GOC

7XWRULDO²14

Structural Isomerism
1. The isomerism observed in alkanes is :
(a) metamerism (b) chain isomerism (c) position isomerism (d) geometrical isomerism
2. Which of the following are functional isomers ?
(a) CH3CH2Cl and CH3CH2Br (b) CH3CHBr2 and CH2Br . CH2Br
(c) C2H5OC2H5 and CH3OC3H7 (d) CH3CH2CHO and

3. Keto-enol tautomerism is observed in

(a) (b)

(c) (d)
4. Tautomerism is exhibited by

(a) (b)

(c) (d)

5. The enolic form of acetone contains

(a) 9 V bonds, 1 S bond and 2 lone pairs (b) 8 V bonds, 2 S bonds and 2 lone pairs
(c) 10 V bonds, 1 S bond and 1 lone pair (d) 9 V bonds, 2 S bonds and 1 lone pair
6. Which of the following has maximum enol content ?

(a) Acetaldehyde (b)

(c) (d)
7. Tautomerism is not exhibited by

(a) (b)

(c) (d)

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8. Which organic structure among the following is not an isomer of the compound ?

(a) (b)

(c) CH3CH2COCH2CH2CH3 (d)

9. The compound which is not isomeric with diethyl ether is

(a) n – propylmethyl ether (b) butanol – 1

(c) 2 – methylpropanol (d) butanone

10. The maximum number of an alkene with molecular formula C4H8 is

(a) 2 (b) 3 (c) 4 (d) 5

11. How many cyclic isomer of C5H10 are possible ?

(a) 4 (b) 3 (c) 2 (d) 5

12. How many chain isomers can be obtained form the alkane C6H14 ?

(a) 3 (b) 5 (c) 6 (d) 7

13. Write the structural isomers of the compound having formula C4H9Br.

14. (i) Draw the structures of all isomeric alcohols of molecular formula C5H12O and give their IUPAC names.

(ii) Classify the isomers of alcohols in question as primary, secondary and tertiary alcohols.

15. Write position isomers of .

Answer Key

1. (a,b,c) 2. (d) 3. (b,d) 4. (a,c,d) 5. (a) 6. (c) 7. (b) 8. (a) 9. (d)

10. (b) 11. (a) 12. (a)

13.

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14. (i)

15.

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