ejem 13.4.

- a) P(bar) ΔHo(J/mol) -46110

1 ΔGo(J/mol) -16450

componentes Y �_𝑖� Vi A B
Metano 0.0162714849 0.5 -0.5 3.28 0.000593
Agua 0.0488144546 1.5 -1.5 3.249 0.000422
Eatanol 0.9349140605 0 1 3.578 0.00302
1 2 -1 -2.9355 0.0020905

b) P(bar) ΔHo(J/mol) -46110

1 ΔGo(J/mol) -16450

componentes Y �_𝑖� Vi A B
N2 0.1249458456 0.5 -0.5 3.28 0.000593
H2 0.3748375368 1.5 -1.5 3.249 0.000422
NH3 0.5002166176 0 1 3.578 0.00302
1 2 -1 -2.9355 0.0020905

C) P(bar) ΔHo(J/mol) -46110

100 ΔGo(J/mol) -16450

componentes Y �_𝑖� Vi A B
N2 0.1249458456 0.5 -0.5 3.28 0.000593
H2 0.3748375368 1.5 -1.5 3.249 0.000422
NH3 0.5002166176 0 1 3.578 0.00302
1 2 -1 -2.9355 0.0020905
d) Solucion ideal P(bar) ΔHo(J/mol) -46110
1 ΔGo(J/mol) -16450

componentes Y �_𝑖� Vi A B
N2 0.0162714849 0.5 -0.5 3.28 0.000593
H2 0.0488144546 1.5 -1.5 3.249 0.000422
NH3 0.9349140605 0 1 3.578 0.00302
1 2 -1 -2.9355 0.0020905
R(J/molK) Pci Tci ωi
8.314
∫24_(𝑇_0)^𝑇▒
∫24_(𝑇_0)^𝑇▒ 〖 Δ�
〖 Δ� 〗 _�/𝑅 𝑑𝑇〗 _�/𝑅 𝑑𝑇/𝑇
C D T0 (K) T (K) τ ΔG/RT
4000 298.15 300 1.0062049304 -4.9576014 -0.0165765 -6.5214634
8300
-18600
-33050

ε (sup) K
0.96636236 679.571935629

R(J/molK) Y(amoniaco)
8.314 0.5
∫24_(𝑇_0)^𝑇▒
∫24_(𝑇_0)^𝑇▒ 〖 Δ�
〖 Δ� 〗 _�/𝑅 𝑑𝑇〗 _�/𝑅 𝑑𝑇/𝑇
C D T0 (K) T (K)(sup) τ ΔG/RT
4000 298.15 399.462909 1.3398051614 -251.64286 -0.7292478 -1.8191396
8300
-18600
-33050

ε (sup) K
0.66685919 6.1664127641

R(J/molK) Y(amoniaco)
8.314 0.5
∫24_(𝑇_0)^𝑇▒
∫24_(𝑇_0)^𝑇▒ 〖 Δ�
〖 Δ� 〗 _�/𝑅 𝑑𝑇〗 _�/𝑅 𝑑𝑇/𝑇
C D T0 (K) T (K)(sup) τ ΔG/RT
4000 298.15 577.471461 1.9368487702 -617.91902 -1.4929695 2.78424828
8300
-18600
-33050

ε (sup) K
0.66685919 0.0616641276
R(J/molK) Pci Tci ωi
8.314
∫24_(𝑇_0)^𝑇▒
∫24_(𝑇_0)^𝑇▒ 〖 Δ�
〖 Δ� 〗 _�/𝑅 𝑑𝑇〗 _�/𝑅 𝑑𝑇/𝑇
C D T0 (K) T (K) τ ΔG/RT
4000 298.15 300 1.0062049304 -4.9576014 -0.0165765 -6.5214634
8300
-18600
-33050

ε (sup) K
0.96636236 679.571935629
ΔG K
-16265.834 679.572164

ΔG K
-6041.6077 6.16655074

ΔG K
13367.4481 0.06177551
ΔG K
-16265.834 679.572164