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CORROSION SCIENCE SECTION

Stress Corrosion Cracking of Steam Turbine Rotors

D.A. Rosario,* R. Viswanathan,** C.H. Wells, and G.J. Licina*

ABSTRACT INTRODUCTION
In the wake of the catastrophic failure of a low-pressure (LP) Stress corrosion cracking (SCC) is an ubiquitous
turbine disk at the Hinkley Point Nuclear Station in 1969, problem in power station equipment subject to flow-
considerable research and development has been devoted to ing or condensing wet surface films. The problem is
the problem of stress corrosion cracking (SCC) in steam tur- particularly insidious at the highly stressed mating
bine rotors. Principle factors affecting the susceptibility of
surfaces of steam turbine rotors, where crevice corro-
rotors to SCC have been identified as disk yield strength,
sion conditions, crack initiation, and early growth of
applied stress level, and surface film/crevice chemistry.
Microstructure and cleanliness of the steel have been found cracks may go undetected for many years. Conse-
to have relatively little effect. Advances in steel making and quences of undetected cracking have been
forging over the last 20 years have provided manufacturers demonstrated repeatedly over almost three decades,
with additional design and material options to mitigate the commencing with the Hinkley Point disk burst in
problem. Increases in forging size capabilities of steel compa- 1969 and the discovery of bore cracks in disk tur-
nies and the welded construction of rotors now permit bines. Financial and safety risks of bore cracking,
designing with integral and partial integral rotors that use especially in nuclear plants, prompted a massive
materials with lower yield strength (more SCC resistant) as response from the power industry worldwide to cope
well as eliminating the SCC problem in bores and keyways.
with the complex issues of rotor design, material
However, a recent survey of U.S. utilities has shown that
properties, steam chemistry, and nondestructive
SCC in the blade attachment legion of LP rotors is an increas-
ing concern. This problem has led to development of repair
inspection that govern the economics of turbine
and refurbishment methods for rim attachments, especially maintenance.
weld buildup of rims with corrosion-resistant alloys. Life Research Project RP1398 of the Electric Power
prediction of rotors under SCC conditions currently involves Research Institute (EPRI) addressed the root cause of
estimating crack growth time from assumed defects to critical SCC and produced a survey of the extent of disk
size. Factors that govern the location and time of crack initia- cracking experienced by nuclear and fossil utilities
tion are not understood adequately. up until 1981. Key findings were the dependence of
KEY WORDS: environmentally assisted corrosion, industrial
crack growth rate on disk yield strength, tempera-
applications, nuclear applications, power generation, rotors, ture, applied stress level, and steam chemistry, with
steam turbine, steel, stress corrosion cracking secondary influences of steel composition and the
concentration of cracking at the farthest upstream
Submitted for publication December 1996; in revised form, June
stage of the turbine at which water droplets formed,
1997. commonly referred to as the Wilson line. Combined
* Structural Integrity Associates, 3315 Almaden Expressway, Suite with inspection procedures, this information allows
24, San Jose, CA 95118.
** Electric Power Research Institute, 3412 Hillview Ave., Palo Alto, estimates of the time for crack growth to critical size.
CA 94303. Recently, Lyle reviewed this early research and com-

0010-9312/98/000117/$5.00+$0.50/0
CORROSION–Vol. 54, No. 7 © 1998, NACE International 531
CORROSION SCIENCE SECTION

TABLE 1
Time to Initiate Stress Corrosion Cracks in Creviced Regions at 130°C (266°F) as Reported by Lyle(A)
Time to Initiate Cracks (h)
Yield High-Purity Intermediate Contaminated
Strength Water Oxygen Water
Steel(B) MPa (ksi) Environment(C) Environment(C) Environment(D)

AH 934 (135) 8,585 425 1,289


AL 780 (113) > 17,520 1,924 1,989
JH 941 (136) 8,625 1,866 2,106
JL 741 (108) > 17,520 2,190 3,979
JP 738 (107) > 17,520 1,683 2,650

(A)
Representative of typical short-term upset conditions with 40 ppb oxygen and 20 ppb sodium chloride (NaCl).
(B)
High-strength and low-strength 3.5% Ni-Cr-Mo-V American steels are designated AH and AL, respectively, while Japanese
steels are designated JH and JL, respectively. The Japanese high-purity steel is designated JP.
(C)
Representative of secondary-side water in a PWR during normal operation with < 5 ppb oxygen.
(D)
Representative of a severe secondary water upset condition with 6ppm to 8 ppm oxygen and 20 ppb NaCl.

