Safety Data Sheet

according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier

DELTASECT
1.2 Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses
Insecticide
1.3 Details of the supplier of the safety data sheet
Supplier (manufacturer/importer/only representative/downstream
user/distributor)
I.N.D.I.A. INDUSTRIE CHIMICHE SRL
Street : Via Sorgaglia, 25
Postal code/city : 35020 Arre
Telephone : +39 049.807.61.44
Information contact : info@indiacare.it
1.4 Emergency telephone number
+39 049.807.61.44 from 8.30 to 12.30 and from 14.00 to 17.00.

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture

Classification according to Regulation (EC) No. 1272/2008 [CLP]
Aquatic Acute 1 ; H400 - Hazardous to the aquatic environment : Category 1 ; Very toxic to aquatic life.
Aquatic Chronic 1 ; H410 - Hazardous to the aquatic environment : Category 1 ; Very toxic to aquatic life with long
lasting effects.
Eye Irrit. 2 ; H319 - Serious eye damage/eye irritation : Category 2A ; Causes serious eye irritation.
2.2 Label elements
Labelling according to Regulation (EC) No. 1272/2008 [CLP]
Hazard pictograms

Environment (GHS09) · Exclamation mark (GHS07)

Signal word
Warning
Hazard statements
H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P102 Keep out of reach of children.
P260 Do not breathe vapours/spray.
P270 Do no eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or a doctor.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P501 Dispose of contents/container in accordance with national regulations.
2.3 Other hazards
None

SECTION 3: Composition / information on ingredients

3.2 Mixtures
Hazardous ingredients
Piperonyl butoxide 94% ; REACH registration No. : 01-2119537431-46-0000 ; EC No. : 200-076-7; CAS No. : 51-03-6
Weight fraction : 6%
Classification 1272/2008 [CLP] : Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410
Tetramethrin 94% ; EC No. : 231-711-6; CAS No. : 7696-12-0
Weight fraction : 5%
Classification 1272/2008 [CLP] : Aquatic Acute 1 ; H400 Aquatic Chronic 1 ; H410
Deltamethrin 98% ; EC No. : 258-256-6; CAS No. : 52918-63-5
Weight fraction : 2%
Classification 1272/2008 [CLP] : Acute Tox. 3 ; H301 Acute Tox. 3 ; H331 Aquatic Acute 1 ; H400 Aquatic Chronic 1 ;
H410
Additional information
Full text of H- and EUH-phrases: see section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures

Following inhalation
Remove victim out of the danger area. Provide fresh air. When in doubt or if symptoms are observed, get medical
advice.
In case of skin contact
Remove contaminated, saturated clothing immediately. Rinse immediately with plenty of water and soap. In case of
skin irritation, consult a physician. If irritation persists apply an antihistaminic lotion or vitamin E.
After eye contact
Rinse immediately with plenty of water, with eyelids open. Remove contact lenses, if present, and rinse eyes with
water at least for 15 minutes. If irritation persist, seek medical attention.
After ingestion
Rinse mouth with water, without swallowing. Seek medical attention or call a Poison Center immediately . Never give
anything by mouth to an unconscious person or a person with cramps, if not authorized by a physician. Do not induce
vomiting.
4.2 Most important symptoms and effects, both acute and delayed
The product can be irritating to eyes, skin and the first respiratory tracts. Pyrethroids are not highly toxic to people but
the ingestion of large amounts of product may affect the Central Nervous System. Paraesthesia, hyper-excitability,
tremors may appear following the blockage of nervous transmission caused by pyrethroids.
4.3 Indication of any immediate medical attention and special treatment needed
Call a Poison Center. No antidotes exist for intoxication by pyrethroids. A symptomatic treatment is required.

