200 250 300 350 400 450

Kesetimbangan Freundlich
slope (1/n) = 0.2345
491677x - 0.5399095243 intercept (Ln kF) = 3.6394
n= 4.2643923241
kF = 38.068988479
R^2 = 0.0272

3 3 3 3 4
ln C*

Kesetimbangan Langmuir
slope (1/Cµ,max)
intercept =
(1/Cµ,max.kL) 0.0074
- 0.0952660681 = 0.0953
Cµ,max = 135.13513514
kL = 0.0776495278
0.0 15.0 20.0 25.0 30.0 35.0 40.0 R^2 = 0.3427

C*
C*

C* Cµ
14.1595454545 1531.7818181818
29.3695454545 1940.1454545455
63.63 2879.5636363636
11.0868181818 4207.5636363636
Data Percobaan
Li ni er 1.0128636364 5304.0509090909
Freundl i ch
Langmui r

40 50 60 70
m]


Langmuir
0
9.7370983447
18.165304269
25.531914894
32.025620496
37.792894936
42.949176807
47.586675731
51.779935275
55.58987029
59.066745422
62.252405207
65.181966323
67.885117493
70.387129211
72.709646146
82.203041513
89.190153407
94.547746612
98.786339261
102.22335804
105.06654214
107.45755427
109.49631694
111.25533098
112.78847822
Co= 50 ppm C C-C*teoritis 1/C-C*teoritis
m= 0.05 gr 4.9672727273 3049.99809465 0.0003278691
C* teoritis = -3045.031 4.9772727273 3050.00809465 0.000327868
5.4827272727 3050.51354919 0.0003278137
4.8790909091 3049.90991283 0.0003278785
4.385 3049.41582192 0.0003279317
4.2731818182 3049.30400374 0.0003279437
3.7713636364 3048.80218555 0.0003279977
4.9359090909 3049.96673101 0.0003278724
-1.818181818 3043.2126401 0.0003286001
2.3722727273 3047.40309465 0.0003281483
-1.818181818 3043.2126401 0.0003286001
0.1905909091 3045.22141283 0.0003283833
-1.818181818 3043.2126401 0.0003286001

Co= 50 ppm C C-C*teoritis 1/C-C*teoritis


m= 0.1 gr -1.167454545 -1.7141249738 -0.5833880349
C* teoritis = 0.5466704 -1.457172727 -2.0038431556 -0.4990410538
-0.331818182 -0.8784886101 -1.1383186856
-1.818181818 -2.3648522465 -0.4228593991
1.6881818182 1.1415113899 0.8760315568
0.4754545455 -0.0712158829 -14.0418114565
-0.62 -1.1666704283 -0.8571400935
-0.781818182 -1.3284886101 -0.7527350949
-1.306363636 -1.8530340647 -0.5396554867
-1.818181818 -2.3648522465 -0.4228593991
-1.818181818 -2.3648522465 -0.4228593991
-1.345909091 -1.8925795192 -0.5283793837
-1.671363636 -2.2180340647 -0.4508497033

Co= 150 ppm C C-C*teoritis 1/C-C*teoritis


m= 0.05 gr 54.945454545 73.9448409849 0.0135235939
Faktor
Pengenceran= 2 55 73.9993864394 0.0135136256
C* teoritis = -18.99939 54.836363636 73.8357500758 0.0135435747
57.754545455 76.753931894 0.0130286485
45.435454545 64.4348409849 0.0155195541
40.081818182 59.0812046213 0.0169258566
23.336363636 42.3357500758 0.0236206988
53.557272727 72.5566591667 0.0137823325
49.466363636 68.4657500758 0.0146058431
46.736363636 65.7357500758 0.0152124224
47.415454545 66.4148409849 0.0150568756
52.954545455 71.953931894 0.0138977812
39.236363636 58.2357500758 0.0171715827
Co= 150 ppm C C-C*teoritis 1/C-C*teoritis
m= 0.1 gr 20 6.1895507091 0.1615626153
C* teoritis = 13.810449 20.381818182 6.5713688909 0.1521752951
20.163636364 6.3531870728 0.157401315
19.277272727 5.4668234364 0.1829215836
20.245454545 6.4350052546 0.1554000285
17.75 3.9395507091 0.2538360523
15.418181818 1.6077325273 0.621994009
13.481818182 -0.3286311091 -3.0429255553
16.372727273 2.5622779819 0.3902777166
10.959090909 -2.8513583818 -0.3507100357
16.653636364 2.8431870728 0.3517179751
12.077272727 -1.7331765636 -0.5769752609
16.481818182 2.6713688909 0.3743399137
0.00035

