Roll number

PP
Name

Instructions to candidate
 Read through the entire paper before you start writing
 Fill in your name, date and role number in appropriate Column
 Answer all questions on OMR seat
 Handle each question with managing time
 Use only black or blue ballpoint pen don’t use pencil
 Choose correct answer

Each Correct answer contains +4 marks

Each Incorrect answer contains -1 marks
More than one option marked -1 marks
Question left unanswered 0 marks
Ambition Academy Question paper composed by Dr. Ashok Choudhary

Questions Paper chemistry

1. Calculate the mass in gm of 2NA molecules of CO2 –
(A) 22 gm (B) 44 gm (C) 88 gm (D) None of these
2. 18gm molecule of glucose contains
(A) 6X1022 gm glucose (B) 6X1023 gm glucose (C) 108 X 1022 gm (D) 108 X 1023gm
glucose glucose

3. How many years it would take to spend Avogadro’s number of rupees at rate of 1 million rupees in
one second –
(A) 19.098 × 1019 years (B) 19.098 years
(C) 19.098 × 109 years (D) None of these
4. Calculate number of electron in 5 mol 𝑆𝑂4−2
(A) 150 X 1023 (B) 150 X 1024 (C) 150 X 1025 (D) 150 X 1022
5. Calculate the number of Cl– and Ca+2 ions in 222 g anhydrous CaCl2.
(A) 2NA ions of Ca+2 4 N ions of Cl– (B) 2NA ions of Cl– & 4N ions of Ca+2
(C) 1NA ions of Ca+2 & 1N ions of Cl– (D) None of these.
6. In the Haber process 4 mol of ammonia is formed then quantity of nitrogen will be
(A) 16 gm (B) 32 gm (C) 64gm (D) 80gm
7. 1mole CO2 is equal to
(A) 22.4 liter at STP (B) 6.02X1023molecules (C) 44 gm of gas (D) All of these
8. Calculate number of carbon atoms in 18 gm glucose
(A) 36 X 1022 (B) 36 X 1023 (C) 18 X 1022 (D) 18 X1023
9. Calculate specific density of Na if density of sodium is 0.9 gm/cc
(A) 0.45 gm/cc (B) 0.9 gm/cc (C) 0.45 (D) 0.9
10. Number of neutrons in 1mole protium (1H1)
(A) 6.023X1023 (B) 6.023X1012 (C) 1 (D) None
11. The fraction of total volume occupied by the atom present in a simple cube is
𝜋 𝜋 𝜋 𝜋
(A) 3√2 (B) 4√2 (C) 4 (D) 6
Space for rough work…
12. Which of the following FCC structure contains cation in alternate tetrahedral voids
(A) NaCl (B) ZnS (C) Na2O (D) CaF2
13. Silicon doped with arsenic is an example of which type of semiconductor
(A) Intrinsic (B) p type (C) n type (D) p, n type
14. The closet packing sequence ABAB…represents
(A) SC (B) BCC (C) FCC (D) HCP
15. Which of the following statement is not true about NaCl structure
(A) Each unit cell contains 4 NaCl molecule
(B) CN of Cl ion is 6
(C) CN of Na ion is 4
(D) Cl ions are in FCC arrangement
16. Which of the following statement about amorphous solids is incorrect?
(A) They melt over a range of temperature
(B) They are anisotropic
(C) There is no orderly arrangement of particles
(D) They are rigid and incompressible
17. Due to Frenkel defect, density of ionic solid
(A) Decreases (B) Increases (C) Does not change (D) None
o
18. Iron crystallizes in BCC system with a lattice parameter of 2.861A . calculate the density of iron in
the BCC system (atomic weight of Fe is 56)
(A) 7.92 gm/cc (B) 8.96 gm/cc (C) 2.78 gm/cc (D) 6.72 gm/cc
19. In Stoichiometric defect, the type of compound exhibit Frenkel defect have/ has
(A) Low coordination
(B) High coordination
(C) Small difference in size of cation and anion
(D) None of these
20. On cooling oxygen freezes to dark blue crystalline solid. It is belongs to which of following type of
solid
(A) Covalent solid
(B) Ionic solid
(C) Molecular solid
(D) Metallic solid
21. Coordination number of Zn in ZnS is
(A) 4 (B) 6 (C) 2 (D) None of these
Space for rough work…
22. A substance AxBy has FCC lattice in which atoms ‘A’ occupy corners and ‘B’ atoms occupy face
centers. Identify the correct composition of substance AxBy
(A) A3B (B) AB3 (C) A4B3 (D) None of these
23. Frenkel and Schottky defect are
(A) Nucleus defect
(B) Non crystal defect
(C) Crystal defect
(D) Nuclear defect
24. The crystal system of a compound with unit cell dimensions a= 0.87, b = 0.87, c = 0.504nm and  =
= 900 and  = 1200 is..
(A) Hexagonal
(B) Cubic
(C) Rhombohedral
(D) Orthorhombic
