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I. Moles y partículas
1) ¿Cuál es la unidad del SI para medir el número de partículas de una sustancia?
A) kilogramo B) ampere C) candela
D) mol E) Kelvin
8) El butanol está formado por carbon, hidrógeno y oxígeno. Si 1 mol de butanol contiene 6 x
1024 átomos de hidrógeno, ¿Cuál es el subíndice para el átomo de H en C 4H?O?
A) 1 B)8 C) 6
D) 4 E) 10
17) All of the following are equal to Avogadro's number EXCEPT _____.
A) the number of atoms of gold in 1 mol Au
B) the number of atoms of bromine in 1 mol Br 2
C) the number of molecules of carbon monoxide in 1 mol CO
D) the number of molecules of nitrogen in 1 mol N 2
E) the number of formula units of sodium phosphate in 1 mol Na 3PO4
20) The gram atomic masses of any two elements contain the same number of _____.
A) ions B) atoms C) grams
D) anions E) milliliters
21) The gram formula mass of C7H16 and the gram formula mass of CaCO3 contain
approximately the same number of _____.
A) anions B) carbon atoms C) grams
D) cations E) atoms
33) How many moles of CaBr2 are there in 5.0 grams of CaBr2?
A) 1.0 x 103 mol B) 2.5 x 10-2 mol C) 4.2 x 10-2 mol
1
D) 4.0 x 10 mol E) 3.0 x 1024 mol
34) The chemical formula of aspirin is C9H8O4. What is the mass of 0.40 mol of aspirin?
A) 72 g B) 45 g C) 160 g
D) 10.8 g E) 80 g
42) How many moles of Ar atoms are there in 202 L of Ar gas at STP?
A) 1.20 x 1024 mol B) 1.11 x 10-1 mol C) 4.52 x 103 mol
D) 9.02 mol E) 1.79 mol
43) What is the volume (in liters at STP) of 2.50 mol of carbon monoxide?
A) 3.1 L B) 9.0 L C) 56 L
D) 70 L E) 560 L
44) The volume of one mole of substance is 22.4 L at STP for all _____.
A) liquids B) elements C) solids
D) gases E) compounds
45) A 22.4-L sample of which of the following substances, at STP, would contain 6.02 x 10 23
representative particles?
A) sulfur B) cesium iodide C) gold
D) oxygen E) All would have the same number of representative
particles.
46) Which of the following gas samples would have the largest number of representative
particles at STP?
A) 7.0 L O2 B) 0.007 L SO3 C) 0.10 L Xe
D) 12.0 L He E) 5.5 L N2O4
48) Which combination of temperature and pressure correctly describes standard temperature
and pressure, STP?
A) 100°C and 100 kPa B) 0°C and 101 kPa C) 1°C and 0 kPa
23
D) 22.4°C and 6.02 x 10 kPa E) 0°C and 22.4 kPa
49) Which of the following conversion processes does NOT depend upon the gram formula
mass of a substance? (volume refers to the volume of a gas at STP.)
A) mass → mole → volume
B) mass → mole → number of representative particles
C) volume → mole → number of representative particles
D) number of representative particles → mole → mass
E) volume → mole → mass
50) For which of the following conversions does the value of the conversion factor depend
upon the formula of the substance?
A) mass of any substance to moles
B) volume of gas (STP) to moles
C) number of particles to moles of gas (STP)
D) density of gas (STP) to gram formula mass
E) moles of any substance to number of particles
51) A large weather balloon filled with helium has a volume of 7.00 x 10 2 L at STP. Which
expression should be used to find the mass of helium in the balloon?
A) (7.00 x 102 / L) x (4 g He/mol)
B) (22.4 L/mol / 7.00 x 102 L) x (4 g He/mol)
C) (7.00 x 102 L / 22.4 L/mol) x (4 g He/mol)
D) (22.4 L/mol) x (4 g He/mol)
E) 22.4 L/(4 g/mol)
IV. Percent composition
52) To determine the formula of a new substance, one of the first steps is to find the _____.
A) gram formula mass B) number of particles per mole C) percent
composition D) volume at STP E) value for Avogadro's number
53) If 60.2 grams of Hg combines completely with 24.0 grams of Br to form a compound, what
is the percent composition of Hg in the compound?
A) 71.50% B) 251% C) 60.10%
D) 39.90% E) 28.50%
57) If 20.0 grams of Ca combines completely with 16.0 grams of S to form a compound, what
is the percent composition of Ca in the compound?
A) 1.25% B) 55.60% C) 20.00%
D) 80.00% E) 44.40%
62) What is the empirical formula of a compound that is 50.7% antimony and 49.3% selenium
by weight?
A) Sb3Se2 B) SbSe2 C) Sb2Se3
D) SbSe E) Sb2Se
63) What is the empirical formula of a substance that is 53.5% C, 15.5% H, and 31.1% N by
weight?
A) C4H14N2 B) C2H7N C) CH4N7
D) C4.5H15.5N2.2 E) C3HN2
64) The ratio of carbon atoms to hydrogen atoms to oxygen atoms in a molecule of
dicyclohexyl maleate is 4 to 6 to 1. What is the molecular formula of this substance if its gram
formula mass is 280 g?
A) C4H6O1 B) C12H18O3 C) C8H12O2
D) C20H30O5 E) C16H24O4
65) Which of the following compounds has the lowest percent gold content by weight?