0.0003

0.00025

0.0002
1/(C-C*)

0.00015

0.0001

0.00005

0
-3 -2 -1 0 1 2 3 4 5 6
C

2
0
-2 -1.5 -1 -0.5 0 0.5 1 1.5 2
-2
-4
1/(C-C*)

-6
-8
-10
-12
-14
-16
C

0.025

0.02

0.015
1/(C-C*)

0.01

0.005

0
20 25 30 35 40 45 50 55 60
C
1
0.5
0
5 7 9 11 13 15 17 19 21 23
-0.5
1/(C-C*)

-1
-1.5
-2
-2.5
-3
-3.5
C
Co= 50 ppm t C
h= 3.3927272727 m= 0.05 gr 0 4.9673
x2 = 1.5745454545 C* teoritis = 4.2512850876 1 4.9773
f2 = 0.000328234 C* permodelan = 13 3 5.4827
simpson = 0.0022272181 Kc permodelan = 5 4.8791
A= 47.5 10 4.3850
Kc1 = 0.00019537 15 4.2732
Kc2 = 0.000019537 20 3.7714
-1.8181818182 0 25 4.9359
-1.8181818182 0.0003286001 30 -1.8182
1.5745454545 0 35 2.3723
1.5745454545 0.000328234 40 -1.8182
4.9672727273 0 50 0.1906
4.9672727273 0.0003278691 60 -1.8182

Co= 50 ppm t C
h= 0.2519545455 m= 0.1 gr 0 -1.1675
x2 = -1.419409091 C* teoritis = 6.9629713411 1 -1.4572
f2 = -0.341361804 C* permodelan = 33 3 -0.3318
simpson = -0.201537177 Kc permodelan = 5 -1.8182
A= 47.5 10 1.6882
Kc1 = -0.0176787 15 0.4755
Kc2 = -0.00176787 20 -0.6200
-1.6713636364 0 25 -0.7818
-1.6713636364 -0.450849703 30 -1.3064
-1.4194090909 0 35 -1.8182
-1.4194090909 -0.341361804 40 -1.8182
-1.1674545455 0 50 -1.3459
-1.1674545455 -0.583388035 60 -1.6714

Co= 150 ppm t C


h= 7.8545454545 m= 0.05 gr 0 54.9455
Faktor
x2 = 47.090909091 Pengenceran= 2 1 55.0000
f2 = 0.0158874463 C* teoritis = 31.729351426 3 54.8364
simpson = 0.2467504457 C* permodelan = 60 5 57.7545
A= 47.5 Kc permodelan = 10 45.4355
Kc1 = 0.0216447759 15 40.0818
Kc2 = 0.0021644776 20 23.3364
39.236363636 0 25 53.5573
39.236363636 0.0171715827 30 49.4664
47.090909091 0 35 46.7364
47.090909091 0.0158874463 40 47.4155
54.945454545 0 50 52.9545
54.945454545 0.0135235939 60 39.2364
Co= 150 ppm t C
h= 1.7590909091 m= 0.1 gr 0 20.0000
x2 = 18.240909091 C* teoritis = -24.06438911 1 20.3818
f2 = 0.2048113406 C* permodelan = 14.5 3 20.1636
simpson = 0.7946094453 Kc permodelan = 5 19.2773
A= 95 10 20.2455
Kc1 = 0.0348512915 15 17.7500
Kc2 = 0.0069702583 20 15.4182
16.481818182 0 25 13.4818
16.481818182 0.3743399137 30 16.3727
18.240909091 0 35 10.9591
18.240909091 0.2048113406 40 16.6536
20 0 50 12.0773
20 0.1615626153 60 16.4818
Cteoritis Cpermodelan
6
4.9672727273 4.9672727273
5
4.9672461501 4.9672727273
4.9671929987 4.9672727273 4
4.9671398512 4.9672727273 3
4.9670069998 4.9672727273 2

