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Thomson was born on December 18, 1856, in Cheetham Hill, England, and went on to
attend Trinity College at Cambridge, where he would come to head the Cavendish Laboratory.
His research in cathode rays led to the discovery of the electron, and he pursued further
Sir Joseph John Thomson OM PRS[1] (18 December 1856 – 30 August 1940) was an
English physicist and Nobel Laureate in Physics, credited with the discovery and identification of
the electron, the first subatomic particle to be discovered.
In 1897, Thomson showed that cathode rays were composed of previously unknown negatively
charged particles (now called electrons), which he calculated must have bodies much smaller than
atoms and a very large charge-to-mass ratio.[2] Thomson is also credited with finding the first
evidence for isotopes of a stable (non-radioactive) element in 1913, as part of his exploration into the
composition of canal rays (positive ions). His experiments to determine the nature of positively
charged particles, with Francis William Aston, were the first use of mass spectrometry and led to the
development of the mass spectrograph.[2]
Thomson was awarded the 1906 Nobel Prize in Physics for his work on the conduction of electricity
in gases.[3]
A physicist is a scientist who specializes in the field of physics, which encompasses the interactions
of matter and energy at all length and time scales in the physical universe.[1][2] Physicists generally
are interested in the root or ultimate causes of phenomena, and usually frame their understanding in
mathematical terms. Physicists work across a wide range of research fields, spanning all length
scales: from sub-atomic and particle physics, through biological physics, to cosmological length
scales encompassing the universe as a whole. The field generally includes two types of
physicists: experimental physicists who specialize in the observation of physical phenomena and the
physical systems to rationalize, explain and predict natural phenomena.[1] Physicists can apply their
knowledge towards solving practical problems or to developing new technologies (also known
The Nobel Prize in Physics (Swedish: Nobelpriset i fysik) is a yearly award given by the Royal
Swedish Academy of Sciences for those who have made the most outstanding contributions for
mankind in the field of physics. It is one of the five Nobel Prizesestablished by the will of Alfred
Nobel in 1895 and awarded since 1901; the others being the Nobel Prize in Chemistry, Nobel Prize
in Literature, Nobel Peace Prize, and Nobel Prize in Physiology or Medicine.
The first Nobel Prize in Physics was awarded to physicist Wilhelm Röntgen in recognition of the
extraordinary services he rendered by the discovery of the remarkable rays (or X-rays). This award
is administered by the Nobel Foundation and is widely regarded as the most prestigious award that a
scientist can receive in physics. It is presented in Stockholm at an annual ceremony on 10
December, the anniversary of Nobel's death. Through 2018, a total of 209 individuals have been
awarded the prize.[2]
Physics (from Ancient Greek: φυσική (ἐπιστήμη), romanized: physikḗ (epistḗmē), lit. 'knowledge of
nature', from φύσις phýsis"nature")[1][2][3] is the natural science that studies matter,[4] its motion and
behavior through space and time, and that studies the related entities of energy and force.[5] Physics
is one of the most fundamental scientific disciplines, and its main goal is to understand how
the universe behaves.[a][6][7][8]
Physics is one of the oldest academic disciplines and, through its inclusion of astronomy,
perhaps the oldest.[9] Over much of the past two millennia, physics, chemistry, biology, and certain
branches of mathematics, were a part of natural philosophy, but during the Scientific Revolution in
the 17th century these natural sciences emerged as unique research endeavors in their own
right.[b] Physics intersects with many interdisciplinary areas of research, such
as biophysics and quantum chemistry, and the boundaries of physics are not rigidly defined. New
ideas in physics often explain the fundamental mechanisms studied by other sciences[6] and suggest
new avenues of research in academic disciplines such as mathematics and philosophy.
The electron is a subatomic particle, symbol
e−
or
β−
, whose electric charge is negative one elementary charge.[8] Electrons belong to the
first generation of the lepton particle family,[9] and are generally thought to be elementary
particles because they have no known components or substructure.[1] The electron has a mass that
is approximately 1/1836 that of the proton.[10]Quantum mechanical properties of the electron include
an intrinsic angular momentum (spin) of a half-integer value, expressed in units of the reduced
Planck constant, ħ. Being fermions, no two electrons can occupy the same quantum state, in
accordance with the Pauli exclusion principle.[9] Like all elementary particles, electrons exhibit
properties of both particles and waves: they can collide with other particles and can be diffracted like
light. The wave properties of electrons are easier to observe with experiments than those of other
particles like neutrons and protons because electrons have a lower mass and hence a longer de
Broglie wavelength for a given energy.
Electrons play an essential role in numerous physical phenomena, such
as electricity, magnetism, chemistry and thermal conductivity, and they also participate
in gravitational, electromagnetic and weak interactions.[11] Since an electron has charge, it has a
surrounding electric field, and if that electron is moving relative to an observer, said observer will
observe it to generate a magnetic field.
