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ABSTRACT INTRODUCTION
In the wake of the catastrophic failure of a low-pressure (LP) Stress corrosion cracking (SCC) is an ubiquitous
turbine disk at the Hinkley Point Nuclear Station in 1969, problem in power station equipment subject to flow-
considerable research and development has been devoted to ing or condensing wet surface films. The problem is
the problem of stress corrosion cracking (SCC) in steam tur- particularly insidious at the highly stressed mating
bine rotors. Principle factors affecting the susceptibility of
surfaces of steam turbine rotors, where crevice corro-
rotors to SCC have been identified as disk yield strength,
sion conditions, crack initiation, and early growth of
applied stress level, and surface film/crevice chemistry.
Microstructure and cleanliness of the steel have been found cracks may go undetected for many years. Conse-
to have relatively little effect. Advances in steel making and quences of undetected cracking have been
forging over the last 20 years have provided manufacturers demonstrated repeatedly over almost three decades,
with additional design and material options to mitigate the commencing with the Hinkley Point disk burst in
problem. Increases in forging size capabilities of steel compa- 1969 and the discovery of bore cracks in disk tur-
nies and the welded construction of rotors now permit bines. Financial and safety risks of bore cracking,
designing with integral and partial integral rotors that use especially in nuclear plants, prompted a massive
materials with lower yield strength (more SCC resistant) as response from the power industry worldwide to cope
well as eliminating the SCC problem in bores and keyways.
with the complex issues of rotor design, material
However, a recent survey of U.S. utilities has shown that
properties, steam chemistry, and nondestructive
SCC in the blade attachment legion of LP rotors is an increas-
ing concern. This problem has led to development of repair
inspection that govern the economics of turbine
and refurbishment methods for rim attachments, especially maintenance.
weld buildup of rims with corrosion-resistant alloys. Life Research Project RP1398 of the Electric Power
prediction of rotors under SCC conditions currently involves Research Institute (EPRI) addressed the root cause of
estimating crack growth time from assumed defects to critical SCC and produced a survey of the extent of disk
size. Factors that govern the location and time of crack initia- cracking experienced by nuclear and fossil utilities
tion are not understood adequately. up until 1981. Key findings were the dependence of
KEY WORDS: environmentally assisted corrosion, industrial
crack growth rate on disk yield strength, tempera-
applications, nuclear applications, power generation, rotors, ture, applied stress level, and steam chemistry, with
steam turbine, steel, stress corrosion cracking secondary influences of steel composition and the
concentration of cracking at the farthest upstream
Submitted for publication December 1996; in revised form, June
stage of the turbine at which water droplets formed,
1997. commonly referred to as the Wilson line. Combined
* Structural Integrity Associates, 3315 Almaden Expressway, Suite with inspection procedures, this information allows
24, San Jose, CA 95118.
** Electric Power Research Institute, 3412 Hillview Ave., Palo Alto, estimates of the time for crack growth to critical size.
CA 94303. Recently, Lyle reviewed this early research and com-
0010-9312/98/000117/$5.00+$0.50/0
CORROSION–Vol. 54, No. 7 © 1998, NACE International 531
CORROSION SCIENCE SECTION
TABLE 1
Time to Initiate Stress Corrosion Cracks in Creviced Regions at 130°C (266°F) as Reported by Lyle(A)
Time to Initiate Cracks (h)
Yield High-Purity Intermediate Contaminated
Strength Water Oxygen Water
Steel(B) MPa (ksi) Environment(C) Environment(C) Environment(D)
(A)
Representative of typical short-term upset conditions with 40 ppb oxygen and 20 ppb sodium chloride (NaCl).
(B)
High-strength and low-strength 3.5% Ni-Cr-Mo-V American steels are designated AH and AL, respectively, while Japanese
steels are designated JH and JL, respectively. The Japanese high-purity steel is designated JP.
(C)
Representative of secondary-side water in a PWR during normal operation with < 5 ppb oxygen.
