Fiitjee Aits

FIITJEE JEE (Advanced)-2019
HALF COURSE TEST – III

ALL INDIA INTEGRATED TEST SERIES
Paper 1
Time Allotted: 3 Hours Maximum Marks: 186

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into two sections: Section-A & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

1. Section-A (01 – 05, 19 – 23, 37 – 41) contains 15 Multiple Choice Questions which have Only
One Correct answer. Each question carries +3 marks for correct answer and –1 mark for wrong
answer.
2. Section -A (06 – 13, 24 – 31, 42 – 49) contains 24 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for correct answer and –2 mark
for wrong answer
3. Section-C (14 – 18, 32 – 36, 50 – 54) contains 15 Numerical based questions with answers as
numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no
negative marking.
Name of the Candidate
Enrolment No.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
2
AIITS-HCT-III-(Paper-1)-PCM-JEE(Advanced)/19
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2

Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6  1019 C
Mass of electron me = 9.1  1031 kg
Permittivity of free space 0 = 8.85  1012 C2/N-m2
Density of water water = 103 kg/m3
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s constant h = 6.625  1034 Js
= 6.625  10–27 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J
Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8, N=9,
Na=11, Mg=12, Si=14, Al=13, P=15, S=16, Cl=17,
Ar=18, K =19, Ca=20, Cr=24, Mn=25, Fe=26, Co=27,
Ni=28, Cu = 29, Zn=30, As=33, Br=35, Ag=47, Sn=50,
I=53, Xe=54, Ba=56, Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3
Physics PART – I
SECTION – A
(One Options Correct Type)
This section contains 5 multiple choice questions. Each question has four choices (A), (B), (C) and
(D), out of which ONLY ONE option is correct.
1. A body of mass 25 kg is dragged on a horizontal rough road with a constant speed of 20 km/hr. If
the coefficient of friction is 0.5. If 50% of the heat is absorbed by the body, find the rise in
-1 -1
temperature in an hour. Specific heat of the material of the body is 0.1cal.gm  °C  .
2
(g=9.8m/s )
(A) 116.4C (B) 110.8C
(C) 128.6C (D) None of these
2 The first allowed excited state of a hydrogen atom is 10.2eV above its lowest energy (ground)
state. To what temperature should hydrogen gas be raised so that inelastic collisions may excite
an appreciable number of atoms to their first excited state?
4 4
(A) 4.58×10 K (B) 7.88×10 K
4
(C) 8.28×10 K (D) None of these
3. A hot body placed in air cooled down according to Newton's law of cooling, the rate of decrease
of temperature being k times the temperature difference from the surrounding. Starting from t=0 ,
find the time in which the body will lose half the maximum heat it can lose.
ln 2 2 ln 2
(A) (B)
k k
(C) Cannot be determent (D) None of these
Space for Rough work
4
4. Particles P and Q of mass 20 gm and 40 gm respectively are

simultaneously projected from points A and B on the ground. The Q
initial velocities of P and Q make 45 and 135 angles P 45º 135º
respectively with the horizontal AB, as shown in the figure. Each
A B
particle has an initial speed of 49 m. The separation AB is 245 m.
Both particles travel in the same vertical plane and undergo a
collision. After collision P retraces its path. How much time after
the collision does the particle Q take to reach the ground? (g =
9.8 m/s2).
(A) 4.36s (B) 3.54s
(C) 5.23s (D) None
5. A uniform cylinder of radius R and mass M can rotate freely about a

stationary horizontal axis O as shown in figure. A thin cord of length  and
mass m is wound on the cylinder in a single layer. Find the angular M R O
acceleration of the cylinder as a function of the length x of the hanging part
of the cord. The wound part of the cord is supposed to have its centre of
T x
gravity on the cylinder axis. a
2m g x 2m g x
(A) (B)
(4m  M ) R (2m  M ) R m'g
4m g x
(C) (D) None of these
( m  M ) R
5
(One or More than one correct type)
This section contains EIGHT questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
6. Logarithms of readings of pressure and volume for an ideal gas log (P)
were plotted on a graph as shown in figure. By measuring the
gradient, it can be shown that the gas may be– 2.38
(A) Monoatomic and undergoing an adiabatic change 2.30
(B) Monoatomic and undergoing an isothermal change 2.20
(C) Diatomic and undergoing an adiabatic change 2.10
(D) Triatomic and undergoing an adiabatic change 1.10 1.20 1.30
log(V)
7. A thin uniform rod of mass m and length  is free to rotate about its upper end. When it is at rest, it
receives an impulse J at its lowest point, normal to its length. Immediately, after impact-
3J
(A) the angular momentum of rod is J  (B) the angular velocity of rod is
m
2
3J 3J
(C) the kinetic energy of rod is (D) the linear velocity of midpoint of rod is
2m 2m
8. A horizontal plane supports a fixed vertical cylinder of radius

