41.2: a) b) ©) The angle is areee and the angles are, for The angle corresponding to will always be larger for larger 41.3: ‘The maximum orbital quantum number The maximum angular momentum value gets closer to the Bohr model value the larger the value of 414: The combinations are (0, 0), (1, 0), +(2, 0), G, 0), atotal of 25. b) Each state has the same energy (_ is the same), 41.6: a) As in Example 41.3, the probability is ) The difference in the probabilities is4a a) which is independent of b a) For transition, the coefficient is (0.75)(13.59 eV)=10.19 eV. b) If using the result from part (a), Similarly, the transition, olf using the result from part (a), and the transition gives (10.19 eV)(185.8)=1893 eV. ») ° 41.10: and to be periodic with period must be an integer multiple of must be an integer.41: 41.12: a) the lowest possible value of °) (d); field on] m (a); no field 41.13; a) » °) 41.14: a) According to Fig. 41.8 there are three different transitions that are consistent with the selection rules. The initial values are, and the final value is 0 b) The transition from produces the same wavelength (122 nm) that was seen without the magnetic field. ©) The larger wavelength (smaller energy) is produced from the transition. 4) The shorter wavelength (greater energy) is produced from the transition. 41.15: a) b) Three