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PART TEST – I
Paper 2
s p ec i f i c a ll y f o r t h i s p u r p o s e.
Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-D.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet
1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
Section-A (07 – 10, 25 – 28, 43 – 46) contains 12 questions. Each question has TWO (02)
matching lists: LIST‐ I and LIST‐ II. FOUR options are given representing matching of elements
from LIST‐ I and LIST‐ II. ONLY ONE of these four options corresponds to a correct matching.
For each question, choose the option corresponding to the correct matching.
Each question has only one correct answer and carries +3 marks for correct answer and –1
mark for wrong answer.
2. Section-D (11 – 18, 29 – 36, 47 – 54) contains 24 Numerical answer type questions with answer
XXXXX.XX and each question carries +3 marks for correct answer. There is no negative marking.
Enrolment No.
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Useful Data
PHYSICS
2
Acceleration due to gravity g = 10 m/s
Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6 1019 C
Mass of electron me = 9.1 1031 kg
Permittivity of free space 0 = 8.85 1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
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(SECTION – D)
Correct Method :
0 0 3 4 8 . 4 0
0 0 2 5 1 . 3 7
0 0 2 1 3 . 0 0
Wrong Method :
3 4 8 . 4
3 4 8 . 4
3 4 8 . 4
3 4 8 . 4
2 5 1 . 3 7
2 1 3 .
2 1 3 . 0
2 1 3 . 0
3 4 8 . 4 0
2 5 1 . 3 7
2 1 3 . 0 0
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Physics PART – I
SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
1. A long thin uniform rod lies flat on the table as shown. One end of the
rod is slowly pulled up by a force that remains perpendicular to the rod
at all times. The rod is to be brought to the vertical position without any
slipping of the bottom end? The coefficient of static friction between rod
and ground can be:
(A) 0.2 (B) 0.3
(C) 0.4 (D) 0.5
2. Board A is placed on board B as shown. Both boards slide, without moving with respect to each
other, along a frictionless horizontal surface at a speed v . Board B hits a resting board C “head-
on.”
A A
B C B C
V=0
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4. A dumbbell consists of a light rod of length r and two small masses m attached to it.
The dumbbell stands vertically in the corner formed by two frictionless planes. After the
bottom end is slightly moved to the right, the dumbbell begins to slide. At the moment
the top end loses contact with the vertical plane:
(A) The acceleration of top mass is g.
(B) Horizontal component of acceleration of bottom mass is zero.
(C) The height of the top mass will be 2r/3.
2
(D) Speed of the bottom mass will be gR .
3
5. Two small spheres of mass m each are attached to the ends of a light rigid rod pivot
bent at a right angle and pivoted in the vertical plane at the vertex of the right
angle. The vertical part of the rod is three times as long as the horizontal part.
Initially, the rod is held at rest in the position shown in the diagram. The pivot is
frictionless. Assume that mass of rods are negligible. Immediately after the
system is released.
3
(A) Horizontal component of acceleration of center of mass of the system is m/s2 towards
10
right.
1
(B) Vertical component of acceleration of center of mass of the system is m/s2 downwards.
20
3mg
(C) Horizontal component of hinge reaction is towards right.
10
19mg
(D) Vertical component of hinge reaction is upwards.
20
6. Two identical uniform cylinders of radius R each are placed on top of each
other next to a wall as shown. After a disturbance, the bottom cylinder slightly
moves to the right and the system comes into motion. Neglect friction
between all surfaces.
(A) The top cylinder will have maximum acceleration g.
(B) The speed of the bottom cylinder will first increase then decrease.
(C) Minimum acceleration of the bottom cylinder is zero.
2
(D) Maximum speed of the bottom cylinder is gR
3
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R. Velocity of blocks
time
4.
