Académique Documents
Professionnel Documents
Culture Documents
9
Industrial Batteries
I ndustrial B atteries
Maxell batteries: Meeting a variety of energy needs
CR/ER/SR/ICP/ML/TC Industrial Batteries
Maxell supplies various battery lineups corresponding to application usage of diversified equipment,
ranging from lithium ion batteries as the main power sources of portable information devices to backup power
sources for various electronics devices.
ICP ER ICP
(Li-ion) (Li-ion)
3
V)
ge (
Total
ML CR CR ML Capacity
(Coin-Type) (Cylindrical)
a
2
Volt
Total
Capacity
TC SR TC LR
(Alkaline
Battery)
1
Total
Capacity
0
0.1 1 10 100 1,000 10,000 100,000 1,000,000
Capacity (mAh)
1
CONTENTS
Battery 33
2
CR
Lithium Manganese
Dioxide Battery (Li/MnO2)
CR2450 / CR2430 / CR2032H / CR2032 / CR2025 / CR2016 /
CR2012 / CR1620 / CR1616 / CR1220 / CR1216 / CR1025 /
With Terminals and Wire Connectors
(CR2450 / CR2032 / CR2025 / CR1616 / CR1220)
Heat Resistant Coin Type
CR2450HR / CR2450HR-Ex
CR17450 / CR17335
3
Safety Instructions
This battery contains lithium, organic solvents, and other combustible materials. For this reason, improper handling of
the battery could lead to distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble.
Please observe the following instructions to prevent accidents.
(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Never swallow. This is a primary battery and cannot be charged. If used in memory
Always keep the battery out of the reach of infants and young children or RTC back-up applications, be sure to use diodes to prevent
to prevent it from being swallowed. If swallowed, consult a physician
charging from the main power source or other batteries, and a
immediately.
protective resistor to regulate the current as shown in the figure
Never charge. below. Note that the points described below should be taken into
The battery is not designed to be charged by any other electrical
careful consideration when selecting diodes and protective resistors.
source. Charging could generate gas and internal short-circuiting,
leading to distortion, leakage, overheating, explosion, or fire. Diode Diode
+5V Load +5V Load
Never heat. Diode
Heating the battery to more than 100 deg. C* could increase the internal Diode
Diode
pressure, causing distortion, leakage, overheating, explosion, or
fire. (* Consult Maxell regarding heat resistant coin type lithium Protective
Protective
resistor
manganese dioxide batteries.) resistor
Battery
Never expose to open flames. Battery
Never reverse the positive and negative terminals when mounting. Using diodes to prevent charging
Improper mounting of the battery could lead to short-circuiting, Please choose diodes with leak current as small as possible. Please
charging or forced-discharging. This could cause distortion, keep the charged capacity due to leak current to within 1% of
leakage, overheating, explosion, or fire. nominal capacity.
Never short-circuit the battery. Using and setting protective Type Maximum Current
Do not allow the positive and negative terminals to short-circuit. resistors
Never carry or store the battery with metal objects such as a CR2450 15mA
A protective resistor is used to 15mA
necklace or a hairpin. Do not take multiple batteries out of the CR2430
package and pile or mix them when storing. Otherwise, this could prevent the battery from being CR2032H 10mA
lead to distortion, leakage, overheating, explosion, or fire. charged by large surges of current CR2032 10mA
during diode failure. Please set the CR2025 10mA
Never weld the terminals or weld a wire to the body of the
battery directly. resistor so that the maximum CR2016 10mA
The heat of welding or soldering could cause the lithium to melt, or current shown in the right table is CR2012 10mA
cause damage to the insulating material in the battery. This could not exceeded. For example, say a CR1620 4.0mA
cause distortion, leakage, overheating, explosion, or fire. When CR2032 battery is used in sample CR1616 2.5mA
soldering the battery directly to equipment, solder only the tabs or circuit (A) in combination with a CR1220 3.0mA
leads. Even then, the temperature of the soldering iron must be
main power source 5 volt. Since the CR1216 2.5mA
below 350 deg. C and the soldering time less than 5 seconds. Do
not use a soldering bath, because the circuit board with battery permitted charge current is 10mA CR1025 2.5mA
attached could stop moving or the battery could drop into the bath. and this battery’s voltage is 3V, let CR2450HR 15mA
Moreover do not use excessive solder, because the solder could the resistor be CR2450HR-Ex 15mA
flow to unwanted portions of the board, leading to a short-circuit or R>=(5V-3V)/10mA=0.2k ohm, CR17450 20mA
charging of the battery. meaning that at least 0.2k ohm is CR17335 20mA
Never use different batteries together. required.
Using different batteries together, i.e. different type or used and new
or different manufacturer could cause distortion, leakage,
overheating, explosion, or fire because of the differences in battery Warnings Disposal
property. If using two or more batteries connected in series or in The battery may be Do not pile up or mix
parallel even same batteries, please consult with Maxell before Tape
regulated by national or batteries.
using.
local regulation.
Never allow liquid leaking from the battery to get in your eyes Please follow the
or mouth. —
instructions of proper
Because this liquid could cause serious damage, if it does come in Enlarged view +
contact with your eyes, flush them immediately with plenty of water regulation. As electric
Electric current flows. Battery
and consult a physician. Likewise, If the liquid gets in your mouth, capacity is left in a
rinse immediately with plenty of water and consult a physician. discarded battery and
(Example of
Keep leaking batteries away from fire. it comes into contact battery insulation)
If leakage is suspected or you detect a strong odor, keep the battery with other metals, it These batteries generate heat.
away from fire, because the leaked liquid could catch on fire. could lead to
Never touch the battery electrodes. distortion, leakage, overheating, or explosion, so make sure to cover
Do not allow the battery electrodes to come in contact with your skin the (+) and (-) terminals with friction tape or some other insulator
or fingers. Otherwise, the moisture from your skin could cause a before disposal.
discharge of the battery, which could produce certain chemical
substances causing you to receive a chemical burns.
4
CR Coin Type Lithium Manganese Dioxide Battery
Caution Handling/Storage
Never expose the battery to ultrasonic sound. Never use or leave the battery in a hot place such as under
Exposing the battery to ultrasonic sound may cause the direct rays of the sun or in a car in hot weather.
short-circuiting because the inside material is broken into If you do, this may cause distortion, leakage, overheating,
pieces, leading to distortion, leakage, overheating, explosion, or fire.
explosion, or fire. Never allow the battery to come in contact with water.
Never subject the battery to severe shock. If it does, this may cause the battery to rust or lead to
Dropping, throwing or stomping on the battery may cause distortion, leakage, overheating, explosion, or fire.
distortion, leakage, overheating, explosion, or fire. Never store the battery in a hot and highly humid
Never short-circuit the battery while installing into environment.
equipment. Doing so may cause the performance of the battery to
Please be careful when installing the battery not to deteriorate. In certain environments, this may lead to
short-circuit it with metal portions of the equipment. distortion, leakage, overheating, explosion, or fire.
Use the correct battery suitable for the equipment. Keep contact pressure more than 2N.
The battery may not be suitable for the specific equipment The battery voltage may be lower than intended value
due to the using conditions or type of equipment. Please because of poor contact condition, please keep contact
select the suitable battery according to the handling pressure more than 2N for suitable contact resistance.
instructions of the equipment.
Overview
The coin-type lithium manganese dioxide battery (CR battery) is a small, lightweight battery with an operating voltage of 3V and
the ability to operate over a wide temperature range. It has a wide range of applications, both for powering devices such as
wristwatches and electronic calculators and can be used in all types of electronic devices mainly as memory and RTC backup.
Products
Model CR2450 CR2430 CR2032H CR2032 CR2025 CR2016 CR2012 CR1620 CR1616 CR1220 CR1216 CR1025
Nominal Discharge Current (mA) 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1
Operating Temperature –20 to +85
Range (deg. C)***
Diameter (mm) 24.5 24.5 20.0 20.0 20.0 20.0 20.0 16.0 16.0 12.5 12.5 10.0
Dimensions*
Height (mm) 5.0 3.0 3.2 3.2 2.5 1.6 1.2 2.0 1.6 2.0 1.6 2.5
Weight (g)* 6.6 4.6 3.0 3.0 2.5 1.7 1.4 1.3 1.1 0.8 0.6 0.6
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.
** Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.
***When using these batteries at temperatures outside the range of 0 to +40 deg. C, please consult Maxell in advance for conditions of use.
• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
5
LITHIUM MANGANESE DIOXIDE BATTERY
Features
Optimum for Memory and RTC Backup (Fig. 1) operating voltage at room temperature as well as high and
Displays long-term stable operating voltage at low load low temperatures.
discharge. Superior leakage resistance and excellent storage
High 3 volt energy density characteristics (Fig. 2)
High energy density. At 3 volts (nominal voltage), it has Employs a leak-resistant organic electrolyte, giving it better
about twice the voltage of alkaline button batteries and leakage resistance than battery types using alkaline
silver oxide batteries. electrolytes. Furthermore, the high degree of seal of the
Stable discharge characteristics through low internal seal structure and application of sealant keep
resistance and high operating voltage self-discharge to about 1% per year.