In the physical sciences, subatomic particles are particles much smaller than
atoms.[1] The two types of subatomic particles are: elementary particles, which
according to current theories are not made of other particles; and composite
particles.[2] Particle physics and nuclear physics study these particles and how
they interact.[3] The idea of a particle underwent serious rethinking when
experiments showed that light could behave like a stream of particles (called
photons) as well as exhibiting wave-like properties. This led to the new concept
of wave–particle duality to reflect that quantum-scale "particles" behave like
both particles and waves (they are sometimes described as wavicles to reflect
this). Another new concept, the uncertainty principle, states that some of their
properties taken together, such as their simultaneous position and momentum,
cannot be measured exactly.[4] In more recent times, wave–particle duality has
been shown to apply not only to photons but to increasingly massive particles
as well.[5]
Cathode rays (electron beam or e-beam) are streams of electrons observed in vacuum tubes. If an
evacuated glass tube is equipped with two electrodes and a voltage is applied, glass behind the
positive electrode is observed to glow, due to electrons emitted from the cathode (the electrode
connected to the negative terminal of the voltage supply). They were first observed in 1869 by
German physicist Julius Plücker and Johann Wilhelm Hittorf,[1] and were named in 1876 by Eugen
Goldstein Kathodenstrahlen, or cathode rays.[2][3] In 1897, British physicist J. J. Thomson showed that
cathode rays were composed of a previously unknown negatively charged particle, which was later
named the electron. Cathode ray tubes (CRTs) use a focused beam of electrons deflected by
electric or magnetic fields to render an image on a screen.
The mass-to-charge ratio (m/Q) is a physical quantity that is most widely used in
the electrodynamics of charged particles, e.g. in electron optics and ion optics. It appears in the
scientific fields of electron microscopy, cathode ray tubes, accelerator physics, nuclear
physics, Auger electron spectroscopy, cosmology and mass spectrometry.[1] The importance of the
mass-to-charge ratio, according to classical electrodynamics, is that two particles with the same
mass-to-charge ratio move in the same path in a vacuum , when subjected to the same electric and
magnetic fields. Its SI units are kg/C. In rare occasions the thomson has been used as its unit in the
field of mass spectrometry.
Some fields use the charge-to-mass ratio (Q/m) instead, which is the multiplicative inverse of the
mass-to-charge ratio. The 2014 CODATA recommended value for an electron is
Q
⁄m = 1.758820024(11)×1011 C/kg.[2]
Isotopes are variants of a particular chemical element which differ in neutron number, and
consequently in nucleon number. All isotopes of a given element have the same number
of protons but different numbers of neutrons in each atom.[1]
The term isotope is formed from the Greek roots isos (ἴσος "equal") and topos (τόπος "place"),
meaning "the same place"; thus, the meaning behind the name is that different isotopes of a single
element occupy the same position on the periodic table.[2] It was coined by a Scottish doctor and
writer Margaret Todd in 1913 in a suggestion to chemist Frederick Soddy.
An anode ray (also positive ray or canal ray) is a beam of positive ions that is created by certain
types of gas-discharge tubes. They were first observed in Crookes tubes during experiments by
the German scientist Eugen Goldstein, in 1886.[1] Later work on anode rays by Wilhelm Wienand J.
J. Thomson led to the development of mass spectrometry.
Mass spectrometry (MS) is an analytical technique that measures the mass-to-charge ratio of ions.
The results are typically presented as a mass spectrum, a plot of intensity as a function of the mass-
to-charge ratio. Mass spectrometry is used in many different fields and is applied to pure samples as
well as complex mixtures.
A mass spectrum is a plot of the ion signal as a function of the mass-to-charge ratio. These spectra
are used to determine the elemental or isotopic signature of a sample, the masses of particles and
of molecules, and to elucidate the chemical identity or structure of molecules and other chemical
compounds.
Francis William Aston FRS[4] (1 September 1877 – 20 November 1945) was
an English chemist and physicist who won the 1922 Nobel Prize in Chemistry
for his discovery, by means of his mass spectrograph, of isotopes, in a large
number of non-radioactive elements, and for his enunciation of the whole
number rule.[5][6] He was a fellow of the Royal Society[4] and Fellow of Trinity
College, Cambridge.[7]
The Nobel Prize in Physics (Swedish: Nobelpriset i fysik) is a yearly award given by the Royal
Swedish Academy of Sciences for those who have made the most outstanding contributions for
mankind in the field of physics. It is one of the five Nobel Prizesestablished by the will of Alfred
Nobel in 1895 and awarded since 1901; the others being the Nobel Prize in Chemistry, Nobel Prize
in Literature, Nobel Peace Prize, and Nobel Prize in Physiology or Medicine.