(D)
Representative of a severe secondary water upset condition with 6ppm to 8 ppm oxygen and 20 ppb NaCl.
bined with it the results of international projects on and applied stress in establishing susceptibility.
characterization of the susceptibility of rotor steels of Temperature was a constant 130°C (266°F) in these
various composition and strength levels to environ- tests. Estimates were made of the time to crack ini-
mental factors, including his own results with tiation in typical disks on the basis of the results and
simulated crevices.1 This recent review, combined a generalized SCC crack growth rate correlation.
with other observations, underscores some signifi- Specimens were tested at stress levels equal to 70%
cant gaps in understanding crack initiation and the and 90% of yield strength and at stresses in excess of
ability to predict the onset of cracking. yield strength. Initiation times were on the order of
Refurbishment and repair methods have been 1 year to 2 years as shown in Table 1 for typical
introduced to reduce or eliminate the risk of SCC, as American- and Japanese-made high- and low-
have improvements in steel making and processing strength steel in various environments.3 The short
for more resistant forgings. At the same time, indus- initiation times in the laboratory tests were not con-
try efforts to reduce the risk of bore and keyway sistent with field experience, which indicated the first
cracking through integrally forged and welded rotor detection of SCC in certain disk rims generally is
construction have shifted concern somewhat to the observed after many years of operation. Lyle also
susceptibility of rim attachments. It has been par- concluded that crevices and crevice chemistry played
ticularly important to determine whether this a strong role in crack initiation, but that steel micro-
cracking mode should become more prevalent with structure and chemistry effects were relatively weak.
aging of the fleet and what mitigation steps should be Oxygen was reported to be the dominant impurity.
taken. Only a few instances of cracks growing from pits
These issues led to a survey of U.S. utility expe- were observed on test specimens. Initiation from
rience and of the efficacy of repair methods, the corrosion trenches was favored strongly over initia-
results of which are summarized in the present work. tion from pits.
Also addressed are the adequacy of life prediction Rau, et al., proposed a quantitative model for
and nondestructive examination methods to provide SCC initiation time, using a normalized initiation
the basis of maintenance decisions. An overview of time (tN) given by:4
key research results generated during recent years
also is presented.
σ 3
tN = td R (1)
σys
SCC and Life Prediction Methods
SCC Initiation — Cheruvu and Seth investigated
factors that control initiation and found that oxygen where td is the actual or calculated initiation time
and caustic were the most aggressive.2 However, from field experience, (/ys) is the ratio of surface
rotor materials exposed at < 200°F (93.3°C) or that tensile stress to yield, and R is the SCC crack growth
had a yield strength (ys) < 110 ksi (758 MPa) exhib- rate (computed wing data from EPRI RP2408-1) to
ited no significant cracking. Lyle recently published account for the dependence of initiation time on disk
results of a test that addressed the influence of water temperature, yield strength, manganese content, and
chemistry and material composition and hardness tempering temperature. The effect of surface stress
on relative rates of SCC over a 24-month duration.3 was accounted for using a third-power dependence
Results confirmed the dominant role of yield strength based on laboratory test data.5-6 The normalized ini-
tN – t0
P = 1.0 – exp – α (2)
β – t0
affected by the cleanliness of steel (i.e., nonmetallic This equation has been accepted by the U.S.
inclusions do not serve as initiation sites for corro- Nuclear Regulatory Commission for remaining life
sion pits). predictions of turbine disks with cracks.14 Since that
Part of the problem in predicting the initiation time, additional crack growth rate data has been
life of a disk rim is the uncertain history of attach- generated under EPRI RP2408-1.15 Recalibration of
ment crevice chemistry and existence of a liquid film. the two-variable Clark model yielded the equation:
A program is under way that includes monitoring of
droplet nucleation and growth in the steam path, ln R = –8.8 – (4,040/T) + 0.0231σys (5)
simulating the enthalpy drop in a bypass loop, and
measuring the chemistry of a crevice placed in the The standard deviation of residuals was 120 for the
flow loop.11 Condensation can take place on the up- above equation, which was based on 228 data points,
stream rim face if the surface temperature is vs 0.587 for the Clark model, which was based on 70
sufficiently low and the total pressure is sufficiently data points. The study also identified two more sig-
high. In addition, water may condense on adjacent nificant variables. Manganese content and tempering
surfaces, such as the web of a disk or ID stator temperature for disks that were tempered specifically
shroud and flow past the rim if no seal is present. No below the ASTM A 471 standards(1) (1,050°F) to ob-
mapping of surface temperature or liquid films has tain high strength. The three-variable model with the
been reported. effect of manganese is given as:
Early studies concluded that cracking occurred
at the blade stage just downstream of the point of ln R = –4.74 – (9,270/T) + 0.0337σys + 4.53Mn (6)
thermodynamic equilibrium moisture formation, or
Wilson line, since that stage would experience the where Mn is the weight percent of manganese. The
highest film temperature.12 In fact, it appeared that standard deviation for this model is 1.17. For disks
upstream blade rows were primarily susceptible to tempered above 1,050°F, the effect of tempering tem-
cracking in the 1980 survey. It followed that down- perature was included as:
stream rows, assuming the presence of moisture,
also eventually should crack with increasing expo- lnR = – 7.04 – (9,270/T) + 0.0337σys
sure time. The picture is complicated by the (7)
+ 4.53Mn – 0.0127TT
possibility of excessively wet operation at one point
in a unit’s history, as was attributed in some units to
moisture/separator malfunction. where TT is the tempering temperature in degrees
Once the solute concentration in a crevice has Kelvin. The standard deviation for this model is 1.20.
