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Abstract: We study the energy consumption optimization of a reverse osmosis water desalination
process producing a constant permeate flow in the presence of feed concentration fluctuation.
We propose a time-varying optimal operation strategy that can significantly reduce the specific
energy consumption compared to time-invariant process operation.
where Qp is the permeate flow rate and Ẇpump is the rate Δπexit = fos Cr − πp (9)
of work done by the pump, given by:
where Cr is the salt concentration of the exit brine (i.e.,
Ẇpump = ΔP × Qf (2) concentrate) stream. For sufficiently high rejection level,
the osmotic pressure of the permeate can be taken to be
in which
negligible relative to the feed or concentrate streams and
ΔP = Pf − P0 (3) Cr can be approximated by:
where Pf is the water pressure at the entrance of the Cf
Cr = (10)
membrane module, P0 is the pressure of the raw water 1−Y
which is assumed (for simplicity) to be the same as the
permeate pressure, and Qf is the volumetric feed flow Thus, by combining Eqs. (8)–(10), the osmotic pressure
rate. In order to simplify the analysis, we initially assume difference between the retentate and permeate stream at
that the impact of the pressure drop (within the RO the exit of the module can be expressed as:
module) on locating the minimum SEC is negligible; this π0
issue is addressed further in Zhu et al. (2008). It is Δπexit = (11)
1−Y
acknowledged that, fouling and scaling will impact the
selection of practical RO process operating conditions and where π0 = fos Cf is the feed osmotic pressure. Eq. (11)
feed pretreatment. However, the inclusion of such effects is a simple relationship that illustrates that the well
is beyond the scope of the present paper. known inherent difficulty in reaching high recovery in RO
The permeate product water recovery for the RO process, desalting is due to the rapid rise in osmotic pressure with
Y , is an important measure of the process productivity, increased recovery.
defined as:
Qp 2.2 Thermodynamic Restriction of Cross-flow RO Operation
Y = (4)
Qf
In the process of RO desalting, an external pressure is
and combining Eqs. (1), (2) and (4), the SEC can be applied to overcome the osmotic pressure, and pure water
rewritten as follows: is recovered from the feed solution through the use of a
ΔP semipermeable membrane. Assuming that the permeate
SEC = (5)
Y pressure is the same as the raw water pressure, P0 , the
applied pressure (ΔP ) needed to obtain a water recovery
The permeate flow rate can be approximated by the of Y should be no less than the osmotic pressure difference
classical reverse osmosis flux equation Mulder (1997): at the exit region (Wilf (1997); Song et al. (2003b)), which
Qp = Am Lp (ΔP − σΔπ) = Am Lp (N DP ) (6) is given by Eq. (11). Therefore, in order to ensure permeate
productivity along the entire RO module (or stage), the
following lower bound is imposed on the applied pressure: 12
π0
ΔP ≥ Δπexit = (12)
1−Y 10
SECtr/π0
This is the so-called thermodynamic restriction of cross-
flow RO (Song et al. (2003a); Song and Tay (2006)) 8
and referred to as the “thermodynamic restriction” in
the current work. The equality on the right-hand-side of
Eq. (12) is the condition at the “limit of thermodynamic 6
restriction” in the exit of the membrane module and is
attained at the limit of infinite membrane permeability
for a finite membrane area. It is particularly important 4
0 0.2 0.4 0.6 0.8 1
from a practical point of view when a highly-permeable Fractional water recovery, Y
membrane is used for water desalination at low pressures.
It is emphasized that the constraint of Eq. (12) arises Figure 2. Variation of the normalized SEC with water
when one wants to ensure that the entire membrane area recovery for a single-stage RO at the limit of ther-
is utilized for permeate production. modynamic restriction.
The specific energy consumption (SEC) for the RO desalt-
600
Normalized SECavg
hrs is 2.5 times that of the water recovery in the first 10
hrs. In order to produce the same amount of permeate
4
volume, the feed flow rate in the first 10 hrs has to be 2.5
times the feed flow rate in the last 10 hrs (Qf,2 ). Therefore,
the permeate flow and energy consumption in the first and
last 10 hrs are: 3
2 50
Vp,1 = 2.5 × Qf,2 × × 10 hr = Qf,2 × hr (36)
7 7 Time−varying operating pressure
W1ERD = ΔP1 × (Vf,1 − η(Vf,1 − Vp,1 )) (37) 2
0 50 100
5 50 ERD efficiency (%)
Vp,2 = Qf,2 × × 10 hr = Qf,2 × hr (38)
7 7
Figure 5. Percentage SEC increase when feed pressure is
W2ERD = ΔP2 × (Vf,2 − η(Vf,2 − Vp,2 )) (39)
not adjusted. vs. ERD efficiency.