R and a particle is attached to the cylinder by a horizontal
thread AB as shown in figure. A horizontal velocity v 0 is
O v0
imparted to the particle, normal to the thread, mark the R
incorrect options during subsequent motion–
B A
(A) Angular momentum of particle about O remains constant
(B) Angular momentum about B remains constant
(C) Momentum and kinetic energy both remain constant
(D) Kinetic energy alone remains constant
6
9. A liquid of density ρ1 and ρ 2 stand in the bent tube as

shown. Then: 2
(A) PM =PN 1 2x
M x
(B) ρ 2 =2 3 ρ1 x N
60º 30º
(C) ρ1 =2 3 ρ 2
(D) PN =Px
10. In the figure shown, water drains out through a small hole of a
large tank (P0 : atmospheric pressure)-
A
(A) Pressure at the point C is atmospheric
H H/2
(B) Gauze pressure at the point B is g H B
2 C
H
(C) Gauze pressure at the point B is less than g
2
(D) Velocity head at the point B is negligible
11. Two concentric spherical shells have masses m1 and m2 and radii r1 and m2 m1 m3
r2 , there is a particle of mass m3 is placed at p. Then– r P
r1 O
(A) Outer shell will have no contribution in gravitational field at point P
(B) Force on P is directed towards O r2
Gm1m 2
(C) Force on the particle at P is
r2
Gm1m 3
(D) Force on the particle at P is
r2
12. A particle of mass m is attached to three identical springs A, B and C each C

of force constant k as shown in figure. If the particle of mass m is pushed B
slightly against the spring A and released, then the time period of oscillation 90º
is: O m
m
(A) Extension in springs are same (B) 2
2k
m A
(C) Extension in A is different from B and C (D) 2
3k
7
13. The potential energy U in joule of a particle of mass 1 kg, moving in the XY plane, obeys the law
U = 3x + 4y, where (x, y) are the coordinates of the particle in metre. If the particle is at rest at (6,
4) at time t = 0, then
(A) The particle has constant acceleration
(B) The work done by the external force from the position of rest of the particle and the instant of the
particle crossing X-axis, is 25 joule
(C) The speed of the particle when it crosses the Y-axis is 10 m/s
(D) The coordinates of the particle at time t = 4s are (–18, –28)
SECTION – C
(Single digit integer type)
This section contains FIVE questions. The answer to each question is a single Digit integer ranging from
0 to 9, both inclusive.
3 3
14. A calorimeter of water equivalent 5  10 kg contains 25  10 kg of water. It takes 3 minutes to
3
cool from 28°C to 21°C . When the same calorimeter is filled with 30  10 kg of turpentine oil,
then it takes 2 minutes to cool from 28°C to 21°C . The calorimeter losses heat at the same rate
in both the cases. The specific heat of turpentine oil is C in J kg °C -1 -1
. Then find the value of
2C.
15. As insulated container is divided into two equal portions. One portion contains an ideal gas at
pressure P and temperature T, while the other portion is a perfect vacuum. If a hole is opened
between the two portions, find the change in the temperature of the gas.
16. For the arrangement shown in fig. Find one fourth of the M = 20 kg
maximum value of the horizontal acceleration a of the system
so that the block remains stationary with respect to wedge. a µ = 0.5
(g=10 m/s2)
37º
17. Uniform cylinder rolls from rest down the parabolic surface whose equation is A y C
2
given by y  kx . The cylinder does not slip from A to B but the surface is
y1
ny
frictionless from B to C. Then height of ascent of cylinder towards C is 1 ,
3
the find the value of n– B x
18. The difference between the apparent frequency of a source of sound as perceived by an observer
during its approach and recession is 2% of the natural frequency of the source. Find twice of the
velocity of the source. Take the velocity of sound as 350 m/s. (assume, velocity of source to be
very small as compared to the velocity of sound)
8
Chemistry PART – II
SECTION – A
19. Incorrect statement(s) regarding following reaction sequence is/are:

