Chemistry @Deshpande Sir, Akola:9421754921, Producing PMT CHEMISTRY Topper Since 17 Years.

Date:-11-07-2019 MEEEGS, AKOLA. IB

Subject :-Chemistry Chapter:-Periodic Properties
1.Which is the correct order of ionic sizes? 14.Which one of the following sets of ions represents
(1)Ce>Sn>Yb> Lu (2)Sn>Ce> Cu>Yb a collection of isoelectronic species?
(3)Lu>Yb>Sn>Ce (4)Sn>Yb>Ce>Lu (1) K+, Cl-, Ca2+, Sc+3 (2) Ba2+,Sr2+,K, S-2
2.The radius of La3+ (Atomic number of La = 57) is (3) N , 0 ; F , S
3- 2- -1 2- (4)Li+ , Na+, Mg2+,Ca2+
1.06A. Which one of the given values will be closest 15.The increasing order of the first ionization
to the radius of Lu3+ (Atomic number of Lu = 71)? enthaples of the elements B, P, S and F (lowest first)is
(1) 40 A (2) 1.06 A (3) 0.85 A (4) 1.60 A (1)F<S<P<B (2)P<S<B<F
3.According to the Periodic Law of elements, the (3)B<P<S<F (4)B<S<P<F
variation in properties of elements is related to their. 16. Following statements regarding the periodic
(1)nuclear masses (2) atomic numbers trends of chemical reactivity of the alkali metals and
(3)nuclear neutron-porton number ratios the halogens are given. Which of these statements
(4)atomic masses gives the correct picture?
4.Which one of the following is an amphoteric oxide? (1) The reactivity decreases in the alkali metals but
(1)Na2O(2)B2O3(3) B2O2(4)ZnO increases in the halogens with increases in atomic
5.The atomic numbers of vanadium (V), chromium number down the group
(Cr), manganese (Mn) and iron (Fe) are respectively (2) In both the alkali metals and the halogens the
23, 24,25 and 26. Which one of these may be chemical reactivity decreases with in crease in atomic
expected to have the highest second ionization number down the group
enthalpy? (3) Chemical reactivity increases with in creases with
(1)Cr (2)Mn (3) Fe (4) V increase in atomic number down the group in both
6.Which one the following ions has the highest value the alkali metals and halogens
of ionic radius? (4) In alkali metals the reactivity increases but in th
(1) Li+(2) F- (3)O-(4) B3+ halogens it decreases with increase in atomic number
7.Which one the following sets of ions represents the down the group
collection of isoelectronic species? 17.The charge / size ratio of a cation determines its
(1) K+,Ca2+,Sc3+,Cl- (2) Na+,Mg2+ ,Al3+,Cl- polarizing power. Which one of the following
(3) K , Cl , Mg ,Sc
+ - 2+ 3+ (4) Na+,Ca2+,Sc3+,F- sequenes represents the increasing order of the
8.Among Al2O3,SiO2,P2O3 and SO2 the correct order of polarizing order of the polarizing power of the
acid strength is cationic species, K , Ca2+,Mg2+,Be2+?
(1)SO2<P2O3<SiO2< Al2P3(2)Al2O3<SiO2< P2O3<SO2 (1)Mg2+, Be2+, K+,Ca2+ (2) Be2+, K+ , Ca2+, Mg2+
(3)Al2O3<SiO2< SO2<P2O3 (3) K , Ca ,Mg ,Be
+ 2+ 2+ 2+ (4) Ca2+,Mg2+, Be2+, K+
(4) SiO2< SO2< Al2O3< P2O3 18.The set representing the ocrrect order of ionic
9.The formation of the oxide ion O2-(g) requires first radius is:
an exothermic and then an endothermic step as (1) Li+> Be2+>Na+>Mg2+ (2)Na+>Li+>Mg2+>Be2+
shown below (3) Li+> Na+> Mg2+>Be2+(4)Mg2+>Be2+>Li+>Na+
O(g)+e-xO- (g); ∆H°=-142kJmol-1 19.The correct order of radii is
O(g) + e-  O2-(g);∆H°=844kJmol-1 (1)Al3+>Mg2+>Na+>O2- >F-(2)Na+>Mg2+>Al3+>O2->F-
The correct statements is (3) Na+>F->Mg2+>O2->Al3+(4)O2-> F->Na+>Mg2+>Al3+
(1) Oxygen is more electronegative
20.Out of Na+, Mg+2, O-2 and N-3, the pair of species
(2) 0- ion has comparatively larger size than oxygen
showing minimum and maximum IP would be.