Employs highly conductive electrolyte, lowering internal Superior high rate discharge characteristics (Fig. 3)
resistance and providing stable operating voltage. This
allows stable power to be obtained, with little change in
Fig. 1 Relationship between Discharge Current Consumption and Duration Time Fig. 2 Discharge Characteristics after Storage
10 2
Discharge current consumption (µA)
CR2032H
3.5
3.3 Discharge load : 15k ohm
CR2450 Temperature : 20 deg. C
10 1 3.1
CR2430
CR2032H 2.9 Initial
CR2032
CR2025 2.7
Voltage (V)
CR2016 2.5
10 0 CR1620 After stored for 100 days at 60 deg. C
2.3
CR1616 (equivalent to storage at 20 deg. C for 5 years)
CR2012 2.1
CR1220
CR1025 1.9
CR1216 1.7
10-1
1 2 3 4 5 6 7 8 9 10 1.5
0 200 400 600 800 1000 1200 1400
Discharge duration time (years)
Discharge duration time (hours)
2.0
CR2012, CR1620, CR1616, CR1220, CR1216, CR1025
Certification Number: MH12568
1k ohm
2.0
1.5
0 50 100 150 200 250
Discharge capacity (mAh)
Applications
OA Machines (Fax, Copiers, Printers) Notebook PCs Desktop PCs
PDAs Electronic Dictionaries Calculators
Camcorders Digital Still Cameras Film Cameras
Portable CD/MD Players Watches Medical Instruments, Cash Registers
Electronic Meters (Water, Gas, Electricity) Keyless Entry Systems Portable Game Devices
Remote Controllers
FA Instruments (Measuring Instruments, Onboard Microcomputers, Sensors)
6
CR Coin Type Lithium Manganese Dioxide Battery
CR2450 (610mAh)
Voltage (V)
Voltage (V)
2.0 2.0
15k 56k 150k 300k
1.5 1 1.5
10 102 103 104 105 0 1000 2000 3000 4000
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5
600
1.5 300
0 100 200 300 400 500 600 101 102 103
Discharge capacity (mAh) Discharge current (A)
CR2430 (290mAh)
2.0 2.0
15k 56k 150k 300k
1.5 1 1.5
10 102 103 104 105 0 200 400 600 800 1000 1200 1400 1600
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 350
45 deg. C
Discharge capacity (mAh)
20 deg. C
300 5 sec.
2.5 250
–10 deg. C
1M
2.0 200 –20 deg. C
300 5 sec.
1.5 150
0 50 100 150 200 250 300 101 102 103
Discharge capacity (mAh) Discharge current (A)
7
LITHIUM MANGANESE DIOXIDE BATTERY
CR2032H (240mAh)
3.0 3.0
Voltage (V)
Voltage (V)
0 deg. C
2.5 2.5
–10 deg. C
2.0 2.0
15k 150k 300k 1M
1.5 1.5
101 102 103 104 105 0 200 400 600 800 1000 1200 1400
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 250
45 deg. C
300 5 sec.
2.5
–20 deg. C
1M 150
2.0
300 5 sec.
1.5 100
0 20 40 60 80 100 120 140 160 180 200 220 240 260 101 102 103
Discharge capacity (mAh) Discharge current (A)
CR2032 (220mAh)
0 deg. C 0 deg. C
2.5 2.5 –10 deg. C
–10 deg. C
2.0 2.0 20 deg. C
15kΩ
15k 150kΩ
150k 300k kΩ Ω
3001M
1M
60 deg. C
1.5 1.5
101 102 103 104 105 0 200 400 600 800 1000 1200 1400
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 250
45 deg. C
Discharge capacity (mAh)
1 M continuous
3.0
200
Voltage (V)
20 deg. C
300 5sec
2.5
1.5 100
0 20 40 60 80 100 120 140 160 180 200 220 240 101 102 103 104
Discharge capacity (mAh) Discharge current (A)
8
CR Coin Type Lithium Manganese Dioxide Battery
CR2025 (170mAh)
Voltage (V)
Voltage (V)
2.0 2.0
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 200
45 deg. C
300 5 sec.
2.5
–10 deg. C
–20 deg. C
1M 100
2.0
300 5 sec.
1.5 50 1
0 20 40 60 80 100 120 140 160 180 10 102 103
Discharge capacity (mAh) Discharge current (A)
CR2016 (90mAh)
2.0 2.0
39k 390k 1M 2.7M
1.5 1.5
101 102 103 104 105 0 50 100 150 200 250 300 350 400 450 500
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 100
45 deg. C 20 deg. C
Discharge capacity (mAh)
1 M continuous
3.0
80
Voltage (V)
1.5 40
0 20 40 60 80 101 102 103
Discharge capacity (mAh) Discharge current (A)
9
LITHIUM MANGANESE DIOXIDE BATTERY
CR2012 (50mAh)
Voltage (V)
Voltage (V)
2.0 2.0
56k 560k 1.8M3.9M
1.5 1.5
101 102 103 104 105 0 100 200 300
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 60
45 deg. C
1.5 0
0 10 20 30 40 50 60 101 102 103
Discharge capacity (mAh) Discharge current (A)
CR1620 (80mAh)
Voltage (V)
2.0 2.0
30k 300k 1M 3M
1.5 1 1.5
10 102 103 104 105 0 200 400 600 800 1000
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 90
45 deg. C
20 deg. C
Discharge capacity (mAh)
80
1 M continuous
3.0
70
Voltage (V)
1M 50
2.0 –20 deg. C
–10 deg. C
40
300 5 sec.
1.5 30
0 10 20 30 40 50 60 70 80 90 100 101 102 103
Discharge capacity (mAh) Discharge current (A)
10
CR Coin Type Lithium Manganese Dioxide Battery
CR1616 (55mAh)
Voltage (V)
Voltage (V)
2.0 2.0
56k 560k 1.5M 3.9M
1.5 1.5
101 102 103 104 105 0 100 200 300 400 500 600
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 80
300 5 sec.
1.5 0 1
0 10 20 30 40 50 60 10 102 103
Discharge capacity (mAh) Discharge current (A)
CR1220 (36mAh)
45 deg. C
3.0 20 deg. C
3.0
Voltage (V)
Voltage (V)
2.5
0 deg. C
–10 deg. C
2.0 2.0
82k 820k 2.2M 5.6M
1.5 1.0
101 102 103 104 105 0 100 200 300 400
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5
40 45 deg. C
Discharge capacity (mAh)
1 M continuous
3.0 20 deg. C
Voltage (V)
30
2.5
300 5 sec. –20 deg. C
1M
20 –10 deg. C
2.0
300 5 sec.
1.5 10 1
0 10 20 30 40 10 102 103
Discharge capacity (mAh) Discharge current (A)
11
LITHIUM MANGANESE DIOXIDE BATTERY
CR1216 (25mAh)
Voltage (V)
2.5 2.5 0 deg. C
–10 deg. C
2.0 2.0
120k 1.2M 3.6M
1.5 1.5
101 102 103 104 105 0 100 200 300
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5
45 deg. C
20 deg. C
20
2.5 300 5 sec.
–10 deg. C
1M –20 deg. C
2.0 10
300 5 sec.
1.5 0 1
0 5 10 15 20 25 30 10 102 103
Discharge capacity (mAh) Discharge current (A)
CR1025 (30mAh)
45 deg. C
20 deg. C
3.0 3.0
Voltage (V)
Voltage (V)
2.5 2.5
10 deg. C
2.0 2.0
100k 1M 2.2M 6.8M –10 deg. C
1.5 1.5
101 102 103 104 105 0 100 200
Discharge duration time (h) Duration (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 40
45 deg. C
Discharge capacity (mAh)
20 deg. C
1 M continuous
3.0 30
Voltage (V)
2.5 20
600 5 sec. 10 deg. C
1M –10 deg. C
2.0 10
600 5 sec.