bined with it the results of international projects on and applied stress in establishing susceptibility.
characterization of the susceptibility of rotor steels of Temperature was a constant 130°C (266°F) in these
various composition and strength levels to environ- tests. Estimates were made of the time to crack ini-
mental factors, including his own results with tiation in typical disks on the basis of the results and
simulated crevices.1 This recent review, combined a generalized SCC crack growth rate correlation.
with other observations, underscores some signifi- Specimens were tested at stress levels equal to 70%
cant gaps in understanding crack initiation and the and 90% of yield strength and at stresses in excess of
ability to predict the onset of cracking. yield strength. Initiation times were on the order of
Refurbishment and repair methods have been 1 year to 2 years as shown in Table 1 for typical
introduced to reduce or eliminate the risk of SCC, as American- and Japanese-made high- and low-
have improvements in steel making and processing strength steel in various environments.3 The short
for more resistant forgings. At the same time, indus- initiation times in the laboratory tests were not con-
try efforts to reduce the risk of bore and keyway sistent with field experience, which indicated the first
cracking through integrally forged and welded rotor detection of SCC in certain disk rims generally is
construction have shifted concern somewhat to the observed after many years of operation. Lyle also
susceptibility of rim attachments. It has been par- concluded that crevices and crevice chemistry played
ticularly important to determine whether this a strong role in crack initiation, but that steel micro-
cracking mode should become more prevalent with structure and chemistry effects were relatively weak.
aging of the fleet and what mitigation steps should be Oxygen was reported to be the dominant impurity.
taken. Only a few instances of cracks growing from pits
These issues led to a survey of U.S. utility expe- were observed on test specimens. Initiation from
rience and of the efficacy of repair methods, the corrosion trenches was favored strongly over initia-
results of which are summarized in the present work. tion from pits.
Also addressed are the adequacy of life prediction Rau, et al., proposed a quantitative model for
and nondestructive examination methods to provide SCC initiation time, using a normalized initiation
the basis of maintenance decisions. An overview of time (tN) given by:4
key research results generated during recent years
also is presented.
σ 3
tN = td R (1)
σys
SCC and Life Prediction Methods
SCC Initiation — Cheruvu and Seth investigated
factors that control initiation and found that oxygen where td is the actual or calculated initiation time
and caustic were the most aggressive.2 However, from field experience, (␴/␴ys) is the ratio of surface
rotor materials exposed at < 200°F (93.3°C) or that tensile stress to yield, and R is the SCC crack growth
had a yield strength (ys) < 110 ksi (758 MPa) exhib- rate (computed wing data from EPRI RP2408-1) to
ited no significant cracking. Lyle recently published account for the dependence of initiation time on disk
results of a test that addressed the influence of water temperature, yield strength, manganese content, and
chemistry and material composition and hardness tempering temperature. The effect of surface stress
on relative rates of SCC over a 24-month duration.3 was accounted for using a third-power dependence
Results confirmed the dominant role of yield strength based on laboratory test data.5-6 The normalized ini-

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tiation times then were fit statistically to yield an


initiation probability (P) given by:

tN – t0
P = 1.0 – exp – α (2)
β – t0

where ␣, ␤, and t0 are curve fit constants. Figure 1 is


an example of initiation probability data compiled by
Rau for disk keyway cracks.
Endo, et al., recently published results of a labo-
ratory study on environmentally assisted cracking
(SCC and corrosion fatigue) in 3.5% Ni-Cr-Mo-V
steels with yield strengths of 700 MPa to 1,050 MPa
(102 ksi to 152 ksi).7 Testing was performed at stress
FIGURE 1. SCC initiation probability vs tN to account for stress and
levels equal to the disk yield strength. The three SCC growth rate (Rau, et al.4).
damage mechanisms investigated were SCC, dynamic
SCC, and corrosion fatigue. The SCC process was
reported to consist of three stages: pit growth, crack
formation, and macroscopic crack propagation (Fig-
ure 2). Cracks were observed to initiate at corrosion
pits. Lyle has shown that pitting is not required as a
precursor to SCC.3 A correlation was seen by Endo
between the number of pits and the inclusion con-
tent or impurities. Higher material yield strength and
higher temperatures were found to reduce crack ini-
tiation time. Crack initiation from a microscopic pit
was predicted for a critical pit size 2Ccr, which occurs
when the applied stress intensity factor exceeds a
critical value (KISCC)P for static stress or (∆Kth)P where
corrosion fatigue is operative. Increasing the number
of start-stop cycles and longer hold times were found FIGURE 2. Stress corrosion crack initiation and growth model per
to reduce crack initiation time, a phenomenon re- Endo, et al.7
ferred to as dynamic SCC. The dependence of stress
corrosion crack growth rate on yield strength and
temperature per Clark, et al.,8 was verified by Endo.
A summary of Siemens† experience and research
and development studies on low-pressure (LP) rotor
SCC was provided by David, et al.9 Only one of 430
disks in Siemens/KWU nuclear turbines had SCC.
None occurred in the rim attachment region. Exten-
sive SCC initiation testing was performed on
low-alloy LP turbine rotor and disk materials for vari-
ous applied stress-to-yield strength (RSCCI) ratios and
environments (high-purity water up to 212°F, con-
densing steam at 203°F and 30% sodium hydroxide
[NaOH] solution at 212°F to 392°F). Results are sum-
marized in Figure 3. As shown, an improvement in
the operating environment permitted high stress FIGURE 3. Stress corrosion crack initiation results by Siemens.9
levels up to and above the yield strength level of the
material. Even in a severely corrosive environment,
SCC initiation did not occur for stress levels below of the high-purity water condition in those plants,
half the material yield strength (0.5 RSCCI). Siemens which permits operating levels up to 10% above yield
concluded that the absence of SCC in 1970-vintage strength (1.1 RSCCI) without initiating cracking. In
rotors in nuclear power plants probably was a result contradiction with Endo, et al.,7 but consistent with
Lyle3 and Holdsworth, et al.,10 the Siemens data indi-