S. Position of block B
time
5.
time
(A) P → 4; Q → 4; R → 1; S→4
(B) P → 3; Q → 3; R → 1; S→3
(C) P → 3; Q → 5; R → 4; S→2
(D) P → 4; Q → 3; R → 4; S→1
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A (Hinge)
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9. Three identical cylinders are arranged in a triangle as shown in Figure, with (3)
the bottom two lying on the ground. The ground and the cylinders are F (1) (2)
frictionless. You apply a constant horizontal force (directed to the right) on the
left cylinder. Let a be the acceleration you give to the system.
N12 is normal reaction between (1) and (2)
N13 is normal reaction between (1) and (3)
N23 is normal reaction between (2) and (3)
List –II shows various values of a.
Match the functions in List-I with the related charge distributions in List-II.
LIST–I LIST–II (values of a)
P. N12 = 0, N13 0 1. g
2. g
Q. N12 0, N13 0
2 3
3. g
R. N12 0, N13 = 0
4 3
4. g
S. N23 = 0, N13 0
6 3
5. Never possible
(A) P → 3, 4; Q → 2; R → 5; S→1
(B) P → 3, 2; Q → 1; R → 4; S→3
(C) P → 3, 1; Q → 2; R → 3; S→4
(D) P → 3, 3; Q → 1; R → 3; S→4
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SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
11. The wedge shown in the figure can slide without friction on a m
horizontal tabletop. The mass of the wedge is M and its angle of
o
elevation is α =30 . A body of mass m slides down without friction
along the wedge, the path of the body makes an angle of φ = 60o with
M
the ground. Find the ratio of the masses, m/M.
13. A block is placed on a long and wide inclined plane that makes angle = 45 with the horizontal.
The coefficient of kinetic friction between the block and the plane is µk = 2. After a quick push, the
block acquires velocity v 0 = 62 m/s that makes angle = 60 with the line of fastest descent.
Find the time interval t during which the block is in motion. (take g = 10 m/s2)
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15. A ball is thrown at speed v from zero height on level ground. The angle at which the particle is
thrown is such that the area under the trajectory is maximum? If the angle of projection in /k .
Find k .
16. A mass, which is free to move on a horizontal frictionless surface, is (top view)
attached to one end of a massless string that wraps partially around a
frictionless vertical pole of radius r (see the top view in Figure). You
hold on to the other end of the string. At t = 0, the mass has speed v 0 =
1m/s in the tangential direction along the dotted circle of radius R
shown. Your task is to pull on the string so that the mass keeps moving
along the dotted circle. You are required to do this in such a way that
the string remains in contact with the pole at all times. (You will have to
move your hand around the pole, of course.) What is the speed of the hand
R
mass at time t ?
2v 0 tan
17. A mass M collides elastically with a stationary mass m. If M = 2m, then there is a maximal angle
of deflection of M. This maximal angle equals /k radians. Find k .
18. A uniform flexible rope passes over two small frictionless pulleys
h
mounted at the same height (see figure). The length of rope
between the pulleys is = 23 m, and its ‘sag’ is h = 1 m. In
S=?
equilibrium, what is the length s of the rope segments that hang
down on either side?
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Chemistry PART – II
SECTION – A
(One or More than one correct type)
This section contains 6 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
19.