1.5 0 1
0 10 20 30 10 102 103
Discharge capacity (mAh) Discharge current (A)
12
CR
External Dimensions (unit : mm)
Coin Type Lithium Manganese Dioxide Battery
with Terminals and Wire Connectors
0.75
Insulation sleeve 4.5
0.75
ø24.5
10.16
10.16
ø20
ø20
ø20
4.0
25 10.6
5.1 4
1.3
20.3
4.1
21 4 20.6
4 4 4
4
(–) (+)
4.8
0.75 0.2 17.8 0.2
4.1
4.8
4.5
4.5
4
4.5
4
4.5
4.5
(–) (+) (–) (+)
4
(–) (+) 0.2 0.2
0.2 0.75 1.8 4
20.5
0.75 20.5 1.8 15.24
4.5
0.75
0.75
4.5
4
ø20
ø20
ø20
ø20
4
4
3
4.8 5
3 4
21
4 20.5 1.3 4 20.5
21 4
4.1
5.5
6.5
5
4.5
4.5
(–) (+)
4
(–) (+)
4
4.5
(+) Insulation sleeve
0.75
0.75
7.45
ø20
(–)
1.5
3
3.0
(+) (–)
10.16
ø20
10.16
ø20
ø20
3.0
5.0
6.5 5 7
0.75
4.0
4.0
20.3
4.0
(–) (–)
4.0
1.3
4.2
(+)
4.0
8.5
(+)
4
5
4
(–) (+)
10.16
0.75 0.2
4 17.8
Actual appearance
13
L I T H I U M MANGANESE DIOXIDE BATTERY
Insulation sleeve
3.7
(+)
0.2
2
7.5
(–)
4.5
0.2
(+) (–)
4
4.5
21 5
4
4
(–) (+) (+) (–) (+) (–) 3.7
0.75 3.5 1.5
4 0.75 0.2 1.8 0.75 0.2 0.2
10.16
1.8
6 3.7 4 4 3.7
10.5
0.75
10.2
ø20
0.75
4
4
1.5
Actual appearance
20.2
(+)
20.2
5
20.2
(+) (+)
20.2
(–) (–) (–) (+)
70 180 35 65
(+) (+) (+)
(+)
4.5
4.9
(–)
12
12
(+)
12
(+) (+)
Lead wire
Lead wire Lead wire 12 Lead wire
12 12
34 Insulation sleeve
Insulation sleeve
ø12.5
ø1.5
(+)
1.8
20.2
60
(+) (–)
(+) 3
1.5
(–) 2.3
4.5
Adhesive tape
3.5
2.7
(+) (–)
(–) 13 11.5 0.75 0.2
0.2
0.2
12
10 (–)
12 Lead wire
: Tin plating
: Horizontal & Through hole Type
: Horizontal & Surface mounting Type
: Vertical & Through hole Type
: Wire connector Type
14
CR Heat Resistant Coin Type Lithium Manganese Dioxide Battery
Overview
Maxell’s original sealing technology and highly heat-resistant material expands operating temperature range remarkably,
making the batteries supremely suitable for automobile applications — for powering TPMS (Tire Pressure Monitoring System)
sensors, for example.
(Compared to pre-storage)
1200
Nominal Capacity (mAh)** 550 525 1000
Other CR
Nominal Discharge Current (mA) 0.2 0.2 800
Operating Temperature Range (deg. C) –40 to +125 –40 to +125 (max.150)
600
Acceleration Resistance Max. 2000G*** Heat resistant CR (HR)
400
Diameter (mm) 24.5
Dimensions* Height (mm) 5.0 200
Heat resistant CR (HR-Ex)
Weight (g)* 6.8 0
0 50 100 150 200
* Dimensions and weight are for the battery itself, but may vary Storage time (days, at 60 deg. C/90%)
depending on terminal specifications and other factors. Very little deterioration in internal resistance due to high humidity (60 deg. C/90%RH),
** Nominal capacity indicates duration until the voltage drops down compared to other CR batteries.
to 2.0V when discharged at a nominal discharge current at 20 deg. C.
*** Equivalent to acceleration when driving at 300km/h, when Fig. 3 High Rate Discharge Characteristics
attached to a 17-inch wheel
• Data and dimensions are just reference values. For further details, CR2450HR
3.5
please contact your nearest Maxell dealer or distributor. 20 deg. C
3.0
Features 2.5
Voltage (V)
Electric characteristics are maintained after long Discharge duration time (h)
periods of exposure to high temperature and humidity. External Dimensions (unit : mm)
*When using CR2450HR and/or CR2450HR-Ex at temperatures
exceeding 85 deg. C, please consult Maxell in advance for CR2450HR T43
conditions of use. (5.0)
Construction
2.8
φ24.5
− + (0.2)
: Tin plating
1.8 20.5
100
Heat resistant CR (HR, HR-Ex) Set-Top Boxes
80
OA Machines (Fax, Copiers, Printers)
60 Notebook PCs
40
Other CR
Desktop PCs
Medical Instruments, Cash Registers
20 FA Instruments (Measuring Instruments, Onboard
0 Microcomputers, Sensors)
0 50 100 150
Storage time (days, at 80 deg. C)
200
Electronic Meters (Water, Gas, Electricity)
Very little deterioration in capacity due to high storage temperature of 80 deg. C,
compared to other CR batteries.
15
LITHIUM MANGANESE DIOXIDE BATTERY
CR2450HR (550mAh)
Voltage (V)
Voltage (V)
100 deg. C
2.0
2.5 –10 deg. C
1.5
1.0
2.0
3.9k 15k 150k 300k
0.5
1.5 0.0
1 101 102 103 104 105 0 500 1000 1500 2000 2500 3000 3500
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 600
60 deg. C/80 deg. C
3.3 100 deg. C
2.7
2.5 300 5 sec 300
–10 deg. C
2.3
1M 200
2.1
1.9 300 5 sec 100
1.7
1.5 0
0 50 100 150 200 250 300 350 400 450 500 550 0.1 1 10
Discharge capacity (mAh) Discharge current (mA)
CR2450HR-Ex (525mAh)
2.0
2.5 60 deg. C 80 deg. C
1.5
1.0
2.0
3.9k 15k 150k 300k
0.5
1.5 0.0
1 101 102 103 104 105 0 500 1000 1500 2000 2500 3000 3500
Discharge duration time (h) Discharge duration time (h)
Pulse Discharge Characteristics Relationship between Discharge Current and Discharge Capacity
Temperature: 20 deg. C Final voltage: 2.0V
3.5 600
80 deg. C
3.3
500
Discharge capacity (mAh)
60 deg. C
3.1 1M continuous
2.9 100 deg. C
400
Voltage (V)
2.7 20 deg. C
2.5 300 5sec 300
2.3 –10 deg. C
1M 200
2.1
1.9 300 5sec 100
1.7
1.5 0
0 50 100 150 200 250 300 350 400 450 500 550 0.1 1 10
Discharge capacity (mAh) Discharge current (mA)
16
CR Cylindrical Lithium Manganese Dioxide Battery
Overview
The cylindrical lithium manganese dioxide battery (CR battery) features high capacity and excellent load characteristics due to
Maxell’s unique winding method and improved electrical-conductivity structures. Because of its high-reliability, this battery is
ideal for industrial use in, for example, security equipment and the power source of electronic meters.
Products Construction
Positive Terminal
Model CR17450 CR17335 Gas Release Vent
Gasket Collector
Nominal Voltage (V) 3 3 Laser Seal (Copper Foil)
* Dimensions and weight are for the battery itself, but may vary
depending on terminal specifications and other factors.
** Nominal capacity indicates duration until the voltage drops
down to 2.0V when discharged at a nominal discharge current
at 20 deg. C.
Features
High capacity batteries
Principle and Reactions
Maxell’s unique winding method and effective utilization of
The cylindrical lithium manganese dioxide battery uses positive and negative electrodes realize high capacity.
manganese dioxide (MnO2) as its positive active material, Low self-discharge rate and long battery life
and lithium (Li) as its negative active material. A laser seal structure ensures air tightness. Minimized
Battery Reactions electrode surface areas reduce the self-discharge rate.
+ Superior storage characteristics
Positive reaction: MnO2Li e– 씮 MnOOLi The optimization of positive materials and employment of a
+
Negative reaction: Li 씮 Li e– high-reliability sealing structure stabilize pulse discharge
Total reaction: MnO2Li 씮 MnOOLi characteristics over a wide usable temperature range after
long-time storage or discharge.
Applications
Security Devices Electronic Meters (Water, Gas, Electricity)
Home Fire/Smoke Alarms Memory Backup Power
0.75
4.5
4.5
(−) (−)
(+) (+)
4
4
4
0.3
Insulation sleeve
Insulation sleeve
0.3
36.5
48±2
( 33.5 )
( 45 )
0.3
50
0.3
50
ø17
0.75
0.75
4.5
ø17
4.5
4
: Tin plating : Horizontal & Through hole Type : Wire connector Type
17
LITHIUM MANGANESE DIOXIDE BATTERY
CR17450 (2600mAh)
3.2 3.2
5mA 50 deg. C
3.0 3.0
Voltage (V)
Voltage (V)
2.8 2.8
40mA 20 deg. C
2.6 2.6
2.8 2.8
CR17335 (1750mAh)
3.2 3.2
5mA 20 deg. C
3.0 3.0
Voltage (V)
Voltage (V)
2.8 2.8
30mA
2.6 2.6
2.4 2.4
100mA
2.2 200mA 2.2 0 deg. C
–10 deg. C
2.0 2.0
0 500 1000 1500 2000 0 500 1000 1500 2000
Discharge capacity (mAh) Discharge capacity (mAh)
3.1 2.8
3.0 2.6
Batteries stored for
Storage period 2.4 10 equivalent years*
2.9 0 year
2.8 5 equivalent years* 2.2
10 equivalent years**
2.7 2.0
0 20 40 60 80 0 500 1000 1500 2000
Discharge capacity (mAh)
Depth of discharge (%) 1750 mAh: 100%
*After storage for 28 days at 80 deg. C **After storage for 57 days at 80 deg. C *After storage for 57 days at 80 deg. C
18
ER
Lithium Thionyl
Chloride Battery (Li/SOCI2)
With Terminals and Wire Connectors
(ER18/50 / ER17/50 / ER6 / ER6C / ER17/33 / ER3 / ER3S)
19
Safety Instructions
This battery is a high energy density sealed battery containing dangerous (Lithium) and deleterious (Thionyl Chloride) materials. For
this reason, improper handling of the battery could lead to distortion, leakage*, overheating, explosion, fire, or generation of
irritating/corrosive gases, causing bodily injury or equipment trouble. Please observe the following instructions to prevent accidents.