atom
(1) Na+, Mg+2 (2) Mg+2,N-3 (3) N-3,Mg+2(4) O-2, N-2
(3) O- ion will tend to resist the addition of
21.The element having highest I.P. in the two series
anotherelectron
C, N, O and Si, P, S:
(4) Oxygen has high electron affinity
(1) P (2) N (3)S (4) O
10.Beryllium and aluminium exhibit many prop
22.Triad-I [N3-, O-2, Na+]
erties which are similar. But the two elements differ
Triad-II [N+, C+, O+]
in
Choose the species of lowest IP from triad-l and
(1)exhibiting maximum covalency in compound
highest IP from triad-ll respectively
(2)exhibiting amphoteric nature ion their oxides
(3)forming covalent halides (1) N3-,O+ (2)Na+,C+ (3) N3-, N+(4) O-C+
(4)forming polymeric hydrides 23.M(g) M+ (g) + e, ∆H = 100 eV,
11.Which of the following oxides is amphoteric in M(g)  M2-(g) + 2e-, ∆H = 250 eV
character? which is incorrect statements:
(1)CaO (2) C02 (3) SiO2(4) SnO2 (1) I1of M(g) is 100eV (2)I2 of M(g) is 150 eV
12.The lanthanide contraction is responsible for the (3) I2of M (g) is 250 eV(4) None
fact that 24.In which of the following pairs, the ionization
(1)Zr and Y have about the same radius energy of the first species is less than that of the
(2)Zr and Nb have similar oxidation state second
(3)Zr and Hf have about the same radius (1) N, P (2) Be+, Be (3) N, N-(4) Ne, Ne+
(4)Zr and Zn have the same oxidation 25.Which one of the following has highest ionization
13.In which of the following arrangements the order potential:
is NOT according to the property indicated against it? (1) Li+(2) Mg+ (3) He(4) Ne
(1)Al3+<Mg2+<Na+<F-; Increasing ionic size 26.The correct order of electron affinity is:
(2)B < C < N < O ; Increasing first ionization enthalpy (1) Be < B < C < N (2) Be < N < B < C
(3) I < Br < F <Cl; increasing electron gain enthalpy (3) N<Be<C<B (4) N < C < B < Be
(4) Li < Na < K <Rb ; Increasing metallic radius 27.Electron addition would be easter in:
(1) O (2) O+ (3) O- (4) O+2

Chemistry @Deshpande Sir, Akola:9421754921, Producing PMT CHEMISTRY Topper Since 17 Years.
Chemistry @Deshpande Sir, Akola:9421754921, Producing PMT CHEMISTRY Topper Since 17 Years.