C [ppm]
4.9668741731 4.9672727273
1
4.966741371 4.9672727273
0
4.9666085936 4.9672727273 0 10 20 30 40 50 60 70
4.9664758408 4.9672727273 -1

4.9663431126 4.9672727273 -2
4.9662104091 4.9672727273 -3
4.9659450759 4.9672727273 t [menit]
4.9656798412 4.9672727273

Cteoritis Cpermodelan 2
-1.1674545455 -1.1674545455
-1.1948101809 -1.1674545455 1
-1.2497978839 -1.1674545455
0
-1.3051562327 -1.1674545455
0 10 20 30 40 50 60 70
C [ppm]

-1.445190117 -1.1674545455
-1
-1.5875956977 -1.1674545455
-1.7324131433 -1.1674545455 -2
-1.8796833026 -1.1674545455
-2.0294477161 -1.1674545455 -3
-2.1817486281 -1.1674545455
-2.3366289981 -1.1674545455 -4
-2.6543036011 -1.1674545455 t [menit]
-2.9828299772 -1.1674545455

Cteoritis Cpermodelan 70
54.9454545455 54.9454545455
60
54.8501742038 54.9454545455
54.660785025 54.9454545455 50
54.4729471865 54.9454545455 40
C [ppm]

54.0100565665 54.9454545455
30 C
53.5565869601 54.9454545455 Ct
53.1123466256 54.9454545455 20 Cp
52.6771477234 54.9454545455
10
52.2508062373 54.9454545455
51.8331418961 54.9454545455 0
0 10 20 30 40 50 60 70
51.4239780975 54.9454545455
50.6304636179 54.9454545455 t [menit]

49.8689205607 54.9454545455
Cteoritis Cpermodelan
22
20 20
19.4202808956 20 20
18.2836230155 20
18
17.1766765517 20
14.5342509998 20

C [ppm]
16
C
12.0611327315 20
Ct
9.7464737755 20 14
Cp
7.5801212192 20
12
5.5525726744 20
3.6549345961 20 10
1.8788832729 20 0 10 20 30 40 50 60 70
-1.3391215139 20 t [menit]
-4.1579648281 20
6
5
4

C Permodelan [ppm]
3
2

C 1
Cteori tis 0
Cpermodel an -3 -2 -1 0 1 2 3 4 5 6
-1
50 60 70
-2
-3
C Data [ppm]

C Data C teori tis C permodel a n

1
C Permodelan [ppm]

0
-2 -2 -1 -1 0 1 1 2 2
50 60 70
-1
C
Cteori tis -2
Cpermodel a n
-3

-4
C Data [ppm]

C Data C teori tis C permodel an

82
72
62
C Permodelan [ppm]

52
42
32
C
Cteori tis 22
Cpermodel a n
12
2
12 22 32 42 52 62 72 82
-8

50 60 70 C Data [ppm]

C Data C teori tis C permodel an


25
23
21
19

C Permodelan [ppm]
17
15
C 13
Cteori tis 11
Cpermodel a n 9
7
5
5 10 15 20 25 30 35 40
C Data [ppm]
50 60 70

C Data C teori tis C permodel an


3 4 5 6

el a n

1 2 2

el an

62 72 82

el an
30 35 40

el an
t 50 0,05 50 0,1 150 0,05 150 0,1
0 4.967273 54.94545 20
1 4.977273 55 20.38182
70
3 5.482727 54.83636 20.16364
60
5 4.879091 57.75455 19.27727
10 4.385 1.688182 45.43545 20.24545
50

Konsentrasi (ppm)
15 4.273182 0.475455 40.08182 17.75
40
20 3.771364 23.33636 15.41818 50 ppm ; 0,05 gram
25 4.935909 53.55727 13.48182
30 50 ppm ; 0,1 gram
30 49.46636 16.37273 150 ppm ; 0,05 gram
20
35 2.372273 46.73636 10.95909 150 ppm ; 0,1 gram
40 47.41545 16.65364
10
50 0.190591 52.95455 12.07727
0
60 39.23636 16.48182 0 20 40 60 80 100 120
120 33.97273 13.00727
Waktu (menit)
50 ppm ; 0,05 gram
50 ppm ; 0,1 gram
150 ppm ; 0,05 gram
150 ppm ; 0,1 gram