For from your customers to your industrial waste processors (including recycled processor), please have them fully understand
these instructions.
(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Never deform.
Warnings Handling
Deforming could cause leakage, overheating, explosion, fire, or
Do not recharge generation of irritating/corrosive gases.
Never swallow. Never reverse the positive and negative terminals when
mounting.
Always keep the battery out of the reach of infants and young
Improper mounting of the battery could lead to short-circuiting,
children to prevent it from being swallowed. If swallowed, consult a
charging or forced-discharging. This could cause distortion,
physician immediately.
leakage, overheating, explosion, fire, or generation of
Never apply an excessive force to the positive terminal. irritating/corrosive gases.
Because the positive terminal is sealed by a glass, subjecting this
Never use different batteries together.
area to sudden jolts and excessive force (over 19.6 N) could destroy
Using different batteries together, i.e. different type or used and new
the glass seal. This could cause leakage and the generation of
or different manufacturer could cause distortion, leakage,
irritating/corrosive gases.
overheating, explosion, fire, or generation of irritating/corrosive
Never drop. gases because of the differences in battery property. If using two or
Dropping the battery could destroy the glass seal leading to leakage more batteries connected in series or in parallel even same batteries,
and the generation of irritating/corrosive gases. please consult with Maxell before using.
Never weld the terminals or weld a wire to the body of the Never allow liquid leaking from the battery to get in your eyes
battery directly. or mouth.
The heat of welding or soldering could cause the lithium to melt, or Because this liquid could cause serious damage, if it does come in
cause damage to the insulating material in the battery, leading to contact with your eyes, flush them immediately with plenty of water
possible distortion, leakage, overheating, explosion, or fire, or and consult a physician. Likewise, If the liquid gets in your mouth,
generation of irritating/corrosive gases. When soldering the battery rinse immediately with plenty of water and consult a physician.
directly to equipment, solder only the tabs or leads. Even then, the
Never touch the battery electrodes.
temperature of the soldering iron must be below 350 deg. C and the
Do not allow the battery electrodes to come in contact with your skin
soldering time less than 5 seconds. Do not use a soldering bath,
or fingers. Otherwise, the moisture from your skin could cause a
because the circuit board with battery attached could stop moving
discharge of the battery, which could produce certain chemical
or the battery could drop into the bath. Moreover do not use
substances causing you to receive a chemical burns.
excessive solder, because the solder could flow to unwanted
portions of the board, leading to a short-circuit or charging of the
battery.
Never short-circuit the battery. Warnings Circuit Design for Back-up Use
Do not allow the positive and negative terminals to short-circuit. This is a primary battery and cannot be charged. If used in memory
Never carry or store the battery with metal objects such as a or RTC back-up applications, be sure to use diodes to prevent
necklace or a hairpin. Do not take multiple batteries out of the charging from the main power source or other batteries, and a
package and pile or mix them when storing. Otherwise, this could protective resistor to regulate the current as shown in the figure
lead to distortion, leakage, overheating, and explosion of the battery. below. Note that the points described below should be taken into
Never charge. careful consideration when selecting diodes and protective resistors.
The battery is not designed to be charged by any other electrical
source. Charging could generate gas and internal short-circuiting, Diode Diode
+5V Load +5V Load
leading to distortion, leakage, overheating, explosion, fire, or
generation of irritating/corrosive gases. Diode
Diode
Never forcibly discharge. Diode
Protective
Forcibly discharging by an external power source or other batteries resistor Protective
resistor
could cause the voltage to fall below 0V (reversing the poles),
generating gas inside the battery and leading to distortion, leakage, Battery Battery
overheating, explosion, fire, or generation of irritating/corrosive gases.
Never heat. Example (A) Example (B)
Heating the battery to more than 100 deg. C could increase the
internal pressure, causing distortion, leakage, overheating,
explosion, fire, or generation of irritating/corrosive gases. Supplied voltage to load
Because a diode and a resistor generate the voltage drop on
Never expose to open flames.
operating, please take into consideration these voltage drops for
Exposing to flames could cause the lithium metal to melt, causing
supplied voltage to load.
the battery to catch on fire and explode.
Using diodes to prevent charging
Never disassemble the battery.
Please choose diodes with leak current of no more than 0.5μA.
Disassembly could generate the irritating/corrosive gases. In
addition, the lithium metal inside the battery could overheat, leading
to catch on fire.
20
ER Lithium Thionyl Chloride Battery
Warnings Disposal
The battery may be regulated by
national or local regulation. Please Tape
follow the instructions of proper
regulation. As electric capacity is +
left in a discarded battery and it
comes into contact with other
metals, it could lead to distortion,
leakage, overheating, or explosion, –
so make sure to cover the (+) and
(-) terminals with friction tape or Tape
some other insulator before
(Example of battery insulation)
disposal.
Caution Handling
Minimum transient voltage
The various tests have shown that the minimum transient voltage is
influenced greatly by the actual conditions of use and storage
Therefore, please design your circuits using no more than the
standard discharge current, taking into account the voltage drop due
to the minimum transient voltage. Please consult with Maxell
beforehand if you are unsure of anything.
Installing, removing, and disposing of batteries
1) When installing a battery in a device, make sure that the positive
terminal is facing up, or at least to the side. As this battery uses
liquid thionyl chloride as the positive active material, placing the
positive terminal at the bottom will cause the thionyl chloride to
become maldistributed, which could prevent the needed
performance from being obtained when a large amount of current is
used.
2) Please have the installation, removal, and disposal of this battery
performed by a technician with a thorough understanding of the
Warnings and Cautions on handling.
21
LITHIUM THIONYL CHLORIDE BATTERY
Overview
This battery is ideal for such long-term applications as power for electronic devices and electric power, water, and gas meters,
and especially as a backup power source for memory ICs.
Products
Model ER18/50 ER17/50 ER6 ER6C ER17/33 ER3 ER3S
Nominal Voltage (V) 3.6 3.6 3.6 3.6 3.6 3.6 3.6
Nominal Capacity (mAh)** 3,650 2,750 2,000 1,800 1,600 1,100 790
Operating Temperature Range (deg. C) –55 to +85 –55 to +85 –55 to +85 –55 to +85 –55 to +85 –55 to +85 –55 to +85
Diameter (mm) 18 17 14.5 14.5 17.0 14.5 14.5
Dimensions* Height (mm) 52.6 52.6 53.5 51 35 29.9 26
Weight (g)* 22 20 15 15 13 8 7
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.
** Nominal capacity indicates duration until the voltage drops down to 3.0V when discharged at a nominal discharge current at 20 deg. C.
• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
Glass Seal
Metal Can
Features
High 3.6-V voltage
The lithium thionyl chloride battery achieves a high voltage of 3.6 V.
Flat discharge characteristics
The change of internal resistance during discharge is minimal,
allowing for flat discharge voltage until end of discharge life.
High energy density
Provides high energy density of 970m Wh/cm3 with discharge current of 100μA (ER6 type).
Wide usable temperature range
Can be used over a wide temperature range : - 55 deg. C to +85 deg. C (please consult with
Maxell if using in temperatures of -40 deg. C or less).
Superior long-term reliability
The extremely low self-discharge, together with the use of a hermetic seal, allows for stable
use over long periods.