28.In which of the following process energy is 40.4d35s2 configuration belongs to which group:
liberated: (1) II A (2) II B (3) VB (4) IIIB
(1)ClCl+ + e (2)HCl H+ + Cl- 41.Pd has exceptional outer electronic
(3)Cl + eCl- (4) O- +eO-2 configuration as 4d10 5s°, it belong to:
29.The process requiring the absorption of energy is: (1) 4th period, group – 11(2) 5th period, group - 10
(1)FF - -
(2)ClCl (3)O O (4) H H
2- - (3) 6th period, group–9(4) 4th period, group – 10
30.Energy absorbed in second electron addition 42.Uranium (At No. – 92) is the last natural element
in an atom is called: in the periodic table. The last element of the periodic
(1) 1 IP
st (2) 2 EA
nd (3)1 EA(4) 2 IP
st nd table which is recently discovered is Uub. What will
31.The amount of energy released for the process be the total number of transuranic elements in the
−
X+e-𝑋(𝑔) is minimum and maximum respectively periodic table:
(1) 21 (2) 20 (3)11 (4) 12
for:
(1) F (2) Cl (3) N (4) B 43.The formula for effective nuclear charge is
(if 𝜎is screening constant)
Correct answer is:
(1) 3&4 (2) 4&2(3) 1 &2 (4) 3 & 2 (1) Z-𝜎 (2)Z + 𝜎 (3) Z𝜎-1(4) Z𝜎
44.From the given set of species, point out the spe-
32.Correct order of electronegativity of N, P, C and Si
is: cies from each set having least atomic radius:
(1) O-2, F-, Na+ (2) Ni, Cu, Zn
(1) N<P<C<Si (2) N > C > Si > P
(3) N = P > C = Si (4) N > C > P > Si (3) Li, Be, Mg (4) He, Li+, H-
Correct answer is:
33.Electronegativity of the following elements
increases in the order: (1)O-2, Cu, Li, H- (2) Na+, Ni, Be, Li+
(3) F, Zn, Mg, He (4) Na+, Cu, Be, He
(1)O, N, S, P (2) P, S, N, O
(3) P, N, S, O (4) S, P, N, O 45.If the difference in atomic size of:
Na - Li = x Rb - K = y Fr- Cs = z Then correct order
34.Select the group where EN increases down the
group: - will be:
(1)x = y = z (2) x >y > z
(1)Ca, Sr, Ba (2) Zn, Cd, Hg
(3) F, Cl, Br (4) Li, Na, K (3)x<y <z (4) x<y <<z
21.In the isoelectronic species the ionic radii
35. The pair with minimum difference in electro-
(Å)of N3-, Ne and Al+3 are respectively given by:
negativity is:
(1) 1.36,1.40, 1.71 (2) 1.36, 1.71, 1.40
(1) F, Cl (2) C, H
(3) 1.71,1.40, 1.36 (4) 1.71, 1.36, 1.40
(3) P, H (4) Na, Cs
22.Which of the following order of atomic/ionic
36.The nomenclature of ICI is iodine chloride
radius is not correct:
because:
(1)I > I>I+ (2) Mg+2>Na+>F-
(1) Size of 1< Size of Cl
(3)p <p
+5 +3 (4) Li>Be>B
(2) Atomic no. of 1 > Atomic no. of Cl
(3) E.N. of 1< E. N. of Cl 22.In which of the following pair radii of second
species is smaller than that of first species:
(4) E.A. of 1< E.A. of Cl
(1) Li, Na (2) Na+, F-
37.If the ionisation potential is IP, electron affinity is
(3) N ,Al
-3 +3 (4) Mn+7,Mn+4
EA and electronegativity is x then which of the
23.Which of the following orders of ionic radii
following relation is correct
are correct:
(1) 2X-EA-IP = 0 (2) 2EA-X-IP = 0
(3) 2IP-X-EA = 0 (4) All of the above (1) Li < Be < Na (2) Ni < Cu < Zn
38.Which of the following elements have the dif- (3) Ti > V > Cr (4) Ti >Zr≃Hf
Correct answer is:
ferent value of electronegativity:
(1) H (2) S (3)Ts(4) P (1) All (2) 1, 2 (3) 2, 3 (4) 2, 4
28.The correct order of stability of Al+, Al+2, Al+3
39.As we proceed across the period in periodic table,
is:
one finds there is a decrease in:
(1) Al+3>Al+2>Al+1 (2) Al+2>Al+3>Al+
(1)lonization energy (2) Electron affinity
(3) Electronegativity (4) Atomic radii (3) Al <Al >Al
+2 + +3 (4) Al+3>AI+>Al+2

Chemistry @Deshpande Sir, Akola:9421754921, Producing PMT CHEMISTRY Topper Since 17 Years.