SECTION 5: Firefighting measures

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

5.1 Extinguishing media

Suitable extinguishing media
Carbon dioxide (CO2), extinguishing powder, water haze, foam.
Unsuitable extinguishing media
Full water jet. Water is inappropriate to extinguish fire, but it is suitable to cool down the containers exposed to the
flames.
5.2 Special hazards arising from the substance or mixture
Toxic and irritant gases such as carbon oxide (CO), carbon dioxide (CO2) and nitrogen oxides may be released by
thermal combustion. Avoid breathing gases. Exposure to combustion and decomposition products may be dangerous for
health.
5.3 Advice for firefighters
Always wear full fire-protection equipment. If it is safe, remove the products from the fire area or cool down the
containers by means full water jets to prevent pressure rise inside the containers. Collect fire-extinction water, which
should not be dumped into drains. Avoid contact with product or its container without suitable protective equipment.
Special protective equipment for firefighters
Fire resistant equipment such as self-contained breathing apparatus (EN 137), fire-resistant coverall (EN 469), fire-
resistant gloves (EN 659) and firemen boots.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid contact with eyes and skin. Block the access to contaminated areas. Do not stand against the wind. Wear gloves
and safety goggles and protective mask.
For non-emergency personnel
Keep away persons not involved in the emergency operation. Contact the emergency staff on duty or the Fire
Department.
For emergency responders
Comply with the internal emergency plan. Wear suitable protection equipment (protective clothing mask, gloves,
goggles) to prevent contamination of skin, eyes and personal clothing.
6.2 Environmental precautions
Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. If the product has reached a
waterway, the sewage system or has contaminated soil or vegetation, advise local competent Authorities.
6.3 Methods and material for containment and cleaning up
For containment
Collect the spillage product with non-sparking tools into containers for recovery or disposal.
For cleaning up
The contaminated area should be immediately cleaned with water or cleaning agent. Retain contaminated washing
water and dispose it. Provide adequate ventilation.
6.4 Reference to other sections
Further information regarding individual protection and disposal is given at paragraphs 8 and 13.

SECTION 7: Handling and storage

When using do not eat, drink, smoke.

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

7.1 Precautions for safe handling

Recommended safety equipment is reported at paragraph 8. After contact with skin, wash immediateley with water and
soap.
7.2 Conditions for safe storage, including any incompatibilities
Requirements for storage rooms and vessels
Keep in a cool, well-ventilated place. Keep away from heat, sun-light and humidity.
Hints on joint storage
Keep away from
Keep away from food, drinks and animal feeding stuff.
Further information on storage conditions
Keep container tightly closed and in a well-ventilated place. Keep locked up and out of reach of children. Keep/Store
only in original container.
7.3 Specific end use(s)
Recommendation
The product user is responsible for any damage resulting from improper use.

SECTION 8: Exposure controls/personal protection

8.1 Control parameters

None
8.2 Exposure controls
Appropriate engineering controls
If local exhaust ventilation is not possible or not sufficient, the entire working area must be ventilated by technical
means.
Personal protection equipment

Eye/face protection
Suitable eye protection
Wear safety goggles.
Skin protection
Hand protection
Wear suitable protective gloves (DIN EN 374). Replace in case of internal contamination, break or if external
contamination cannot be removed. Wash hands before eating, drinking or smoking.
Body protection
Wear suitable protective clothing.
Respiratory protection
Recommendation Filtering Half-face mask (DIN EN 149)

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance : liquid
Colour : light yellow

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

Odour : characteristic
Safety relevant basis data
Melting point/melting range : ( 1013 hPa ) No data available
Freezing point : ( 1013 hPa ) No data available
Initial boiling point and boiling
( 1013 hPa ) > 150 °C
range :
Decomposition temperature : ( 1013 hPa ) No data available
Flash point : > 55 °C
Ignition temperature : No data available
Lower explosion limit : No data available
Upper explosion limit : No data available
Vapour pressure : ( 50 °C ) No data available
Density : ( 20 °C ) 0,92 g/cm3
Relative density : ( 20 °C ) No data available
pH : No data available
log P O/W : No data available
Viscosity : ( 20 °C ) No data available
Odour threshold : No data available
Relative vapour density : ( 20 °C ) No data available
Evaporation rate : No data available
9.2 Other information
None

SECTION 10: Stability and reactivity

10.1 Reactivity
Stable under recommended storage and handling conditions(See section 7).
10.2 Chemical stability
The product is stable if stored under normal ambient temperature and pressure conditions.
10.3 Possibility of hazardous reactions
No information available.
10.4 Conditions to avoid
To prevent degradation, do not expose to high temperatures or frost.
10.5 Incompatible materials
Oxidising agent.
10.6 Hazardous decomposition products
The burning of the product may release toxic gasses dangerous for the human health.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Acute effects
Acute oral toxicity
Parameter : LD50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Exposure route : Oral
Species : Rat
Effective dose : 7500 mg/kg
Parameter : LD50 ( Tetramethrin ; CAS No. : 7696-12-0 )
Exposure route : Oral