22
ER Lithium Thionyl Chloride Battery
3.5
3
Voltage
Voltage
Time 2
1.5 20 deg C
–10 deg C
1 –40 deg C
2.5
Operating Voltage (V)
1.5 20 deg C 2
–10 deg C Initial
1 –40 deg C
1
0.5 Temp:20 deg.C
After 3 months at 20 deg. C discharge current: 100 μA
0 0
103 104 0 25 50 75 100
Discharge load (ohm)
Discharge capacity (%)
23
LITHIUM THIONYL CHLORIDE BATTERY
ER18/50 (3650mAh)
3.5
Voltage (V)
3.0
10,000 1
Temperature: –40 deg. C
7,000
4.0
5,000 0.5
Voltage (V)
2,000
3.0
1,000
10 20 30 50 70 100 200 300 500 1000
2.0 Discharge current (A)
1.2mA 120A 24A
3.5
3.0
Voltage (V)
3.0
After stored for 200 days at 60 deg. C*
2.0
2.5
Initial
2.0 1.0
(*Equivalent to storage at 20 deg. C for 10 years)
1.2mA 20A
10 102 103 104 105 106 0
Discharge duration time (h) 0 1000 2000 3000 4000
Discharge duration time (h)
ER17/50 (2750mAh)
100,000 Year
Voltage (V)
10
3.0
70,000
7
Discharge duration time (h)
50,000 5
4
2.0
3
1.2mA 120A 24A 20 deg. C
20,000 2
10 102 103 104 105 106
60 deg. C
Discharge duration time (h)
5,000
0.5
Voltage (V)
3.0
2,000
20 30 50 70 100 200 300 500
2.0 Discharge current (A)
1.2mA 120A 24A
3.0
Voltage (V)
3.0 Initial
2.0 After stored for 200 days at 60 deg. C*
1.0
2.0
(*Equivalent to storage at 20 deg. C for 10 years)
1.2mA 1 20A
0
10 102 103 104 105 106 0 1000 2000 3000
Discharge duration time (h) Discharge duration time (h)
24
ER Lithium Thionyl Chloride Battery
ER6 (2000mAh)
3.0 50,000 5
4
5,000 0.5
Temperature: –40 deg. C
4.0
2,000
Voltage (V)
3.0
1,000
20 30 50 70 100 200 300 500
Discharge current (μA)
2.0
1mA 100μA 20μA
Storage Characteristics
1 10 102 103 104 105
Discharge duration time (h)
3.0
Voltage (V)
3.0
2.0 1.0
1mA 100μA (*Equivalent to storage at 20 deg. C for 10 years)
ER6C (1800mAh)
3.0 50,000 5
4
Discharge duration time (h)
3
20,000
2.0 20 deg. C 2
1mA 100 μ A 20 μ A 60 deg. C
1 10 102 103 104 105 10,000
1
Discharge duration time (h)
7,000
5,000 0.5
Temperature: –40 deg. C
4.0
2,000
Voltage (V)
3.0
1,000
20 30 50 70 100 200 300 500
Discharge current (μA)
2.0
1mA 100 μA 20 μ A
1 10 102 103
Discharge duration time (h)
104 105
Storage Characteristics
Temperature: 60 deg. C Discharge current: 1mA Temperature: 20 deg. C
4.0 4.0
3.0
Voltage (V)
Voltage (V)
3.0
Initial
2.0 After stored for 200 days at 60 deg. C*
2.0 1.0
1mA 100 μ A (*Equivalent to storage at 20 deg. C for 10 years)
25
LITHIUM THIONYL CHLORIDE BATTERY
ER17/33 (1600mAh)
3.0 50,000 5
2,000
Voltage (V)
3.0
1,000
20 30 50 70 100 200 300 500
Discharge current (A)
2.0
800A 80A 16A
Storage Characteristics
1 10 102 103 104 105
Discharge duration time (h)
3.0
Voltage (V)
3.0
Initial
2.0 After stored for 200 days at 60 deg. C*
2.0 1.0
800A 80A (*Equivalent to storage at 20 deg. C for 10 years)
ER3 (1100mAh)
3.0 50,000 5
4
Discharge duration time (h)
3
20,000
2.0
400μA 40μA 8μA 20 deg. C 2
5,000 0.5
Temperature: –40 deg. C 60 deg. C
4.0
2,000
Voltage (V)
3.0
1,000
8 10 30 50 100 200 300 500
Discharge current (μA)
2.0
400μA 40μA 8μA
Storage Characteristics
1 10 102 103 104 105 106
Discharge duration time (h)
3.0
Voltage (V)
Voltage (V)
3.0
After stored for 200 days at 60 deg. C*
2.0 Initial
2.0 1.0
400μA 40μA (*Equivalent to storage at 20 deg. C for 10 years)
26
ER Lithium Thionyl Chloride Battery
ER3S (790mAh)
3.0 50,000 5
2,000
Voltage (V)
3.0
1,000
8 10 30 50 70 100 200 300 500
Discharge current (μA)
2.0
400μA 40μA 8μA
Storage Characteristics
1 10 102 103 104 105
Discharge duration time (h)
3.0
Voltage (V)
3.0
After stored for 200 days at 60 deg. C* Initial
2.0
2.0 1.0
400μA 40μA
(*Equivalent to storage at 20 deg. C for 10 years)
27
With Terminals and Wire Connectors
LITHIUM THIONYL CHLORIDE BATTERY
ø0.63
ø0.63
ø0.63
6.5 7.5
6 (+)
(+)
(53.6)
53.8
54.7
(52.6)
47.7
ø14.5
(53.5)
53.8
ø18
47.7
47.6
ø17
0.25
0.25
(–)
(–)
0.75
0.75
0.75
6.5
6.5 7.5
11.5
8.5
3.5 Plastic cap
ø0.63
(+)1
(–)2
53.0
45.0
Loop
Hook
(51)
ø14.5
44.5
52
1(+)
2(–)
0.25
ø14.5 100
15.2
(–)
0.75
2(+)
1(–)
ø0.63
11.5
8.5
8.5
7.5
ø0.63
55
3.5
1(+)
2(–)
6.0
31.1
31.0
36.2
(35)
30.1
30
ø14.5
24.6
ø17
24
MAX18.2
0.25
0.25
(–)
MAX17
(–)
(–)
0.75
ø14.9
0.75
6.5
Housing: HNC2-2.5S-2 (Hirose)
Contact: HNC-2.5S-C-B(03) (Hirose) Housing: IL-2S-S3L-(N) (JAE)
7.5
Lead wire: AWG26 Contact: IL-C2-1-1000 (JAE)
Lead wire: AWG24
7.5 ø16.4 63
3.5 (+)
90
POS 2(+)
(+) POS 1(–)
6.0
28
29.3
21.9
28.5
(26)
21.3
ø14.5
0.25
MAX17.0
(–)
0.75
ø14.9
7.5
Housing: IL-S-2S-S2C2- S
Housing: 2695-02RP : Tin plating
Contact: 2759 GS
Contact: IL-S-C2-1-10000 : Horizontal & Through hole Type
Lead wire: UL1007 AWG26
Lead wire: AWG26
: Wire connector Type
28
ICP
Lithium Ion
Rechargeable Battery
ICP403450AR / ICP463443SR / ICP463446AR / ICP463450AR /
ICP483640SR / ICP533640SR / ICP553443AR
ICP553446AR / ICP553450SR / ICP653047AS / ICP653443AR /
ICP653450AR / ICP783640SR / ICP803443AR
33
Safety Instructions
Improper use of the battery may cause heat, fire, explosion, damage or reduced battery capacity. Please read and follow the handling instructions for the
battery before and during usage. The followings are general cautions and guidelines only and as such may not include every possible usage scenario. The
manufacturer will not be liable for actions taken or accidents caused by any usage not documented below.
Danger Warnings
Do not dip or wet the battery in water, seawater, or other liquid. Do not put the battery in a microwave oven or a pressure cooker.
Otherwise the battery may be shorted, which may generate heat or Sudden heat may damage the seal of the battery and may cause
cause damage. heat generation, explosion or fire.
Do not put the battery into a fire. Otherwise, the electrolyte may Do not use the battery together with a primary battery such as a
burn or cause an explosion. dry battery or other battery of a different capacity, type and/or
brand. In such a case, over-discharge during use or over-charge
Do not heat the battery. Otherwise the electrolyte may boil and during charging may occur and abnormal chemical reactions may
resin parts may melt, causing leakage, explosion or fire. cause heat generation, explosion or fire from the battery.
The battery has a predetermined polarity. If the battery will not If you notice any unusual odor, heat, discoloration, deformation or
connect well to the charger or equipment, do not try to connect the any other characteristic apart from what you are used to while
battery forcefully. Check the polarity first. If the battery is using, charging or storing the battery, then take it out of the
connected in reverse, it will be charged in reverse and may cause equipment or charger, and avoid using it. Using it in such state
leakage, heat generation, explosion or fire due to an abnormal may result in heat generation, explosion or fire.
chemical reaction.
If the battery leaks or emits an unusual odor, remove it from the
Do not connect the battery in reverse relation to the positive (+) vicinity of any fire immediately. The electrolyte may catch fire,
and negative (-) terminals in the charger or equipment. If the which may cause heat generation or explosion.
battery is connected in reverse, it will be charged in reverse,
discharge excessive current and may cause heat generation, Do not let leaked electrolyte come into contact with the eyes. In
explosion or fire due to an abnormal chemical reaction. the event of such contact, flush the eyes with plenty of water
immediately and consult a doctor. Otherwise prolonged contact
Do not let the battery terminals (+ and -) come into contact with a may cause serious injury.
wire or any metal (like a metal necklace or a hairpin) with which it is
carried or stored. In such a case, the battery will be shorted and Caution
discharge excessive current, which may result in heat generation,
explosion or fire. If the battery leaks and its electrolyte comes into contact with skin
or clothes, wash the contact area well with tap water or other clean
Do not apply any heavy impact to the battery, throw or drop it. water right away. Otherwise skin may break out in a rash.