increased because of off-design operation or other Data on foul disk crack growth rate was pre-
factors, the vapor pressure is lowered, and moisture sented by U.S. and foreign researchers at the EPRI
may remain stable at temperatures above the Wilson Fossil Steam Turbine Disk Cracking Workshop in
line.11 October 1990.16 In summary, the roles of tempera-
Another factor complicating the prediction of ture, stress, environment, material condition, etc., on
SCC initiation is the uncertainty in local surface crack growth rate have been investigated extensively.
tensile stress, which requires knowledge of residual However, the wide scatter in the data suggests that
machining stress and the machining tolerances and further studies and modeling would be required to
variation of the blade-to-disk fit-up. Finite element better characterize the data.
models exist for most of the blade attachments sus- Life Prediction Codes — Two crack propagation-
ceptible to SCC,13 although few are in the public based life prediction codes have been developed and
domain. A quantitative data base should incorporate publicized for LP blade attachments, Lifetime Analy-
the nominal attachment stress, with statistical vari- sis of Steeples (LAST) by the Southwest Research
ability in fit-up. Institute (SWRI)17 and the Disk Crack Evaluator
SCC Crack Growth Rate — The most widely ac- (DICE) developed under EPRI RP1929-14 as part of
cepted model for crack growth rate was given by the EPRI guidelines for predicting the life of steam
Clark, et al., in 1981, as expressed by:8 turbine disks exhibiting SCC.18
The LAST code was developed for two
ln R = –4.968– (7,302/T) + 0.0278σys (4) Westinghouse† design L-5 and L-0 steeples and one
General Electric† (GE) L-1 steeple. The code assumes
where R is the crack growth rate in in./h, T is the an existing crack, and propagation is simulated by
temperature in °Rankine (i.e., °F + 460), and ys is SCC and corrosion fatigue. Remaining life is the time
the room-temperature disk yield strength in ksi. required to grow the existing crack to critical size.
Typically, very little life remains once the crack
(1)
ASTM A 471-77, “Standard Specification for Vacuum-Treated
Alloy Steel Forgings for Turbine Rotor Disks and Wheels (West
reaches the fatigue threshold depth. Proprietary cor-
Conshohocken, PA: ASTM, 1982). rosion fatigue threshold and crack growth data are
FIGURE 12. Apparent crack growth rates versus disk yield strength
from 1995 survey compared with mean Westinghouse data and a
best fit to the 1980 survey data.
FIGURE 13. Rim attachment cracking in nuclear units with
Westinghouse turbines by row number, per the 1980 survey.