Therefore, the average SEC is: and has a higher SEC. In others words, by adjusting
A W ERD + W2ERD operating pressure to be double that of the instantaneous
SEC ERD = 1 = (1715 − 1015η) psi (40) feed osmotic pressure, the system needs to process less
Vp,1 + Vp,2
volume of feed water to produce the same amount of
Operating strategy B. The water recovery in the last 10 permeate water and has a lower SEC.
hrs is the same as the water recovery in the first 10 hrs.
In order to produce the same amount of permeate volume, 4. DISCUSSION
the feed flow rate in the first 10 hrs has to be the same as
that the feed flow rate in the last 10 hrs (Qf,2 ’). Therefore, 4.1 Effect of the Feed salinity Fluctuation Percentage on
the permeate flow and energy consumption in the first and Energy Savings
last 10 hrs are:
1 The effect of the fluctuation amplitude on energy savings
Vp,1 = Qf,2 × × 10 hr = 5Qf,2 × hr (41) can be studied following the same procedure presented
2 in Section 3.3. Assuming the average osmotic pressure is
W1ERD = ΔP1 × (Vf,1
− η(Vf,1
− Vp,1 )) (42) π0 , the osmotic pressure in the first 10 hrs is (1 + σ)π0
1 (0 < σ < 1), and the osmotic pressure in the last 10 hrs
Vp,2 = Qf,2 × × 10 hr = 5Qf,2 × hr (43) is (1 − σ)π0 . Therefore, the feed fractional fluctuation is
2
σ. Similarly, the following two operating strategies may be
W2ERD = ΔP2 × (Vf,2 − η(Vf,2 − Vp,2 )) (44) considered.
Therefore, the average SEC is: • Operating strategy A: The transmembrane pressure is
maintained at double that of the average feed osmotic
B W1ERD + W2ERD pressure, i.e. 2π0 .
SEC ERD = +V = 700(2 − η) psi (45)
Vp,1 p,2 • Operating strategy B: The transmembrane pressure
is maintained at double that of the instantaneous feed
The SEC difference between operating strategy A and osmotic pressure.
operating strategy B is (1715 − 1015η) − 700(2 − η) psi =
315(1 − η) psi. Thus, when 0 < η < 1, the SEC of Operating strategy A. The water recovery in the last 10
operating strategy A will be always greater than the SEC hrs, Y1 = 1 − (1+σ)π
2π0
0
= 1−σ
2 , and in the last 10 hrs,
of operating strategy B. The fractional SEC increase is,
Y2 = 1 − (1−σ)π
2π0
0
= 1+σ2 . In order to produce the same
A B
SEC ERD − SEC ERD 315 (1 − η) amount of permeate volume, the feed flow rate in the first
= (46) 1+σ
B
SEC ERD 700 [1 + (1 − η)] 10 hrs has to be 1−σ times that of the feed flow rate
in the last 10 hrs (Qf,2 ). The permeate flow and energy
which is plotted in Fig. 5. For example, when the ERD consumption in the first and last 10 hrs are:
efficiency is 90%, the fractional SEC increase is 4.1%. 1+σ 1−σ
Furthermore, in order to equate the total permeate volume Vp,1 = · Qf,2 · · 10 hr = 5(1 + σ) · Qf,2 · hr(47)
1−σ 2
in operating strategy A and operating strategy B, Qf,2 =
10 W1ERD = ΔP1 × (Vf,1 − η(Vf,1 − Vp,1 )) (48)
7 Qf,2 . Thus, the total feed volume in operating strategy 1+σ
B is 2 × 10 20
7 Qf,2 = 7 Qf,2 , while the total feed volume in Vp,2 = Qf,2 × × 10 hr = 5(1 + σ) · Qf,2 · hr (49)
operating strategy A is (2.5 + 1)Qf,2 = 3.5Qf,2 . Therefore, 2
in order to get the same amount of permeate volume, W2ERD = ΔP2 × (Vf,2 − η(Vf,2 − Vp,2 )) (50)
operating strategy A requires a higher amount of feed
water, and thus, it has a lower overall water recovery. Therefore, the average SEC is:
A W ERD + W2ERD (1 − η) (1 + ησ)
In summary, operating strategy A is worse since we need SEC ERD = 1 = 2π0 [ + ](51)
to process more feed water to obtain the same permeate Vp,1 + Vp,2 1−σ 1+σ
Operating strategy B. The water recovery in the last 10
hrs is the same as the water recovery in the first 10 hrs. 4
In order to produce the same amount of permeate volume,
avg
the feed flow rate in the first 10 hrs has to be the same as 3.5 Constant operating pressure
Normalized SEC
the feed flow rate in the last 10 hrs (Qf,2 ’). The permeate
flow and energy consumption in the first and last 10 hrs
are: 3
1
Vp,1 = Qf,2 × × 10 hr = 5Qf,2 × hr (52)
2
2.5
W1ERD = ΔP1 × (Vf,1
− η(Vf,1 − Vp,1
)) (53)
1
Vp,2 = Qf,2 × × 10 hr = 5Qf,2 × hr (54) 2
Time−varying operating pressure
2 0 50 100
W2ERD = ΔP2 × (Vf,2 − η(Vf,2 − Vp,2 )) (55) Fluctuation of feed salinity (%)
Therefore, the average SEC is: Figure 6. Percentage SEC increase without adjusting the
B W ERD + W2ERD operating pressure vs. feed concentration fluctuation
SEC ERD = 1 = 2(2 − η) · π0 (56) percentage.