Trade name. cated that SCC initiation in high-purity water is not

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affected by the cleanliness of steel (i.e., nonmetallic This equation has been accepted by the U.S.
inclusions do not serve as initiation sites for corro- Nuclear Regulatory Commission for remaining life
sion pits). predictions of turbine disks with cracks.14 Since that
Part of the problem in predicting the initiation time, additional crack growth rate data has been
life of a disk rim is the uncertain history of attach- generated under EPRI RP2408-1.15 Recalibration of
ment crevice chemistry and existence of a liquid film. the two-variable Clark model yielded the equation:
A program is under way that includes monitoring of
droplet nucleation and growth in the steam path, ln R = –8.8 – (4,040/T) + 0.0231σys (5)
simulating the enthalpy drop in a bypass loop, and
measuring the chemistry of a crevice placed in the The standard deviation of residuals was 120 for the
flow loop.11 Condensation can take place on the up- above equation, which was based on 228 data points,
stream rim face if the surface temperature is vs 0.587 for the Clark model, which was based on 70
sufficiently low and the total pressure is sufficiently data points. The study also identified two more sig-
high. In addition, water may condense on adjacent nificant variables. Manganese content and tempering
surfaces, such as the web of a disk or ID stator temperature for disks that were tempered specifically
shroud and flow past the rim if no seal is present. No below the ASTM A 471 standards(1) (1,050°F) to ob-
mapping of surface temperature or liquid films has tain high strength. The three-variable model with the
been reported. effect of manganese is given as:
Early studies concluded that cracking occurred
at the blade stage just downstream of the point of ln R = –4.74 – (9,270/T) + 0.0337σys + 4.53Mn (6)
thermodynamic equilibrium moisture formation, or
Wilson line, since that stage would experience the where Mn is the weight percent of manganese. The
highest film temperature.12 In fact, it appeared that standard deviation for this model is 1.17. For disks
upstream blade rows were primarily susceptible to tempered above 1,050°F, the effect of tempering tem-
cracking in the 1980 survey. It followed that down- perature was included as:
stream rows, assuming the presence of moisture,
also eventually should crack with increasing expo- lnR = – 7.04 – (9,270/T) + 0.0337σys
sure time. The picture is complicated by the (7)
+ 4.53Mn – 0.0127TT
possibility of excessively wet operation at one point
in a unit’s history, as was attributed in some units to
moisture/separator malfunction. where TT is the tempering temperature in degrees
Once the solute concentration in a crevice has Kelvin. The standard deviation for this model is 1.20.
increased because of off-design operation or other Data on foul disk crack growth rate was pre-
factors, the vapor pressure is lowered, and moisture sented by U.S. and foreign researchers at the EPRI
may remain stable at temperatures above the Wilson Fossil Steam Turbine Disk Cracking Workshop in
line.11 October 1990.16 In summary, the roles of tempera-
Another factor complicating the prediction of ture, stress, environment, material condition, etc., on
SCC initiation is the uncertainty in local surface crack growth rate have been investigated extensively.
tensile stress, which requires knowledge of residual However, the wide scatter in the data suggests that
machining stress and the machining tolerances and further studies and modeling would be required to
variation of the blade-to-disk fit-up. Finite element better characterize the data.
models exist for most of the blade attachments sus- Life Prediction Codes — Two crack propagation-
ceptible to SCC,13 although few are in the public based life prediction codes have been developed and
domain. A quantitative data base should incorporate publicized for LP blade attachments, Lifetime Analy-
the nominal attachment stress, with statistical vari- sis of Steeples (LAST) by the Southwest Research
ability in fit-up. Institute (SWRI)17 and the Disk Crack Evaluator
SCC Crack Growth Rate — The most widely ac- (DICE) developed under EPRI RP1929-14 as part of
cepted model for crack growth rate was given by the EPRI guidelines for predicting the life of steam
Clark, et al., in 1981, as expressed by:8 turbine disks exhibiting SCC.18
The LAST code was developed for two
ln R = –4.968– (7,302/T) + 0.0278σys (4) Westinghouse† design L-5 and L-0 steeples and one
General Electric† (GE) L-1 steeple. The code assumes
where R is the crack growth rate in in./h, T is the an existing crack, and propagation is simulated by
temperature in °Rankine (i.e., °F + 460), and ␴ys is SCC and corrosion fatigue. Remaining life is the time
the room-temperature disk yield strength in ksi. required to grow the existing crack to critical size.
Typically, very little life remains once the crack
(1)
ASTM A 471-77, “Standard Specification for Vacuum-Treated
Alloy Steel Forgings for Turbine Rotor Disks and Wheels (West
reaches the fatigue threshold depth. Proprietary cor-
Conshohocken, PA: ASTM, 1982). rosion fatigue threshold and crack growth data are

534 CORROSION–JULY 1998


CORROSION SCIENCE SECTION

used by the code. Two crack geometries, an edge


crack and a semielliptic surface crack, can be evalu-
ated. The SCC growth rate is simulated using the
Westinghouse equation (Equation [4]). Sample re-
maining life results are shown in Figure 4 as a func-
tion of initial crack depth and alternating stress level.
The DICE code performs calculations of stress
intensity vs crack size and critical crack size for an
edge crack and a semielliptic surface crack. The user
specifies a stress distribution and fracture toughness
value. These calculations are part of the overall 1989
EPRI guidelines for predicting the life of steam tur-
bine disks with SCC.18 These guidelines offer two
levels of analyses, depending upon the amount of
information available. SCC growth rates are simu-
lated using Equations (5) through (7).15
In summary, there does not appear to be a single
commercially available code that combines the expe-
rience-based crack initiation probability and
incorporates distributions of stress, temperature,
presence of wet surface films (flowing/stagnant,
refluxing, condensing, etc.) and material properties, FIGURE 4. Sample remaining life results of the SWRI LAST computer
code.17
with a probabilistic crack growth rate analysis.