NH2
NaNO 2 CuCN Na

HCl  0-5°C 
 Q 
HCN
 R 
C2 H 5OH
S
 P
(A) P & S can be distinguished by Carbylamine test
(B) S is more basic than P
+
(C) R give Benzophenone with PhMgBr followed by H3 O
(D) Q on passing with steam produces phenol.
20. How many degrees of unsaturation are there in the following compound?
OH
HC O
OH
(A) 6 (B) 7
(C) 10 (D) 11
21. 50 mL of a solution, containing 1gm each of Na 2 CO 3 , NaHCO 3 and NaOH , was titrated
with 1N HCl . What will be the titre reading if only phenolphthalein is used as indicator?
(A) 34.4 mL (B) 55.8mL
(C) 21.3mL (D) 38.2 mL
9
22. Which of the following substances cannot be used directly as fertilizer?

(A)  NH 4  2 SO 4 (B) Ca 3  PO 4  2
(C) Ca  H 2 PO 4  2 (D) CaCN 2 +C
23. The equilibrium constant for the following reaction in aqueous solution is 0.90.
  H 3 BO 3 -glycerine 
H 3 BO 3 +glycerine 
How many moles of glycerine should be added per litre of 0.10M H 3 BO 3 so that 80% of the
H 3 BO 3 is converted to the boric acid-glycerine complex?
(A) 4.44 (B) 4.52
(C) 3.6 (D) 0.08
24. Which is/are correct statement(s)?

 
(A) CH 3COO NH 4 have greater degree of hydrolysis in 0.2M solution in comparison of 0.4M
solution

(B) Anions which are weaker base than OH , do not hydrolyse
 
(C) The CH 3COO have greater degree of hydrolysis in comparison of HCOO when their
salt solution have equal concentration
2 
(D) SO4 hydrolysis but HSO4 does not undergo hydrolysis
10
25. Select the correct curve(s):

If v  velocity of electron in Bohr ' s orbit
r  radius of electronin Bohr ' s orbit
PE  potential energy of electronin Bohr ' s orbit
KE  kinetic energy of electron in Bohr ' s orbit
(A) (B)
v
r
1
n n
(C) (D)
PE KE
1
n
n
26. Which is/are correct for real gases?

(A) lim  PVm   constant at constant high temperature
P0
(B) lim  PVm   constant at constant low temperature

Vm 0
(C) lim
 PVm   1at high temperature
P 0 RT
(D) lim
 PVm   R
V 0 RT
11
27. Which of the following orbital(s) cannot form δ bond?

(A) d x 2 -y2 orbital (B) d xy
(C) d z 2 (D) p x
28. Which of the following statements are correct?

(A) ClF3 molecule is bent T-shape
(B) In SF4 molecule, F-S-F equational bond angle is 103° due to lp-lp repulsion
-

(C) In ICl 4  molecular ion, Cl-I-Cl bond angle is 90°.
(D) In OBr2 , the bond angle is less than OCl 2
29. Twist boat conformer of cyclohexane is more stable than:

(A) Boat (B) half-chair
(C) Chair (D) all of these
30. Which of the following is/are correct for 17g/L of H 2 O 2 solution?

(A) Volume strength is 5.6 at 273K and 1 atm
(B) Molarity of solution is 0.5M
(C) 1mL of this solution gives 2.8mL O 2 at 273K and 2 atm
(D) The normality of solution is 2N
31. When an equimolar mixture of Cu 2S and CuS is titrated with Ba  MnO 4  2 in acidic medium,
2+ 2
the final products contain Cu ,SO 2 and Mn . If the molecular mass of Cu 2S , CuS and
Ba  MnO 4  2 are M1 ,M 2 and M 3 respectively then:
(A) Equivalent mass of Cu 2S is M1 /8
(B) Equivalent mass of CuS is M 2 /6
(C) Equivalent mass of Ba  MnO 4  2 is M 3 /5
(D) Cu 2S and CuS both have same equivalents in mixture
12
SECTION – C
32. Total number of isomers for C4 H 6 Br2 containing cyclobutane ring are (including stereoisomer)?
33. CH3
Cold HIO4 NH 2OH

dil. KMnO 4
   
 excess 
Total number of isomers (including stereo) are formed in the products:
34. Among the following, total number of planar species are:

(i) SF4 (ii) BrF3
(iii) XeF2 (iv) IF5
 
(v) SbF 4 (vi) SF5

(vii) XeF4 (viii) CH 3

(ix) PCl4
35. How many pairs are, in which first species has lower ionisation energy than second species?
(i) N and O (ii) Br and K

(iii) Be and B (iv) I and I
+
(v) Li and Li (vi) O and S
(vii) Ba andSr
36. water
P+Q
0°C
Na 2 O 2
water
25°C P+RT+S
Calculate sum of bond order between same bonded atoms in Q and R compounds.
13
Mathematics PART – III
SECTION – A
37. If p,x1 ,x 2 ,.....xi ,... are in A.P with common difference a and q,y1 , y2 ,... yi ,... are in A.P with
common difference b then the centre of mean position of the points
(x i ,yi ),i=1,2,.....,n lies on the line:
(A) ax-by=aq-bp (B) bx-ay=ap-bq
(C) ax-by=bq-ap (D) bx-ay=bp-aq
38. A square of side ‘a’ lies above X-axis and has one vertex at the origin. A side passing through
 
origin makes an angle   0     with the positive X-axis. Find the equation of the diagonal
 4
not passing through origin.
(A) (cos   sin  ) x  (cos   sin  ) y  a (B) (cos   sin  ) x  (cos   sin  ) y  a
a
(C) x  y  (D) None of these
cos   sin 
39. A point (4,1) undergoes the following transformations successively:
(i) Reflection about the line y=x
(ii) Translation through a distance 2 unit along the positive direction of X-axis

(iii) Rotation through an angle about the origin in the anticlockwise direction
4
(iv) Reflection about the line x=0
The coordination of the point in the final position are:
 1 7 1 
(A)   ,  (B)  ,7 2 
 2 2 2 
 1 7   1 7
(C)  ,  (D)   , 
 2 2  2 2
14
40. The range of a for which

2 2

equation x  x  2
2
   a  3  x 2
 x  2  x 2  x  1   a  4   x 2  x  1  0 has atleast
one real root
 19 
(A)  5, (B)  0,1
 3 
 19 
(C)  1, 0  (D)  0,
 3 
41. If  be the difference of the eccentric angles of two points on an ellipse the tangents at which
are at right angles, a and b are the semi-axes of the ellipse and  and  are the semi-diameters
parallel to the tangents at the points, then the product  is equal to:
(A) ab sin  (B) 2ab sin 
(C) ab cos  (D) 2ab cos 
x2 y2 x2 y2
42. Let t and f(t) be the eccentricities of the ellipses + =1 , and + =1 ,
3b 2 -2a 2 2b 2 -a 2 2b 2 -a 2 b 2
where b2  a 2 , a  0 respectively, then:
2t
(A) f(t)= (B) fofof (t )  2 2t
1+t 2
1
1
(C) 2
fofofof (t )dt  (D) et [ f (t )  f ''(t )]dt  et   1 t 
0 4  