Vp,1 + Vp,2
Bartman, A., McFall, C.W., Christofides, P.D., and Co-
The SEC difference of operating strategy A from operating hen, Y. (2009). Model-predictive control of feed flow
strategy B is (2[ (1−η) (1+ησ)
1−σ + 1+σ ] − 2(2 − η)) · π0 . When
reversal in a reverse osmosis desalination process. Jour-
0 < η < 1, the SEC of operating strategy A will be nal of Process Control, 19, 433–442.
always greater than the SEC of operating strategy B. The Busch, M. and Mickols, W. (2004). Reducing energy
fractional SEC increase is: consumption in seawater desalination. Desalination,
A
SEC ERD − SEC ERD
B
[ (1−η) (1+ησ)
1−σ + 1+σ ]
165, 299–312.
= −1 (57) Manth, T., Gabor, M., and Oklejas, E. (2003). Minimizing
SEC
B (2 − η) RO energy consumption under variable conditions of
ERD
operation. Desalination, 157(1-3), 9–21.
which is plotted in Fig. 6 when the efficiency of the ERD is McCool, B.C. (2008). The feasibility of reverse osmosis
set to be 90%. Fig. 6 shows that as feed salinity fluctuation desalination of brackish water in the San Joaquin Valley.
percentage increases, time-invariant operation increases UCLA master thesis.
SEC more remarkably. Even in some cases there is only McFall, C.W., Bartman, A., Christofides, P.D., and Co-
marginal energy savings, it is still worthwhile to adopt hen, Y. (2008). Control and monitoring of a high
the proposed operating strategy accompanied by the con- recovery reverse osmosis desalination process. Industrial
trol algorithms developed at UCLA M3 group regarding & Engineering Chemistry Research, 47(17):6698–6710.
reverse osmosis water desalination system (McFall et al. Mulder, M. (1997). Basic Principles of Membrane Tech-
(2008); Bartman et al. (2008)) since we will not be able nology. Kluwer Academic Publishers (Boston).
to know what the future salinity profile would exactly Song, L., Hu, J.Y., Ong, S.L., Ng, W.J., Elimelech, M.,
be. Furthermore, in order to equate the total permeate and Wilf, M. (2003a). Emergence of thermodynamic
volume in operating strategy A and operating strategy restriction and its implications for full-scale reverse
B, Qf,2 = (1 + σ)Qf,2 . Thus, the total feed volume in osmosis processes. Desalination, 155(3), 213–228.
operating strategy B is 2(1 + σ) · Qf,2 , while the total feed Song, L., Hu, J.Y., Ong, S.L., Ng, W.J., Elimelech, M.,
1+σ
volume in operating strategy A is ( 1−σ + 1)Qf,2 = (1 + and Wilf, M. (2003b). Performance limitation of the
2σ full-scale reverse osmosis process. Journal of Membrane
1−σ + 1)Q f,2 > (1 + 2σ + 1)Qf,2 . Therefore, in order to get
the same amount of permeate volume, operating strategy Science, 214(2), 239–244.
A requires a higher amount of feed water, and thus, it has Song, L. and Tay, K.G. (2006). Performance prediction
a lower overall water recovery. of a long crossflow reverse osmosis membrane channel.
Journal of Membrane Science, 281(1-2), 163–169.
5. CONCLUSION Wilf, M. (1997). Design consequences of recent improve-
ments in membrane performance. Desalination, 113(2-
Based on a model for a reverse osmosis membrane desali- 3), 157–163.
nation plant and the feed concentration fluctuation (which Wilf, M. and Bartels, C. (2005). Optimization of seawater
is common in both seawater and brackish water desalina- RO systems design. Desalination, 173(1), 1–12.
tion) profile, the proposed approach requires less amount Zhu, A., Christofides, P.D., and Cohen, Y. (2008). Effect of
of feed water and decreases specific energy consumption thermodynamic restriction on energy cost optimization
by as much as 22%, providing the same permeate flow. of RO membrane water desalination. Industrial & En-
Experimental results confirming the proposed operating gineering Chemistry Research, Publication Date (Web):
policy will be presented at the conference. August 29, 2008 (DOI: 10.1021/ie800735q).
Zhu, A., Christofides, P.D., and Cohen, Y. (2009). Mini-
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