The first Nobel Prize in Physics was awarded to physicist Wilhelm Röntgen in recognition of the
extraordinary services he rendered by the discovery of the remarkable rays (or X-rays). This award
is administered by the Nobel Foundation and is widely regarded as the most prestigious award that a
scientist can receive in physics. It is presented in Stockholm at an annual ceremony on 10
December, the anniversary of Nobel's death. Through 2018, a total of 209 individuals have been
awarded the prize.[2]
Family[edit]
In 1890, Thomson married Rose Elisabeth Paget, one of his former students,[11] daughter of Sir
George Edward Paget, KCB, a physician and then Regius Professor of Physic at Cambridge at the
church of St. Mary the Less. They had one son, George Paget Thomson, and one daughter, Joan
Paget Thomson.
Early work[edit]
Thomson's prize-winning master's work, Treatise on the motion of vortex rings, shows his early
interest in atomic structure.[3] In it, Thomson mathematically described the motions of William
Thomson's vortex theory of atoms.[12]
Thomson published a number of papers addressing both mathematical and experimental issues of
electromagnetism. He examined the electromagnetic theory of light of James Clerk Maxwell,
introduced the concept of electromagnetic mass of a charged particle, and demonstrated that a
moving charged body would apparently increase in mass.[12]
Much of his work in mathematical modelling of chemical processes can be thought of as
early computational chemistry.[2] In further work, published in book form as Applications of dynamics
to physics and chemistry (1888), Thomson addressed the transformation of energy in mathematical
and theoretical terms, suggesting that all energy might be kinetic.[12] His next book, Notes on recent
researches in electricity and magnetism (1893), built upon Maxwell's Treatise upon electricity and
magnetism, and was sometimes referred to as "the third volume of Maxwell".[3] In it, Thomson
emphasized physical methods and experimentation and included extensive figures and diagrams of
apparatus, including a number for the passage of electricity through gases.[12] His third
book, Elements of the mathematical theory of electricity and magnetism (1895)[14] was a readable
introduction to a wide variety of subjects, and achieved considerable popularity as a textbook.[12]
A series of four lectures, given by Thomson on a visit to Princeton University in 1896, were
subsequently published as Discharge of electricity through gases (1897). Thomson also presented a
series of six lectures at Yale University in 1904.[3]
In the bottom right corner of this photographic plate are markings for the two isotopes of neon: neon-20 and
neon-22.
In 1912, as part of his exploration into the composition of the streams of positively charged particles
then known as canal rays, Thomson and his research assistant F. W. Aston channelled a stream of
neon ions through a magnetic and an electric field and measured its deflection by placing a
photographic plate in its path.[4] They observed two patches of light on the photographic plate (see
image on right), which suggested two different parabolas of deflection, and concluded that neon is
composed of atoms of two different atomic masses (neon-20 and neon-22), that is to say of
two isotopes.[20][21] This was the first evidence for isotopes of a stable element; Frederick Soddy had
previously proposed the existence of isotopes to explain the decay of certain radioactive elements.
J. J. Thomson's separation of neon isotopes by their mass was the first example of mass
spectrometry, which was subsequently improved and developed into a general method by F. W.
Aston and by A. J. Dempster.[2]
The cathode ray tube by which J. J. Thomson demonstrated that cathode rays could be deflected by a
magnetic field, and that their negative charge was not a separate phenomenon.
While supporters of the aetherial theory accepted the possibility that negatively charged particles are
produced in Crookes tubes,[citation needed] they believed that they are a mere by-product and that the
cathode rays themselves are immaterial.[citation needed]Thomson set out to investigate whether or not he
could actually separate the charge from the rays.
Thomson constructed a Crookes tube with an electrometer set to one side, out of the direct path of
the cathode rays. Thomson could trace the path of the ray by observing the phosphorescent patch it
created where it hit the surface of the tube. Thomson observed that the electrometer registered a
charge only when he deflected the cathode ray to it with a magnet. He concluded that the negative
charge and the rays were one and the same.[15]
Electrical deflection[edit]
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Thomson's illustration of the Crookes tube by which he observed the deflection of cathode rays by an electric
field (and later measured their mass-to-charge ratio). Cathode rays were emitted from the cathode C, passed
through slits A (the anode) and B (grounded), then through the electric field generated between plates D and E,
finally impacting the surface at the far end.
The cathode ray (blue line) was deflected by the electric field (yellow).
In May–June 1897, Thomson investigated whether or not the rays could be deflected by an electric
field.[4] Previous experimenters had failed to observe this, but Thomson believed their experiments
were flawed because their tubes contained too much gas.