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

Species : Rat
Effective dose : > 5000 mg/kg
Parameter : LD50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Exposure route : Oral
Species : Rat
Effective dose : 135 mg/kg
Acute dermal toxicity
Parameter : LD50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Exposure route : Dermal
Species : Rat
Effective dose : > 7950 mg/kg
Parameter : LD50 ( Tetramethrin ; CAS No. : 7696-12-0 )
Exposure route : Dermal
Species : Rabbit
Effective dose : > 2000 mg/kg
Parameter : LD50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Exposure route : Dermal
Species : Rabbit
Effective dose : > 2000 mg/kg
Acute inhalation toxicity
Parameter : LC50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Exposure route : Inhalation
Species : Rat
Effective dose : > 5,9 mg/l
Exposure time : 4h
Parameter : LC50 ( Tetramethrin ; CAS No. : 7696-12-0 )
Exposure route : Inhalation
Species : Rat
Effective dose : > 2,73 mg/l
Parameter : LC50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Exposure route : Inhalation
Species : Rat
Effective dose : 2,2 mg/l
Exposure time : 4h
Irritant and corrosive effects
Primary irritation to the skin
Available data show no specific hazards.
Irritation to eyes
Causes serious eye irritation.
Irritation to respiratory tract
Available data show no specific hazards.
Sensitisation
In case of skin contact
Available data show no specific hazards.
In case of inhalation
Available data show no specific hazards.
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
The ingredients in this mixture do not meet the criteria for classification as CMR category 1A or 1B according to CLP.

SECTION 12: Ecological information

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

Do not allow uncontrolled discharge of product into the environment.

12.1 Toxicity
Aquatic toxicity
Acute (short-term) fish toxicity
Parameter : LC50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Species : Cyprinus carpio (Common Carp)
Effective dose : 5,3 mg/l
Exposure time : 24 h
Parameter : LC50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Species : Daphnia magna (Big water flea)
Effective dose : 2,95 mg/l
Exposure time : 24 h
Parameter : Acute (short-term) fish toxicity ( Tetramethrin ; CAS No. : 7696-12-0 )
Species : Lepomis macrochirus (Bluegill)
Evaluation parameter : Acute (short-term) fish toxicity
Effective dose : 16 µg/l
Parameter : LC50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Species : Oncorhynchus mykiss (Rainbow trout)
Effective dose : 0,91 µg/l
Exposure time : 96 h
Acute (short-term) daphnia toxicity
Parameter : Acute (short-term) daphnia toxicity ( Tetramethrin ; CAS No. : 7696-12-0 )
Species : Daphnia pulex (water flea)
Evaluation parameter : Acute (short-term) daphnia toxicity
Effective dose : 0,11 mg/l
Parameter : EC50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Species : Daphnia magna (Big water flea)
Effective dose : 3,5 µg/l
Exposure time : 48 h
Acute (short-term) algae toxicity
Parameter : EC50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Species : Chlorella fusca
Effective dose : 44 µmol/L
Parameter : EC50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Species : Selenastrum capricornutum
Effective dose : > 9,1 mg/l
Exposure time : 96 h
Terrestrial toxicity
Toxicity to terrestrial arthropods
Useful insect toxicity
Parameter : LD50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Species : Apis mellifera (bee)
Effective dose : > 25 µg/bee
Parameter : LD50 ( Deltamethrin ; CAS No. : 52918-63-5 )
Species : Apis mellifera (bee)
Effective dose : 79 ng/bee
Toxicity to birds
Acute and subchronic bird toxicity
Parameter : LD50 ( Piperonyl butoxide ; CAS No. : 51-03-6 )
Species : Colinus virginianus (bobwhite quail)

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

Effective dose : > 2250 mg/kg

Parameter : Acute and subchronic bird toxicity ( Tetramethrin ; CAS No. : 7696-12-0 )
Species : Colinus virginianus (bobwhite quail)
Evaluation parameter : Acute and subchronic bird toxicity
Effective dose : > 2250 mg/kg
12.2 Persistence and degradability
No information available.
12.3 Bioaccumulative potential
Parameter : Bioconcentration factor (BCF) ( Deltamethrin ; CAS No. : 52918-63-5 )
Bioconcentration factor (BCF)
Concentration : 1400
Parameter : Partition coefficient n-octanol /water (log P O/W) ( Piperonyl butoxide ; CAS No. : 51-03-6
)
Partition coefficient n-octanol /water (log P O/W)
Concentration : 4,75 logPow
Parameter : Partition coefficient n-octanol /water (log P O/W) ( Tetramethrin ; CAS No. : 7696-12-0 )
Partition coefficient n-octanol /water (log P O/W)
Concentration : 4,6 logPow
12.4 Mobility in soil
No information available.
12.5 Results of PBT and vPvB assessment
This substance does not meet the PBT/vPvB criteria of REACH, annex XIII.
12.6 Other adverse effects
No information available.
12.7 Additional ecotoxicological information
None.