For the equilibrium SO 2 g Cl2 g
SO 2Cl2 g , the correct statement(s) is/are
(A) Addition of SO2(g) at constant volume at equilibrium increases the concentration of SO2Cl2(g)
(B) Addition of SO2(g) at constant volume at equilibrium increases the concentration of SO2(g)
(C) Addition of SO2Cl2(g) at constant volume at equilibrium increases the concentration of
SO2Cl2(g)
(D) Addition of inert gas at constant volume at equilibrium increases the concentration of
SO2Cl2 (g)
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25. Match each set of hybrid orbital from List – I with the molecule or ion given in List - II
LIST–I LIST–II
P. sp2 1. XeF5
Q. sp3 2. NO3
R. sp3d 3. NF4
S. sp3d2 4. SF2Cl2
5. IOF4
6. F2SeO
(A) P → 2; Q → 3; R → 4, 6; S → 1, 5
(B) P → 2; Q → 3, 6; R → 4; S → 1, 5
(C) P → 4; Q → 2; R → 3, 5; S→6
(D) P → 6; Q → 3, 6; R → 4, 2; S→1
26. Match the resulting solution in List-I with one or more properties in List – II and choose the correct
option. log2 = 0.3, log5 = 0.7. pKa CH3COOH = 4.74, pKb NH4OH = 4.74,
LIST–I LIST–II
P. 10 ml 0.1 M H2SO4 + 40 ml 0.1 M NH4OH 1. Acidic buffer solution
Q. 20 ml 0.1 M CH3COOH + 16 ml 0.1 M NaOH 2. Basic buffer solution
R. 50 ml 0.1 M CH3COOH + 50 ml 0.1 M NaOH 3. pH of the solution is 8.72
S. 10 ml 0.1 M NH4OH + 20 ml 0.1 M NH4Cl 4. pH of the solution is 8.96
5. pH of the solution 9.26
(A) P → 2, 4; Q → 1, 5; R → 3; S→2
(B) P → 2, 3; Q → 1, 4; R → 3, 1; S → 2, 4
(C) P → 5; Q → 1; R → 3, 4; S → 2
(D) P → 2, 5; Q → 1; R → 3; S → 2, 4
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27. Match the half-life of the reaction in List-I with the integrated rate equation in List-II(a = initial
concentration of reactant and a – x = concentration of reactant at time ‘t’.)
LIST–I LIST–II
0.586 1. x
P. t1/2 a k
k t
0.693 2. 1 1 1
Q. t1/2 k
k t a x a
a 3. 2
R. t1/2 k a a x
2k t
1 4. 2.303 a
S. t1/2 k log
ka t ax
5. 2 1 1
k
t ax a
(A) P → 5; Q → 4; R → 1; S→2
(B) P → 3; Q → 4; R → 1; S→2
(C) P → 2; Q → 3; R → 1; S→2
(D) P → 3; Q → 2; R → 4; S→5
28. List-I contains carbides and List-II contains the type of carbide and their hydrolysis product.
LIST–I LIST–II
P. Al4C3 1. Covalent carbide
Q. Mg2C3 2. Ionic carbide
R. CaC2 3. CH4
S. SiC 4. C3H4
5. C2H2
(A) P → 2, 3; Q → 2, 4; R → 2, 5; S → 1
(B) P → 1, 3; Q → 1, 4; R → 2, 5; S → 2
(C) P → 2, 4; Q → 1, 3; R → 1, 5; S → 5
(D) P → 2, 5; Q → 2, 4; R → 2, 3; S → 1
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SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
29. A first order reaction has a rate constant 5 10 2 s1 . The time required (in sec) for the reaction to
reduce 20 gram of the reactant to 2 g is
30. 20 g of CaCO3 is placed in a vessel of volume 12.315 litre at 1000 K. The following equilibrium
was established.
CaCO3 s
CaO s CO2 g
KP for the reaction at 1000 K is 0.3 atm. The mass of CaCO3 in gram at equilibrium is
31. 100 ml of 0.1 M CH3COOH, 50 ml 0.1 M HCl and 50 ml 0.1 M Ba(OH)2 are mixed together. pKa of
CH3COOH is 4.74. The pH of the resulting solution is
32. The mass of a dust particle is 10-12 g and its velocity is 10-4 cm/sec. The error in the
measurement of velocity is 0.01%. The uncertainty in the measurement of position in A o unit is