Otherwise the battery may be shorted and result in heat
generation, explosion or fire. When the battery is expected not to be used for a long time, take
the battery out of the equipment or device and store it in a less
Do not drive a nail into, hammer or stamp on the battery. humid area.
Otherwise the battery may be shorted and result in heat
generation, explosion or fire. After long periods of storage without being used, the battery
should be charged before it is used. Charge the battery every 6
Do not solder the battery directly. Heat applied during soldering months to the level specified by the manufacturer, even if the
may melt resin parts such as separator or gasket, and result in battery is not used.
leakage, heat generation, explosion or fire.
Do not leave the battery pack connected to the charger. It may
Do not disassemble or alter the battery. Otherwise the battery may cause the degradation of battery performance, such as a
be shorted and result in heat generation or fire. shortening of battery life.
Do not use or leave the battery near fire, heaters, inside an Turn off your equipment or device power switch after use.
automobile in hot weather or under strong sunshine. Such
conditions of high temperature may damage the separator, and the Do not use the battery in other than the following temperature
battery may be shorted and result in heat generation, explosion or ranges:
fire.
Charge 0 deg. C to +45 deg. C
When charging the battery, do not use any battery charger not Discharge -20 deg. C to +60 deg. C
specified by the manufacturer. Always follow the charge conditions Storage (less than 30 days) -20 deg. C to +50 deg. C
specified by the manufacturer. If the battery is charged under other
Storage (less than 90 days) -20 deg. C to +35 deg. C
conditions (a high temperature, a high voltage/current or an altered
charger) not specified by the manufacturer, the battery may cause
Notes for treating used batteries
heat generation, explosion or fire due to abnormal chemical
• Insulate (+) and (–) terminals with tape.
reactions.
• Do not remove coating.
• Do not expose to rain or water.
Do not connect the battery directly to an electric outlet or cigarette
• Do not disassemble.
lighter socket in a car. Applying a high voltage may generate an
• Do not leave under strong sunshine.
excessive current and cause an electric shock. In such a case, the
• Store in rugged receptacle and cover with a lid.
battery may leak electrolyte, overheat, explode or cause fire.
34
ICP Lithium Ion Rechargeable Battery
Overview
Maxell has concentrated its original technologies accumulated during the development of various products such as magnetic tapes, IC
cards and memory cards, as well as its battery technology into Maxell’s lithium ion batteries. With Maxell’s unique manufacturing
technology and quality control system, including carefully selected electrode materials, sealing technology, and micron-order accuracy
control, Maxell has developed lithium ion batteries featuring various excellent characteristics and high reliability.
Products
Cell Type ICP403450AR ICP463443SR ICP463446AR ICP463450AR ICP483640SR ICP533640SR ICP553443AR
Thickness 3.9±0.2 4.4±0.2 4.4±0.2 4.4±0.2 4.6±0.2 5.0±0.3 5.2±0.3
Dimensions*1
Width 33.7±0.2 33.8±0.2 33.8±0.2 33.8±0.2 35.8±0.2 35.8±0.2 33.8±0.2
(mm)
Height 49.7+0/-0.5 42.95+0/-0.5 46.0+0/-0.5 49.6+0/-0.5 40.0+0/-0.5 40.0+0/-0.5 42.8+0/-0.5
Weight (g)*2 16 15 16 18 17 18 18
Charge Max. Voltage (V) 4.2 4.2 4.2 4.2 4.2 4.2 4.2
(CCCV) Max. Current (A) 0.80 0.79 0.82 0.92 0.82 0.90 0.92
Discharge End Voltage (V) 2.75 2.75 2.75 2.75 2.75 2.75 2.75
(CC) Max. Current (A) 1.20 1.19 1.23 1.38 1.23 1.35 1.38
Nominal Voltage (V) 3.7 3.7 3.7 3.7 3.7 3.7 3.7
Minimum Capacity (mAh)*3 800 790 820 920 820 900 920
Note
This brochure introduces lithium-ion cells only. Maxell offers these cells in battery pack format only, which include electronic circuits to
prevent overcharge, overdischarge and so on. These battery packs are custom-developed and produced according to special
requirements regarding operating conditions and specifications. As a result, a minimum number of units may apply to such customized
orders from customers purchasing battery packs. For details, consult your nearest Maxell dealer or distributor.
35
LITHIUM ION RECHARGEABLE BATTERY
Charge Current
Positive Electrode
40 600 3.0
Charge:1150mA(1C)/4.2V (CC-CV)
Temperature: 25 deg. C
Positive Can 20 300 2.5
Negative Electrode
0 0 2.0
0 30 60 90 120 150 180
Time (min)
0.2C (230mA)
4.0 0.5C (575mA)
1C (1150mA)
Cell voltage (V)
Features 3.5
36
ML
LITHIUM MANGANESE DIOXIDE
RECHARGEABLE BATTERY
ML2032 / ML2016 / ML1220
With Terminals and Wire Connectors
(ML2032 / ML2016 / ML1220)
37
Safety Instructions
This battery contains lithium, organic solvents, and other combustible materials. For this reason, improper handling of
the battery could lead to distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble.
Please observe the following instructions to prevent accidents.
(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Never allow liquid leaking from the battery to get in your eyes
Warnings Handling
or mouth.
Never swallow. Because this liquid could cause serious damage, if it does come in
Always keep the battery out of the reach of infants and young contact with your eyes, flush them immediately with plenty of water
children to prevent it from being swallowed. If wallowed, consult a and consult a physician. Likewise, if the liquid gets in your mouth,
physician immediately. rinse immediately with plenty of water and consult a physician.
Do not replace. Keep leaking batteries away from fire.
Depending on the battery manufacturer, there might be major If leakage is suspected or you detect a strong odor, keep the battery
differences in performance even among the same types or models of away from fire, because the leaked liquid could catch on fire.
batteries. If you are an equipment manufacturer and need to replace Never touch the battery electrodes.
the battery, please use a new one of the same type and same model Do not allow the battery electrodes to come in contact with your skin
as the existing one. Because this is a rechargeable battery, its or fingers. Otherwise, the moisture from your skin could cause a
characteristics are completely different from a primary battery even discharge of the battery, which could produce certain chemical
though their shapes are alike. If a primary battery is installed in the substances causing you to receive a chemical burns.
circuit in place of a rechargeable battery, gas could be generated or
the primary battery could be short-circuited by charging. This could
lead to distortion, leakage, overheating, explosion, or fire. Please
design your equipment so that the end user cannot replace the
Warnings Circuit Design
38
ML Lithium Manganese Dioxide Rechargeable Battery
Overview
The coin-type lithium manganese dioxide rechargeable battery is a small, lightweight rechargeable battery. This battery
employs specially treated manganese dioxide for the positive material and a lithium-aluminum compound for the negative
material. A specially formulated organic electrolyte is also used, yielding excellent discharge characteristics with low
self-discharge.
Products
Model ML2032 ML2016 ML1220
Nominal Voltage (V) 3 3 3
Operating Temperature Ranges (deg.C) -20 to +60 -20 to +60 -20 to +60
* Dimensions and weight are for the battery itself, but may vary depending on terminal specifications and other factors.
** Nominal capacity indicates duration until the voltage drops down to 2.0V when discharged at a nominal discharge current at 20 deg. C.
• Data and dimensions are just reference values. For further details, please contact your nearest Maxell dealer or distributor.
(+) Collector
Charge/Discharge Reactions
Positive ElectrodePositive Can
Charge
MnO2(Li-Al) LiMnO2Al
Discharge
39
LITHIUM MANGANESE DIOXIDE RECHARGEABLE BATTERY
Features
Approx. 2.5V operating voltage
The operating voltage is about twice that of nickel cadmium rechargeable batteries. Displays a high discharge voltage of 2.8 V
when at 10% of nominal capacity (depth of discharge is 10% or less), when charged at 3.0 to 3.3 V.
Superior charge/discharge cycle characteristics (Fig. 2)
Achieves 1,000 cycles of discharging to 10% of nominal capacity (Depth of discharge = 10%). The total discharge capacity is
quite high at 100 times nominal capacity.
Wide -20 deg. C to 60 deg. C usable temperature range
Demonstrates stable operating voltage in temperatures as low as -20 deg. C and as high as 60 deg. C.
Low self-discharge and superior leakage resistance (Fig. 3)
Self-discharge at 20 deg. C is no more than 2% per year. Supplies a nominal capacity of about 95% even when stored at 20
deg. C for roughly five years (according to accelerated test conducted by Maxell). And since organic electrolyte is used, the
battery has superior leakage resistance (shipped fully charged).