certain advantages in terms of its inherent capacity
for automation, which provides for comprehensive
scan coverage and digital acquisition and storage of
data. For interior flaws (i.e., those originating along a
hook away from the exposed end faces), ultrasonic
pulse-echo and pitch-catch inspections must be em-
ployed as shown systematically in Figure 21.20 For
portions of the attachment where the transducer can
be positioned directly in line radially (or near radially)
with the area of interest, pulse-echo inspection can be
performed. For the central portion of the attachment
above the disk web, where the transducers cannot be
positioned radially beneath the area of interest,
pitch-catch inspections must be performed with the
transmitter on one side of the disk and the receiver
on the opposite side of the disk. This, of course, re-
quires relatively precise coordination of the transducer
positions and beam directions from two opposite
sides of the disk. Regarding detectability, SWRI has
reported good reliability of detection down to 1-mm
(0.039-in.) crack depth in the absence of significant
pitting or machining scratches, using fixed focus lens
contact transducers at compound angles.21
EPRI is currently conducting a three-phase FIGURE 14. Number of fossil units surveyed by steam type
program to characterize and improve inspection (supercritical or subscritical) and fraction with rim attachment cracking.
capabilities for disk rim inspection. Phase 1 activities
comprised a study of inspection practices currently
being implemented, development of a variable depth for rim attachment cracking: flaw excavation, shot
focused phased array transducer assembly to assess peening, blade removal, use of steel/titanium notch
potential improvement and advantages of such a blocks, pressure plates, and long shank buckets.
system,22 and compilation of an inspection guide to Though weld repair of cracked rims has been imple-
document the Phase 1 project findings.23 Phase 2 is mented successfully for fossil rotors, it has not yet
nearing completion and compares the detection and been reported for U.S. nuclear rotors. However, weld
sizing capabilities of conventional broad-beam and repairs are being initiated for some foreign nuclear
focused-beam inspection approaches for the GE rotors. In addition to the mechanical repairs listed
straddle-mount design.24 Phase 3 activities will for nuclear rotors, U.S. fossil utility operation re-
address the more difficult axial-entry configuration. ported that the repair of choice was a 360° weld
Repairs —␣ U.S. nuclear utility operators reported repair of the rim, with 21 of 49 fossil units with rim
the use of the following types of mechanical repairs crack being weld repaired. No recurrence of rim
FIGURE 15. Rim attachment cracking in fossil supercritical units by FIGURE 16. Rim attachment cracking in fossil units by turbine
boiler manufacturer. manufacturer.
Weld Repairs
Utilities and OEM have demonstrated that dam-
FIGURE 17. Rim attachment cracking in fossil units by in-service aged LP turbine rims may be repaired and refur-
year. bished. Over the past 10 years, weld repair of LP
turbine rotors has become a routine method for re-
turning a rotor to a condition as good as new or,
cracking in weld repaired rotors was reported with possible, even better. This trend is illustrated in Fig-
20,000 to 40,000 successful operating hours. ure 22.26 Weld repairs offer a distinct advantage since
the composition and mechanical properties of the
Remedies weld-deposited replacement material can be optimized
The remedy for bore-connected cracking is usu- so that the repair has greater resistance to SCC. The
ally replacement of the disk or rotor with a design development of rotor weld repair technology has re-
that eliminates the keyway or the bore itself. Axial quired extensive qualification of processes, weld filler
keyways have been eliminated by substituting inter- metals, and testing to demonstrate that the as-
FIGURE 18. Rim attachment cracking in fossil units with GE turbines FIGURE 19. Rim attachment cracking in fossil units with Westinghouse
by row number. turbines by tow number.
FIGURE 23. Illustration of the types of weld repairs that have been performed.26
Ni-Cr-Mo-V rotors. By the same token, the elimina- was reported to be in progress on superclean steel
tion of embrittlement allows increased stress levels with a yield strength of 740 MPa in pure steam in an
for the same critical crack size, affording the option attempt to resolve this apparent discrepancy.10
of increased last stage blade length. Holdsworth, et al., suggested that the discrepancy
From the standpoint of SCC, the benefits of su- might be the result of a noted susceptibility to creep
perclean LP rotors are less dramatic and the amount at 95°C when loaded to yield point level stresses
of benefit more problematic. Early stress corrosion which necessitated repeated loading to counterbal-
tests of superclean 3.5% Ni-Cr-Mo-V demonstrated ance the relaxation of stress during the test.