h
0.527 10 27 erg sec
4
33. Vapour density of a metal chloride is 85.02. The equivalent weight of the metal is 7.01. The
atomic weight of the metal is
34. In He2+ an electron undergoes transition from 3rd excited state of to 2nd energy level. The
1
wavelength of the light emitted in Ao is 911.7A o
R
35. In the thermal decomposition of NH4NO2, 50% of the compound decomposed in 34.65 min. The
time required in minutes for the 90% decomposition of the compound is
36. The equilibrium constant (KP) for a reaction at 27oC for a homogeneous gaseous reaction is 10-2.
The standard free energy change Go for the reaction in calorie is (R = 2 cal)
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SECTION – A
m
cos x n cos x
37. For two positive integers m and n lim , then which is true?
x 0 x2
1 3
(A) m = 3, n = 2 it is (B) m = 5, n = 2 it is
6 13
1 3
(C) m = 3, n = 2 it is (D) m = 5, n = 2 it is
12 20
ex
38. Let f x and g(x) = f(x), then
1 x2
(A) g(x) has two local maxima and two local minima points
(B) g(x) has exactly one local maxima and one local minima point
(C) x = 1 is a point of local maxima of g(x)
(D) there is a point of local maxima for g(x) in the interval (–1, 0)
minf t , 2 t x, 2 x 0
2
39. Let f(x) = x – 2|x| and g x max f t , 0 t x, 0 x 2 , then g(x) is not differentiable at
f x x2
(A) x = 0 (B) x = –1
(C) x = 2 (D) x = 1
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x
41. The equations of the normals to the curve f x at the points where the tangents make
1 x2
angle of with the positive direction of x-axis are
4
3
(A) x + y = 0 (B) x y
2
3
(C) x y 2 2 (D) x y
2
42. Let f be a function defined for all real x and let it satisfy the relation f(x + y) = f(x) + f(y) + xy(x + y)
if f(0) = –1, then
(A) f is differentiable for all real x
(B) f is differentiable for all real x
(C) f(3) = 8
1 1
(D) f satisfies the relation f x f f x f x 0
x
x
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5. 2
6. 0
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/2
x cos x sin x 3
R. dx 3. tan1
0 x2 sin x 4
1 3
x 3
S. 3 1 x 3 1 x dx 4.
18
1
3
5.
3
2 3
6.
18
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f: R R; f x e x (where [.] denotes the
P. 1. one-one
greatest integer function, and {.} denotes fractional
part function)
2
sgn x
Let f: R R defined as f x e ex (where
Q. 2. many one
sgn x denotes signum function of x, then f(x))
1 1
f: R R; f x x x 2 x (where [.]
R. 2 2 3. into and periodic
denotes the greatest integer function)
x2 x
S. f: [–1, ) (0, ) defined as f x e , then f(x) 4. onto
is
5. periodic
6. constant
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SECTION – D
(Numerical Answer Type)
This section contains EIGHT questions. The answer to each question is a NUMERICAL VALUE. For
each question, enter the correct numerical value (in decimal notation, truncated/rounded‐off to the
second decimal place; e.g. xxxxx.xx).
1 1 1
1
47. If limit lim n
n
2 n
11 22 33 ..... nn n2 = L, then –ln L is _____
48. The positive value of ‘a’ such that the parabola y = x2 + 1, bisects the area of the rectangle with
a
vertices (0, 0), (a, 0), (0, a2 + 1), (a, a2 + 1), then is _____
2 3
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49. Let A – rational number between (0, 1), and a function f: A R has the property that for all x A
1 2001 f 2007
f x f 1 ln x , then the value and e is _____
x 2014
4
k
50. The value of which minimizes F k x 4 x k dx _____
2 0
51. For x a real number, let f(x) = 0 if x < 1 and f(x) = 2x – 2 if x 1. If number of solutions to the
n
equation f f f f x x is n, then
5
is equal to _____
52. For any real 1 denote by f() the real solution to the equation x(1 + ln x) = , then
1 f
lim is _____
2
ln
1 4
x x
6
53. x3 3
2 3 dx = x 6 2x3 3 c , then 2 is equal to _____
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