U.S. Industry Experience


Typical locations and orientations of cracks
documented in the original industry survey through
July 1980 are illustrated in Figure 5.12 This survey
included one decommissioned plant and 33 of 72
operating U.S. nuclear plants at that time: 29 pres-
surized-water reactors (PWR) with steam generators
made by Westinghouse, Combustion Engineering†
(CE), and Babcock & Wilcox† (B&W); and 5 boiling-
water reactors (BWR) made by GE. Power ratings
ranged from 100 MW to 1,100 MW with operating
times from 6 month to 20 years. The 33 plants had a
total of 79 LP turbines, of which 76 had disks made
of quenched-and-tempered 3.5% Ni-Cr-Mo-V steels.
Two turbines had disks made of normalized-and-
tempered 2.5% Ni-Cr-Mo-V steels, and one had disks
made of 1% Cr-1/2% Mo steel. Cracking was found
only in Westinghouse rotors in 20 of 33 plants, of
which 19 were PWR and one was a BWR. Cracking
was found in 70 disks from 36 LP rotors, 35 disks
had keyway cracks, 5 disks had bore surface cracks,
7 disks had face cracks, and 30 disks had rim
attachment cracks (some had more than one type of FIGURE 5. Illustration of typical locations and orientations of cracks
crack). Crack depths ranged from 2.5 mm to 75 mm in U.S. LP rotor disks.12
(0.1 in. to 3.0 in.). Cracks were predominantly inter-
granular and branched and usually were filled with
iron oxides. It generally was agreed that the operative of 20 ppm to 30 ppm. Plants with oxygen levels nor-
mechanism was SCC. Survey data indicated a corre- mally < 5 ppb and never > 15 ppb did not develop
lation between disk cracking and the following cracking. The source of oxygen in most of the plants
variables: was air in leakage through the condenser, which
— All cracking occurred at or downstream of the typically occurs during plant start-ups; and
saturation line where wet steam is usually present; — The crack growth rate was higher for disks
— The most widespread and most severe crack- with higher yield strengths and also increased with
ing occurred in a plant with the highest oxygen level disk operating temperature.

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pertinent industry experience was gathered regarding


the problem of SCC in fossil turbine disks.16 GE
reported that 1,049 disks in 85 of the older fossil
turbines of GE design had been inspected. Of these,
36 disks were reported to have ultrasonic indications
in the keyways. Twelve of the indications were re-
moved and analyzed, and SCC was confirmed in six
of these disks. It was GE’s assessment that keyway
crack-like indications could be found in any of the LP
stages, though the first and last stages appeared to
be considerably less susceptible. Westinghouse also
provided a summary of its disk cracking experience.
Of a total of 220 fossil disks inspected, no cracking
of any type was reported. For nuclear units,
Westinghouse reported 1,475 disks inspected, of
which 119 (or 8.1%) were cracked: 105 of these disks
had keyway cracks and 27 disks had bore cracks. No
instance of cracking in rim attachments or on disk
faces was reported.
Over the last 5 years or so, industry concern has
shifted toward addressing cracking in rim attach-
FIGURE 6. Rim attachment cracking in nuclear units by reactor type ments of LP rotors, which has increased dramatically
and manufacturer. over this period.

LP Disk Rim Blade Attachment Cracking


The 1980 survey included only 34 U.S. fossil- Cracking in rim attachments of LP steam turbine
fueled plants with 45 LP turbines, of which 18 were rotor disks has increased dramatically since the
made by Westinghouse, 19 by GE, and 8 by Allis- original 1980 survey.12 The 1980 survey documented
Chalmers†. Disk cracking was reported in 49 disks in rim attachment cracking in only seven nuclear units
31 turbines of 22 plants: 31 disks had web face and a few fossil units. In response to recent industry
cracks (29 of these were Westinghouse) 16 disks had concerns with regard to the increasing number of
rim attachment cracks (14 of these were GE), one rotors that either have been repaired or retired be-
disk had a bore crack (Allis-Chalmers), and one disk cause of this problem, an industry-wide survey was
had a keyway crack (Allis-Chalmers). Cracking conducted of rim attachment cracking in nuclear and
occurred in 22 of 24 rotors used in plants with once- fossil units. The objectives of this survey (RP9005-
through boilers and all-volatile water treatment 01)19 were to collect data on LP rotor rim cracking to
compared with cracking in only 9 of 21 rotors in document the location, extent, and mechanism of
plants with drum boilers and phosphate water treat- cracking; the repair methods used; and possible rela-
ment. Survey data for fossil-fueled plants were not tionships between cracking experience and various
sufficient to establish relationships between disk design and operating parameters. Disk cracking
cracking and system variables. The only apparent experience in U.S. nuclear utilities and several fossil
trend was for boiler type and water treatment. utilities was determined from a review of literature
Since the 1980 survey, inspection of GE turbines data and a questionnaire survey mailed to the utili-
used in nuclear plants in the United States and in ties. Information on rotor repair methods was
other countries has revealed disk keyway crack indi- obtained from a separate survey of repair vendors
cations in ≈ 60 disks.1 In the United States, at least and original equipment manufacturers (OEM). Data
four nuclear units with GE shrunk-on disk LP de- was gathered through December 1995.
signs have had their LP rotors replaced with the new U.S. Nuclear Units — The survey included all 109
GE monoblock design to eliminate the risk associated currently operating nuclear units in the United
with catastrophic failure of disks with bore/keyway States. LP rotor rim attachment cracking was re-
cracks. With regard to fossil units, it was felt that LP ported in 41 (38%) of these units. The cracking
rotors in reheat machines of up to 500-MW output mechanism reported was predominantly SCC, with a
were immune to SCC. This belief changed in 1987 few instances of corrosion fatigue and one incident of
with the discovery of SCC in turbine disks in fossil high-cycle fatigue in the L4 stage attributed to high
reheat units and was highlighted in February 1989 back-pressure operation. Based on the survey, data
with the burst of an IP/LP rotor disk from a 200-MW cracking did not appear to be related to steam gen-
reheat unit in the United Kingdom. Subsequent to erator (Figure 6) or turbine manufacturer (Figure 7)
this incident and in response to utility concerns, or power rating (Figure 8). Since BWR typically oper-