Excellent floating characteristics (Fig. 4)
A specially formulated organic electrolyte is employed to provide stable discharge characteristics even if charged for a year at
3.3 V at 20 deg. C (according to accelerated test conducted by Maxell).
Excellent high rate discharge characteristics (Fig. 5)
100 104
Available discharge capacity at
40 ML2016
Prohibited 102 ML2032
area
20 ML1220
0 101
2.5 2.6 2.7 2.8 2.9 3.0 3.1 3.2 3.3 3.4 3.5 0 20 40 60 80 100
Depth of discharge (%)
Charge voltage (V)
100 4
Discharge load:15 K
Discharge temperature: 20 deg. C
voltage (V)
90
3
Storage temperature: 60 deg. C
80 Discharge temperature: 20 deg. C
Load: 15 K Initial
2
70 After charged at 60 deg. C
for 20 days at 3.3V*
60 1
0 100 200 300 400 500
2.5
Mobile Phones PHS
2.0 OA Machines (Fax, Copiers, Printers) Notebook PCs
1.5
Desktop PCs PDAs Camcorders
4mA 3mA 2mA 1mA
Digital Still Cameras Portable CD/MD Players
1.0
0 10 20 30 40 50 60 70 80 Watches Medical Instruments, Cash Registers
Discharge duration time (h) FA Instruments (Measuring Instruments, Onboard
Microcomputers, Sensors)
Electronic Meters (Water, Gas, Electricity)
40
ML Lithium Manganese Dioxide Rechargeable Battery
ML2032 (65mAh)
3.0 3.0
20 deg. C
240k
Voltage (V)
Voltage (V)
2.5 2.5
100k 60 deg. C
2.0 15k 2.0
30k
1.5 1.5 –20 deg. C
0 deg. C
1.0 1.0
0 10 20 30 40 50 60 70 80 0 100 200 300 400 500
Discharge capacity (mAh) Discharge duration time (h)
Relationship between Discharge Current and Duration Time High Rate Discharge Characteristics
Discharge final voltage: 2V Temperature: 20 deg. C Temperature: 20 deg. C
104 3.5
Discharge duration time (days)
3.0
103
2.5
Voltage (V)
102
2.0
101
1.5
3.0
3
After charged at 3.3V for
Voltage (V)
Voltage (V)
2 1.5
Initial After stored for 60 days at 60 deg. C
1.0
1.5 0 100 200 300 400 500
0 100 200 300 400 500
Discharge duration time (h) Discharge duration time (h)
ML2016 (25mAh)
2.5
Voltage (V)
100k 2.5
Relationship between Discharge Current and Duration Time High Rate Discharge Characteristics
Discharge final voltage: 2V Temperature: 20 deg. C
104 3.5
Discharge duration time (days)
103 3.0
Voltage (V)
2.5
102
2.0
101
1.5
4mA 3mA 2mA 1mA
100 1.0
100 101
102
0 5 10 15 20 25 30
Discharge current (μA) Discharge duration time (h)
3.0
3
After charged at 3.3V for Initial
Voltage (V)
Voltage (V)
2
Initial 1.5 After stored for 60 days at 60 deg. C
1.5 1.0
0 50 100 150 200 0 20 40 60 80 100 120 140 160 180
Discharge duration time (h) Discharge duration time (h)
41
LITHIUM MANGANESE DIOXIDE RECHARGEABLE BATTERY
ML1220 (18mAh)
3.0 3.0
100k
20 deg. C
Voltage (V)
Voltage (V)
2.5 2.5
60 deg. C
2.0 2.0
30k
–20 deg. C
1.5 1.5
0 deg. C
1.0 1.0
0 2 4 6 8 10 12 14 16 18 20 0 20 40 60 80 100 120 140 160 180 200 220 240 260
Discharge capacity (mAh) Discharge duration time (h)
Relationship between Discharge Current and Duration Time High Rate Discharge Characteristics
Discharge final voltage: 2V Temperature: 20 deg. C Temperature: 20 deg. C
104 3.5
Discharge duration time (days)
3.0
103
Voltage (V)
2.5
102 1mA
2.0
3mA
101 2mA
1.5
4mA
100 1.0
1 101 102 0 2 4 6 8 10 12 14 16
Discharge current (μA) Discharge duration time (h)
Voltage (V)
2.5 Initial
2.5
2.0 After stored for 60 days at 60 deg. C
Initial
2
1.5
1.5 1.0
0 50 100 150 200 250 300 0 50 100 150 200 250
Discharge duration time (h) Discharge duration time (h)
42
ML
External Dimensions (unit : mm)
Lithium Manganese Dioxide Rechargeable Battery
with Terminals and Wire Connectors
4.5 4.5
0.75
ø20
0.75
ø20
10.16
ø20
10.16
ø20
20.3 4 21 4
4 4
4.1
4.1
4 4.8
4 4.8
5.1 4
4.5
4.5
4.5
4.5
4
4
(–) (+) (–) (+) 20.6 20.3
0.2 0.2
20.5 1.8 20.5 1.8
1.3
0.75 0.75
8.5
4
4
(–) (+)
4.5
4
(–) (+) 0.75 0.2
4 0.2 4 18.05
15.24
(–)
20.2
0.75
(+)
ø20
(+) (–)
Hook Loop
4.5
0.2
7.5
1.8 0.75 0.2 0.2
4.5
7.5
4.0
4.8 4
4 4 3.7
10.5 0.75 (–)
3.7
10.16
(–) (+)
Lead wire
(+)
0.2
25.4 (–)
4.0
(+)
20.2
ø20
(–)
10.16
ø20
ø20
65
(+)
(–)
3
4 4 20.3
21
4.5
2.9
(+) (–)
2.5
4 3.2
8.8
4 4
4
43
LITHIUM MANGANESE DIOXIDE RECHARGEABLE BATTERY
(–) (+)
4
(–) (+) (+) (–)
16.25
0.75
0.75
(+) (–)
7.5
3.5
3.75
4.5
0.2
3.0
(+) )–(
3.0
2.1 (+) (–)
4
Actual appearance
ML1220 T13
: Tin plating
Insulation sleeve : Horizontal & Through hole Type
ø12.5 : Horizontal & Surface mounting Type
: Vertical & Through hole Type
(+) (–) : Wire connector Type
3.5
3.0
(+) )–(
3.25 2.7
44
TC
TITANIUM CARBON LITHIUM
RECHARGEABLE BATTERY
TC920S
45
Safety Instructions
This battery contains organic solvents, and other combustible materials. For this reason, improper handling of the battery
could lead to distortion, leakage*, overheating, explosion, or fire, causing bodily injury or equipment trouble. Please
observe the following instructions to prevent accidents.
(* Leakage is defined as the unintentional escape of a liquid from a battery.)
Never allow liquid leaking from the battery to get in your eyes
Warnings Handling
or mouth.
Never swallow. Because this liquid could cause serious damage, if it does come in
Always keep the battery out of the reach of infants and young contact with your eyes, flush them immediately with plenty of water
children to prevent it from being swallowed. If swallowed, consult a and consult a physician. Likewise, if the liquid gets in your mouth,
physician immediately. rinse immediately with plenty of water and consult a physician..
Do not replace. Keep leaking batteries away from fire.
Depending on the battery manufacturer, there might be major If leakage is suspected or you detect a strong odor, keep the battery
differences in performance even among the same types or models of away from fire, because the leaked liquid could catch on fire.
batteries. If you are an equipment manufacturer and need to replace Never touch the battery electrodes.
the battery, please use a new one of the same type and same model Do not allow the battery electrodes to come in contact with your skin
as the existing one. Because this is a rechargeable battery, its or fingers. Otherwise, the moisture from your skin could cause a
characteristics are completely different from a primary battery even discharge of the battery, which could produce certain chemical
though their shapes are alike. If a primary battery is installed in the substances causing you to receive a chemical burns.
circuit in place of a rechargeable battery, gas could be generated or
the primary battery could be short-circuited by charging. This could
lead to distortion, leakage, overheating, explosion, or fire. Please Warnings Circuit Design
design your equipment so that the end user cannot replace the
Never set the charge voltage above 3.15V.
battery by mistake.
Charging at a higher voltage could cause the generation of gas,
Never use two or more batteries connected in series or in parallel. internal short-circuiting, or other malfunctions, leading to distortion,
If batteries are connected together, it is very difficult to design a leakage, overheating, explosion, or fire. For details, see the
circuit to observe whether or not the batteries are charged at recommended circuits in the figure below.
specified voltage or current as described in "Warning -Circuit
Always charge at the nominal currents shown below.
Design".
Large surges of current could degrade the battery’s characteristics,
Never reverse the positive and negative terminals when leading to distortion, leakage, overheating, explosion, or fire. To
mounting.
avoid excessive current at the initiation of charging, make sure to
Improper mounting of the battery could lead to equipment trouble or
attach a protective resistor for current control. See the
short-circuiting. This could cause distortion, leakage, overheating,
recommended circuits below.
explosion, or fire.
