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1
D 1141 – 98 (2003)
5.2 Purity of Water—Unless otherwise indicated, references Zn(NO3)2·6H2O 0.151 g
to water shall be understood to mean reagent water conforming Pb(NO3)2 0.066 g
AgNO3 0.0049 g
to Specification D 1193, Type II.
5.3 Sodium Hydroxide, Solution, Standard (0.10 N)— Pre- NOTE 3—To make the addition of AgNO3 in the above solution,
pare and standardize as directed in Practice E 200. dissolve 0.049 g of AgNO3 in water and dilute to 1 L. Add 100 mL of this
solution to Stock Solution No. 3 before diluting to 10.0 L.
5.4 Stock Solution No. 1—Dissolve the indicated amounts
of the following salts in water and dilute to a total volume of 6. Preparation of Substitute Ocean Water
7.0 L. Store in well stoppered glass containers. 6.1 To prepare 10.0 L of substitute ocean water, dissolve
MgCl2·6H2O 3889.0 g ( = 555.6 g/L) 245.34 g of sodium chloride and 40.94 g of anhydrous sodium
CaCl2(anhydrous) 405.6 g ( = 57.9 g/L)
SrCl2·6H2O 14.8 g ( = 2.1 g/L) sulfate in 8 to 9 L of water. Add 200 mL of Stock Solution No.
1 slowly with vigorous stirring and then 100 mL of Stock
5.5 Stock Solution No. 2—Dissolve the indicated amounts Solution No. 2. Dilute to 10.0 L. Adjust the pH to 8.2 with 0.1
of the following salts in water and dilute to a total volume of N sodium hydroxide solution. Only a few millilitres of NaOH
7.0 L or a convenient volume. Store in well stoppered amber solution should be required.
glass containers.
KCl 486.2 g ( = 69.5 g/L) NOTE 4—Prepare the solution and adjust the pH immediately prior to
NaHCO3 140.7 g ( = 20.1 g/L) use.
KBr 70.4 g ( = 10.0 g/L)
H3BO3 19.0 g ( = 2.7 g/L) 7. Preparation of Substitute Ocean Water with Heavy
NaF 2.1 g ( = 0.3 g/L) Metals
5.6 Stock Solution No. 3—Dissolve the indicated amounts 7.1 Add 10 mL of Stock Solution No. 3 slowly and with
of the following salts in water and dilute to a total volume of vigorous stirring to 10.0 L of the substitute ocean water
10.0 L or a convenient volume. Store in well stoppered amber prepared as described in Section 6.
glass containers.
8. Keywords
Ba(NO3)2 0.994 g
Mn(NO3)2·6H2O 0.546 g 8.1 substitute brine; substitute ocean water; substitute salt
Cu(NO3)2·3H2O 0.396 g water; substitute seawater
APPENDIX
(Nonmandatory Information)
2
D 1141 – 98 (2003)
TABLE X1.1 Chemical Composition of Substitute Ocean Water A,B
Compound Concentration, g/L
NaCl 24.53
MgCl2 5.20
Na2SO4 4.09
CaCl2 1.16
KCl 0.695
NaHCO3 0.201
KBr 0.101
H3BO3 0.027
SrCl2 0.025
NaF 0.003
Ba(NO3)2 0.0000994
Mn(NO2)2 0.0000340
Cu(NO3)2 0.0000308
Zn(NO3)2 0.0000096
Pb(NO3)2 0.0000066
AgNO3 0.00000049
A
Chlorinity of this substitute ocean water is 19.38.
B
The pH (after adjustment with 0.1 N NaOH solution) is 8.2.
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