SISTEMA ETHANOL - ETHIL ACETATE PROCESO ISOTERMICO

HALLAMOS PRESION DE VAPOR

DATOS DE LA TABLA 1 "CTES ANTOINE" T°C 40
COMPONENT A B C PvC1 134.023
ETHANOL 8.04494 1,554.300 222.65 pvC2 189.756531
ETHYL ACETATE 7.0981 1238.71 217
ESION DE VAPOR
HALLAMOS LOS VALORES DE:

DE LA TABLA DE MARGULES PARA:

A12 A21 PROCESO X1 0.1
ETHANOL 0.4816 0.413 ISOTERMICO X2 0.9
ETHIL ACETATE 0.3925 0.3313 ISOBARICO

λ1= 2.39322097 2.39322097

λ2= 1.01021683 1.01021683

X1 Y1 P
0.2 0.2489 210.27
0.1 0.1567 204.6
PARA UN PROCESO ISOTERMICO X1 0.1
CALCULAMOS LA PRESION X2 0.9
P=X1*PvC1*L1+x2PvC2*L2 PvC1 134.023
P= 204.600383 mm Hg PvC2 189.756531
λ1= 2.39322097
λ2= 1.01021683

Hallamos:
y1 0.15676738
y2 0.84323262
X1 X2 PvC1 PvC2 λ1 λ2 P Y1
0.0001 0.9999 134.0228104214 189.756531 3.03033029 1.00000001 189.778171 0.000214
0.1 0.9 134.0228104214 189.756531 2.39322097 1.01242952 204.978222 0.15647818
0.2 0.8 134.0228104214 189.756531 1.95282083 1.04932592 211.637664 0.24733077
0.3 0.7 134.0228104214 189.756531 1.64367368 1.11125467 213.694412 0.30925905
0.4 0.6 134.0228104214 189.756531 1.42435813 1.20019331 213.005303 0.35848212
0.5 0.5 134.0228104214 189.756531 1.2683818 1.31947146 210.185209 0.40438643
0.6 0.4 134.0228104214 189.756531 1.15847002 1.47379405 205.021664 0.45437562
0.7 0.3 134.0228104214 189.756531 1.08317942 1.6693154 196.648575 0.51675699
0.8 0.2 134.0228104214 189.756531 1.03484094 1.91373412 183.582542 0.60438118
0.9 0.1 134.0228104214 189.756531 1.00828011 2.21637478 163.67644 0.74304696
1 0 134.0228104214 189.756531 1 2.58821292 134.02281 1

X1 vs Y1 220
1.2 210

1 200
190
0.8
180
0.6 170
X1

0.4 160
150
0.2
140
0 130
0 0.2 0.4 0.6 0.8 1 1.2
120
Y1 0 0.2
 CONSTANTE DE ANTOINE T° 40
Y2 COMPONENTE A B C
0.999786 ETHANOL 8.04494 1,554.300 222.65
0.84352182 ETHYL ACETATE 7.0981 1238.71 217
0.75266923
0.69074095
0.64151788
0.59561357
0.54562438
0.48324301
0.39561882
0.25695304
0

P2 vs X1 y Y1
220
210
200
190
180
170
160
150
140
130
120
0 0.2 0.4 0.6 0.8 1 1.2
0 1
0 1