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ate at higher oxygen levels than PWR, the 1995


survey finding that cracking in BWR (35%) was no
different from PWR (38%) contradicted results of the
1980 survey. Though no specific reason for the differ-
ence could be pinpointed, it is worth noting that the
1980 survey focused on plants with SCC problems
and that data on oxygen levels was available for
these plants, whereas the 1995 survey included all
operating nuclear plants but specific information on
oxygen levels or excursions was not available. The
survey database included primarily GE and
Westinghouse turbines. Data on Asea Brown Boveri†
(ABB) and GEC Alsthom† (GEC) turbines was too
limited to be included in the overall comparison. Rim
cracking was reported in nuclear units with operat-
ing times ranging from 33,000 h to 140,000 h (Figure
9). In GE turbines, cracking was most severe in the
L-2 and L-3 rows, which have circumferential entry,
straddle-mount blade attachments (Figure 10). Tem-
peratures at these rows are in the 220°F to 260°F
range. No cracking was reported in the L-0 and L-1
FIGURE 7. Rim attachment cracking in nuclear units by turbine
rows of GE turbines, which have a finger and pin
manufacturer.
attachment design. In Westinghouse turbines, crack-
ing was primarily in the L-0 through L-4 rows which
have axial-entry blade attachments (Figure 11). Tem-
peratures at these rows are in the 120°F to 260°F
range. Most of the reported cracking propagated
across the steeples, with a few cracks propagating
radially downward from the base of the steeple.
Higher incidences of cracking were reported in units
with longer last stage blades. Data was insufficient to
establish a relationship between the incidence of rim
cracking and operating time, number of startups,
type of water treatment, oxygen levels, condenser
cooling, and water and condenser leakage rate. Lim-
ited rim attachment crack growth data (Figure 12)
suggested the Westinghouse Equation (8) to estimate
crack growth rates is an adequate representation for
use in life prediction. Compared to results of the
1980 survey where rim attachment cracking was
reported only in certain rows of Westinghouse tur-
bines (Figure 13), the 1995 data showed a significant
shift in the number of cracks by row number to
downstream rows (Figure 11) and a significant rate
of cracking in GE rotors not reported prior to 1980
(Figure 10).
U.S. Fossil Units —␣ The survey included 757 fos-
sil units from 33 utilities. The incidence of cracking FIGURE 8. Rim attachment cracking in nuclear units by power rating
was 10 times higher in supercritical units with once- (MW).
through boilers than in subcritical units (Figure 14).
The cracking mechanism reported was predomi-
nantly SCC, with a few instances of corrosion fatigue ever, the number of units with rim attachment
and reportedly excessive attachment stress attrib- cracks by in-service year (Figure 17) indicated the
uted to an overhung blade design. Higher incidences largest fraction of units with rim cracks went into
of cracking were reported in units with Combustion service between 1977 and 1975 (i.e., approximately
Engineering and Foster Wheeler† boilers (Figure 15) 100,000 to 200,000 operating hours). Compared with
and in units with Westinghouse turbines (Figure 16). nuclear units, the apparently longer time required for
Data on unit operating time was insufficient; how- initiation of cracking in fossil units was related to

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FIGURE 10. Rim attachment cracking in nuclear units with GE


turbines by row number.

33.5-in. (85.1-cm) last stage blades. For


FIGURE 9. Rim attachment cracking in nuclear units by total operating Westinghouse turbines, rim cracking reported was
time. most severe in the L-0 and L-1 rows (Figure 19).
Temperatures in these rows are in the 100°F to
160°F range. Most of the reported cracking propa-
gated across the steeples, with no radial cracking
reported at the base of the steeples.
Inspection Methods —␣ A review of disk blade
attachment inspection methods in the United States
focused on the GE straddle-mount and Westinghouse
axial-entry attachment designs for which most of the
rim attachment cracking has been reported. For GE
straddle-mount designs, unless blades are removed
to expose the rim surfaces, inspection generally is
performed using ultrasonic methods. The ultrasound
is introduced from the side of the disk immediately
below the blade such that the sound is directed radi-
ally upward into the rim toward the blade hooks on
the opposite side of the rim attachment. The inspec-
tion is conducted in a pulse-echo mode using shear
waves (S-waves) at the appropriate refracted angles
(Figure 20). The beam is directed toward the base of
FIGURE 11. Rim attachment cracking in nuclear units with the different hooks by moving the transducer radially
Westinghouse turbines by row number. along the face of the disk, by changing the refracted
angle of the transmitted beam, or a combination of
the two. Depending on the exact geometry of the
steam conditions (wetness and temperature) during attachment, it is not always possible to direct a beam
operation, which typically are drier for fossil units. toward all the hooks, particularly the outermost
For GE turbines, no rim cracking was reported in hook. The presence of a crack or pit typically results
subcritical units. In supercritical units, cracking was in disruptions to the uniformity of the hook reflec-
reported to be most severe in the L-1 and L-2 rows tions and is discriminated by comparing time and
(Figure 18). Temperatures in these rows are approxi- frequency domain signals. This inspection can be
mately in the 160°F to 200°F range. Cracking in GE implemented either manually or automated.
designs also was reported at various locations (pin For Westinghouse axial-entry designs, inspec-
holes, base radius, and ledges) in the multifinger tions at the exposed disk faces can be accomplished
pinned type of attachment used in the L-0 and L-1 using surface inspection methods including magnetic
rows of four units (of 39 units in the survey) with particle and eddy current. Eddy current provides

