CHEMISTRY

JEE ADVANCED SAMPLE PAPER

Chapter 29. Carbonyl Compounds

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1. When propanoic acid is treated with aqueous NaHCO3, CO2 is liberated. The carbon of carbon
dioxide comes from:
(a) methyl group
(b) carboxylic group
(c) methylene group
(d) bicarbonate

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 JEE Advanced Sample Paper – 29. Carbonyl Compounds

2. 0.759 g of a silver salt of a dibasic organic acid on ignition left 0.463 g metallic silver. The
equivalent weight of acid is:
(a) 70
(b) 108
(c) 60
(d) 50

3. Which of the following compounds easily undergoes decarboxylation?

(a) CCl3COOH
(b) β- Keto carboxylic acid
(c) HCOOH
(d) CH3COOH

Br2/Red Alc. NH3

4. CH3CH2COOH (A) (B)
P ∆
The final product (B) in above reaction is:
(a) alanine
(b) pyruvic acid
(c) citric acid
(d) lactic acid

5. What reagent is used in the Rosenmund’s reduction?

(a) H2/Pb-BaSO4
(b) LiAlH4
(c) NH2NH2/KOH/CH2OH-CH2OH
(d) Zn-Hg/HCl

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 JEE Advanced Sample Paper – 29. Carbonyl Compounds

6. The smallest ketone and its next homolgoue are reacted with NH2OH to form oxime:
(a) two different oximes are formed
(b) three different oximes are formed
(c) two oximees are optically active
(d) all oximes are optically active

7. The product formed in Aldol condensation is:

(a) an alpha-hydroxy aldehyde or ketone
(b) an alpha beta unsaturated ester
(c) a beta-hydroxy acid
(d) a beta-hydroxy aldehyde or beta-hydroxy ketone

8. The most suitable reagent for the conversion of primary alcohol into aldehyde with the same
number of carbon is:
(a) acidified K2Cr2O7
(b) acidified KMnO4
(c) alkaline KMnO4
(d) pyridinium chlorochromate

9. When acetaldehyde is treated with ammonical silver nitrate solution, we get:

(a) silver mirror
(b) a brown precipitate
(c) red colouration
(d) no precipitate

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 JEE Advanced Sample Paper – 29. Carbonyl Compounds

Passage
10. Aldehydes and ketones are specially susceptible to nucleopilic addition because carbonyl group

C=O is polar (due to electronegativity difference between carbon and oxygen).

δ+ δ−
C=O Positive charge on carbon makes it reactive towards the nucleophile. This addition
is catalysed by acid. Reactivity of carbonyl compound towards nucleophilic addition increases
with increase in the electron deficiency at carbonyl carbon. Thus, (−I.E.) group increase while
(+I.E.) groups decrease the reactivity of carbonyl compound.

Answer the following is most reactive to give nucleophiliic addition?

I. Which among the following is most reactive to give nuclophilic addition?

(a) FCH2CHO
(b) CICH2CHO
(c) BrCH2CHO
(d) ICH2CHO

II. Carbonyl compounds show nucleophilic addition with:

(a) HCN
(b) NaHSO3
(c) (CH3OH + HCl)
(d) all of these

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 JEE Advanced Sample Paper – 29. Carbonyl Compounds

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 JEE Advanced Sample Paper – 29. Carbonyl Compounds

Answer Keys

Q1 Q2 Q3 Q4 Q5
(d) (a) (b) (a) (a)

Q6 Q7 Q8 Q9 Q10
(b) (d) (d) (a) Ⅰ. (a)
Ⅱ. (d)

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