Table 1 Nominal Charge Current by Model
Never short-circuit the battery.
Model TC920S
Do not allow the positive and negative terminals to short-circuit.
Never carry or store the battery with metal objects such as a Charge Current 5mA or lower
necklace or a hairpin. Do not take multiple batteries out of the
Recommended Circuits
package and pile or mix them when storing. Please be careful when
Please refer to the representative basic circuits shown below. If you
installing the battery not to short-circuit it with metal portions of the
have any questions about circuit design, please feel free to contact
equipment. Otherwise this could lead to distortion, leakage,
Maxell.
overheating, explosion, or fire.
(A) Main power source of 1.6 to 3.15V (B) Other main power source
Never heat. + + Voltage
D Regulator D
Heating the battery to more than 100 deg. C could increase the
R GND R
internal pressure, causing distortion, leakage, overheating, explosion, 1.6 to 3.15V
Load Load
(1.6 to 3.15V) To 16V (1.6 to 3.15V)
or fire. TC TC
– –
Never expose to open flames. D: Diode; R: Resistor D: Diode; R: Resistor
46
TC Titanium Carbon Lithium Rechargeable Battery
Overview
The button-type titanium carbon lithium ion rechargeable battery is a small rechargeable battery developed as a backup power
source for real-time clocks and SRAM like digital cameras and mobile phones. It provides fully 10 times the capacity of a
capacitor of the same size.
Products
Model TC 920S
47
TITANIUM CARBON LITHIUM RECHARGEABLE BATTERY
Features
Approx. 1.5V operating voltage Excellent overcharge characteristics
The operating voltage is about 1 to 1.5V the same as the A special formulated organic electrolyte is employed to
SR, LR battery. provide stable discharge characteristics even if charged for
Wide range charging voltage (Fig. 1) 10 years at 3.15V at 20 deg. C. (under accelerated test
Charging voltage is 1.6 to 3.15V. conditions conducted by Maxell)
Excellent cycle performance (Fig. 2) Superior leakage resistance
500 charge/discharge cycles is archived because by Leakage resistance can withstand over 1,200 heat shock
utilizing lithium ion. cycles between 60 deg. C and-10 deg. C.
Wide temperature characteristics (Fig. 3)
Usable in a wide temperature range of-20 to 60 deg. C.
4.0
Recoverable ratio (%)
80
3.5 20 deg. C
60 Recommended area
3.0 Charge voltage: 2.4V
1.6V—3.15V
40 Protective resistor: 300
2.5 Charge time: 6hr
20 Prohibited area Discharge load: 1k
FV=1.0V 2.0
Discharge time: 6hr
0 1.5
1.5 2.0 2.5 3.0 3.5 0 100 200 300 400 500
Charge voltage (V) Charge/discharge cycle (Numbers)
1.5
20 deg. C Watches
1.0
0.5
–20 deg. C
0
0 1.0 2.0 3.0 4.0 5.0 6.0
Discharge capacity (mAh)
48
TC Titanium Carbon Lithium Rechargeable Battery
TC920S (3.5mAh)
2.0 2.0
Charge Charge voltage: 2.4V
Protective resistor: 300
Voltage (V)
Voltage (V)
1.5 1.5
Charge time: 24 hrs 20 deg. C
1.0 1.0
Discharge
Discharge load: 15k –20 deg. C
0.5 0.5
Final voltage: 0.5V
0 0
0 1.0 2.0 3.0 4.0 5.0 6.0 7.0 0 1.0 2.0 3.0 4.0 5.0 6.0
Discharge capacity (mAh) Discharge capacity (mAh)
Discharge load: 15k Temperature: 20 deg. C Discharge load: 15k Temperature: 20 deg. C
2.5 2.5
2.0 2.0
Voltage (V)
Voltage (V)
1.5 1.5
Initial Initial
1.0 1.0
0.5 0.5
After charged at 2.4V for 80 days at 60 deg. C After discharged at 0V for 80 days at 60 deg. C
0 0
0 1.0 2.0 3.0 4.0 5.0 6.0 0 1.0 2.0 3.0 4.0 5.0 6.0
Discharge capacity (mAh) Discharge capacity (mAh)
49
ISO 14001
EMS Accreditation
RE 009
ISO14001 ISO14001
Hitachi Maxell, Ltd., Osaka-Ono Site Hitachi Maxell, Ltd., Kyoto Site
Certificate Number: EC97J1166 Certificate Number: EC97J1188
Certificate Expiry: 25/Dec/2008 Certificate Expiry: 22/Feb/2010
Registration Date: 26/Jan/1998 Registration Date: 23/Feb/1998
Issue Date: 26/Dec/2005 Issue Date: 23/Feb/2007
ISO9001
QS Accreditation
R009
ISO9001 ISO9001
Hitachi Maxell, Ltd. Hitachi Maxell, Ltd.
Energy Solution Business Group Rechargeable Battery Division
Primary Battery Division Certificate Number: JQA-3029
Certificate Number : JQA-0986 Registration Date: January 29, 1999
JQA-0986 Registration Date: September 29, 1995 JQA-3029 Last Renewal Date: December 27, 2005
Last Renewal Date: December 19, 2006 Expiry Date: December 26, 2008
Expiry Date: December 18, 2009
Scope of Registration: The design/development Scope of Registration: The design/development
and the manufacture of cylindrical alkaline battery, silver and manufacture of lithium ion rechargeable battery.
oxide battery, alkaline button battery, manganese dioxide
lithium battery (coin type and cylindrical type), thionyl chloride
lithium battery, manganese dioxide lithium rechargeable
battery and titanium carbon lithium ion rechargeable battery.
ISO/TS 16949
ISO/TS16949
Hitachi Maxell, Ltd.
Energy Solution Business Group
Primary Battery Division, Ono Works
Certificate Number : JQA-AU0078
JQA-AU0078 Registration Date: January 7, 2005
Last Renewal Date: January 7, 2008
Expiry Date: January 6, 2011
Scope of Registration: The design/development
and manufacture of manganese dioxide lithium
battery (coin type) for automobile use.
50
Hitachi Maxell, Ltd.
2-18-2, Iidabashi,
Chiyoda-ku, Tokyo
102-8521 Japan
Tel: (+81) 3-3515-8249
Fax: (+81) 3-3515-8305
Visit our website at: www.maxell.com
NORTH AMERICA / SOUTH AMERICA
Maxell Corporation of America Maxell Latin America
Main Office: Plaza Btesh - Calle 50, Panama City,
22-08, Route 208 Fair Lawn, NJ Panama
07410, U.S.A. Tel: (+507) 269-6737
Tel: (+1) 201-794-5900 Fax: (+507) 263-4413
Fax: (+1) 201-796-8790 E-mail: maxell@ciabtesh.com
Canada Branch:
50 Locke Street, Unit #2, Concord,
Ontario L4K 5R4, Canada
Tel: (+1) 905-669-8107
Fax: (+1) 905-669-8108
E-mail: support@maxellcanada.com
EUROPE
ASIA
Maxell Asia, Ltd. Maxell (Shanghai) Trading Co., Ltd. Maxell Taiwan, Ltd.
Main Office: Main Office: 14F, No.111, Sung Chiang Road,
506, World Commerce Centre, PLAZA 336, Room No.1801, 18th Floor, Taipei, Taiwan
Harbour City, Phase 1, No.336, Xi Zang Middle Road, Huang Pu Tel: (+886) 2-2516-5553
Canton Road, Kowloon, District, Shanghai 200001, China Fax: (+886) 2-2516-4804
Hong Kong Tel: (+86) 21-3330-3377 E-mail: maxell@maxell.com.tw
Tel: (+852) 2730 9243 Fax: (+86) 21-3330-4001
Fax: (+852) 2735 6250 E-mail: maxell@maxell.net.cn
E-mail: maxell@maxell.com.hk Beijing Office Maxell Asia (Singapore) Pte. Ltd.
Vietnam Office: Room 905, C Wantong Tower, No.6
Main Office:
Suite 15, Mezzanine Floor, Chaowai Road, Chaoyang District 100020,
10 Anson Road, #25-06,
Sun Wah Tower, 115 Nguyen Hue Beijing, China
International Plaza, Singapore 079903
Boulevard, District 1, Tel: (+86) 10-5907-0016
Tel: (+65) 6220-9291
Ho Chi Minh City, Vietnam Fax: (+86) 10-5907-0017
Fax: (+65) 6220-6070
Tel: (+84) 8-821-9183 E-mail: maxellbj@public.bta.net.cn
E-mail: sales@maxell.com.sg
Fax: (+84) 8-821-9181
E-mail: maxellvn@saigonnet.vn Chennai Office:
DBS Office Business Center, 31A,
Cathedral Garden Road, Near
Palmgrove Hotel, Chennai-600 034,
Tamil Nadu, India
Tel: (+91) 44-5264-9495
Fax: (+91) 44-5264-9495
E-mail: maxellchennai@touchtelindia.net