538 CORROSION–JULY 1998


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FIGURE 12. Apparent crack growth rates versus disk yield strength
from 1995 survey compared with mean Westinghouse data and a
best fit to the 1980 survey data.
FIGURE 13. Rim attachment cracking in nuclear units with
Westinghouse turbines by row number, per the 1980 survey.
certain advantages in terms of its inherent capacity
for automation, which provides for comprehensive
scan coverage and digital acquisition and storage of
data. For interior flaws (i.e., those originating along a
hook away from the exposed end faces), ultrasonic
pulse-echo and pitch-catch inspections must be em-
ployed as shown systematically in Figure 21.20 For
portions of the attachment where the transducer can
be positioned directly in line radially (or near radially)
with the area of interest, pulse-echo inspection can be
performed. For the central portion of the attachment
above the disk web, where the transducers cannot be
positioned radially beneath the area of interest,
pitch-catch inspections must be performed with the
transmitter on one side of the disk and the receiver
on the opposite side of the disk. This, of course, re-
quires relatively precise coordination of the transducer
positions and beam directions from two opposite
sides of the disk. Regarding detectability, SWRI has
reported good reliability of detection down to 1-mm
(0.039-in.) crack depth in the absence of significant
pitting or machining scratches, using fixed focus lens
contact transducers at compound angles.21
EPRI is currently conducting a three-phase FIGURE 14. Number of fossil units surveyed by steam type
program to characterize and improve inspection (supercritical or subscritical) and fraction with rim attachment cracking.
capabilities for disk rim inspection. Phase 1 activities
comprised a study of inspection practices currently
being implemented, development of a variable depth for rim attachment cracking: flaw excavation, shot
focused phased array transducer assembly to assess peening, blade removal, use of steel/titanium notch
potential improvement and advantages of such a blocks, pressure plates, and long shank buckets.
system,22 and compilation of an inspection guide to Though weld repair of cracked rims has been imple-
document the Phase 1 project findings.23 Phase 2 is mented successfully for fossil rotors, it has not yet
nearing completion and compares the detection and been reported for U.S. nuclear rotors. However, weld
sizing capabilities of conventional broad-beam and repairs are being initiated for some foreign nuclear
focused-beam inspection approaches for the GE rotors. In addition to the mechanical repairs listed
straddle-mount design.24 Phase 3 activities will for nuclear rotors, U.S. fossil utility operation re-
address the more difficult axial-entry configuration. ported that the repair of choice was a 360° weld
Repairs —␣ U.S. nuclear utility operators reported repair of the rim, with 21 of 49 fossil units with rim
the use of the following types of mechanical repairs crack being weld repaired. No recurrence of rim

CORROSION–Vol. 54, No. 7 539


CORROSION SCIENCE SECTION

FIGURE 15. Rim attachment cracking in fossil supercritical units by FIGURE 16. Rim attachment cracking in fossil units by turbine
boiler manufacturer. manufacturer.

locking tabs to prevent slippage. Replacement rotor


designs that feature integrally forged or welded disks
afford the opportunity to reduce strength level in
order to provide more resistance to SCC in the rim
attachments.25 Welded construction allows the use of
smaller forgings than required for integral forgings
although excellent control of microstructure report-
edly has been achieved with both methods of
construction.25 Weldability of 3.5% Ni-Cr-Mo-V also
has been excellent. The stress corrosion resistance of
weldments of this material has been reported by
Holdsworth, et al., to be equivalent to parent material.10
Replacement of disks or rotors with forgings of
the same strength level and without redesign of the
attachments leaves the rim area susceptible to SCC
and cracking of integral or partial integral rotors
reportedly has occurred. In such cases, recourse
must be taken to weld repair.

Weld Repairs
Utilities and OEM have demonstrated that dam-
FIGURE 17. Rim attachment cracking in fossil units by in-service aged LP turbine rims may be repaired and refur-
year. bished. Over the past 10 years, weld repair of LP
turbine rotors has become a routine method for re-
turning a rotor to a condition as good as new or,
cracking in weld repaired rotors was reported with possible, even better. This trend is illustrated in Fig-
20,000 to 40,000 successful operating hours. ure 22.26 Weld repairs offer a distinct advantage since
the composition and mechanical properties of the
Remedies weld-deposited replacement material can be optimized
The remedy for bore-connected cracking is usu- so that the repair has greater resistance to SCC. The
ally replacement of the disk or rotor with a design development of rotor weld repair technology has re-
that eliminates the keyway or the bore itself. Axial quired extensive qualification of processes, weld filler
keyways have been eliminated by substituting inter- metals, and testing to demonstrate that the as-

540 CORROSION–JULY 1998


CORROSION SCIENCE SECTION

FIGURE 18. Rim attachment cracking in fossil units with GE turbines FIGURE 19. Rim attachment cracking in fossil units with Westinghouse
by row number. turbines by tow number.