25. If Z is number of atoms per unit cell that represent the closest packing sequence ABCABCA..the
number of tetrahedral void in the unit cell is equal to
(A) 4 (B) 6 (C) 8 (D) 12
26. Zn converts its melted state to its solid state. It has HCP structure then find out nearest neighbor of
Zn atom
(A) 4 (B) 6 (C) 8 (D) 12
+2 -
27. The Ca and F are located in CaF2 crystal respectively at face centered cubic lattice points and in..
(A) T.V (B) Half of TV (C) OV (D) Half of OV
28. Schottky defect in crystal is observed when…
(A) Equal number of cation and anion are missing from lattice
(B) Density of crystal is increased
(C) An anion leaves its normal site and occupy interstitial site
(D) Unequal number of cation and anion are missing from crystal
29. The Ca+2 and F- are located in CaF2 crystal respectively at face centered cubic lattice points and in..
(E) T.V (F) Half of TV (G) OV (H) Half of OV
30. Schottky defect in crystal is observed when…
(E) Equal number of cation and anion are missing from lattice
(F) Density of crystal is increased
(G) An anion leaves its normal site and occupy interstitial site
(H) Unequal number of cation and anion are missing from crystal
Space for rough work…
31. Sodium chloride, NaCl usually crystallizes in a face centered cubic lattice. How many ions are in
contact with any single Na+ ion
(A) 1
(B) 4
(C) 6
(D) 8
32. Percentage of free space in cubic close packed structure and in body centered packed structure
respectively
(A) 74% and 68%
(B) 30% and 48 %
(C) 26% and 32%
(D) 32% and 26%
33. Copper crystallize in FCC with a unit cell length of 361pm. What is the radius of copper atom
(A) 157pm
(B) 128pm
(C) 108pm
(D) 181pm
34. An ionic compound is expected to have tetrahedral structure if r+/r- lies in the range of
(A) 0.414 to 0.732
(B) 0.732 to 1
(C) 0.155 to 0.225
(D) 0.225 to 0.414
35. in which of the following crystal alternate tetrahedral voids are occupied
(A) NaCl
(B) ZnS
(C) Na2O
(D) CaF2
36. Density of a crystal remain unchanged as a result of
(A) Vacancy defect
(B) Interstitial defect
(C) Schottky defect
(D) Frankel defect
Space for rough work…
37. Which of the following units is useful in relating concentration of solution with its vapour pressure
(A) Mole fraction
(B) Parts per million
(C) Mass percentage
(D) Molality
38. On dissolving sugar in water at room temperature solution feels cool to touch.
Under which of the following cases dissolution of sugar will be most rapid.
(A) Sugar crystal in cold water
(B) Sugar crystals in hot water
(C) Powdered sugar in cold water
(D) Powdered sugar in hot water
39. At equilibrium rate of dissolution of a solid solute in a volatile liquid solvent is
(A) Less than rate of crystallization
(B) Greater than rate of crystallization
(C) Equal to rate of crystallization
(D) Zero
40. A beaker contains solution of substance ‘A’. Precipitation of substance ‘A’ takes place when small
amount of ‘A’ is added to solution. The solution is
(A) Saturated
(B) Unsaturated
(C) Supersaturated
(D) Concentrated
41. Colligative properties depends on
(A) The nature of solute particles dissolved in solution
(B) The number of solute particle in solution
(C) The physical properties of solute dissolved in a solution
(D) The nature of the solvent
Space for rough work…
42. Which of the following aqueous solution should have highest boiling point
(A) 0.1 NaOH
(B) 0.1 Na2SO4
(C) 0.1 NH4NO3
(D) 0.1 KNO3
43. The unit of ebulioscopic constant is
(A) K kg mol-1 or K (molality)-1
(B) Mol kg K-1 or K-1 (molality)
(C) Kg mol-1K-1 or K-1 (molality)-1
(D) K mol kg-1 or K (molality)
44. The value of Van’t Hoff constant for HCl, NaCl, and K2SO4, respectively
(A) 2, 2, and 2
(B) 2, 2 and 3
(C) 1, 1 and 2
(D) 1, 1 and 1
45. At a given temperature osmotic pressure of a concentrated solution of a substance
(A) Is higher than that at a dilute solution
(B) Is lower than that of a dilute solution
(C) As same as that of a dilute solution
(D) Cannot be compared with osmotic pressure of dilute solution
Space for rough work…
.