ACETIC ACID

Persamaan Reaksi

Fase Cair – Gas :

CH3OH + CO CH3COOH

T1 = 298 ⁰K ; T2 = 448 ; P = 1 atm ; Basic = 1 mol

Komponen

Senyawa ∆Hf⁰ (Kj/mol) ∆Gf⁰ (Kj/mol)

CH3OH -239.03 -166.81
CO -110.53 -137.36
CH3COOH -484.13 -389.94
R = 8,314

1. Setarakan Reaksi

CH3OH + CO CH3COOH

2. Hitung ∆GR⁰ dan ∆HR⁰

∆GR⁰ = ( - 389.94 ) - ( - 166.81 + [- 137.36] ) = - 85.77 Kj/mol

∆HR⁰ = ( - 484.13 ) - ( - 239.03 + [- 110.53] ) = - 134.57 Kj/mol

3. Ka1
= e -∆G/RT = e –85.77/8.314 x 298 = 0.996

4.
CH3OH + CO CH3COOH
m 1 1
b -x -x x
s 1–x 1–x x
5. Secara Komposisi Ka1

2
Y setimbang produk x1.x 1 x
Ka = = =
Y setimbangreaktan (1−x ) (1−x) (1−x )2❑
2
x x x
0.996 = → √0.996 = → 0.997 = → 0.997 –
(1−x ) 2❑ (1−x ) (1−x )
0.997x = x

0.997
0.997 = 1.997x → x = → x = 0.4992
1.997
6. α
Y reaktan bereaksi 0.4992
= → → 0.4992 %
Y reaktan mula−mula 1

7. Ka2
∆ Hf ⁰
ln Ka2 - ln Ka1 =
R ( T11 − T12 )
−134 57 0
ln Ka2 - ln Ka1 =
8.314 ( 2981 − 4481 )
ln Ka2 - ln 0.996 = - 18.186

ln Ka2 + 0.004 = - 18.186

ln Ka2 = - 18.186 - 0.004

ln Ka2 = - 18.182

Ka2 = e – 18.182

Ka2 = 0.0000000127

8. Secara Komposisi Ka2

2
Y setimbang produk x1.x 1 x
Ka2 = = =
Y setimbangreaktan (1−x ) (1−x) (1−x )2❑
2
x x
→ 0.0000000127 = → √ 0.0000000127 = → 0.0001127
(1−x ) 2❑ (1−x )
x
=
(1−x )
→ 0.0001127 – 0.0001127x = x → 0.0001127 = 1.0001127x → x =
0.0001127
1 .0001127

→ x = 0.00011268