deposited weld metal and the heat-affected zone have


adequate properties. High-purity, vacuum-melted
filler wire and carefully controlled welding procedures
and post-weld heat treatments are specified.
Carefully controlled weld buildups have been
used successfully for a variety of turbine applications
(Figure 23).27-31 When defects are found in one or two
blade attachments, local repairs may be adequate.
Local repairs require extreme care during preheating,
welding, and post-weld heat treatment to avoid dis-
tortion and residual stresses in adjacent areas. More
often, the damage is more widespread and a full 360°
repair is performed. Full 360° repairs offer distinct
advantages with respect to the level of residual stress
that is likely to be encountered. Most of the vendors
surveyed indicated that all or nearly all of their
repairs were full 360° repairs.
The majority of weld repairs to LP rotors have used
filler metal with a composition very similar to that of
FIGURE 20. Ultrasonic examination of GE straddle-mount design
the rotor. Slight modifications to the composition have
rim attachment.
been made to improve weldability and to achieve
improved resistance to SCC.30,32-34 Weld filler metal
compositions similar to that of types 403 or 410
Both the gas tungsten arc welding (GTAW)
stainless steel (UNS S40300 or UNS S41000)(2) with
process, using a temper bead technique, in which
addition requirements on many of the alloying and
the heat of welding serves to temper beads applied
trace elements have been selected for some of the
earlier in the sequence, and the SAW process have
weld repairs to produce good weldability and deposits
been used for repairs. Both processes are readily
with the desired combination of mechanical proper-
amenable to automation a key consideration for ap-
ties and SCC resistance.7,27,33,35 The SCC resistance of
plications where large amounts of weld metal must
martensitic stainless steels is a strong function of the
be deposited and the quality requirements on the
strength level. Lower strength material (e.g., tensile
deposit are critical.
strength < 100 ksi or hardness < Rc 32) exhibits a
The major advantage of the GTAW process is the
high resistance to SCC in all of the solutions of inter-
flexibility and capability for control that are afforded
est (i.e., hydroxides, sulfates, chlorides, etc.).36-40
by separate controls on arc parameters and filler
(2)
metal addition. The major disadvantage is the limita-
UNS numbers are listed in Metals and Alloys in the Unified
Numbering System, published by the Society of Automotive tion on deposition rates. Use of multiple wire and hot
Engineers (SAE) and cosponsored by ASTM. wire technique can improve deposition rates. The

CORROSION–Vol. 54, No. 7 541


CORROSION SCIENCE SECTION

manent repair or replacement can be implemented.


No performance data was available for the prevention
of the recurrence of SCC by shot peening in low-alloy
steels, albeit, the benefit has been demonstrated for
other materials.

Effect of Steel Composition


The 3% Cr-Mo disks of the original Hinkley Point
design combined the adverse effects of high strength,
high operating stress, and low fracture toughness. It
has long been recognized that nickel additions
increase fracture toughness and lower fracture ap-
pearance transition temperature (FATT), but it has
been thought that increased nickel concentration
relative to chromium would reduce the resistance to
SCC. For this reason, 2% Cr-Ni-Mo steel was selected
by certain OEM in preference to 2% Ni-Cr-Mo-V to
3.5% Ni-Cr-Mo-V used elsewhere. It now is recog-
nized that, in addition to improved brittle facture
resistance, increased nickel level provides greater
resistance to SCC, although the effect of yield
FIGURE 21. Ultrasonic examination of Westinghouse axial-entry strength clearly dominates both the initiation and
design rim attachment. propagation stages of cracking. The superior
through-thickness hardenability and toughness of
3% Ni-Cr-Mo-V have been cited as the basis for
selecting this material for welded rotor construction.
The introduction of vacuum degassing and
vacuum carbon deoxidizing into steel making prac-
tice by 1975 allowed the reduction of sulfur levels to
the vicinity of 10 ppm and the achievement of total
concentrations of tramp elements of < 20 ppm. The
reduction of sulfur, in turn, allowed steel makers to
lower manganese content to around 200 ppm with-
out incurring the risk of hot shortness.25 The results
were a dramatic reduction in the size and density of
nonmetallic inclusions and the virtual elimination of
temper embrittlement associated with segregation of
tramp elements on prior austentite grain boundaries.
FIGURE 22. Number of weld repairs to utility steam turbine generators The steel industry has been able to produce
by year.26 “superclean” Ni-Cr-Mo-V for LP turbine rotors in
sizes up to 9 ft (2.74 m) in diameter and ingot
weights up to 570 tons.46 One rotor manufacturer,
GTAW process described in several patent disclo- Japan Steel Works,† has reported delivery of 28 fossil
sures for rotor repair, offers some advantages in LP nonblock rotors.46 Several potential advantages
toughness of as-deposited weld metal for 12% Cr.41-45 have been claimed for superclean rotor forgings. The
In general, the fracture toughness of SAW deposits is most dramatic improvements have been achieved in
less than that of GTAW or GMAW deposits. Nonethe- elevated temperature properties, both in the resis-
less, hundreds of rows of turbine rotors have been tance to temper embrittlement and the increase of
repaired successfully using SAW. creep properties form 350°C to 500°C, the latter
attributed to the elimination of sulfur-containing
Shot Peening intergranular inclusions. These improvements allow
While some OEM reportedly have adopted shot additional flexibility in design that result in more
peening for additional protection against stress cor- efficient and cost-effective turbine designs, such as
rosion, at least one other OEM avoids peening in an increase in the crossover steam temperature for a
initial manufacturing and in repair. However, the fossil plant and combined cycle steam turbines with
process is used increasingly in the field by utilities in high-and low-pressure sections on the same rotor.47
conjunction with the removal of cracks by grinding The crossover temperature heretofore has been lim-
generally as a temporary measure until a more per- ited by the concern for embrittlement of conventional