A) AuBr3 B) AuOH C) AuCl3
D) AuI3 E) Au(OH)3
66) Which of the following compounds has the highest oxygen content, by weight?
A) Na2O B) CO2 C) BaO
D) NO E) H2O
69) The lowest whole-number ratio of the elements in a compound is called the _____.
A) representative formula B) ionic compound C) empirical formula
D) molecular formula E) binary formula
70) Which of the following is not an empirical formula?
A) MoO2Cl2 B) BeCr2O7 C) C2N2H8
D) C3H8O E) Sb2S3
73) Which of the following is NOT a true statement concerning empirical and molecular
formulas?
A) The molecular formula of a compound can be some whole-number multiple of its
empirical formula.
B) Several compounds can have the same empirical formula, but have different
molecular formulas.
C) The molecular formula of a compound can be the same as its empirical formula.
D) If the molecular formula of hydrogen peroxide is H 2O2, its empirical formula is HO.
E) The empirical formula of a compound can be triple its molecular formula.
74) Which of the following sets of empirical formula, gram formula mass, and molecular
formula is correct?
A)C3H8O, 120 g, C3H8O2 B) HO, 34 g, H2O C) CH, 78 g, C13H13
D) CH4N, 90 g, C3H12N3 E) CaO, 56 g, Ca2O2
1. 25 g NaCl
2. 125 g of H2SO4
3. 100.0 g of KMnO4
4. 74 g of KCl
5. 35 g of CuSO4●5H2O
IV- For gases at STP (273 K and 1 atm pressure), one mole occupies a volume of 22.4
L. What volume will the following quantities of gases occupy at STP?
1. 1.00 mole of H2
2. 3.20 moles of O2
3. 0.750 mole of N2
4. 1.75 moles of CO2
5. 0.50 mole of NH3
6. 5.0 g of H2
7. 100 g of O2
8. 28.0 g of N2
9. 60 g of CO2
10. 10 g of NH3
VIII- What is the empirical formula (lowest whole number ratio) of the compounds below?
1. The empirical formula of a compound is NO2. Its molecular mass is 92 g/mol. What is its
molecular formula?
2. The empirical formula of a compound is CH2. Its molecular mass is 70 g/mol. What is its
molecular formula?
3. A compound is found to be 40.0% carbon, 6.7% hydrogen and 53.5% oxygen. Its
molecular mass is 60.0 g/mol. What is its molecular formula?
4. A compound is found to be 64.9% carbon, 13.5% hydrogen and 21.6% oxygen. Its
molecular mass is 74 g/mol. What is its molecular formula?
5. A compound is found to be 54.5% carbon, 9.1% hydrogen and 36.4% oxygen. Its
molecular mass is 88 g/mol. What is its molecular formula?
1. KMnO4
K=
Mn=
O=
2. HCl
H=
Cl=
3. Mg(NO3)2
Mg=
N=
O=
4. (NH4)3PO4
N=
H=
P=
O=
5. Al2(SO4)3
Al=
S=
O=
6. How many grams of oxygen can be produced from the decomposition of 100.0 g of
KClO3?
7. How much iron can be recovered from 25.0 g of Fe 2O3?
8. How much silver can be produced from 125 g of Ag 2S?
Answers
II
1. 0.427 mol NaCl
2. 1.28 mol H2SO4
3. 0.671 mol KMnO4
4. 0.994 mol KCl
5. 0.140 mol CuSO4 •5H2O
III
1. 146 g NaCl
2. 49 g H2SO4
3. 253 g KMnO4
4. 18.6 g KCl
5. 798.6 g CuSO4 •5H2O
IV
1. 22.4 L H2
2. 71.7 L O2
3. 16.8 L N2
4. 39.2 L CO2
5. 11.2 L NH3
6. 56 L H2
7. 70 L O2
8. 22.4 L N2
9. 30.5 L CO2
10. 13.2 L NH3
V
1. 1.2x1024 molecules H2O
2. 9.0x1023 molecules H2O
3. 4.5x1023 molecules H2O
4. 9.0x1024 molecules CO2
5. 2.1x1023 molecules CO2
VI
1. 10 mol CO2
2. 2 mol H2O
3. 2.5x10-4 mol H2O
4. 564.8 mol CO2
5. 1.2x10-4 mol CO2
VII
1. 1096.4 g
2. 558.1 L
3. 2.0x1024 molecules
4. 57 g
5. 3.9x1022 atoms
6. 3.5 L
7. 9.4x1022 molecules / 1.9x1023 atoms
VIII
1. C6H12
2. KCl
3. AlPO4
4. MgBr2
5. Na2SO4
6. CuSO4 •5H2O
IX
1. N2O4
2. C5H10
3.C2H4O2
4. C4H10O
5. C4H8O2
X
1. KMnO4
K= 24.68 %
Mn= 34.81 %
O= 40.51 %
2. HCl
H= 2.74%
Cl= 97.26%
3. Mg(NO3)2
Mg= 16.39 %
N= 18.88 %
O= 64.73 %
4. (NH4)3PO4
N= 28.21 %
H= 8.05 %
P= 20.79 %
O= 42.95 %
5. Al2(SO4)3
Al= 15.79%
S= 28.07%
O= 56.14%
6. 39.2 g O2
7. 17.49 g Fe
8. 108.87 g Ag