(1  t 2 3/2
)
 C
1 t2 
15
43. Let R represents a region such that for any two points ( x1 , y1 ) and ( x2 , y2 ) in the region, the point
 x1  x2 y1  y2 
 ,  is also in the region. Which of the following can represents the region R?
 2 2 
2 2
(A) x  2 y  1 (B) max{ x , y }  1
2
(C) x  y2  1 (D) y
2
x0
2
44. Let y  4ax be a parabola and PQ be a focal chord. Let R be the point of intersection of the
tangents at P and Q, then:
 ( PQ) 2
(A) area of circumcentre of PQR is 
4
(B) orthocentre of PQR lies at the directrix
(C) incentre of PQR lies at the vertex
2
(D) minimum area of the circumcircle of PQR is 4 a
45. The equations of the circles touching the line y=0 and y  3( x  1) and having the centre at a
distance 1 from the origin are:
2 2 2 2
(A) 4(x +y )+4x-4 3y+1=0 (B) 4(x +y )-4x-4 3y+1=0
2 2 2 2
(C) 4(x +y )+4 3x+4y+1=0 (D) 4(x +y )+4x+4 3y+1=0
2
46. The equations of four circles are (x  a)  ( y  a) 2  a2 ,where a>0. The radius of circle
touching all the four circles is equal to:
(A) 2 2a (B) (2  2)a
(C) ( 2  1)a (D) ( 2  1)a
47. If two of the lines given by the equation ax3  9 yx2  y 2 x  4 y3  0 are perpendicular then ‘a’ is
equal to ( a  0) :
(A) -5 (B) -4
(C) 4 (D) 5
16
48. Equation of a line which is parallel to the line common to the pairs of lines given by
3x2  2 xy  8 y 2  0 and 15 x2  14 xy  8 y 2  0 and lying at a distance 5 unit from it is:
(A) 3 x  4 y  25 (B) x  2 y  5
(C) 3 x  4 y  25 (D) x  2 y  5
2 2 2
49. Number of ordered pairs (x,y)satisfying x + y =1and x +y =a is  then
1 1
(A) λ=0if a< ,a>1 (B) λ=4if a= ,a=1
2 2
1
(C) λ=8if <a<1 (D) None
2
SECTION – C
50. P(x)=x5  x2  1 has roots x1 ,x 2 ,x 3 ,x 4 ,x 5 and g(x)=x 2 -2 then

g(x 1 )g(x 2 )g(x 3 )g(x 4 )g(x 5 )  30 g  x 1x 2 x 3 x 4 x 5  
51.  ,  are roots of ax 2 +bx+c=0 . If  + , 2   2 , 3   3 are in G.P and

If
  b 2  4ac then  
52. Let ABCD be a quadrilateral with area 18, side AB parallel to the side CD and AB=2CD. Let AD
be perpendicular to AB and CD. If a circle is drawn inside the quadrilateral ABCD touching all the
sides, then its diameter is equal to______.
(x-4)2 (y-3) 2
53. The equation of the curve obtained by reflecting the ellipse + =1 about the line
16 9
x-y-2=0 is 16x 2 +9y 2 +k1 x-36y+k 2 =0 , then the number of prime factors of k1  k2 is _____.
54. Let e the eccentricity of a hyperbola and f(e) be the eccentricity of its conjugate hyperbola. If n is
3
an even positive integer, then  fofofo...of(e)de is equal to__________.
1   
n times

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FIITJEE JEE (Advanced)-2019

HALF COURSE TEST – III

Time Allotted: 3 Hours Maximum Marks: 186

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate

Acceleration due to gravity g = 10 m/s2

Gas Constant R = 8.314 J K1 mol1

Space for Rough work

4. Particles P and Q of mass 20 gm and 40 gm respectively are

5. A uniform cylinder of radius R and mass M can rotate freely about a

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(One or More than one correct type)

8. A horizontal plane supports a fixed vertical cylinder of radius

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9. A liquid of density ρ1 and ρ 2 stand in the bent tube as

12. A particle of mass m is attached to three identical springs A, B and C each C

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19. Incorrect statement(s) regarding following reaction sequence is/are:

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22. Which of the following substances cannot be used directly as fertilizer?

(C) Ca  H 2 PO 4  2 (D) CaCN 2 +C

(One or More than one correct type)

24. Which is/are correct statement(s)?

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25. Select the correct curve(s):

26. Which is/are correct for real gases?

(B) lim  PVm   constant at constant low temperature

27. Which of the following orbital(s) cannot form δ bond?

28. Which of the following statements are correct?

29. Twist boat conformer of cyclohexane is more stable than:

30. Which of the following is/are correct for 17g/L of H 2 O 2 solution?

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Total number of isomers (including stereo) are formed in the products:

34. Among the following, total number of planar species are:

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Mathematics PART – III

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40. The range of a for which

(One or More than one correct type)

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50. P(x)=x5  x2  1 has roots x1 ,x 2 ,x 3 ,x 4 ,x 5 and g(x)=x 2 -2 then

51.  ,  are roots of ax 2 +bx+c=0 . If  + , 2   2 , 3   3 are in G.P and

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