clear superiority with respect to crack initiation, al- Despite substantial differences in pit depth
beit, not much difference in crack growth rates. For between superclean and conventional steels, it ap-
example, Scarlin and Denk compared conventional peared that extensive cracking had occurred in the
and superclean 3.5% Ni-Cr-Mo-V at a yield strength superclean steel at times prior to microcrack initia-
level of 860 MPa in 30% NaOH at 100°C and demon- tion in the conventional steel. Holdsworth, et al.,
strated increased initiation life at stresses from observed initiation of stress corrosion cracks at pits
700 MPa up to yield.48 Such increased life would be obtained in low- to medium-strength steel with yield
expected in view of the reduced size and density of stress < 850 MPa, but at higher strength levels
inclusions in the superclean steel, which are known (above 900 MPa), cracks could initiate at grain
to govern the formation of pits that may be the site of boundaries by a film rupture process. Denk reported
microcracking. However, testing of clean and conven- observations of pitting and crack initiation in conven-
tional rotor steels by Magdowski and Speidel in water tional and superclean 3.5% Ni-Cr-Mo-V steels at a
at various temperatures and yield strength ranging yield strength level of 700 MPa to 750 MPa.50 Pitting
from 600 MPa to 1,300 MPa did not reveal any sig- occurred readily in stagnant aerated water with
nificant difference in stress corrosion crack growth much larger density in the conventional steel. How-
rates for these steels.49 Testing of superclean 3.5% ever, in deaerated water, the superclean steel did not
Ni-Cr-Mo-V in pure steam at 95°C by Holdsworth, pit, while pits developed in the conventional steel.
et al.,10 also failed to establish any superiority over Stresses near the yield level were required to form
conventional steels at the same stress level and, at active pits. In 30% NaOH, intergranular cracks
stresses close to yield, exhibited significantly inferior occurred at the same stress level in both steels. Ini-
initiation resistance to that of conventional steels of tiation was attributed to a strain-controlled film
comparable strength level (i.e., 875 MPa). Testing rupture mechanism. Denk commented that, in addi-
tion to environmental conditions, the film rupture The chemistry of the forging does not appear to influ-
mechanism is influenced strongly by loading history ence significantly the initiation or propagation resis-
effects. tance, provided the strength level remains constant.
Lyle investigated the crack initiation lifetime of To extend the interval between turbine outages,
superclean and conventional 3.5% Ni-Cr-Mo-V steels it would be desirable to be able to predict the time,
at a yield strength of 740 MPa (108 ksi) in 130°C past or future, at which stress corrosion cracks initiate
(266°F) water of three different purity levels under and, in the process, to take advantage of improve-
simulated crevice conditions.3 The times to initiate ments in steam chemistry control. Such prediction
cracking in the superclean steel were ≈ 70% of those would entail knowledge of the corrosion conditions in
for the conventional steel and the cracks were gener- crevices of the bore or rim attachments, in addition
ally deeper. Lyle observed that cracks initiated to strength of the disk, stress level, and temperature.
preferentially in grain boundary trenches rather than Monitoring of the presence of wet surface films would
at pits, which he attributed to the existence of an aid in assessing the long-term accumulation of stress
oxygen-depleted zone under the crevice corrosion corrosion under variable operating conditions. Moni-
film. He commented that this lack of association of toring film chemistry obviously would enhance this
cracks with pitting was consistent with examinations assessment, and monitoring of crevice chemistry or
of cracked disks. potential, if it were feasible, would be even better. The
The conclusion that can be drawn from the pub- current international effort to monitor droplet nucle-
lished data on SCC of superclean steels is that the ation, growth, and chemistry in a bypass circuit of
relative lifetime in crack initiation is not understood the main steam flow is intended to provide this local
adequately at present, particularly in regard to the chemistry. To make full use of this information, it
role of transient low-temperature creep under crevice would appear that the understanding of crack initia-
corrosion conditions. tion in crevices should be revisited. Several issues
require resolution, beginning with the basic mechanism
SUMMARY of initiation, which recent research now suggests
may involve strain rate-controlled film rupture rather
Comparison of the results of the current industry than pitting. If this is the case, the accelerating effect
survey with those of the 1981 survey indicated the of periodic unloading, the influence of surface cold
downstream stages of nuclear LP turbines eventually work on film formation, the benefit of surface com-
crack despite lower surface temperature and presum- pressive stress, the allowable stress level relative to
ably cleaner steam. This observation appears consis- the yield strength, and the low-temperature transient
tent with the dominant effects of material strength creep of the material may come into play.
level, oxygen imbalance, and crevice conditions on
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