Thomson constructed a Crookes tube with a better vacuum. At the start of the tube was the cathode
from which the rays projected. The rays were sharpened to a beam by two metal slits – the first of
these slits doubled as the anode, the second was connected to the earth. The beam then passed
between two parallel aluminium plates, which produced an electric field between them when they
were connected to a battery. The end of the tube was a large sphere where the beam would impact
on the glass, created a glowing patch. Thomson pasted a scale to the surface of this sphere to
measure the deflection of the beam. Note that any electron beam would collide with some residual
gas atoms within the Crookes tube, thereby ionizing them and producing electrons and ions in the
tube (space charge); in previous experiments this space charge electrically screened the externally
applied electric field. However, in Thomson's Crookes tube the density of residual atoms was so low
that the space charge from the electrons and ions was insufficient to electrically screen the
externally applied electric field, which permitted Thomson to successfully observe electrical
deflection.
When the upper plate was connected to the negative pole of the battery and the lower plate to the
positive pole, the glowing patch moved downwards, and when the polarity was reversed, the patch
moved upwards.
Measurement of mass-to-charge ratio[edit]
In his classic experiment, Thomson measured the mass-to-charge ratio of the cathode rays by
measuring how much they were deflected by a magnetic field and comparing this with the electric
deflection. He used the same apparatus as in his previous experiment, but placed the discharge
tube between the poles of a large electromagnet. He found that the mass-to-charge ratio was over a
thousand times lower than that of a hydrogen ion (H+), suggesting either that the particles were very
light and/or very highly charged.[17] Significantly, the rays from every cathode yielded the same mass-
to-charge ratio. This is in contrast to anode rays (now known to arise from positive ions emitted by
the anode), where the mass-to-charge ratio varies from anode-to-anode. Thomson himself remained
critical of what his work established, in his Nobel Prize acceptance speech referring to "corpuscles"
rather than "electrons".
Thomson's calculations can be summarised as follows (notice that we reproduce here Thomson's
original notations, using F instead of E for the electric field and H instead of B for the magnetic field):
The electric deflection is given by , where Θ is the angular electric deflection, F is applied
electric intensity, e is the charge of the cathode ray particles, l is the length of the electric plates, m is
the mass of the cathode ray particles and v is the velocity of the cathode ray particles. The magnetic
deflection is given by , where φ is the angular magnetic deflection and H is the applied
magnetic field intensity.
The magnetic field was varied until the magnetic and electric deflections were the same, when .
This can be simplified to give . The electric deflection was measured separately to give Θ and
H, F and l were known, so m/e could be calculated.
Conclusions[edit]
As the cathode rays carry a charge of negative electricity, are deflected by an electrostatic force as if
they were negatively electrified, and are acted on by a magnetic force in just the way in which this
force would act on a negatively electrified body moving along the path of these rays, I can see no
escape from the conclusion that they are charges of negative electricity carried by particles of
matter.
— J. J. Thomson[17]
As to the source of these particles, Thomson believed they emerged from the molecules of gas in
the vicinity of the cathode.
If, in the very intense electric field in the neighbourhood of the cathode, the molecules of the gas are
dissociated and are split up, not into the ordinary chemical atoms, but into these primordial atoms,
which we shall for brevity call corpuscles; and if these corpuscles are charged with electricity and
projected from the cathode by the electric field, they would behave exactly like the cathode rays.
— J. J. Thomson[23]
Thomson imagined the atom as being made up of these corpuscles orbiting in a sea of positive
charge; this was his plum pudding model. This model was later proved incorrect when his
student Ernest Rutherford showed that the positive charge is concentrated in the nucleus of the
atom.
Other work[edit]
In 1905, Thomson discovered the natural radioactivity of potassium.[24]
In 1906, Thomson demonstrated that hydrogen had only a single electron per atom. Previous
theories allowed various numbers of electrons.[25][26]
Plaque commemorating J. J. Thomson's discovery of the electron outside the old Cavendish Laboratory in
Cambridge
Thomson was elected a Fellow of the Royal Society (FRS)[1][27] and appointed to the Cavendish
Professorship of Experimental Physics at the Cavendish Laboratory, University of Cambridge in
1884.[2] Thomson won numerous awards and honours during his career including:
His Master's thesis, Treatise on the motion of vortex rings, described the
mathematics of William Thomson's vortex theory of atoms.
In 1887 he measured the heat generated by cathode rays and found that
they were 1000 times lighter than the hydrogen atom and that their mass
was the same as that of the atom from which they were generated.
This finding suggested that cathode rays were of the same form independent
of their origin.
He published many papers laying down the mathematical models for James
Maxwell's theories in electromagnetism.
In 1906 he demonstrated that hydrogen had only one electron per atom.
In 1918 he became Master of Trinity College and held the post until his death.