SECTION 13: Disposal considerations

13.1 Waste treatment methods

Product/Packaging disposal
Dispose of waste according to applicable legislation. Do not allow to enter into surface water or drains.
Waste treatment options
Appropriate disposal / Product
Dispose according to legislation.

SECTION 14: Transport information

14.1 UN number
UN 3082
14.2 UN proper shipping name
Land transport (ADR/RID)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Tetramethrin · Deltamethrin )
Sea transport (IMDG)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Tetramethrin · Deltamethrin )
Air transport (ICAO-TI / IATA-DGR)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. ( Tetramethrin · Deltamethrin )
14.3 Transport hazard class(es)

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

Land transport (ADR/RID)

Class(es) : 9
Classification code : M6
Hazard identification number (Kemler
No.) : 90
Tunnel restriction code : E
Special provisions : LQ 7 · E 1
Hazard label(s) : 9/N
Sea transport (IMDG)
Class(es) : 9
EmS-No. : F-A / S-F
Special provisions : LQ 5 l · E 1
Hazard label(s) : 9/N
Air transport (ICAO-TI / IATA-DGR)
Class(es) : 9
Special provisions : E1
Hazard label(s) : 9/N
14.4 Packing group
III
14.5 Environmental hazards
Land transport (ADR/RID) : Yes
Sea transport (IMDG) : Yes (P)
Air transport (ICAO-TI / IATA-DGR) : Yes
14.6 Special precautions for user
None.

SECTION 15: Regulatory information

Safety, health and environmental regulations/legislation specific for the substance or

15.1
mixture
EU legislation
The classification was elaborated according to the calculation method of the Regulation (EC) No. 1272/2008 [CLP].
Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH) and amendments: Regulation (CE) No.
453/2010 and regulation (CE) No. 830/2015. Labelling according to Regulation (EC) No. 1272/2008 [CLP].
15.2 Chemical Safety Assessment
No information available.

SECTION 16: Other information

16.1 Indication of changes

None.
16.2 Abbreviations and acronyms

LEGENDA:
ADR: Accord européen relative au transport international des marchandises dangereuses par route
ASTM: ASTM International, originariamente nota come American Society for Testing and Materials (ASTM)
EINECS: European Inventory of Existing Commercial Chemical Substances
EC50: Effective Concentration 50
LC50: Lethal Concentration 50

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Safety Data Sheet
according to Regulation (EC) No. 1907/2006 (REACH)

Trade name : DELTASECT

Revision date : 09/02/2015 Version : 1.0.0
Print date : 05/05/2016

IC50: Inhibitor Concentration 50

NOEL: No Observed Effect Level
DNEL: Derived No Effect Level
DMEL: Derived Minimum Effect Level
CLP: Classification, Labelling and Packaging
CSR: Chemical Safety Report
LD50: Lethal Dose 50
IATA: International Air Transport Association
ICAO: International Civil Aviation Organization
Codice IMDG: International Maritime Dangerous Goods code
PBT: Persistent, bioaccumulative and toxic
RID: Règlement concernent le transport International ferroviaire des marchandises Dangereuses
STEL: Short term exposure limit
TLV: Threshold limit value
TWA: Time Weighted Average
UE: European Union
vPvB: Very persistent very bioaccumulative
N.D.: No data available.
N.A.: Not applicable
VwVwS.: Text of Administrative Regulation on the Classification of Substances hazardous to waters into Water
Hazard Classes (Verwaltungsvorschrift wassergefährdende Stoffe – VwVwS)
16.3 Key literature references and sources for data
Data taken from the Safety Data Sheets of Suppliers.
Classification for mixtures and used evaluation method according to regulation
16.4
(EC) 1272/2008 [CLP]
The classification was elaborated according to the calculation method of the Regulation (EC) No. 1272/2008
[CLP].
16.5 Relevant H- and EUH-phrases (Number and full text)
H301+H331 Toxic if swallowed or if inhaled.
H319 Causes serious eye irritation.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
16.6 Training advice
None.
16.7 Additional information
None.

The above information describes exclusively the safety requirements of the product and is based on our present-day
knowledge. The information is intended to give you advice about the safe handling of the product named in this safety
data sheet, for storage, processing, transport and disposal. The information cannot be transferred to other products. In
the case of mixing the product with other products or in the case of processing, the information on this safety data
sheet is not necessarily valid for the new made-up material.

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