542 CORROSION–JULY 1998


CORROSION SCIENCE SECTION

FIGURE 23. Illustration of the types of weld repairs that have been performed.26

Ni-Cr-Mo-V rotors. By the same token, the elimina- was reported to be in progress on superclean steel
tion of embrittlement allows increased stress levels with a yield strength of 740 MPa in pure steam in an
for the same critical crack size, affording the option attempt to resolve this apparent discrepancy.10
of increased last stage blade length. Holdsworth, et al., suggested that the discrepancy
From the standpoint of SCC, the benefits of su- might be the result of a noted susceptibility to creep
perclean LP rotors are less dramatic and the amount at 95°C when loaded to yield point level stresses
of benefit more problematic. Early stress corrosion which necessitated repeated loading to counterbal-
tests of superclean 3.5% Ni-Cr-Mo-V demonstrated ance the relaxation of stress during the test.
clear superiority with respect to crack initiation, al- Despite substantial differences in pit depth
beit, not much difference in crack growth rates. For between superclean and conventional steels, it ap-
example, Scarlin and Denk compared conventional peared that extensive cracking had occurred in the
and superclean 3.5% Ni-Cr-Mo-V at a yield strength superclean steel at times prior to microcrack initia-
level of 860 MPa in 30% NaOH at 100°C and demon- tion in the conventional steel. Holdsworth, et al.,
strated increased initiation life at stresses from observed initiation of stress corrosion cracks at pits
700 MPa up to yield.48 Such increased life would be obtained in low- to medium-strength steel with yield
expected in view of the reduced size and density of stress < 850 MPa, but at higher strength levels
inclusions in the superclean steel, which are known (above 900 MPa), cracks could initiate at grain
to govern the formation of pits that may be the site of boundaries by a film rupture process. Denk reported
microcracking. However, testing of clean and conven- observations of pitting and crack initiation in conven-
tional rotor steels by Magdowski and Speidel in water tional and superclean 3.5% Ni-Cr-Mo-V steels at a
at various temperatures and yield strength ranging yield strength level of 700 MPa to 750 MPa.50 Pitting
from 600 MPa to 1,300 MPa did not reveal any sig- occurred readily in stagnant aerated water with
nificant difference in stress corrosion crack growth much larger density in the conventional steel. How-
rates for these steels.49 Testing of superclean 3.5% ever, in deaerated water, the superclean steel did not
Ni-Cr-Mo-V in pure steam at 95°C by Holdsworth, pit, while pits developed in the conventional steel.
et al.,10 also failed to establish any superiority over Stresses near the yield level were required to form
conventional steels at the same stress level and, at active pits. In 30% NaOH, intergranular cracks
stresses close to yield, exhibited significantly inferior occurred at the same stress level in both steels. Ini-
initiation resistance to that of conventional steels of tiation was attributed to a strain-controlled film
comparable strength level (i.e., 875 MPa). Testing rupture mechanism. Denk commented that, in addi-

CORROSION–Vol. 54, No. 7 543


CORROSION SCIENCE SECTION

tion to environmental conditions, the film rupture The chemistry of the forging does not appear to influ-
mechanism is influenced strongly by loading history ence significantly the initiation or propagation resis-
effects. tance, provided the strength level remains constant.
Lyle investigated the crack initiation lifetime of To extend the interval between turbine outages,
superclean and conventional 3.5% Ni-Cr-Mo-V steels it would be desirable to be able to predict the time,
at a yield strength of 740 MPa (108 ksi) in 130°C past or future, at which stress corrosion cracks initiate
(266°F) water of three different purity levels under and, in the process, to take advantage of improve-
simulated crevice conditions.3 The times to initiate ments in steam chemistry control. Such prediction
cracking in the superclean steel were ≈ 70% of those would entail knowledge of the corrosion conditions in
for the conventional steel and the cracks were gener- crevices of the bore or rim attachments, in addition
ally deeper. Lyle observed that cracks initiated to strength of the disk, stress level, and temperature.
preferentially in grain boundary trenches rather than Monitoring of the presence of wet surface films would
at pits, which he attributed to the existence of an aid in assessing the long-term accumulation of stress
oxygen-depleted zone under the crevice corrosion corrosion under variable operating conditions. Moni-
film. He commented that this lack of association of toring film chemistry obviously would enhance this
cracks with pitting was consistent with examinations assessment, and monitoring of crevice chemistry or
of cracked disks. potential, if it were feasible, would be even better. The
The conclusion that can be drawn from the pub- current international effort to monitor droplet nucle-
lished data on SCC of superclean steels is that the ation, growth, and chemistry in a bypass circuit of
relative lifetime in crack initiation is not understood the main steam flow is intended to provide this local
adequately at present, particularly in regard to the chemistry. To make full use of this information, it
role of transient low-temperature creep under crevice would appear that the understanding of crack initia-
corrosion conditions. tion in crevices should be revisited. Several issues
require resolution, beginning with the basic mechanism
SUMMARY of initiation, which recent research now suggests
may involve strain rate-controlled film rupture rather
Comparison of the results of the current industry than pitting. If this is the case, the accelerating effect
survey with those of the 1981 survey indicated the of periodic unloading, the influence of surface cold
downstream stages of nuclear LP turbines eventually work on film formation, the benefit of surface com-
crack despite lower surface temperature and presum- pressive stress, the allowable stress level relative to
ably cleaner steam. This observation appears consis- the yield strength, and the low-temperature transient
tent with the dominant effects of material strength creep of the material may come into play.
level, oxygen imbalance, and crevice conditions on
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